CN106172412A - A kind of miticide composition - Google Patents
A kind of miticide composition Download PDFInfo
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- CN106172412A CN106172412A CN201610506353.8A CN201610506353A CN106172412A CN 106172412 A CN106172412 A CN 106172412A CN 201610506353 A CN201610506353 A CN 201610506353A CN 106172412 A CN106172412 A CN 106172412A
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- parts
- envidor
- agent
- miticide composition
- pyrazoles indanyl
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
- A01N43/12—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings condensed with a carbocyclic ring
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a kind of miticide composition, its effective ingredient is Envidor and pyrazoles indanyl Methanamide, and the weight ratio of effective ingredient Envidor and pyrazoles indanyl Methanamide is 1:8～8:1, and preferred proportion of composing is 1:4～4:1.The miticide composition of the present invention can be used for preventing and treating Semen Tritici aestivi white lead or bacterial wilt of ginger or watermelon blight or citrus red mite, has an efficient prevention effect, and two kinds of effective ingredient mixed after greatly improve the synergistic effect of mixture；This acaricide composition has delayed the resistance rise phenomenon that single medicament causes, significant to disease disease comprehensive control.
Description
Technical field
The invention belongs to technical field of pesticide, relate to a kind of miticide composition, especially a kind of containing spirodiclofen and pyrazoles indenes
The miticide composition of full base Methanamide.
Background technology
Envidor (gliotoxin), has the brand-new mechanism of action, has action of contace poison, does not has interior absorption, mainly suppress demodicid mite
Lipogenesis, block demodicid mite energy metabolism, if to evil demodicid mite ovum, children demodicid mite demodicid mite there is good fragmentation effect, to become demodicid mite without
Effect, but there is the effect suppressing female demodicid mite spawning and hatching rate, no interactions resistance between it and existing acaricide, it is adaptable to it is used for preventing and treating
Existing acaricide produces the pest mite class of resistance, and ovicidal effect is the most excellent, if children demodicid mite is also had good work of tagging simultaneously
With.Its chemical name: 3-(2,4-Dichlorobenzene base)-2-oxo-1-oxaspiro [4,5]-decyl-3-alkene 4-base-2,
2-dimethyl butyrate acid esters, its molecular structural formula
As follows:
Pyrazoles indanyl Carbox amide as a kind of novel active composition, can kill efficiently plant fungal,
Bacterial disease, and can be mixed with most insecticide, acaricide, antiviral, herbicide and plant nutrient product etc.,
Improve the effect that single dose is used.Its chemical name: 3-difluoromethyl-N-(7-fluoro-1,1,3-trimethyl-4-indanyl)-1-first
Base-4-pyrazolecarboxamide, its molecular structural formula is following, and (Me represents methyl-CH3):
At present, Envidor is less as acaricide application in crop protection, pyrazoles indanyl formamides compounds
The application patent of thing, document are the most few, and therefore the present inventor is on the basis of exploring two kinds of compound using values, by spiral shell
Demodicid mite ester and the combination of pyrazoles indanyl Methanamide mixture carry out explorative research, and this novel miticide composition and application are the most still
It was not disclosed.
Summary of the invention
Based on case above, it is an object of the invention to provide a kind of containing spirodiclofen and the mite killing of pyrazoles indanyl Methanamide
Compositions, can be used for preventing and treating Semen Tritici aestivi white lead or bacterial wilt of ginger or watermelon blight or citrus red mite.After two kinds of effective ingredient are mixed
Greatly improve the synergistic effect of mixture；This acaricide composition has delayed the resistance rise phenomenon that single medicament causes, right
Disease disease comprehensive control is significant.
Envidor has the brand-new mechanism of action, has action of contace poison, does not has interior absorption, the main lipogenesis suppressing demodicid mite,
Blocking the energy metabolism of demodicid mite, if ovum, the children demodicid mite demodicid mite of evil demodicid mite is had good fragmentation effect, to becoming, demodicid mite is invalid, but has suppression
The effect of female demodicid mite spawning and hatching rate；Pyrazoles indanyl benzamide compound has stomach toxicity and action of contace poison to demodicid mite class and insecticide, no
Energy ovicidal, mechanism of action is that interference nervous physiology is movable, stimulates release γ-aminobutyric acid, and γ-aminobutyric acid is to arthropod
Nerve conduction have inhibitory action.Both with the use of can mite killing, ovum, children demodicid mite, again can to become demodicid mite play killing action, play
Potentiation complementary action, plays good miticidal effect.
