CN106179918A - Graphene strengthens energy-conservation composite membrane and preparation method thereof - Google Patents

Graphene strengthens energy-conservation composite membrane and preparation method thereof Download PDF

Info

Publication number
CN106179918A
CN106179918A CN201610568809.3A CN201610568809A CN106179918A CN 106179918 A CN106179918 A CN 106179918A CN 201610568809 A CN201610568809 A CN 201610568809A CN 106179918 A CN106179918 A CN 106179918A
Authority
CN
China
Prior art keywords
parts
graphene
composite membrane
energy
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201610568809.3A
Other languages
Chinese (zh)
Other versions
CN106179918B (en
Inventor
秦波
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangzhou Boxin Environmental Technology Co Ltd
Original Assignee
Guangzhou Boxin Environmental Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangzhou Boxin Environmental Technology Co Ltd filed Critical Guangzhou Boxin Environmental Technology Co Ltd
Priority to CN201610568809.3A priority Critical patent/CN106179918B/en
Publication of CN106179918A publication Critical patent/CN106179918A/en
Application granted granted Critical
Publication of CN106179918B publication Critical patent/CN106179918B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/02—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to macromolecular substances, e.g. rubber
    • B05D7/04—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to macromolecular substances, e.g. rubber to surfaces of films or sheets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/14—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/24—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials for applying particular liquids or other fluent materials
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0011—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using non-woven fabrics
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/042—Acrylic polymers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/18—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials
    • D06N3/186—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials one of the layers is on one surface of the fibrous web and the other layer is on the other surface of the fibrous web
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2201/00—Polymeric substrate or laminate
    • B05D2201/02—Polymeric substrate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2202/00—Metallic substrate
    • B05D2202/20—Metallic substrate based on light metals
    • B05D2202/25—Metallic substrate based on light metals based on Al
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2202/00—Metallic substrate
    • B05D2202/40—Metallic substrate based on other transition elements
    • B05D2202/45—Metallic substrate based on other transition elements based on Cu
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2502/00—Acrylic polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2503/00—Polyurethanes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2504/00—Epoxy polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2601/00—Inorganic fillers
    • B05D2601/20—Inorganic fillers used for non-pigmentation effect
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/06—Properties of the materials having thermal properties

Abstract

The invention discloses a kind of Graphene and strengthen energy-conservation composite membrane and preparation method thereof, described composite membrane includes tack coat, basal layer and active layer the most successively；Graphene strengthens the preparation method of energy-conservation composite membrane and includes: tack coat coats, prepares active powder mixture, prepares active substance epoxy resin coating and active layer coating and solidification；By adding up-to-date grapheme material, utilize the high specific surface area of Graphene and unique electronic structure, it is obviously enhanced the Chemical Physics performance improving nanoparticle, the original performance of nanoparticle is multiplied, it might even be possible to the special nature that before realizing, homogenous material cannot realize.Can significantly completely cut off External Heat Flux, strengthen internal thermal convection current heat exchange efficiency, and then reach to increase COP value, it is achieved reduce energy consumption, the target of protection environment.

