Summary of the invention
The technical problem to be solved by the present invention is to how provide a kind of baking time and reduction that can reduce battery
The battery apparatus for baking of battery water content.
For this purpose, the invention proposes a kind of battery apparatus for baking, comprising:
Cavity and be located at least one intracorporal sealing structure of the chamber;
Hot wind is connected in the cavity;
The sealing structure is used to seal the opening portion of battery to be injected;
The hot wind is for heating the outer wall of the battery to be injected.
Preferably, the battery apparatus for baking further include:
The air extractor and air charging system being connect with the sealing structure;
The air extractor is for vacuumizing the inside of the battery to be injected;
The air charging system is used to be filled with dry gas to the inside of the battery to be injected.
Preferably, the battery apparatus for baking further include:
The preheating device being connected between the air charging system and sealing structure;
The preheating device makes the temperature of the dry gas for preheating the dry gas for being filled with inside battery to be injected
It is less than preset value with the absolute value of the temperature difference of the battery to be injected.
Preferably, the sealing structure is multiple, is connected between the multiple sealing structure by bracket.
Preferably, the cavity is turntable structure, and the battery to be injected is located at the inside of the turntable structure, described turn
The rotation of dish structure drives the battery to be injected to be moved to lower discharge position by upper discharge position.
On the other hand, battery is carried out using battery apparatus for baking described in any one of the above the present invention also provides a kind of
The method of baking, this method comprises:
The opening portion of battery to be injected is sealed by the sealing structure;
The battery to be injected after sealing is placed in the cavity;
It is passed through hot wind in the cavity, the outer wall of the battery to be injected is heated.
Preferably, this method further include:
It is vacuumized by inside of the air extractor to the battery to be injected;
After vacuumizing, dry gas is filled with to the inside of the battery to be injected by air charging system;
Repeatedly vacuumized and be filled with dry gas operation.
Preferably, this method further include:
The dry gas for being filled with the sealing structure is preheated by preheating device.
Preferably, this method further include:
After the completion of baking, the sealing structure is separated with the battery;
New battery to be injected is sealed using the sealing structure.
Preferably, this method further include:
Battery to be injected is sent to the upper discharge position of the apparatus for baking by drawstring;
By the rotation of the apparatus for baking, the battery to be injected at upper discharge position is moved to the apparatus for baking
Lower discharge position.
The opening portion of battery to be injected is passed through sealing structure by battery apparatus for baking provided in an embodiment of the present invention and method
It is sealed, is heated by leading to hot wind in the outside of battery to be injected to battery surface, so even if by the gas of inside battery
It vacuumizes, the temperature in battery will not sharply decline, and reduce the influence to battery drying temperature, realize and hold to battery
Continuous heating, therefore use battery apparatus for baking provided in an embodiment of the present invention and method, to being dried before lithium ion battery liquid injection
Dry energy consumption is small, high-efficient, greatly reduces the baking time of battery and reduces the water content of battery.
Specific embodiment
Below in conjunction with attached drawing, embodiments of the present invention is described in detail.
Inside battery moisture content is the parameter index of all lithium ion battery preparation manufacturer's strict controls, any moisture
Introducing can all cause inner pressure of battery excessive to cause security risk, however moisture controls always in lithium ion battery manufacturing process
It is a difficult point, especially inside lithium ion cell is compact-sized, and anode, cathode and diaphragm fit closely, and further increases
Its internal moisture is baked out the difficulty come.
In view of the above-mentioned problems, as shown in Figure 1, the embodiment of the invention provides a kind of battery apparatus for baking, which includes:
Cavity 1 and at least one sealing structure 2 in the cavity 1;Hot wind is connected in the cavity 1;The sealing structure 2 is used
In the opening portion for sealing battery 5 to be injected;The hot wind 3 is for heating the outer wall of the battery 5 to be injected.
