CN106146960A - A kind of preparation method of vapor-permeable type antibacterial sponge - Google Patents
A kind of preparation method of vapor-permeable type antibacterial sponge Download PDFInfo
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- CN106146960A CN106146960A CN201610784727.2A CN201610784727A CN106146960A CN 106146960 A CN106146960 A CN 106146960A CN 201610784727 A CN201610784727 A CN 201610784727A CN 106146960 A CN106146960 A CN 106146960A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L21/00—Compositions of unspecified rubbers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/02—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of definite length, i.e. discrete articles
- B29C44/04—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of definite length, i.e. discrete articles consisting of at least two parts of chemically or physically different materials, e.g. having different densities
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/122—Hydrogen, oxygen, CO2, nitrogen or noble gases
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/06—CO2, N2 or noble gases
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/18—Binary blends of expanding agents
- C08J2203/182—Binary blends of expanding agents of physical blowing agents, e.g. acetone and butane
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2205/00—Foams characterised by their properties
- C08J2205/04—Foams characterised by their properties characterised by the foam pores
- C08J2205/05—Open cells, i.e. more than 50% of the pores are open
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2321/00—Characterised by the use of unspecified rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/04—Homopolymers or copolymers of ethene
- C08J2423/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/14—Applications used for foams
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of vapor-permeable type antibacterial sponge, its raw material is as follows by weight: bipeltate 80 160 parts, polyethylene 8 10 parts, vulcanizing activator 35 parts, filler 24 parts, foaming agent 13 parts, antiseptic 68 parts.The present invention is by the addition of polyethylene, vulcanizing activator, filler, foaming agent and antiseptic, the problem of the easy breed bacteria of sponge that can be loose porous effectively solves, so that sponge obtains good anti-microbial property, it is greatly improved the serviceability of sponge, and foaming effect is preferable, can improve the service life of sponge, safety in utilization is higher, and applicability is wider.
Description
Technical field
The present invention relates to sponge technical field, particularly relate to the preparation method of a kind of vapor-permeable type antibacterial sponge.
Background technology
Sponge, is a kind of porous material, has good water imbibition, can be used in clean article.The sponge that people commonly use
It is made up of wood cellulose fibers or foamed plastic polymer.Sponge has insulation, heat insulation, sound-absorbing, damping, fire-retardant, anti-due to it
The characteristics such as electrostatic, permeability are good, therefore relate to various industry, including auto industry, battery industry, cosmetic industry, chest measurement underwear
Manufacturing industry and top-grade furniture manufacturing industry etc., in addition, the synthetic sponge that also three class other materials are made, respectively low-density is gathered
Ether, polyvinyl alcohol and polyester.In actual use, sponge has multiple use, and in the use of sponge, we can find simultaneously
The easy breed bacteria of sponge, these are all to need us to go to the place changing so that sponge obtains more preferable anti-microbial property.
Chinese mugwort is widely used for various medical treatment field now, can control pruitus, pruritus vulvae eczema and mange etc..With Chinese mugwort
Rubbing hands and washing dirt or pan-fried water-bath body, can prevent and treat skin disease, for puerpera and baby, washing can be sterilized by tarragon keeps fit.Existing literary composition
Offering, in report etc., Chinese mugwort powder or the essential oil interpolation in daily life being related to occurred, such as Chinese mugwort patch etc., these produce
Product are all to utilize the distinctive peculiar function realizing product that is worth of Chinese mugwort, but occurring being related to is added on for Chinese mugwort
Application in sponge.
Content of the invention
The invention aims to solve shortcoming present in prior art, and a kind of vapor-permeable type antibacterial sponge proposing
Preparation method.
To achieve these goals, present invention employs following technical scheme:
A kind of vapor-permeable type antibacterial sponge, its raw material is as follows by weight: bipeltate 80-160 part, polyethylene 8-10 part,
Vulcanizing activator 3-5 part, filler 2-4 part, foaming agent 1-3 part, antiseptic 6-8 part.
Preferably, bipeltate 120 parts, polyethylene 9 parts, vulcanizing activator 4 parts, filler 3 parts, foaming agent 2 parts, antibacterial
Agent 7 parts.
The preparation method of a kind of vapor-permeable type antibacterial sponge, comprises the steps:
S1, by bipeltate melting, after bipeltate melting add polyethylene, vulcanizing activator and antiseptic, standby；
S2, by the bipeltate in S1, polyethylene, vulcanizing activator is thoroughly mixed with antiseptic, after being sufficiently mixed
Put in mould；
S3, by S2 bipeltate, polyethylene, the mixture of vulcanizing activator and antiseptic adds filler with
Foaming agent, according to normal sponge foaming technique foaming；
S4, by the polyethylene in S3, vulcanizing activator, antiseptic, filler and foaming agent obtain the demoulding after mixture cooling；
S5, the mixture after the demoulding are finished product.
