CN106187599A - Trace element capsule fertilizer and preparation method thereof in one - Google Patents

Trace element capsule fertilizer and preparation method thereof in one Download PDF

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Publication number
CN106187599A
CN106187599A CN201610549173.8A CN201610549173A CN106187599A CN 106187599 A CN106187599 A CN 106187599A CN 201610549173 A CN201610549173 A CN 201610549173A CN 106187599 A CN106187599 A CN 106187599A
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CN
China
Prior art keywords
parts
fertilizer
trace element
agricultural
fructus
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CN201610549173.8A
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Chinese (zh)
Inventor
李振轩
肖晓樊
石艳萍
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HENAN JINDIBAO ECOLOGICAL FERTILIZER INDUSTRY Co Ltd
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HENAN JINDIBAO ECOLOGICAL FERTILIZER INDUSTRY Co Ltd
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Priority to CN201610549173.8A priority Critical patent/CN106187599A/en
Publication of CN106187599A publication Critical patent/CN106187599A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05BPHOSPHATIC FERTILISERS
    • C05B1/00Superphosphates, i.e. fertilisers produced by reacting rock or bone phosphates with sulfuric or phosphoric acid in such amounts and concentrations as to yield solid products directly
    • C05B1/02Superphosphates
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/60Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/80Soil conditioners
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G5/00Fertilisers characterised by their form
    • C05G5/30Layered or coated, e.g. dust-preventing coatings

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  • Life Sciences & Earth Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Soil Sciences (AREA)
  • Plant Pathology (AREA)
  • Fertilizers (AREA)

Abstract

The invention belongs to Crop fertilizer field, be the middle trace element capsule fertilizer and preparation method thereof of a kind of applicable modern agriculture.Trace element capsule fertilizer in one, including: calcium superphosphate, medical stone powder, ammonium sulfate, agricultural zinc sulfate, agricultural ferrous sulfate, agricultural Borax, soluble starch, trace element, hydrophilic high molecular material, citric acid powder, aminoacid, surfactant, Cortex Meliae, Fructus Quisqualis, Galla Chinensis, Radix Ilicis Pubescentis, Fructus Sapindi Mukouossi episperm, Fructus Gleditsia, Radix Isatidis, Rhizoma Atractylodis, cellulase.Can effectively solve pest and disease damage, bad underproduction problem, the utilization rate improving fertilizer and the regulation to salt-affected soil caused of absorption of nutrient ingredients.