Specifically, the hot wind 3 can be thermal cycle wind, 2 pairs of single batteries of sealing structure are individually sealed, sealing structure
2 and battery to be injected 5 be integrally placed in the closed cavity 1 with thermal cycle wind, battery to be injected 5 and external 1 phase of cavity
To independence, there is no substance transfers between battery 5 and cavity 1 to be injected, and there is only heat to transmit.Thermal cycle wind is in electricity to be injected
The outer wall that intercell 5 is treated on the outside of pond 5 is heated, the inside without entering the battery to be injected 5 sealed.
Battery apparatus for baking provided in an embodiment of the present invention is carried out by sealing structure the opening portion of battery to be injected close
Envelope is heated by leading to hot wind in the outside of battery to be injected to battery surface, so even if the gas of inside battery is vacuumized,
Temperature in battery will not sharply decline, and reduce the influence to battery drying temperature, realize the continuous heating to battery,
Therefore battery apparatus for baking provided in an embodiment of the present invention and method are used, to the energy consumption dried before lithium ion battery liquid injection
It is small, it is high-efficient, it greatly reduces the baking time of battery and reduces the water content of battery.
On the basis of the above embodiments, it is preferred that battery apparatus for baking provided in an embodiment of the present invention further include: with institute
State the air extractor and air charging system of the connection of sealing structure 2;
The air extractor is for vacuumizing the inside of the battery 5 to be injected;
The air charging system is used to be filled with dry gas to the inside of the battery 5 to be injected.
As shown in Fig. 2, the sealing structure 2 includes seal head 23 and the sealing ring for connecting seal head 23 and battery 5 to be injected
24, wherein be equipped with vacuum lead 21 and dry feed channel 22 in seal head 23, air extractor can be with by vacuum lead 21
The gas that steam is had in battery 5 to be injected is taken away, air charging system passes through dry feed channel 22 can be into battery 5 to be injected
It is filled with dry gas, adsorbs a part of steam.Air extractor and the relatively independent work of air charging system were completely toasted at one
Cheng Zhong may be implemented to take away the moisture of inside battery by vacuumizing and filling the multiple switching of dry gas.
The embodiment of the present invention can take the gas in battery 5 to be injected away by air extractor, take away a part of steam,
It is vacuumized again by being filled with dry gas, with this, repeatedly circulation can in time be taken away the moisture baked out, accelerate the drying of battery
Speed, although the temperature in battery 5 to be injected can be reduced using air extractor, since the embodiment of the present invention is in electricity to be injected
The periphery in pond 5 is connected with hot gas, therefore reduces shadow when air extractor takes the gas in battery 5 to be injected away to battery temperature
It rings, further improve the drying efficiency of battery and reduces the water content of battery.
On the basis of the above embodiments, battery apparatus for baking provided in an embodiment of the present invention further include:
The preheating device being connected between the air charging system and sealing structure 2;
The preheating device makes the temperature of the dry gas for preheating the dry gas being filled with inside battery 5 to be injected
The absolute value of degree and the temperature difference of the battery 5 to be injected is less than preset value.
It should be noted that the temperature of battery can be reduced since air extractor vacuumizes the gas in battery 5 to be injected,
It is advantageous to scheme, when vacuumizing to reduce, influence to battery temperature carries out gas when being filled with dry gas
Preheating, makes the temperature for the dry gas being filled with further decrease the influence to battery temperature close to the temperature of battery.
As shown in Figure 1, the sealing structure 2 of battery apparatus for baking provided in an embodiment of the present invention be it is multiple, it is the multiple close
It is connected between seal structure 2 by bracket 4.
Wherein, bracket 4 connects the seal head 23 of multiple sealing structures 2, bracket 4 can be set as chain structure (in this way so as to
It is located in turntable structure in it).More batteries can be set as one group by bracket 4, be conducive to pass through mechanical arm for one group of battery
Global transfer, setting bracket 4 can also be conducive to the transfer of single battery.