Preferably, described antiseptic is the mixture of Nano Silver, Tea Polyphenols and Chinese mugwort powder, and Nano Silver, Tea Polyphenols with beg
Chinese mugwort powder ratio by weight is 0.8:0.8:1.8.
Preferably, described Chinese mugwort powder Main Ingredients and Appearance is ethyl acetate, cineole, camphene hydrate, camphor, terpinol and Pueraria lobota
The mixture of ketone, and ethyl acetate in detail, cineole, camphene hydrate, camphor, terpinol and Eucarvone ratio by weight is
1:1:1.2:1.1:0.8:0.9。
Preferably, described foaming agent is the mixture of liquid carbon dioxide and liquid nitrogen.
Compared with prior art, the invention has the beneficial effects as follows: the present invention by polyethylene, vulcanizing activator, filler,
Foaming agent and the addition of antiseptic, vulcanizing activator strengthens the effect of foaming, and Tea Polyphenols can improve the health care of sponge,
Chinese mugwort powder also has multiple beneficial composition, can solve the problem that the problem in the loose porous easy breed bacteria of sponge effectively solves.With
Shi Haimian is hole-opening foaming, and Chinese mugwort is made its drug effect be slowed down slowly release by sponge molecule parcel, extends the medicinal valency of Chinese mugwort
The effective life of value so that when the sponge in the present invention is for products such as shoe-pads, there is medical value for a long time, so that
Sponge obtains good anti-microbial property, is greatly improved the serviceability of sponge, and foaming effect is preferable, it is possible to increase making of sponge
With the life-span, safety in utilization is higher, and applicability is wider.
Detailed description of the invention
In order to make the purpose of the present invention, technical scheme and advantage clearer, below in conjunction with specific embodiment, to this
Invention is further elaborated.It should be appreciated that specific embodiment described herein only in order to explain the present invention, not
For limiting the present invention.
Embodiment 1
A kind of vapor-permeable type antibacterial sponge, its raw material is as follows by weight: bipeltate 80 parts, polyethylene 8 parts, sulfuration activation
Agent 3 parts, filler 2 parts, foaming agent 1 part, antiseptic 6 parts.
The preparation method of a kind of vapor-permeable type antibacterial sponge, comprises the steps:
S1, by bipeltate melting, after bipeltate melting add polyethylene, vulcanizing activator and antiseptic, standby；
S2, by the bipeltate in S1, polyethylene, vulcanizing activator is thoroughly mixed with antiseptic, after being sufficiently mixed
Put in mould；
S3, by S2 bipeltate, polyethylene, the mixture of vulcanizing activator and antiseptic adds filler with
Foaming agent, according to normal sponge foaming technique foaming；
S4, by the polyethylene in S3, vulcanizing activator, antiseptic, filler and foaming agent obtain the demoulding after mixture cooling；
S5, the mixture after the demoulding are finished product.
Described antiseptic is the mixture of Nano Silver, Tea Polyphenols and Chinese mugwort powder, and Nano Silver, Tea Polyphenols press weight with Chinese mugwort powder
The ratio of amount part is 0.8:0.8:1.8.
Described Chinese mugwort powder Main Ingredients and Appearance is ethyl acetate, cineole, camphene hydrate, camphor, terpinol and Eucarvone
Mixture, and ethyl acetate, cineole, camphene hydrate, camphor, terpinol and Eucarvone ratio by weight be 1:1:
1.2:1.1:0.8:0.9。
Described foaming agent is the mixture of liquid carbon dioxide and liquid nitrogen.
Embodiment 2
A kind of vapor-permeable type antibacterial sponge, its raw material is as follows by weight: bipeltate 120 parts, polyethylene 9 parts, and sulfuration is lived
Agent 4 parts, filler 3 parts, foaming agent 2 parts, antiseptic 7 parts.
The preparation method of a kind of vapor-permeable type antibacterial sponge, comprises the steps:
S1, by bipeltate melting, after bipeltate melting add polyethylene, vulcanizing activator and antiseptic, standby；
S2, by the bipeltate in S1, polyethylene, vulcanizing activator is thoroughly mixed with antiseptic, after being sufficiently mixed
Put in mould；
S3, by S2 bipeltate, polyethylene, the mixture of vulcanizing activator and antiseptic adds filler with
Foaming agent, according to normal sponge foaming technique foaming；
S4, by the polyethylene in S3, vulcanizing activator, antiseptic, filler and foaming agent obtain the demoulding after mixture cooling；
S5, the mixture after the demoulding are finished product.