Description

Graphene strengthens energy-conservation composite membrane and preparation method thereof
Technical field
The present invention relates to central air-conditioning or handpiece Water Chilling Units refrigeration technology field, be specifically related to a kind of for regulating and controlling central air-conditioning Or the graphene composite film of the internal thermal convection current heat exchange efficiency of handpiece Water Chilling Units heat exchanger and preparation method thereof.
Background technology
Graphene is the two dimensional crystal of a kind of monoatomic layer thickness, carbon hexatomic ring the most infinitely repeat and obtain, be Newcomer in nano-carbon material family, the electric property of its excellence, thermal property, mechanical performance, chemical stability etc. are many Performance so that Graphene has huge potential using value at numerous areas such as electronics, energy storage, machinery enhancings.Make graphite Alkene, once appearance, has just attracted the sight of whole world research worker.
Nano material, due to reasons such as dimensional effect, electron tunneling effect, skin effects, often shows and bulk material Different performances, has important effect in numerous areas.
Along with consumers in general are more and more higher to the requirement of indoor environment comfort level, central air-conditioning or handpiece Water Chilling Units are in hotel Among the building such as hotel, office space, residential building, application is more and more extensive.Such as, industry market scale in 2010 reaches 450 Hundred million yuan, within 2011, expanding further, only market scale in the first half of the year just reaches 30,000,000,000 yuan, increases by a year-on-year basis and reach more than 40%.But, central authorities Air-conditioning or handpiece Water Chilling Units bring to consumer comfortable while, meanwhile, also consume substantial amounts of electric energy.With thermal power generation it is being Main China, consumes substantial amounts of electric energy, and often meaning consumes substantial amounts of coal, brings more haze.At present, China face Facing serious energy challenge and environment challenge, energy-conserving and environment-protective become the theme of China's Development Mode Change, are also " 13 " Important goal to be realized.
Therefore, improved the heat exchange efficiency of central air-conditioning or handpiece Water Chilling Units by all approach, i.e. realizing identical refrigeration effect Under conditions of Guo, consume less energy, become one of problem of urgently capturing in central air-conditioning or handpiece Water Chilling Units technology.
Summary of the invention
It is an object of the invention to prepare a kind of Graphene and strengthen energy-conservation composite membrane and preparation method thereof, this composite membrane is comprehensive Utilize the nano material of multiple difference in functionality, energy heat convection efficiency within Effective Regulation heat exchanger.
The technical solution adopted for the present invention to solve the technical problems is: a kind of Graphene strengthens energy-conservation composite membrane, and it is special Levy and be: described composite membrane includes tack coat, basal layer and active layer the most successively；Described tack coat is by poly-third Olefin(e) acid class or polyurethanes binding agent composition, for being attached to heat exchanger surface by composite membrane；Described basal layer is Copper Foil, aluminum The one of paper tinsel, plastic sheeting or non-woven fabrics, for supported active layer material；Described active layer includes the thing of following weight portion Matter: 40～80 parts of aerosil powder, 40～80 parts of Pulvis Talci, 5～10 parts of Graphenes, 1～20 part of aluminium oxide, 1～20 Part zinc oxide, 1～20 part of bismuth oxychloride, 10～20 parts of ferroso-ferric oxide and 1～5 part of chromium oxide.
Graphene of the present invention strengthens the preparation method of energy-conservation composite membrane, comprises the following steps:
The first step, tack coat coats: by polyacrylic or polyurethanes adhesive coated bottom basal layer；
Second step, prepares active powder mixture: by 40～80 parts of aerosil powder, 40～80 parts of Pulvis Talci, 5～10 Part Graphene, 1～20 part of aluminium oxide, 1～20 part of zinc oxide, 1～20 part of bismuth oxychloride, 10～20 parts of ferroso-ferric oxide and 1～5 Part chromium oxide is uniformly mixed by blending apparatus；