In addition, passing through the reciprocating motion of bracket 4, may be implemented inside entire apparatus for baking back and forth to follow sealing structure 2
Ring utilizes, when there is new battery to be injected 5 to enter, sealing structure 2 by this new sealing of battery to be injected 5 and in company with it is new to
Intercell 5 completes entire baking process together, and after battery is completed to toast, sealing structure 2 and battery 5 to be injected are detached from, and
The position that loopy moving is packed into new 5 battery of battery to be injected, the sealing for new battery.
As shown in figure 3, the cavity 1 of battery apparatus for baking provided by the above embodiment is turntable structure, the electricity to be injected
Pond 5 is located at the inside of the turntable structure, and the rotation of the turntable structure drives the battery 5 to be injected to be moved by upper discharge position
To lower discharge position.Wherein, bracket 4 can be placed in turntable structure, by the sealing structure of multiple batteries 5 to be injected in turntable structure
23 connect, and are one group conducive to multiple batteries 5 to be injected and are shifted.As shown in figure 3, can be by 2 batteries 5 to be injected
Seal head 23 is connected as one group, in transfer, can be realized simultaneously and shifts the two batteries 5 to be injected together.
Wherein, the upper discharge position of battery apparatus for baking, battery 5 to be injected are sent to from drawstring when new battery to be injected 5
It is transferred in turntable structure, and then opposing seal is carried out to each battery 5 to be injected by sealing structure 2, turntable structure
Surrounding is connected with thermal cycle wind, and the outer wall for treating intercell 5 is heated.As needed, turntable structure rotates a week
Phase has indicated an entire flow of the drying of battery pair, and when battery 5 to be injected rotates to lower discharge position, battery is from turntable knot
Automatic flow is transferred on drawstring in structure to next station.Wherein, transferring battery to can be by automatic in turntable structure
The mode of transfer, such as by mechanical arm by battery transfer on drawstring to turntable structure etc..Therefore, the embodiment of the present invention provides
Battery apparatus for baking may be implemented to complete entire baking process under continous way flow line production.
On the other hand, as shown in figure 4, the embodiment of the invention also provides a kind of using provided by the above embodiment any one
The method that kind battery apparatus for baking carries out battery baking, this method comprises:
S1: the opening portion of battery to be injected is sealed by the sealing structure;
S2: the battery to be injected after sealing is placed in the cavity;
S3: being passed through hot wind in the cavity, heats to the outer wall of the battery to be injected.
Battery baking method provided in an embodiment of the present invention is carried out by sealing structure the opening portion of battery to be injected close
Envelope is heated by leading to hot wind in the outside of battery to be injected to battery surface, so even if the gas of inside battery is vacuumized,
Temperature in battery will not sharply decline, and reduce the influence to battery drying temperature, realize the continuous heating to battery,
Therefore battery apparatus for baking provided in an embodiment of the present invention and method are used, to the energy consumption dried before lithium ion battery liquid injection
It is small, it is high-efficient, it greatly reduces the baking time of battery and reduces the water content of battery.
On the basis of the above embodiments, the embodiment of the present invention provides battery baking method further include:
It is vacuumized by inside of the air extractor to the battery to be injected;
After vacuumizing, dry gas is filled with to the inside of the battery to be injected by air charging system;
Repeatedly vacuumized and be filled with dry gas operation.
Preferably, battery baking method provided in an embodiment of the present invention further include:
The dry gas for being filled with the sealing structure is preheated by preheating device.
Preferably, this method further include:
After the completion of baking, the sealing structure is separated with the battery;
New battery to be injected is sealed using the sealing structure.
Preferably, this method further include:
Battery to be injected is sent to the upper discharge position of the apparatus for baking by drawstring;
By the rotation of the apparatus for baking, the battery to be injected at upper discharge position is moved to the apparatus for baking
Lower discharge position.
To make those skilled in the art more fully understand implementation result of the invention, below to battery provided by the invention
The effect of apparatus for baking compares description.The actual effect of the specific battery for combining preparation, to using above-mentioned apparatus for baking
The actual effect of production battery is introduced.