Described antiseptic is the mixture of Nano Silver, Tea Polyphenols and Chinese mugwort powder, and Nano Silver, Tea Polyphenols press weight with Chinese mugwort powder
The ratio of amount part is 0.8:0.8:1.8.
Described Chinese mugwort powder Main Ingredients and Appearance is ethyl acetate, cineole, camphene hydrate, camphor, terpinol and Eucarvone
Mixture, and ethyl acetate, cineole, camphene hydrate, camphor, terpinol and Eucarvone ratio by weight be 1:1:
1.2:1.1:0.8:0.9。
Described foaming agent is the mixture of liquid carbon dioxide and liquid nitrogen.
Embodiment 3
A kind of vapor-permeable type antibacterial sponge, its raw material is as follows by weight: bipeltate 160 parts, polyethylene 10 parts, and sulfuration is lived
Agent 5 parts, filler 4 parts, foaming agent 3 parts, antiseptic 8 parts.
The preparation method of a kind of vapor-permeable type antibacterial sponge, comprises the steps:
S1, by bipeltate melting, after bipeltate melting add polyethylene, vulcanizing activator and antiseptic, standby；
S2, by the bipeltate in S1, polyethylene, vulcanizing activator is thoroughly mixed with antiseptic, after being sufficiently mixed
Put in mould；
S3, by S2 bipeltate, polyethylene, the mixture of vulcanizing activator and antiseptic adds filler with
Foaming agent, according to normal sponge foaming technique foaming；
S4, by the polyethylene in S3, vulcanizing activator, antiseptic, filler and foaming agent obtain the demoulding after mixture cooling；
S5, the mixture after the demoulding are finished product.
Described antiseptic is the mixture of Nano Silver, Tea Polyphenols and Chinese mugwort powder, and Nano Silver, Tea Polyphenols press weight with Chinese mugwort powder
The ratio of amount part is 0.8:0.8:1.8.
Described Chinese mugwort powder Main Ingredients and Appearance is ethyl acetate, cineole, camphene hydrate, camphor, terpinol and Eucarvone
Mixture, and ethyl acetate, cineole, camphene hydrate, camphor, terpinol and Eucarvone ratio by weight be 1:1:
1.2:1.1:0.8:0.9。
Described foaming agent is the mixture of liquid carbon dioxide and liquid nitrogen.
The present invention, can be loose porous by the addition of polyethylene, vulcanizing activator, filler, foaming agent and antiseptic
The problem of the easy breed bacteria of sponge effectively solve so that sponge obtains good anti-microbial property, be greatly improved sponge
Serviceability, and foaming effect is preferable, it is possible to increase in the service life of sponge, safety in utilization is higher, and applicability is wider.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention is not limited thereto,
Any those familiar with the art in the technical scope that the invention discloses, according to technical scheme and
Inventive concept equivalent or change in addition, all should cover within protection scope of the present invention.
Claims (6)
1. a vapor-permeable type antibacterial sponge, it is characterised in that: its raw material is as follows by weight: bipeltate 80-160 part, poly-second
Alkene 8-10 part, vulcanizing activator 3-5 part, filler 2-4 part, foaming agent 1-3 part, antiseptic 6-8 part.
2. a kind of vapor-permeable type antibacterial sponge according to claim 1, it is characterised in that: its raw material is as follows by weight: send out
Bubble rubber 120 parts, polyethylene 9 parts, vulcanizing activator 4 parts, filler 3 parts, foaming agent 2 parts, antiseptic 7 parts.
3. the preparation method of a kind of vapor-permeable type antibacterial sponge according to claim 1, it is characterised in that: include walking as follows
Rapid:
S1, by bipeltate melting, after bipeltate melting add polyethylene, vulcanizing activator and antiseptic, standby；
S2, by the bipeltate in S1, polyethylene, vulcanizing activator is thoroughly mixed with antiseptic, puts into after being sufficiently mixed
In mould；
S3, by S2 bipeltate, polyethylene, the mixture of vulcanizing activator and antiseptic adds filler and foaming
Agent, according to normal sponge foaming technique foaming；
S4, by the polyethylene in S3, vulcanizing activator, antiseptic, filler and foaming agent obtain the demoulding after mixture cooling；
S5, the mixture after the demoulding are finished product.