3rd step, prepares active substance epoxy resin coating: 100 parts of virgin resin are heated to 50～80 DEG C, reduces the viscous of virgin resin Degree, under being stirred vigorously, adds TritonX 5～10 parts, adds active powder mixture prepared by 80 parts of second steps, and 50～ 100 parts of firming agent, stir 30～60min, until mix homogeneously, then eliminate the foam of generation in vacuum drying oven；
4th step, active layer coating and solidification: the 3rd step gained composite paint is coated on the base layer, solidifies.
As preferably, the Graphene in described second step is chemical conversion Graphene, the number of plies below 10 layers, specific surface Amass at 600m2/ more than g.
Preferably, the blending apparatus in described second step is ball milling or V-Mixer.
Preferably, the alr mode in described 3rd step is mechanical agitation, and rotating speed is 100～2000 rpm.
Use the present invention can obtain following technique effect:
Improve internal microenvironment, it is to avoid the local concentration of ion is too high.This product adds nano magnetic particle, at heat exchanger It is internally formed a kind of faint magnetic field.Due to ion all with electric charge, in motor process, can produce with magnetic field and interact, Cause magnetic field can affect the warm-up movement of ion so that it is more uniform that foreign ion is distributed in water, particularly avoids and is changing The situation that localized ion concentration that heat pipe wall causes due to the effect of metal Yu water is excessive.
By adding different infrared reflective materials, it is achieved the common wave band during central air-conditioning or handpiece Water Chilling Units are used Infra-red radiation realizes iris action.And nano material has high specific surface area, have more reflection than block materials Plane, it is possible to achieve the infrared barrier of higher efficiency.
The electronics performance of Graphene uniqueness makes it can produce synergism from different nano materials, greatly improves and receives Rice material properties.Additionally, the specific surface area of its superelevation makes to have only to add minimal amount of Graphene, it is possible to realize multiple The overall improvement of condensation material.
Detailed description of the invention
In order to make technical problem solved by the invention, technical scheme and beneficial effect clearer, below in conjunction with Embodiment, the present invention is further illustrated.Should be appreciated that embodiment described herein is used only for explaining the present invention, It is not intended to limit the present invention.
Embodiment 1
The first step, tack coat coats: by polyacrylic adhesive coated bottom Copper Foil.
Second step, prepares active powder mixture: by 45 parts of aerosil powder, 75 parts of Pulvis Talci, 9 parts of graphite Alkene, 16 parts of aluminium oxidies, 7 parts of zinc oxide, 4 parts of bismuth oxychloride, 11 parts of ferroso-ferric oxide and 1 part of chromium oxide are uniformly mixed by ball milling Closing, Graphene is chemical conversion Graphene, and the number of plies is below 10 layers, and specific surface area is at 600m2/ more than g.
3rd step, prepares active substance epoxy resin coating: 100 parts of virgin resin are heated to 55 DEG C, reduces the viscous of virgin resin Degree, under being stirred vigorously, adds TritonX 6 parts, adds active powder mixture prepared by 80 parts of second steps, and 55 parts of solidifications Agent, stirs 35min, until mix homogeneously, then eliminates the foam of generation in vacuum drying oven；Alr mode is mechanical agitation, Rotating speed is 300rpm.
4th step, active layer coating is with solidification: the 3rd step gained composite paint is coated on Copper Foil, solidifies.
Directly this product is pasted on central air-conditioning or handpiece Water Chilling Units condenser surface, by test central air-conditioning or cold water Unit COP value detection energy-saving effect.
Embodiment 2
The first step, tack coat coats: by polyacrylic adhesive coated bottom aluminium foil.
Second step, prepares active powder mixture: by 50 parts of aerosil powder, 70 parts of Pulvis Talci, 8 parts of graphite Alkene, 10 parts of aluminium oxidies, 4 parts of zinc oxide, 13 parts of bismuth oxychloride, 13 parts of ferroso-ferric oxide and 2 parts of chromium oxides are uniformly mixed by ball milling Closing, Graphene is chemical conversion Graphene, and the number of plies is below 10 layers, and specific surface area is at 600m2/ more than g.
3rd step, prepares active substance epoxy resin coating: 100 parts of virgin resin are heated to 60 DEG C, reduces the viscous of virgin resin Degree, under being stirred vigorously, adds TritonX 7 parts, adds active powder mixture prepared by 80 parts of second steps, and 65 parts of solidifications Agent, stirs 40min, until mix homogeneously, then eliminates the foam of generation in vacuum drying oven；Alr mode is mechanical agitation, Rotating speed is 700rpm.
