CN106145811A - A kind of anti-impact folding concrete - Google Patents

A kind of anti-impact folding concrete Download PDF

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Publication number
CN106145811A
CN106145811A CN201610486638.XA CN201610486638A CN106145811A CN 106145811 A CN106145811 A CN 106145811A CN 201610486638 A CN201610486638 A CN 201610486638A CN 106145811 A CN106145811 A CN 106145811A
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CN
China
Prior art keywords
parts
modified polypropylene
fiber
polypropylene fiber
impact
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610486638.XA
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Chinese (zh)
Inventor
朱宏庆
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bengbu Fangzhen Commercial Concrete Co Ltd
Original Assignee
Bengbu Fangzhen Commercial Concrete Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bengbu Fangzhen Commercial Concrete Co Ltd filed Critical Bengbu Fangzhen Commercial Concrete Co Ltd
Priority to CN201610486638.XA priority Critical patent/CN106145811A/en
Publication of CN106145811A publication Critical patent/CN106145811A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/10Coating or impregnating
    • C04B20/1018Coating or impregnating with organic materials
    • C04B20/1022Non-macromolecular compounds

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention discloses a kind of anti-impact folding concrete, its raw material includes by weight: Portland cement 100 parts, fluvial sand 140 180 parts, rubble 250 350 parts, breeze 10 20 parts, silicon ash 20 30 parts, fiber 23 parts, acrylic acid ester emulsion 12 parts, retardation water reducing agent 24 parts, cellulose ether 24 parts, 24 28 parts of water;Wherein, the raw material of fiber is: steel fibre, modified polypropylene fiber.Good mechanical property of the present invention, shock resistance folding endurance can be high.

