CN106147400A - A kind of aquosity optical variable ink - Google Patents

A kind of aquosity optical variable ink Download PDF

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Publication number
CN106147400A
CN106147400A CN201610711534.4A CN201610711534A CN106147400A CN 106147400 A CN106147400 A CN 106147400A CN 201610711534 A CN201610711534 A CN 201610711534A CN 106147400 A CN106147400 A CN 106147400A
Authority
CN
China
Prior art keywords
water
parts
aquosity
soluble resin
acrylic emulsion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610711534.4A
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Chinese (zh)
Inventor
张东明
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Central Asia Suzhou Ink Co Ltd
Original Assignee
Central Asia Suzhou Ink Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Central Asia Suzhou Ink Co Ltd filed Critical Central Asia Suzhou Ink Co Ltd
Priority to CN201610711534.4A priority Critical patent/CN106147400A/en
Publication of CN106147400A publication Critical patent/CN106147400A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/50Sympathetic, colour changing or similar inks
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/037Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/102Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/106Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D11/107Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

The invention discloses a kind of aquosity optical variable ink, it is by acrylic emulsion, water-soluble resin, deionized water, ethanol, optic metachromatic capsule pigment, auxiliary agent is prepared from, described auxiliary agent includes levelling agent, defoamer, adhesion promoter, water-borne wax slurry and plasticizer, the mass fraction of mentioned component is acrylic emulsion 20 ~ 25 parts, water-soluble resin 20 ~ 25 parts, deionized water 8 ~ 10 parts, ethanol 5 ~ 8 parts, optic metachromatic capsule pigment 0.5 ~ 2 part, levelling agent 0.5 ~ 1 part, defoamer 1 ~ 2 part, adhesion promoter 0.5 ~ 1 part, water-borne wax starches 1 ~ 3 part and plasticizer 0.5 ~ 1 part.The present invention uses acrylic emulsion, water-soluble resin, solvent, auxiliary agent, coordinates optic metachromatic capsule pigment, prepares aquosity optical variable ink, and this ink has reversible optic metachromatic function.