To achieve these goals, the technical solution used in the present invention is as follows:
A kind of miticide composition, said composition includes active component and auxiliary agent；Described active component is Envidor and pyrrole
The weight ratio of azoles indanyl Methanamide and Envidor and pyrazoles indanyl Methanamide is: 1:8～8:1.
The weight ratio of described Envidor and pyrazoles indanyl Methanamide is 1:4～4:1.
Described active component accounts for the 8%～60% of miticide composition gross weight.
In described compositions auxiliary agent be dispersant or wetting agent or emulsifying agent or antifreezing agent or defoamer or thickening agent or
One or more in disintegrating agent or stabilizer or filler or solvent.
Its dosage form of described compositions is wettable powder or suspending agent or aqueous emulsion or water dispersible granules or cream.
Technical scheme of the present invention is realized by measure in detail below:
Described miticide composition is cream preparation, and the mass fraction of component is: Envidor 1～60 parts；Pyrazoles indanyl
Methanamide 1～60 parts；Emulsifying agent 12～25 parts；Synergist 1～10 parts；Solvent make-up is to 100 parts.
Described miticide composition is suspending agent, and the mass fraction of component is: Envidor 1～60 parts；Pyrazoles indanyl first
Amide 1～60 parts；Emulsifying agent 0.5-2.5 part；Dispersant 1-2.2 part；Thickening agent 0.15～0.4 part；Defoamer 0.01～0.04
Part；Antifreezing agent 1-5 part；Stabilizer 0.1～0.5 part；Surplus is supplemented to 100 parts with water.
Described miticide composition is wettable powder, and the mass fraction of component is: Envidor 1～60 parts；Pyrazoles indane
Base Methanamide 1～60 parts；Dispersant 4～10 parts；Wetting agent 1～8 parts；Surplus solid carrier polishing.
Described miticide composition is water dispersible granules, and the mass fraction of component is: Envidor 1～60 parts；Pyrazoles indane
Base Methanamide 1～60 parts；Dispersant 2～12 parts；Wetting agent 1～8 parts；Disintegrating agent 1.5～4.5 parts；Surplus solid carrier is mended
Neat to 100 parts.
Described miticide composition is aqueous emulsion, and the mass fraction of component is: Envidor 1～60 parts；Pyrazoles indanyl first
Amide 1～60 parts；Emulsifying agent 2.5～34 parts；Solvent 4～16 parts；Antifreezing agent 0.5～5 parts；Defoamer 0.1～8 parts；Thickening agent
0.3～1.8 part；Surplus complements to 100 parts with water.
Auxiliary agent in compositions of the present invention is the usual auxiliaries of this area.
Composition pesticide dosage form wettable powder of the present invention, suspending agent, aqueous emulsion, water dispersible granules and the processing work of cream
Skill is prior art, and technical staff can be varied from according to different situations.
Compositions of the present invention can be used for preventing and treating wheat powdery mildew, bacterial wilt of ginger and watermelon blight, and achieves
Well prevention effect.
Compared with prior art, having the beneficial effect that the present invention produces expands Envidor and pyrazoles indanyl Methanamide
The range of single dose, can prevent and treat pathogenic fungi, antibacterial and demodicid mite evil simultaneously, reach once to spray medicine and can prevent and treat multiple disease after compounding
The purpose of evil.The medicament of two kinds of different mechanisms of action carries out binary built, can have complementary advantages, and effectively delays single medicament to use and draws
The resistance problems risen, extends the service life of medicament, and the integrated control to agricultural Common Diseases is significant.
Detailed description of the invention
Embodiment 1
A kind of containing spirodiclofen and the miticide composition suspending agent of pyrazoles indanyl Methanamide, by the component group of following weight portion
Become, active component 18 parts, alkylphenol polyoxyethylene 1 part, pull open 1 part of powder, xanthan gum 0.3 part, SAG6220.02 part, glycerol
2 parts, sodium benzoate 0.1 part, remainder deionized water supplies 100 parts；Active component is Envidor and pyrazoles indanyl Methanamide
Mixture, and both weight ratios are: 1:8.