Description

A kind of anti-impact folding concrete
Technical field
The present invention relates to technical field of concrete, particularly relate to a kind of anti-impact folding concrete.
Background technology
At present, concrete is of paramount importance building structure material, its be widely used in road, build, decorate, heavy industry The fields such as industry.But the concrete in high load-bearing, HI high impact environment, the shock resistance of simple concrete material is with anti- Fragility can be relatively low, accordingly, it is desirable to provide the concrete of a kind of good mechanical property.
Summary of the invention
The technical problem existed based on background technology, the present invention proposes a kind of anti-impact folding concrete, mechanicalness of the present invention Can be good, shock resistance folding endurance can be high.
A kind of anti-impact folding concrete that the present invention proposes, its raw material includes by weight: Portland cement 100 parts, Fluvial sand 140-180 part, rubble 250-350 part, breeze 10-20 part, silicon ash 20-30 part, fiber 2-3 part, acrylic acid ester emulsion 1-2 Part, retardation water reducing agent 2-4 part, cellulose ether 2-4 part, water 24-28 part;
Wherein, the raw material of fiber is: steel fibre, modified polypropylene fiber.
Preferably, the particle diameter of fluvial sand is 1-2mm, clay content≤1% of fluvial sand.
Preferably, the particle diameter of rubble is 10-20mm.
Preferably, steel fibre, the weight ratio of modified polypropylene fiber are 2-4:1-3.
Preferably, steel fibre, the length of modified polypropylene fiber are 10-15mm.
Preferably, steel fibre must be through polishing, and depletion washs, and then air-dries with the hot blast that temperature is 30-50 DEG C.
Preferably, in the preparation process of modified polypropylene fiber, it is 2-3wt% that polypropylene fibre adds mass fraction Mixing in the ethanol solution of gamma-aminopropyl-triethoxy-silane, be warming up to 60-70 DEG C, insulated and stirred 60-80min, taking-up processes After polyethylene fibre, washing, drying under reduced pressure obtains material A, material A is added in montmorillonite, is warming up to 70-80 DEG C, with The speed stirring 2-3h of 800-1000r/min, is cooled to room temperature and obtains modified polypropylene fiber.
Preferably, in the preparation process of modified polypropylene fiber, the particle diameter of montmorillonite is 2-3mm.
Preferably, in the preparation process of modified polypropylene fiber, polypropylene fibre and gamma-aminopropyl-triethoxy-silane Weight ratio be 10-15:0.8-1.
Preferably, in the preparation process of modified polypropylene fiber, the weight ratio of material A and montmorillonite is 1-1.2:2-3.
The preparation technology of the present invention is as follows: Portland cement, fluvial sand, rubble, breeze, silicon ash, fiber are mixed To material A;By acrylic acid ester emulsion, retardation water reducing agent, the water of cellulose ether addition 8 times on the basis of acrylic acid ester emulsion weight Mixing, adds material A mixing, adds the mixing of remaining water, Cheng Mo, and maintenance obtains anti-impact folding concrete.
The present invention selects gamma-aminopropyl-triethoxy-silane to react with polypropylene fibre, at polypropylene fibre surface grafting Gamma-aminopropyl-triethoxy-silane, introducing amino on polypropylene fibre, and considerably increase the polarity of polypropylene fibre, make Obtaining polypropylene fibre can be dispersed with montmorillonite, and montmorillonite has layer structure and good absorption property, in high-speed stirring In mixing, montmorillonite can adsorb polypropylene fibre, and polypropylene fibre can be deep between cheating engaging layer, forms fiber intercalation knot Structure obtains modified polypropylene fiber, thus increases the polarity of polypropylene fibre further, and can increase the anti-impact of polypropylene fibre Hitting toughness, modified polypropylene fiber can be dispersed with cement, and the hydroxyl in the amino of fiber surface and cement can occur Bonding, so that cement and polypropylene fibre compact siro spinning technology;Alkali liquid washing, the steel fiber surface after air-drying contains great amount of hydroxy group, Can be bonded with the hydroxyl in cement, be connected with cement, modified polypropylene fiber, steel fibre and cement, at water and third Under the interaction of olefin(e) acid ester emulsion so that polypropylene fibre and steel fibre are combined closely with cement, thus considerably increase this The impact resistance of invention, toughness, thus stop the present invention to be broken off when being impacted by weight;Fluvial sand, rubble, breeze, silicon ash with Steel fibre, modified polypropylene fiber are dispersed, cooperate, and increase the impact resistance of the present invention, toughness further;Suitable long The fiber of degree, can preferably increase impact resistance and the toughness of the present invention;Acrylic acid ester emulsion, retardation water reducing agent, cellulose Ether cooperates, and can reduce water consumption, promotes that each material mutually bonds, and increases the mechanical performance of the present invention, and energy further Increase antifreeze, anticracking, the anti-permeability performance of the present invention.
Detailed description of the invention
Below, by specific embodiment, technical scheme is described in detail.
Embodiment 1