Description

Trace element capsule fertilizer and preparation method thereof in one
Technical field
The invention belongs to Crop fertilizer field, the middle trace element capsule of a kind of applicable modern agriculture Fertilizer and preparation method thereof.
Background technology
Existing complex fertilizer product formula is unreasonable, solely pursues high nitrogen or Gao Jia class compound fertilizer, and blindness is big, utilizes Rate is low, and have even causes quality of agricultural product low, endangers consumer health;Physical behavior is bad, and dust is many, not resistance to compression, knot Block, is not easy to store, transport and apply fertilizer.In the most conventional compound fertilizer, phosphorus potassium is easily by gold such as the calcium in waste water, magnesium, ferrum, aluminum Belonging to ion to fix, reduce the utilization rate of fertilizer, excess is added and is not only increased reagent cost but also phosphorus content in water outlet is easy Exceed standard.From the point of view of crops, its growth supplementing necessary not only for various elements, in addition it is also necessary to a suitable soil environment. And middle trace element capsule fertilizer is exactly a kind of compound fertilizer rich in multielement, demand of plant growth, each unit can be met Element is through miniaturization surface coating modification, it is to avoid deliquescence, caking, the generation of metathesis reaction after compounding, is effectively prevented water Molten fertilizer be dissolved in water after nutrient Ion leakage cause fertilizer efficiency loss.Its aminoacid can reduce the pH value in salt-soda soil again can be for soil Supplement a large amount of organic;Soluble starch, citric acid are not only the cross-linking agent forming cellulose gel, are also equipped with salt-affected soil Middle harmful ion possesses absorption, exchange and buffer capacity, it is achieved that the nutrient slow release in soil, is on the one hand greatly improved Utilization rate of fertilizer, reduces the fertilising secondary salt damage to soil.The Chinese medicine ingredients added in the present invention is combined with other compositions, is increasing On the premise of adding the soil organism, reduce the probability of plant infection pest and disease damage.
Summary of the invention
The present invention is directed to the deficiencies in the prior art, it is provided that the production technology of a kind of middle trace element capsule fertilizer.The present invention is practical Property strong, can effectively solve pest and disease damage, absorption of nutrient ingredients bad cause the underproduction, the utilization rate improving fertilizer, to salt-affected soil Regulation.
First technical problem to be solved by this invention there is provided a kind of secondary and micro-element fertilizers.
According to parts by weight, a kind of secondary and micro-element fertilizers, includes that following components forms: calcium superphosphate 40~60 parts, wheat meal Stone powder 6~12 parts, ammonium sulfate 16~25 parts, agricultural zinc sulfate 5~12 parts, agricultural ferrous sulfate 5~12 parts, agricultural Borax 5~ 12 parts, soluble starch 3~10 parts, trace element 4~7 parts, hydrophilic high molecular material 15~25 parts, citric acid powder 1~5 Part, aminoacid 20~30 parts, surfactant 5~10 parts, Cortex Meliae 40~45 parts, Fructus Quisqualis 10~12 parts, Galla Chinensis 5~8 Part, Radix Ilicis Pubescentis 10~15 parts, Fructus Sapindi Mukouossi episperm 5~15 parts, Fructus Gleditsia 15~20 parts, Radix Isatidis 5~12 parts, Rhizoma Atractylodis 10~15 Part, cellulase 1~2 parts.
Concrete, described surfactant is in sucrose ester, sorbitan ester, alkylsulfonate, amino acid salts Plant or any several combination.
Concrete, described hydrophilic high molecular material is the one in cellulose derivative, chitosan, sodium alginate or appoints Anticipate several combination.
Concrete, described trace element is the combination of Cu, Fe, Mn, B, Mo, Ni, Mg element.
Second technical problem to be solved by this invention there is provided the preparation method of above-mentioned fertilizer.
Technical scheme: in order to solve above-mentioned technical problem, it is provided that the preparation method of a kind of middle trace element capsule fertilizer, Comprise the following steps:
A, by calcium superphosphate 40~60 parts, medical stone powder 6~12 parts and ammonium sulfate 16~25 parts of mix homogeneously, be allowed to reaction certain Time;
B, in the product of step A add agricultural zinc sulfate 5~12 parts, agricultural ferrous sulfate 5~12 parts, agricultural Borax 5~12 Part, continue reaction after mix homogeneously;
C, take outside Cortex Meliae 40~45 parts, Fructus Quisqualis 10~12 parts, Galla Chinensis 5~8 parts, Radix Ilicis Pubescentis 10~15 parts, Fructus Sapindi Mukouossi plant Skin 5~15 parts, Fructus Gleditsia 15~20 parts, Radix Isatidis 5~12 parts, Rhizoma Atractylodis 10~15 parts soak in water after pulverizing and add surface activity Agent surfactant 5~10 parts, cellulase 1~2 parts carry out enzymolysis, control temperature, be filtrated to get herb liquid be dried to powder with In step B, product uniformly mixes;
D, citric acid powder 1~5 parts being added water is configured to the aqueous citric acid solution that mass concentration is 15~20wt%;
E, trace element 4~7 parts are uniformly mixed with product in step C, be placed in sugar coating machine and be heated to 60~85 DEG C, at fertilizer Particle surface sprays atomized water by particle surface moistening, add successively aminoacid 20~30 parts, hydrophilic high molecular material 15~ 25 parts, in sugar coating machine, make aminoacid be coated on the surface of granulated fertilizer, and hydrophilic high molecular material is wrapped in granulated fertilizer Outer layer;
After F, chemical fertilizer nutrient raw material carry out miniaturization cladding process respectively, spray into aqueous citric acid solution, be finally sprinkled into solubility and form sediment Powder 3~10 parts, hydrophilic high molecular material after crosslinking and soluble starch are as the slow release layer of fertilizer;
G, i.e. obtain trace element capsule fertilizer in one after drying.