Embodiment 2
A kind of containing spirodiclofen and the miticide composition suspending agent of pyrazoles indanyl Methanamide, by the component group of following weight portion
Become, active component 30 parts, alkylphenol polyoxyethylene 2 parts, pull open 2.2 parts of powder, xanthan gum 0.4 part, SAG6220.04 part, the third three
Alcohol 1 part, sodium benzoate 0.2 part, remainder deionized water supplies 100 parts；Active component is Envidor and pyrazoles indanyl formyl
The mixture of amine, and both weight ratios are: 1:4.
Embodiment 3
A kind of containing spirodiclofen and the miticide composition suspending agent of pyrazoles indanyl Methanamide, by the component group of following weight portion
Become, active component 50 parts, alkylphenol polyoxyethylene 0.5 part, pull open 2 parts of powder, xanthan gum 0.2 part, SAG6220.01 part, the third three
Alcohol 1.5 parts, sodium benzoate 0.1 part, remainder deionized water supplies 100 parts；Active component is Envidor and pyrazoles indanyl first
The mixture of amide, and both weight ratios are: 8:1.
Embodiment 4
A kind of containing spirodiclofen and the miticide composition water dispersible granules of pyrazoles indanyl Methanamide, by the group of following weight portion
Being grouped into active component 40 parts, dispersant 10 parts, wetting agent 7 parts, disintegrating agent 3 parts, solid carrier complements to 100 parts.Activity group
It is divided into Envidor and the mixture of pyrazoles indanyl Methanamide, and both weight ratios are: 8:1.
Embodiment 5
A kind of containing spirodiclofen and the miticide composition wettable powder of pyrazoles indanyl Methanamide, by the group of following weight portion
Being grouped into, active component 45 parts, dispersant 8 parts, wetting agent 3 parts, solid carrier complements to 100 parts.Active component is Envidor
With the mixture of pyrazoles indanyl Methanamide, and both weight ratios are: 1:8.
Embodiment 6
A kind of containing spirodiclofen and the miticide composition aqueous emulsion of pyrazoles indanyl Methanamide, by the component group of following weight portion
Become, active component 55 parts, emulsifying agent 20 parts, solvent 13 parts, antifreezing agent 2 parts, defoamer 0.2 part, thickening agent 1.6 parts, deionization
Water complements to 100 parts.Active component is Envidor and the mixture of pyrazoles indanyl Methanamide, and both weight ratios are: 8:
1。
Embodiment 7
A kind of containing spirodiclofen and the miticide composition cream preparation of pyrazoles indanyl Methanamide, by the component of following weight portion
Composition, active component 32 parts, emulsifying agent 12 parts, synergist 8 parts, solvent supplies 100 parts.Active component is Envidor and pyrazoles indenes
The completely mixture of base Methanamide, and both weight ratios is: 1:8.
Experimental example
First pass through Toxicity Determination, be tentatively combined the screening of composition formula, on this basis, filter out potentiation effect
After fruit preferably composite formula, carry out the checking of different dosage form compositions corresponding field control effectiveness test.
Semen Tritici aestivi white lead, bacterial wilt of ginger, watermelon blight field efficacy are verified as follows by the present composition:
Envidor: the preparation of pyrazoles indanyl Methanamide (1:3) suspending agent
Raw material consists of: the former medicine of Envidor 2 parts, the former medicine of pyrazoles indanyl Methanamide 6 parts, alkylphenol polyoxyethylene 2.5
Part, pull open 1.2 parts of powder, xanthan gum 0.15 part, SAG622 organosilicon 0.02 part, glycerol 5 parts, sodium benzoate 0.5 part, remaining is used
Deionized water is supplied, and the suspending agent mode of production is prepared and is 8% Envidor routinely: the suspending agent of pyrazoles indanyl Methanamide.
Envidor: the preparation of pyrazoles indanyl Methanamide (1:4) suspending agent
Raw material consists of: the former medicine of Envidor 12 parts, the former medicine of pyrazoles indanyl Methanamide 48 parts, alkylphenol polyoxyethylene
2.5 parts, pull open 1.2 parts of powder, xanthan gum 0.15 part, SAG622 organosilicon 0.02 part, glycerol 5 parts, sodium benzoate 0.5 part, its
Remaining deionized water is supplied, and the suspending agent mode of production is prepared and is 60% Envidor routinely: hanging of pyrazoles indanyl Methanamide
Floating agent.