Comparative example 1
Battery before fluid injection is toasted using apparatus for baking provided in an embodiment of the present invention, Flue curing parameter uses 8h, mistake
Journey interval 30min is vacuumized and is filled the switching of dry gas, and battery is used for experimental evaluation after baking;
Specific evaluation measures:
1, dismantling battery tests the water content of positive plate, negative electrode tab respectively, using karl Fischer moisture tester to sample
It is tested;
2, subsequent production is carried out to 1000pcs battery and the chemical property of battery is counted by statistics gimmick;Specifically
It is as follows:
By above-mentioned lithium ion battery with 0.1C constant-current constant-voltage charging to full piezoelectric voltage 3.6V, when cut-off current 0.01C
Capacity is calculated as C0, and battery is shelved 5min, is calculated as C1 using the capacity of 1C constant-current discharge to 2.0V.C1 is calculated as the capacity of battery,
The ratio of C1/C0 is calculated as the first charge discharge efficiency of battery.
3, subsequent production is carried out to battery, cured effect is compared by the cycle life of control cell;It is specific as follows: will be upper
Battery carries out charge and discharge cycles, the 1C discharge capacity of a certain circulation and the 4th circulation with the multiplying power of 1C after the lithium ion chemical conversion stated
The ratio between discharge capacity be referred to as the capacity retention ratio after a certain circulation of lithium ion battery, capacity of lithium ion battery conservation rate is
Circulating cycle number when 80% is as the index for measuring cycle performance.
Comparative example 2
Battery before fluid injection is toasted using apparatus for baking provided by the invention, Flue curing parameter use 1h, interprocedual every
10min is vacuumized and is filled the switching of dry gas, and battery is used for experimental evaluation after baking;
Specific evaluation measures: with comparative example 1.
Comparative example 3
Battery before fluid injection is toasted using apparatus for baking provided in an embodiment of the present invention, Flue curing parameter uses 30min,
Interprocedual is vacuumized and is filled the switching of dry gas every 5min, and battery is used for experimental evaluation after baking;
Specific evaluation measures: with comparative example 1
Comparative example 4
Battery before fluid injection is toasted using traditional apparatus for baking, Flue curing parameter use 8h, interprocedual every 30min into
Row vacuumizes and fills the switching of dry gas, and battery is used for experimental evaluation after baking;
Specific evaluation measures: with comparative example 1
The moisture content tested after battery dismantling prepared by comparative example 1, comparative example 2, comparative example 3 and comparative example 4 is listed in down
Table.
Table 1: comparative example 1, comparative example 2, comparative example 3 and comparative example 4 prepare battery pole piece moisture
Content balance table
From table 1 it follows that the pole piece moisture content of comparative example 1 and comparative example 2 is close with comparative example 4, comparative example 3
Pole piece moisture content is apparently higher than comparative example 4.Comparative example 2 and comparative example 4 are compared as can be seen that using baking provided by the invention
Device is toasted, and baking 1h is the effect that can reach traditional roasting mode baking 8h, greatly improves baking efficiency.Comparison
Comparative example 1, comparative example 2 and comparative example 3 using apparatus for baking provided by the invention as can be seen that toasted, baking time 1h
Shi Jineng reaches preferably cured effect can greatly improve production efficiency again.
Battery performance and cycle performance prepared by comparative example 1, comparative example 2, comparative example 3 and comparative example 4 compares position
In following table.
Table 2: comparative example 1, comparative example 2, comparative example 3 and comparative example 4 prepare battery electrical property contrast table
From Table 2, it can be seen that comparative example 1, comparative example 2, charge efficiency and capacity are better than comparative example 3 and comparative example 4,
Cycle life quite but is substantially better than comparative example 3 with comparative example 4.
To sum up, battery apparatus for baking provided in an embodiment of the present invention, baking 1h can reach to be toasted with traditional roasting mode
The cured effect of 8h, it is even more excellent.Electricity with the lengthening of battery apparatus for baking baking time provided by the invention, after baking
Core moisture content reduce, electrical property and cycle performance it is more excellent, when baked between more than 1h after, moisture content and chemical property change
Kind amplitude reduces.