A kind of anti-impact folding concrete, its raw material includes by weight: Portland cement 100 parts, and fluvial sand 160 parts is broken 300 parts of stone, breeze 15 parts, silicon ash 25 parts, fiber 2.5 parts, acrylic acid ester emulsion 1.5 parts, retardation water reducing agent 3 parts, cellulose ether 3 Part, 26 parts of water;
Wherein, the raw material of fiber is: steel fibre, modified polypropylene fiber.
Embodiment 2
A kind of anti-impact folding concrete, its raw material includes by weight: Portland cement 100 parts, and fluvial sand 140 parts is broken 350 parts of stone, breeze 10 parts, silicon ash 30 parts, fiber 2 parts, acrylic acid ester emulsion 2 parts, retardation water reducing agent 2 parts, cellulose ether 4 parts, 24 parts of water;
Wherein, the raw material of fiber is: steel fibre, modified polypropylene fiber, wherein, and steel fibre, modified polypropylene fiber Weight ratio is 4:1, and steel fibre, the length of modified polypropylene fiber are 15mm.
Embodiment 3
A kind of anti-impact folding concrete, its raw material includes by weight: Portland cement 100 parts, and fluvial sand 180 parts is broken 250 parts of stone, breeze 20 parts, silicon ash 20 parts, fiber 3 parts, acrylic acid ester emulsion 1 part, retardation water reducing agent 4 parts, cellulose ether 2 parts, 28 parts of water;
Wherein, the raw material of fiber is: steel fibre, modified polypropylene fiber, wherein, and steel fibre, modified polypropylene fiber Weight ratio is 2:3, and steel fibre, the length of modified polypropylene fiber are 10mm;
Steel fibre must be through polishing, and depletion washs, and then air-dries with the hot blast that temperature is 50 DEG C;
In the preparation process of modified polypropylene fiber, it is 2wt% γ-aminopropyl that polypropylene fibre adds mass fraction The ethanol solution of triethoxysilane mixes, is warming up to 70 DEG C, insulated and stirred 60min, the polyethylene fibre after taking-up process, Washing, drying under reduced pressure obtains material A, material A is added in the montmorillonite that particle diameter is 3mm, is warming up to 70 DEG C, with 1000r/min Speed stirring 2h, be cooled to room temperature and obtain modified polypropylene fiber, wherein, polypropylene fibre and gamma-aminopropyl-triethoxy The weight ratio of silane be the weight ratio of 15:0.8, material A and montmorillonite be 1.2:2.
Embodiment 4
A kind of anti-impact folding concrete, its raw material includes by weight: Portland cement 100 parts, particle diameter is 1mm, contains The fluvial sand of mud amount≤1% 170 parts, particle diameter is the rubble 320 parts of 10mm, breeze 13 parts, silicon ash 28 parts, fiber 2.2 parts, acrylic acid Ester emulsion 1.7 parts, retardation water reducing agent 2.5 parts, cellulose ether 3.5 parts, 25 parts of water;
Wherein, the raw material of fiber is: steel fibre, modified polypropylene fiber, wherein, and steel fibre, modified polypropylene fiber Weight ratio is 4:1, and steel fibre, the length of modified polypropylene fiber are 15mm;
Steel fibre must be through polishing, and depletion washs, and then air-dries with the hot blast that temperature is 30 DEG C;
In the preparation process of modified polypropylene fiber, it is 3wt% γ-aminopropyl that polypropylene fibre adds mass fraction The ethanol solution of triethoxysilane mixes, is warming up to 60 DEG C, insulated and stirred 80min, the polyethylene fibre after taking-up process, Washing, drying under reduced pressure obtains material A, material A is added in the montmorillonite that particle diameter is 2mm, is warming up to 80 DEG C, with 800r/min's Speed stirring 3h, is cooled to room temperature and obtains modified polypropylene fiber, wherein, and polypropylene fibre and gamma-aminopropyl-triethoxy silicon The weight ratio of alkane be the weight ratio of 10:1, material A and montmorillonite be 1:3.
Embodiment 5
A kind of anti-impact folding concrete, its raw material includes by weight: Portland cement 100 parts, particle diameter is 2mm, contains The fluvial sand of mud amount≤1% 150 parts, particle diameter is the rubble 280 parts of 20mm, breeze 17 parts, silicon ash 22 parts, fiber 2.8 parts, acrylic acid Ester emulsion 1.3 parts, retardation water reducing agent 3.5 parts, cellulose ether 2.5 parts, 27 parts of water;
Wherein, the raw material of fiber is: steel fibre, modified polypropylene fiber, wherein, and steel fibre, modified polypropylene fiber Weight ratio is 3:2, and steel fibre, the length of modified polypropylene fiber are 13mm;
Steel fibre must be through polishing, and depletion washs, and then air-dries with the hot blast that temperature is 40 DEG C;
In the preparation process of modified polypropylene fiber, it is 2.5wt% γ-ammonia third that polypropylene fibre adds mass fraction The ethanol solution of ethyl triethoxy silicane alkane mixes, is warming up to 65 DEG C, insulated and stirred 70min, the polyethylene fiber after taking-up process Dimension, washing, drying under reduced pressure obtains material A, material A is added in the montmorillonite that particle diameter is 2.5mm, is warming up to 75 DEG C, with 900r/ The speed stirring 2.5h of min, is cooled to room temperature and obtains modified polypropylene fiber, wherein, and polypropylene fibre and γ-aminopropyl three second The weight ratio of TMOS be the weight ratio of 13:0.9, material A and montmorillonite be 1.1:2.5.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention is not limited thereto, Any those familiar with the art in the technical scope that the invention discloses, according to technical scheme and Inventive concept equivalent or change in addition, all should contain within protection scope of the present invention.