Envidor: the preparation of pyrazoles indanyl Methanamide (1:1) suspending agent
Raw material consists of: the former medicine of Envidor 5 parts, the former medicine of pyrazoles indanyl Methanamide 5 parts, alkylphenol polyoxyethylene 2.5
Part, pull open 1.2 parts of powder, xanthan gum 0.15 part, SAG622 organosilicon 0.02 part, glycerol 5 parts, sodium benzoate 0.5 part, remaining is used
Deionized water is supplied, and the suspending agent mode of production is prepared and is 10% Envidor routinely: the suspending agent of pyrazoles indanyl Methanamide.
Envidor: the preparation of pyrazoles indanyl Methanamide (2:1) water dispersible granules
Raw material consists of: Envidor 8 parts, pyrazoles indanyl Methanamide 4 parts, sodium lauryl sulphate 5 parts, to methoxyl group fat
Fat amide groups benzenesulfonic acid 8 parts, 2 parts of ammonium sulfate, Kaolin supplies 100 parts.By above-mentioned effective ingredient, dispersant, wetting agent, disintegrate
Agent and solid carrier mix homogeneously, pulverize with micro jet, through mediating, is subsequently adding in fluidized-bed granulation dryer
Row pelletize, be dried, screening, can be prepared by 12% Envidor: pyrazoles indanyl Methanamide water dispersible granules.
Envidor: the preparation of pyrazoles indanyl Methanamide (4:1) wettable powder
Raw material consists of: Envidor 16 parts, pyrazoles indanyl Methanamide 4 parts, sodium butylnaphthalenesulfonate 6 parts, fatty acid ester sulfur
Hydrochlorate 8 parts, kieselguhr supplies 100 parts.By above-mentioned, effective ingredient, dispersant, wetting agent and solid carrier are mixed, mechanical activation comminution
After again through comminution by gas stream, mix homogeneously, can be prepared by 20% Envidor: pyrazoles indanyl Methanamide wettable powder.
Envidor: the preparation of pyrazoles indanyl Methanamide (1:4) aqueous emulsion
Raw material consists of: Envidor 3 parts, pyrazoles indanyl Methanamide 12 parts, castor oil polyoxyethylene ether 20 parts, Ketohexamethylene
10 parts, propylene glycol 2 parts, silicone oil 0.5 part, xanthan gum 0.2 part, deionized water complements to 100 parts.The producer of aqueous emulsion routinely
Formula prepares 15% Envidor: pyrazoles indanyl Methanamide aqueous emulsion.
Envidor: the preparation of pyrazoles indanyl Methanamide (8:1) cream
Raw material consists of: Envidor 8 parts, pyrazoles indanyl Methanamide 1 part, N-Methyl pyrrolidone 10 parts, agriculture breast 500 breast
Agent 9 parts, Nonyl pheno 10 ether TX-10 emulsifying agent 9 parts, methyl oleate is supplemented to 100 parts.Active component is Envidor
With the mixture of pyrazoles indanyl Methanamide, and both weight ratios are: 8:1.The mode of production of cream prepares 9% breast routinely
Oil product.
Envidor: the preparation of pyrazoles indanyl Methanamide (1:8) cream
Raw material consists of: Envidor 1 part, pyrazoles indanyl Methanamide 8 parts, N-Methyl pyrrolidone 10 parts, agriculture breast 500 breast
Agent 9 parts, Nonyl pheno 10 ether TX-10 emulsifying agent 9 parts, methyl oleate is supplemented to 100 parts.Active component is Envidor
With the mixture of pyrazoles indanyl Methanamide, and both weight ratios are: 1:8.The mode of production of cream prepares 9% breast routinely
Oil product.
Field test embodiment one: Envidor and the pyrazoles indanyl Methanamide compositions field efficacy to wheat powdery mildew
Test determination
After Envidor and pyrazoles indanyl Methanamide are re-dubbed 5 kinds of different dosage forms under different proportion, at wheat powdery mildew
Their early stage is sprayed, and every mu is watered 15L, and two kinds of total effective ingredient of medicament are 1.5g, and comparison medicament is 30% kresoxim-methyl
Wettable powder.Result shows: Envidor and each mixture of pyrazoles indanyl Methanamide process preventive effect and be above compareing medicament, after medicine
The preventive effect of 14d is up to 79.66%～90.15%.