4. the preparation method of a kind of vapor-permeable type antibacterial sponge according to claim 3, it is characterised in that: described antiseptic is
The mixture of Nano Silver, Tea Polyphenols and Chinese mugwort powder, and Nano Silver, Tea Polyphenols be 0.8:0.8 with Chinese mugwort powder ratio by weight:
1.8。
5. the preparation method of a kind of vapor-permeable type antibacterial sponge according to claim 4, it is characterised in that: described Chinese mugwort powder master
The mixture wanting composition to be ethyl acetate, cineole, camphene hydrate, camphor, terpinol and Eucarvone, and ethyl acetate, eucalyptus
Leaf oil element, camphene hydrate, camphor, terpinol and Eucarvone ratio by weight are 1:1:1.2:1.1:0.8:0.9.
6. the preparation method of a kind of vapor-permeable type antibacterial sponge according to claim 2, it is characterised in that: described foaming agent is
Liquid carbon dioxide and the mixture of liquid nitrogen.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610784727.2A CN106146960A (en) | 2016-08-31 | 2016-08-31 | A kind of preparation method of vapor-permeable type antibacterial sponge |
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| CN201610784727.2A CN106146960A (en) | 2016-08-31 | 2016-08-31 | A kind of preparation method of vapor-permeable type antibacterial sponge |
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| CN201610784727.2A Pending CN106146960A (en) | 2016-08-31 | 2016-08-31 | A kind of preparation method of vapor-permeable type antibacterial sponge |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108713933A (en) * | 2018-05-24 | 2018-10-30 | 福建大方睡眠科技股份有限公司 | A kind of antibiotic bed mattress of perfect heat-dissipating and preparation method thereof |
| CN109320755A (en) * | 2018-07-20 | 2019-02-12 | 广州市欧亚床垫家具有限公司 | A kind of novel antimicrobial sponge and preparation method thereof |
| CN112890371A (en) * | 2021-01-30 | 2021-06-04 | 莆田市荔城区富立鞋用材料有限公司 | Antibacterial and deodorant EVA (ethylene vinyl acetate) insole and preparation method thereof |
| CN112914198A (en) * | 2021-01-21 | 2021-06-08 | 佛山市品亿高分子材料科技有限公司 | Antibacterial and deodorant moxa sponge insole |
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| WO2002077095A2 (en) * | 2001-03-23 | 2002-10-03 | Milliken & Company | Antimicrobial rubber compositions |
| CN101058653A (en) * | 2007-05-23 | 2007-10-24 | 泉州云麻新资源高分子材料研究中心有限公司 | Composition for preparing shoe sole |
| CN101659763A (en) * | 2009-10-09 | 2010-03-03 | 际华三五三七制鞋有限责任公司 | Light high elasticity deodorant rubber spongy cushion for shoes and preparation method thereof |
| CN104140576A (en) * | 2014-08-10 | 2014-11-12 | 宁国市宁盛橡塑制品有限公司 | High-elasticity foamed rubber |
| CN104987551A (en) * | 2015-08-04 | 2015-10-21 | 晋江金飞鞋材有限公司 | Environmental-friendly ventilation type composite natural emulsion product as well as preparation method and application thereof |
-
2016
- 2016-08-31 CN CN201610784727.2A patent/CN106146960A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002077095A2 (en) * | 2001-03-23 | 2002-10-03 | Milliken & Company | Antimicrobial rubber compositions |
| CN101058653A (en) * | 2007-05-23 | 2007-10-24 | 泉州云麻新资源高分子材料研究中心有限公司 | Composition for preparing shoe sole |
| CN101659763A (en) * | 2009-10-09 | 2010-03-03 | 际华三五三七制鞋有限责任公司 | Light high elasticity deodorant rubber spongy cushion for shoes and preparation method thereof |
| CN104140576A (en) * | 2014-08-10 | 2014-11-12 | 宁国市宁盛橡塑制品有限公司 | High-elasticity foamed rubber |
| CN104987551A (en) * | 2015-08-04 | 2015-10-21 | 晋江金飞鞋材有限公司 | Environmental-friendly ventilation type composite natural emulsion product as well as preparation method and application thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108713933A (en) * | 2018-05-24 | 2018-10-30 | 福建大方睡眠科技股份有限公司 | A kind of antibiotic bed mattress of perfect heat-dissipating and preparation method thereof |
| CN109320755A (en) * | 2018-07-20 | 2019-02-12 | 广州市欧亚床垫家具有限公司 | A kind of novel antimicrobial sponge and preparation method thereof |
| CN112914198A (en) * | 2021-01-21 | 2021-06-08 | 佛山市品亿高分子材料科技有限公司 | Antibacterial and deodorant moxa sponge insole |
| CN112890371A (en) * | 2021-01-30 | 2021-06-04 | 莆田市荔城区富立鞋用材料有限公司 | Antibacterial and deodorant EVA (ethylene vinyl acetate) insole and preparation method thereof |
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Application publication date: 20161123 |
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