Description

A kind of aquosity optical variable ink
Technical field
The present invention relates to technical field of ink, particularly relate to a kind of aquosity optical variable ink.
Background technology
Ink is the important materials for packaging material printing, and it is by printing by pattern, literal table the most on the substrate. Ink includes main component and auxiliary element, and they mix uniformly and form a kind of viscosity colloidal fluid through repeat-rolling. It is made up of pigment, link stuff, auxiliary agent and solvent.For various printings such as books and periodicals, packing and decorating, building decorations.Along with society needs Ask increase, ink kind and yield also respective extension and growth.Along with the development of printing technology, for the examining of the feature of environmental protection of ink Considering more and more, people start progressively to study the petroleum-type composition using the replacement of multiple renewable composition traditional.
Summary of the invention
The technical problem that present invention mainly solves is to provide a kind of aquosity optical variable ink.
For solving above-mentioned technical problem, the technical scheme that the present invention uses is:
A kind of aquosity optical variable ink is provided, is by acrylic emulsion, water-soluble resin, deionized water, ethanol, optic metachromatic Capsule pigment, auxiliary agent are prepared from, and described auxiliary agent includes levelling agent, defoamer, adhesion promoter, water-borne wax slurry and plasticising Agent, the mass fraction of mentioned component is acrylic emulsion 20 ~ 25 parts, water-soluble resin 20 ~ 25 parts, deionized water 8 ~ 10 parts, second Alcohol 5 ~ 8 parts, optic metachromatic capsule pigment 0.5 ~ 2 part, levelling agent 0.5 ~ 1 part, defoamer 1 ~ 2 part, adhesion promoter 0.5 ~ 1 Part, water-borne wax starch 1 ~ 3 part and plasticizer 0.5 ~ 1 part.
In a preferred embodiment of the present invention, described water-soluble resin is modified epoxy acrylic ester resin.
In a preferred embodiment of the present invention, the solid content in described acrylic emulsion is 65 ~ 70%.
In a preferred embodiment of the present invention, it it is to be prepared from by the composition of following mass fraction: acrylic emulsion 22 ~ 24 parts, water-soluble resin 22 ~ 24 parts, deionized water 9 parts, ethanol 6 ~ 7 parts, optic metachromatic capsule pigment 1 ~ 1.5 part, levelling Agent 0.5 ~ 1 part, defoamer 1 ~ 2 part, adhesion promoter 0.5 ~ 1 part, water-borne wax starch 1 ~ 3 part and plasticizer 0.5 ~ 1 part.
The invention has the beneficial effects as follows: one aquosity optical variable ink of the present invention, use acrylic emulsion, water solublity tree Fat, solvent, auxiliary agent, coordinate optic metachromatic capsule pigment, prepare aquosity optical variable ink, and this ink has reversible light Learn colour change function.
Detailed description of the invention
Below presently preferred embodiments of the present invention is described in detail so that advantages and features of the invention can be easier to by It will be appreciated by those skilled in the art that thus protection scope of the present invention is made apparent clear and definite defining.
Embodiment 1: a kind of aquosity optical variable ink, be by acrylic emulsion, water-soluble resin, deionized water, ethanol, Optic metachromatic capsule pigment, auxiliary agent are prepared from, and described auxiliary agent includes that levelling agent, defoamer, adhesion promoter, water-borne wax are starched And plasticizer, the mass fraction of mentioned component is acrylic emulsion 22.5 parts, water-soluble resin 24 parts, deionized water 9 parts, ethanol 6.5 parts, optic metachromatic capsule pigment 1.5 parts, levelling agent 0.8 part, defoamer 1.5 parts, adhesion promoter 0.8 part, water-borne wax Starch 2.5 parts and plasticizer 0.5 part.
Described water-soluble resin is modified epoxy acrylic ester resin, the solid content in described acrylic emulsion 65 ~ 70%。
Embodiment 2: a kind of aquosity optical variable ink, be by acrylic emulsion, water-soluble resin, deionized water, ethanol, Optic metachromatic capsule pigment, auxiliary agent are prepared from, and described auxiliary agent includes that levelling agent, defoamer, adhesion promoter, water-borne wax are starched And plasticizer, the mass fraction of mentioned component is acrylic emulsion 24 parts, water-soluble resin 22 parts, deionized water 9 parts, ethanol 7 Part, optic metachromatic capsule pigment 1.5 parts, levelling agent 0.6 part, defoamer 2 parts, adhesion promoter 0.5 part, water-borne wax slurry 1.5 Part and plasticizer 0.8 part.
Embodiment 3: a kind of aquosity optical variable ink, be by acrylic emulsion, water-soluble resin, deionized water, ethanol, Optic metachromatic capsule pigment, auxiliary agent are prepared from, and described auxiliary agent includes that levelling agent, defoamer, adhesion promoter, water-borne wax are starched And plasticizer, the mass fraction of mentioned component is acrylic emulsion 24 parts, water-soluble resin 22.5 parts, deionized water 9 parts, ethanol 7 parts, optic metachromatic capsule pigment 1.5 parts, levelling agent 0.5 part, defoamer 1 part, adhesion promoter 1 part, water-borne wax starch 1.5 parts With plasticizer 0.5 part.
Aquosity optical variable ink in any of the above-described embodiment, is prepared from by following step:
1) weigh, weigh material according to formulation weight standby;
2) premixing, dissolves water-soluble resin with water, stirs 10min, then be added thereto with ethanol by acrylic emulsion, continue Continuous stirring 30min;
3) mixing, adds step 2 by defoamer, water-borne wax slurry, optic metachromatic capsule pigment) in the premixing material that obtains, continue Continuous stirring 1h;
4) grinding, compound step 3) obtained puts into grinding machine for grinding, and the grinding pressure of regulation grinder is unlikely to brokenly Capsule in bad optic metachromatic capsule pigment;
5) quenched, in the grinding material that step 4) obtains, add levelling agent, adhesion promoter and plasticizer be stirred, and The optic metachromatic capsule pigment adding trace is finely adjusted color to slurry, obtains finished product ink.
The foregoing is only embodiments of the invention, not thereby limit the scope of the claims of the present invention, every utilize this Equivalent structure or equivalence flow process that bright description is made convert, or are directly or indirectly used in other relevant technology necks Territory, is the most in like manner included in the scope of patent protection of the present invention.