Table 1 Envidor and pyrazoles indanyl Methanamide compositions are to wheat powdery mildew test of pesticide effectiveness result
Field test embodiment two: Envidor and the pyrazoles indanyl Methanamide compositions field control effectiveness test to bacterial wilt of ginger
Measure
After Envidor and pyrazoles indanyl Methanamide are re-dubbed 5 kinds of different dosage forms under different proportion, fall ill at bacterial wilt of ginger
Initial stage carries out root irrigation, every strain pouring root 200mL, and comparison medicament is 70% mould spirit soluble powder.Result shows: Envidor
Being above compareing medicament to the preventive effect of bacterial wilt of ginger with pyrazoles indanyl Methanamide each mixture root irrigation, after medicine, the preventive effect of 14d is high
Reach 69.70%～88.69%.
Table 2 Envidor and pyrazoles indanyl Methanamide compositions are to bacterial wilt of ginger test of pesticide effectiveness result
Field test embodiment three: Envidor and the pyrazoles indanyl Methanamide compositions field efficacy to watermelon blight
Test determination
After Envidor and pyrazoles indanyl Methanamide are re-dubbed 5 kinds of different dosage forms under different proportion, at watermelon blight
Their early stage carries out root irrigation, every strain pouring root 200mL, and comparison medicament is 70% mould spirit soluble powder.Result shows: spiral shell
Watermelon blight preventive effect is above compareing medicament, 14d after medicine by demodicid mite ester and pyrazoles indanyl Methanamide each mixture root irrigation
Preventive effect is up to 77.56%～92.69%.
Table 3 Envidor and pyrazoles indanyl Methanamide compositions are to watermelon blight test of pesticide effectiveness result
Field test embodiment four: Envidor and pyrazoles indanyl Methanamide compositions are to citrus red mite killing effect
After Envidor and pyrazoles indanyl Methanamide are re-dubbed 5 kinds of different dosage forms under different proportion, every mu is watered 15L,
Two kinds of total effective ingredient of medicament are 1.5g, and comparison medicament is 30% Envidor wettable powder, detects it to citrus red mite 7
My god, 15 days, 45 days killing effects.Result shows: it is right that Envidor and pyrazoles indanyl Methanamide each mixture process preventive effect are above
According to medicament.
Table 1 Envidor and pyrazoles indanyl Methanamide compositions are to citrus red mite test of pesticide effectiveness result
Claims (6)
1. a miticide composition, it is characterised in that: said composition includes active component and auxiliary agent；Described active component is spiral shell
The weight ratio of demodicid mite ester and pyrazoles indanyl Methanamide and Envidor and pyrazoles indanyl Methanamide is: 1:8～8:1.
2. a kind of miticide composition as claimed in claim 1, it is characterised in that: described Envidor and pyrazoles indanyl formyl
The weight ratio of amine is 1:4～4:1.
3. a kind of miticide composition as claimed in claim 1, it is characterised in that: described active component accounts for miticide composition gross weight
The 8%～60% of amount.
4. miticide composition as claimed in claim 1 a kind of, it is characterised in that: in described compositions auxiliary agent be dispersant or
One in wetting agent or emulsifying agent or antifreezing agent or defoamer or thickening agent or disintegrating agent or stabilizer or filler or solvent or
Multiple.
5. a kind of miticide composition as claimed in claim 1, it is characterised in that: its dosage form of described compositions is wettable powder
Agent or suspending agent or aqueous emulsion or water dispersible granules or cream.
6. the purposes of the miticide composition described in a claim 1, it is characterised in that: described miticide composition is used for preventing and treating
Semen Tritici aestivi white lead or bacterial wilt of ginger or watermelon blight or citrus red mite.
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|---|---|---|---|
| CN201610506353.8A CN106172412A (en) | 2016-06-30 | 2016-06-30 | A kind of miticide composition |
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| CN201610506353.8A CN106172412A (en) | 2016-06-30 | 2016-06-30 | A kind of miticide composition |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102696651A (en) * | 2012-06-12 | 2012-10-03 | 永农生物科学有限公司 | Spirodiclofen-containing compound pesticidal composition and preparation thereof |
| CN104602523A (en) * | 2012-06-15 | 2015-05-06 | I-F产品协作基金会 | Synergistic compositions for the protection of agrarian crops and the use thereof |
-
2016
- 2016-06-30 CN CN201610506353.8A patent/CN106172412A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102696651A (en) * | 2012-06-12 | 2012-10-03 | 永农生物科学有限公司 | Spirodiclofen-containing compound pesticidal composition and preparation thereof |
| CN104602523A (en) * | 2012-06-15 | 2015-05-06 | I-F产品协作基金会 | Synergistic compositions for the protection of agrarian crops and the use thereof |
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