The invention provides trace element capsule fertilizer in one, product with organic waste, Cortex Meliae, Fructus Quisqualis, five Gall nut, Radix Ilicis Pubescentis, Fructus Sapindi Mukouossi episperm, Fructus Gleditsia, Radix Isatidis, Rhizoma Atractylodis are raw material, are aided with surfactant, trace element, hydrophilic Property macromolecular material etc., prepared by coating technology.
For middle trace element capsule fertilizer, the effective ingredient in its Chinese medicine can effectively bacteria growing inhibiting and pest and disease damage Generation;The recycling of organic waste;To increasing the soil organism, improve soil physico-chemical property and will get positive effect; Achieve the nutrient slow release in soil, be on the one hand greatly improved utilization rate of fertilizer, reduce the fertilising secondary salt to soil Evil, on the other hand, can significantly improve soil fertility, free salinity superfluous in absorption salt-soda soil, improve the sustainable life of soil Production capacity power;Hydrophilic high molecular material used by the present invention and soluble starch, nonhazardous and environmentally degradable, be manured into soil a large amount of Stable hydrogel can be formed after water suction, there is preferable water holding capacity, the evaporation of soil moisture can be slowed down, slowly discharge institute The moisture of storage so that it is fully absorbed by crops, promotes crop growth, is effectively improved the utilization rate of water resource;Hydrophilic Macromolecular material and aminoacid have the improved effect of highly significant to salinized soil, and aminoacid can not only supplement in salt-affected soil and lack Organic matter, moreover it is possible to reduce salt-affected soil pH value, moreover it is possible to stimulate crop root growth, the lapping as fertilizer can make fertilizer Material slowly discharges in soil.This product has preferable biocompatibility, biodegradability, belongs to environmentally friendly fertilizer Material, the beneficially sustainable development of resource.
Detailed description of the invention
The preparation method of a kind of middle trace element capsule fertilizer, comprises the following steps:
A, by calcium superphosphate 50 parts, medical stone powder 10 parts and 20 parts of mix homogeneously of ammonium sulfate, be allowed to react certain time;
B, in the product of step A add agricultural 10 parts of zinc sulfate, agricultural 10 parts of ferrous sulfate, agricultural Borax 5 parts, mix homogeneously Rear continuation reacts;
C, take Cortex Meliae 40 parts, Fructus Quisqualis 10 parts, Galla Chinensis 5 parts, Radix Ilicis Pubescentis 10 parts, Fructus Sapindi Mukouossi episperm 5 parts, Fructus Gleditsia 15 parts, Radix Isatidis 5 parts, Rhizoma Atractylodis 10 parts soak and add 8 parts of surfactant after pulverizing in water, and cellulase 2 parts carries out enzymolysis, control Temperature, is filtrated to get herb liquid and is dried to powder and uniformly mixes with product in step B;
D, being added water by 4 parts of citric acid powder is configured to the aqueous citric acid solution that mass concentration is 15~20wt%;
E, trace element 5 parts is uniformly mixed with product in step C, be placed in sugar coating machine and be heated to 60~85 DEG C, at fertilizer Atomized water is sprayed by particle surface moistening in grain surface, adds 25 parts of aminoacid, hydrophilic high molecular material 25 parts successively to sugar-coat In machine, making aminoacid be coated on the surface of granulated fertilizer, hydrophilic high molecular material is wrapped in granulated fertilizer outermost layer;
After F, chemical fertilizer nutrient raw material carry out miniaturization cladding process respectively, spray into aqueous citric acid solution, be finally sprinkled into solubility and form sediment 10 parts of powder, hydrophilic high molecular material after crosslinking and soluble starch are as the slow release layer of fertilizer;
G, i.e. obtain trace element capsule fertilizer in one after drying.
Surfactant is a kind of or the most several in sucrose ester, sorbitan ester, alkylsulfonate, amino acid salts Combination.
Described hydrophilic high molecular material is a kind of or the most several in cellulose derivative, chitosan, sodium alginate Combination.
Described trace element is the combination of Cu, Fe, Mn, B, Mo, Ni, Mg element.
The middle trace element capsule fertilizer that the present invention prepares understands after testing: application of the farming of the fertilizer of the present invention Thing upgrading effect of increasing production is the most obvious.The clad of this product can be degraded, and does not results in soil pollution, and be manured into soil a large amount of suction Can form stable hydrogel after water, have preferable water holding capacity, can slow down the evaporation of soil moisture, slowly release is deposited The moisture of storage so that it is fully absorbed by crops, promotes crop growth, is effectively improved the utilization rate of water resource;Hydrophilic is high Molecular material and aminoacid have the improved effect of highly significant to salinized soil, and aminoacid can not only supplement shortage in salt-affected soil Organic, moreover it is possible to reduce the pH value of salt-affected soil, moreover it is possible to stimulating crop root growth, the lapping as fertilizer can make fertilizer Soil slowly discharges.This product has preferable biocompatibility, biodegradability, belongs to environmental friendly fertilizer, It is beneficial to the sustainable development of resource;It is simultaneously achieved the nutrient slow release in soil, is on the one hand greatly improved fertilizer utilization Rate, reduces the fertilising secondary salt damage to soil, on the other hand, can significantly improve soil fertility, trip superfluous in absorption salt-soda soil From salinity, improve the sustainable production capacity of soil;Each element is through miniaturization surface coating modification, it is to avoid tide after compounding Solution, caking, the generation of metathesis reaction, be effectively prevented the fertilizer efficiency loss that after Water soluble fertilizer is dissolved in water, nutrient Ion leakage causes.