Claims (4)

1. an aquosity optical variable ink, it is characterised in that be by acrylic emulsion, water-soluble resin, deionized water, second Alcohol, optic metachromatic capsule pigment, auxiliary agent are prepared from, and described auxiliary agent includes levelling agent, defoamer, adhesion promoter, aqueous Wax slurry and plasticizer, the mass fraction of mentioned component is acrylic emulsion 20 ~ 25 parts, water-soluble resin 20 ~ 25 parts, deionized water 8 ~ 10 parts, ethanol 5 ~ 8 parts, optic metachromatic capsule pigment 0.5 ~ 2 part, levelling agent 0.5 ~ 1 part, defoamer 1 ~ 2 part, adhesive force promote Agent 0.5 ~ 1 part, water-borne wax starch 1 ~ 3 part and plasticizer 0.5 ~ 1 part.
Aquosity optical variable ink the most according to claim 1, it is characterised in that described water-soluble resin is modified epoxy Acrylate.
Aquosity optical variable ink the most according to claim 1, it is characterised in that the solid content in described acrylic emulsion 65 ~ 70%.
Aquosity optical variable ink the most according to claim 1, it is characterised in that be by the composition system of following mass fraction Standby: acrylic emulsion 22 ~ 24 parts, water-soluble resin 22 ~ 24 parts, deionized water 9 parts, ethanol 6 ~ 7 parts, optic metachromatic glue Capsule pigment 1 ~ 1.5 part, levelling agent 0.5 ~ 1 part, defoamer 1 ~ 2 part, adhesion promoter 0.5 ~ 1 part, water-borne wax are starched 1 ~ 3 part and increase Mould agent 0.5 ~ 1 part.
CN201610711534.4A 2016-08-24 2016-08-24 A kind of aquosity optical variable ink Pending CN106147400A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610711534.4A CN106147400A (en) 2016-08-24 2016-08-24 A kind of aquosity optical variable ink

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610711534.4A CN106147400A (en) 2016-08-24 2016-08-24 A kind of aquosity optical variable ink

Publications (1)

Publication Number Publication Date
CN106147400A true CN106147400A (en) 2016-11-23

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113956716A (en) * 2021-12-13 2022-01-21 中山市中益油墨涂料有限公司 Water-based optically variable ink and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101665638A (en) * 2009-08-12 2010-03-10 江阴市兰天彩印包装有限公司 Aquosity optical variable ink and preparing method thereof
CN104130627A (en) * 2014-07-23 2014-11-05 王勇 Stable discoloration ink
CN105017863A (en) * 2015-07-01 2015-11-04 苏州中科纳福材料科技有限公司 Formula of water-based ink for preparation of printed matters with structural color light variability and preparation method of water-based ink
CN105567016A (en) * 2016-03-08 2016-05-11 中钞油墨有限公司 Preparation and production method of optical variable anti-counterfeiting printing ink for sculpture gravure

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101665638A (en) * 2009-08-12 2010-03-10 江阴市兰天彩印包装有限公司 Aquosity optical variable ink and preparing method thereof
CN104130627A (en) * 2014-07-23 2014-11-05 王勇 Stable discoloration ink
CN105017863A (en) * 2015-07-01 2015-11-04 苏州中科纳福材料科技有限公司 Formula of water-based ink for preparation of printed matters with structural color light variability and preparation method of water-based ink
CN105567016A (en) * 2016-03-08 2016-05-11 中钞油墨有限公司 Preparation and production method of optical variable anti-counterfeiting printing ink for sculpture gravure

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113956716A (en) * 2021-12-13 2022-01-21 中山市中益油墨涂料有限公司 Water-based optically variable ink and preparation method thereof

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Application publication date: 20161123