Claims (10)

1. an anti-impact folding concrete, it is characterised in that its raw material includes by weight: Portland cement 100 parts, fluvial sand 140-180 part, rubble 250-350 part, breeze 10-20 part, silicon ash 20-30 part, fiber 2-3 part, acrylic acid ester emulsion 1-2 part, Retardation water reducing agent 2-4 part, cellulose ether 2-4 part, water 24-28 part;
Wherein, the raw material of fiber is: steel fibre, modified polypropylene fiber.
Anti-impact folding concrete the most according to claim 1, it is characterised in that the particle diameter of fluvial sand is 1-2mm, the clay content of fluvial sand ≤ 1%.
Anti-impact the most according to claim 1 or claim 2 folding concrete, it is characterised in that the particle diameter of rubble is 10-20mm.
4. according to anti-impact folding concrete described in any one of claim 1-3, it is characterised in that steel fibre, modified polypropylene fiber Weight ratio be 2-4:1-3.
5. according to anti-impact folding concrete described in any one of claim 1-4, it is characterised in that steel fibre, modified polypropylene fiber Length be 10-15mm.
6. according to anti-impact folding concrete described in any one of claim 1-5, it is characterised in that steel fibre must be through polishing, and depletion is washed Wash, then air-dry with the hot blast that temperature is 30-50 DEG C.
7. according to anti-impact folding concrete described in any one of claim 1-6, it is characterised in that in the preparation of modified polypropylene fiber During, polypropylene fibre is added in the ethanol solution that mass fraction is 2-3wt% gamma-aminopropyl-triethoxy-silane mixed Even, it is warming up to 60-70 DEG C, insulated and stirred 60-80min, the polyethylene fibre after taking-up process, washing, drying under reduced pressure obtains thing Material A, adds material A in montmorillonite, is warming up to 70-80 DEG C, stirs 2-3h with the speed of 800-1000r/min, is cooled to room Temperature obtains modified polypropylene fiber.
Anti-impact folding concrete the most according to claim 7, it is characterised in that in the preparation process of modified polypropylene fiber, The particle diameter of montmorillonite is 2-3mm.
Anti-impact folding concrete the most according to claim 7, it is characterised in that in the preparation process of modified polypropylene fiber, The weight ratio of polypropylene fibre and gamma-aminopropyl-triethoxy-silane is 10-15:0.8-1.
Anti-impact folding concrete the most according to claim 7, it is characterised in that in the preparation process of modified polypropylene fiber, The weight ratio of material A and montmorillonite is 1-1.2:2-3.
CN201610486638.XA 2016-06-28 2016-06-28 A kind of anti-impact folding concrete Pending CN106145811A (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
CN201610486638.XA CN106145811A (en) 2016-06-28 2016-06-28 A kind of anti-impact folding concrete

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CN106145811A true CN106145811A (en) 2016-11-23

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106587820A (en) * 2016-12-08 2017-04-26 东南大学 Hand throwing type early-strength impermeable concrete and preparation method thereof
CN117185731A (en) * 2023-11-08 2023-12-08 邢台建工商品混凝土有限公司 Preparation process of anti-cracking concrete

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101759411A (en) * 2010-01-14 2010-06-30 赵国平 Cement concrete
CN104926253A (en) * 2015-06-03 2015-09-23 河南汇能路桥科技有限公司 Pavement/bridge deck concrete fast mending material and application thereof
CN105506999A (en) * 2016-01-29 2016-04-20 杭州赛奇丝科技有限公司 Surface treatment and modification method for high-strength high-mold polyvinyl alcohol fibers

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101759411A (en) * 2010-01-14 2010-06-30 赵国平 Cement concrete
CN104926253A (en) * 2015-06-03 2015-09-23 河南汇能路桥科技有限公司 Pavement/bridge deck concrete fast mending material and application thereof
CN105506999A (en) * 2016-01-29 2016-04-20 杭州赛奇丝科技有限公司 Surface treatment and modification method for high-strength high-mold polyvinyl alcohol fibers

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106587820A (en) * 2016-12-08 2017-04-26 东南大学 Hand throwing type early-strength impermeable concrete and preparation method thereof
CN117185731A (en) * 2023-11-08 2023-12-08 邢台建工商品混凝土有限公司 Preparation process of anti-cracking concrete

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Application publication date: 20161123