4th step, active layer coating is with solidification: the 3rd step gained composite paint is coated on aluminium foil, solidifies.
Directly this product is pasted on central air-conditioning or handpiece Water Chilling Units condenser surface, by test central air-conditioning or cold water Unit COP value detection energy-saving effect.
Embodiment 3
The first step, tack coat coats: by polyurethanes adhesive coated bottom plastic sheeting.
Second step, prepares active powder mixture: by 65 parts of aerosil powder, 60 parts of Pulvis Talci, 7 parts of graphite Alkene, 4 parts of aluminium oxidies, 10 parts of zinc oxide, 16 parts of bismuth oxychloride, 15 parts of ferroso-ferric oxide and 3 parts of chromium oxides are equal by V-Mixer Even mixing, Graphene is chemical conversion Graphene, and the number of plies is below 10 layers, and specific surface area is at 600m2/ more than g.
3rd step, prepares active substance epoxy resin coating: 100 parts of virgin resin are heated to 65 DEG C, reduces the viscous of virgin resin Degree, under being stirred vigorously, adds TritonX 8 parts, adds active powder mixture prepared by 80 parts of second steps, and 75 parts of solidifications Agent, stirs 45 min, until mix homogeneously, then eliminates the foam of generation in vacuum drying oven；Alr mode is mechanical agitation, Rotating speed is 1100rpm.
4th step, active layer coating and solidification: the 3rd step gained composite paint is coated on a plastic film, solidifies.
Directly this product is pasted on central air-conditioning or handpiece Water Chilling Units condenser surface, by test central air-conditioning or cold water Unit COP value detection energy-saving effect.
Embodiment 4
The first step, tack coat coats: by polyurethanes adhesive coated bottom non-woven fabrics.
Second step, prepares active powder mixture: by 70 parts of aerosil powder, 55 parts of Pulvis Talci, 6 parts of graphite Alkene, 7 parts of aluminium oxidies, 13 parts of zinc oxide, 10 parts of bismuth oxychloride, 17 parts of ferroso-ferric oxide and 4 parts of chromium oxides are equal by V-Mixer Even mixing, Graphene is chemical conversion Graphene, and the number of plies is below 10 layers, and specific surface area is at 600m2/ more than g.
3rd step, prepares active substance epoxy resin coating: 100 parts of virgin resin are heated to 70 DEG C, reduces the viscous of virgin resin Degree, under being stirred vigorously, adds TritonX 9 parts, adds active powder mixture prepared by 80 parts of second steps, and 85 parts of solidifications Agent, stirs 50 min, until mix homogeneously, then eliminates the foam of generation in vacuum drying oven；Alr mode is mechanical agitation, Rotating speed is 1500rpm.
4th step, active layer coating is with solidification: the 3rd step gained composite paint is coated on non-woven fabrics, solidifies.
Directly this product is pasted on central air-conditioning or handpiece Water Chilling Units condenser surface, by test central air-conditioning or cold water Unit COP value detection energy-saving effect.
Embodiment 5
The first step, tack coat coats: by polyurethanes adhesive coated bottom non-woven fabrics.
Second step, prepares active powder mixture: by 75 parts of aerosil powder, 45 parts of Pulvis Talci, 5 parts of graphite Alkene, 13 parts of aluminium oxidies, 16 parts of zinc oxide, 7 parts of bismuth oxychloride, 19 parts of ferroso-ferric oxide and 5 parts of chromium oxides are equal by V-Mixer Even mixing, Graphene is chemical conversion Graphene, and the number of plies is below 10 layers, and specific surface area is at 600m2/ more than g.
3rd step, prepares active substance epoxy resin coating: 100 parts of virgin resin are heated to 75 DEG C, reduces the viscous of virgin resin Degree, under being stirred vigorously, adds TritonX 10 parts, adds active powder mixture prepared by 80 parts of second steps, and 95 parts are consolidated Agent, stirs 55min, until mix homogeneously, then eliminates the foam of generation in vacuum drying oven；Alr mode is that machinery stirs Mixing, rotating speed is 1800rpm.
4th step, active layer coating is with solidification: the 3rd step gained composite paint is coated on non-woven fabrics, solidifies.
Directly this product is pasted on central air-conditioning or handpiece Water Chilling Units condenser surface, by test central air-conditioning or cold water Unit COP value detection energy-saving effect.
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all spirit in the present invention and Any amendment made within principle, equal replacement and improvement etc., all should fall within the scope and spirit of the invention.