Claims (5)

1. trace element capsule fertilizer in a kind, it is characterised in that include that following components forms according to parts by weight: calcium superphosphate 40~60 parts, medical stone powder 6~12 parts, ammonium sulfate 16~25 parts, agricultural zinc sulfate 5~12 parts, agricultural ferrous sulfate 5~12 Part, agricultural Borax 5~12 parts, soluble starch 3~10 parts, trace element 4~7 parts, hydrophilic high molecular material 15~25 parts, Citric acid powder 1~5 parts, aminoacid 20~30 parts, surfactant 5~10 parts, Cortex Meliae 40~45 parts, Fructus Quisqualis 10~12 Part, Galla Chinensis 5~8 parts, Radix Ilicis Pubescentis 10~15 parts, Fructus Sapindi Mukouossi episperm 5~15 parts, Fructus Gleditsia 15~20 parts, Radix Isatidis 5~12 Part, Rhizoma Atractylodis 10~15 parts, cellulase 1~2 parts.
Trace element capsule fertilizer in one the most according to claim 1, it is characterised in that described surfactant is sugarcane A kind of or any several combination in sugar ester, sorbitan ester, alkylsulfonate, amino acid salts.
Trace element capsule fertilizer in one the most according to claim 1, it is characterised in that described hydrophilicity macromolecule material Material is a kind of or any several combination in dimension element derivant, chitosan, sodium alginate.
Trace element capsule fertilizer in one the most according to claim 1, it is characterised in that described trace element be Cu, The combination of Fe, Mn, B, Mo, Ni, Mg element.
The preparation method of a kind of middle trace element capsule fertilizer the most according to claim 1, it is characterised in that include following Step:
A, by calcium superphosphate 40~60 parts, medical stone powder 6~12 parts and ammonium sulfate 16~25 parts of mix homogeneously, be allowed to reaction certain Time;
B, in the product of step A add agricultural zinc sulfate 5~12 parts, agricultural ferrous sulfate 5~12 parts, agricultural Borax 5~12 Part, continue reaction after mix homogeneously;
C, take outside Cortex Meliae 40~45 parts, Fructus Quisqualis 10~12 parts, Galla Chinensis 5~8 parts, Radix Ilicis Pubescentis 10~15 parts, Fructus Sapindi Mukouossi plant Skin 5~15 parts, Fructus Gleditsia 15~20 parts, Radix Isatidis 5~12 parts, Rhizoma Atractylodis 10~15 parts soak in water after pulverizing and add surface activity Agent surfactant 5~10 parts, cellulase 1~2 parts carry out enzymolysis, control temperature, be filtrated to get herb liquid be dried to powder with In step B, product uniformly mixes;
D, citric acid powder 1~5 parts being added water is configured to the aqueous citric acid solution that mass concentration is 15~20wt%;
E, trace element 4~7 parts are uniformly mixed with product in step C, be placed in sugar coating machine and be heated to 60~85 DEG C, at fertilizer Particle surface sprays atomized water by particle surface moistening, add successively aminoacid 20~30 parts, hydrophilic high molecular material 15~ 25 parts, in sugar coating machine, make aminoacid be coated on the surface of granulated fertilizer, and hydrophilic high molecular material is wrapped in granulated fertilizer Outer layer;
After F, chemical fertilizer nutrient raw material carry out miniaturization cladding process respectively, spray into aqueous citric acid solution, be finally sprinkled into solubility and form sediment Powder 3~10 parts, hydrophilic high molecular material after crosslinking and soluble starch are as the slow release layer of fertilizer;
G, i.e. obtain trace element capsule fertilizer in one after drying.
CN201610549173.8A 2016-07-13 2016-07-13 Trace element capsule fertilizer and preparation method thereof in one Pending CN106187599A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108658660A (en) * 2018-05-25 2018-10-16 陕西科技大学 A kind of preparation process of the water polo of degradable polymer shell package
CN109369261A (en) * 2018-11-17 2019-02-22 长沙小如信息科技有限公司 A kind of active improved soil fertilizer and preparation method thereof
CN110734336A (en) * 2019-11-28 2020-01-31 哈尔滨坤丰生物工程有限公司 microelement empty capsule used by plants and application method thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103396213A (en) * 2013-07-23 2013-11-20 苏州仁成生物科技有限公司 Potassium-rich microcapsule fertilizer and preparation method thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103396213A (en) * 2013-07-23 2013-11-20 苏州仁成生物科技有限公司 Potassium-rich microcapsule fertilizer and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
刘程等: "《表面活性剂性质理论与应用》", 30 June 2003, 北京工业大学出版社 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108658660A (en) * 2018-05-25 2018-10-16 陕西科技大学 A kind of preparation process of the water polo of degradable polymer shell package
CN109369261A (en) * 2018-11-17 2019-02-22 长沙小如信息科技有限公司 A kind of active improved soil fertilizer and preparation method thereof
CN110734336A (en) * 2019-11-28 2020-01-31 哈尔滨坤丰生物工程有限公司 microelement empty capsule used by plants and application method thereof

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Application publication date: 20161207