Claims (5)

1. a Graphene strengthens energy-conservation composite membrane, it is characterised in that: described composite membrane include the most successively tack coat, Basal layer and active layer；
Described tack coat is made up of polyacrylic or polyurethanes binding agent, for composite membrane is attached to heat exchanger table Face；
Described basal layer is the one of Copper Foil, aluminium foil, plastic sheeting or non-woven fabrics, for supported active layer material；
Described active layer includes the material of following weight portion: 40～80 parts of aerosil powder, 40～80 parts of Pulvis Talci, 5～10 parts of Graphenes, 1～20 part of aluminium oxide, 1～20 part of zinc oxide, 1～20 part of bismuth oxychloride, 10～20 parts of ferroso-ferric oxide With 1～5 part of chromium oxide.
2. the preparation method of the Graphene energy-conservation composite membrane of enhancing, it is characterised in that comprise the following steps:
The first step, tack coat coats: by polyacrylic or polyurethanes adhesive coated bottom basal layer；
Second step, prepares active powder mixture: by 40～80 parts of aerosil powder, 40～80 parts of Pulvis Talci, 5～10 Part Graphene, 1～20 part of aluminium oxide, 1～20 part of zinc oxide, 1～20 part of bismuth oxychloride, 10～20 parts of ferroso-ferric oxide and 1～5 Part chromium oxide is uniformly mixed by blending apparatus；
3rd step, prepares active substance epoxy resin coating: 100 parts of virgin resin are heated to 50～80 DEG C, reduces the viscous of virgin resin Degree, under being stirred vigorously, adds TritonX 5～10 parts, adds active powder mixture prepared by 80 parts of second steps, and 50～ 100 parts of firming agent, stir 30～60min, until mix homogeneously, then eliminate the foam of generation in vacuum drying oven；
4th step, active layer coating and solidification: the 3rd step gained composite paint is coated on the base layer, solidifies.
Graphene the most according to claim 2 strengthens the preparation method of energy-conservation composite membrane, it is characterised in that: described second step In Graphene be chemical conversion Graphene, the number of plies is below 10 layers, and specific surface area is at 600m2/ more than g.
Graphene the most according to claim 2 strengthens the preparation method of energy-conservation composite membrane, it is characterised in that: described second step In blending apparatus be ball milling or V-Mixer.
Graphene the most according to claim 2 strengthens the preparation method of energy-conservation composite membrane, it is characterised in that: described 3rd step In alr mode be mechanical agitation, rotating speed is 100～2000rpm.
CN201610568809.3A 2016-07-19 2016-07-19 Graphene reinforced energy-saving composite membrane and preparation method thereof Active CN106179918B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610568809.3A CN106179918B (en) 2016-07-19 2016-07-19 Graphene reinforced energy-saving composite membrane and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610568809.3A CN106179918B (en) 2016-07-19 2016-07-19 Graphene reinforced energy-saving composite membrane and preparation method thereof

Publications (2)

Publication Number Publication Date
CN106179918A true CN106179918A (en) 2016-12-07
CN106179918B CN106179918B (en) 2021-04-09

Family

ID=57494591

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610568809.3A Active CN106179918B (en) 2016-07-19 2016-07-19 Graphene reinforced energy-saving composite membrane and preparation method thereof

Country Status (1)

Country Link
CN (1) CN106179918B (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101474899A (en) * 2009-01-16 2009-07-08 南开大学 Grapheme-organic material layered assembling film and preparation method thereof
US20110143045A1 (en) * 2009-12-15 2011-06-16 Veerasamy Vijayen S Large area deposition of graphene on substrates, and products including the same
CN104310381A (en) * 2014-09-28 2015-01-28 北京理工大学 Method for on-scale continuous production of three-dimensional graphene membrane and application
CN105514066A (en) * 2016-01-19 2016-04-20 合肥微晶材料科技有限公司 Composite graphene infrared radiation and heat conduction film and manufacturing method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101474899A (en) * 2009-01-16 2009-07-08 南开大学 Grapheme-organic material layered assembling film and preparation method thereof
US20110143045A1 (en) * 2009-12-15 2011-06-16 Veerasamy Vijayen S Large area deposition of graphene on substrates, and products including the same
CN104310381A (en) * 2014-09-28 2015-01-28 北京理工大学 Method for on-scale continuous production of three-dimensional graphene membrane and application
CN105514066A (en) * 2016-01-19 2016-04-20 合肥微晶材料科技有限公司 Composite graphene infrared radiation and heat conduction film and manufacturing method thereof

Also Published As

Publication number Publication date
CN106179918B (en) 2021-04-09

Similar Documents

Publication Publication Date Title
Zhang et al. Segregated double network enabled effective electromagnetic shielding composites with extraordinary electrical insulation and thermal conductivity
CN107359051B (en) A kind of high-energy density sandwich structure flexible composite and preparation method thereof
CN107342392A (en) The method for preparing battery electrode
CN106299208A (en) A kind of preparation method of high temperature resistant low-resistivity lithium ion battery separator
KR20070097100A (en) Composition for heat-storage object formation, heat-storage object, and process for producing heat-storage object
CN105898906A (en) Method for preparing electrothermal film by graphene aqueous slurry
CN104774573B (en) A kind of high-performance conductive silver paste of containing graphene and preparation method thereof
CN106384807B (en) A kind of based lithium-ion battery positive plate and preparation method thereof
CN107739581A (en) High thermal conductivity wave absorbing patch
Li et al. Synergy improvement of dielectric properties and thermal conductivity in PVDF composites with core‐shell structured Ni@ SiO 2
CN103722832A (en) Insulating polymer based electromagnetic shielding material and preparation method thereof
CN115449121B (en) Polypyrrole coated polyimide hybrid aerogel/phase change material composite film with infrared/electromagnetic double stealth function and preparation method thereof
Chen et al. Study on microwave absorption properties of metal-containing foam glass
CN108624153A (en) A kind of coatings and preparation method thereof for electrical equipment
WO2022166345A1 (en) Large-scale preparation method for three-dimensional porous nano composite cooling thin film
Peng et al. Novel ZnFe2O4@ MnO2@ MXene composites with ultrathin thickness and excellent electromagnetic absorption performance
CN106179918A (en) Graphene strengthens energy-conservation composite membrane and preparation method thereof
Wang et al. Hydrothermal synthesis and microwave absorption properties of Fe 3 O 4@ SnO 2 core–shell structured microspheres
Gao et al. Using “intercalation bridging” to effectively improve the electrothermal properties of sheet graphite/ultrafine carbon powder conductive paste for screen printing
He et al. Preparation of FeSiAl–Fe3O4 reinforced graphene/polylactic acid composites and their microwave absorption properties
CN109244321A (en) A kind of lithium battery diaphragm hot water resistance coating and preparation method thereof, application
Liao et al. Synthesis and characterization of BiFeO 3/RGO composites for promising microwave absorption materials
CN110183945A (en) Low temperature impact heat insulating coat and preparation method thereof
CN102924920A (en) Amorphous calcium-copper-titanium-oxygen ceramic/polyimide composite film and preparation method thereof
Zhang et al. Preparation and dielectric properties of (Ba0. 5Sr0. 4Ca0. 1) TiO3/polystyrene composites

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant