CN106120404A - In protein fibre mineralising dyeing in situ, dyestuff separates used additives and application with fiber - Google Patents

In protein fibre mineralising dyeing in situ, dyestuff separates used additives and application with fiber Download PDF

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Publication number
CN106120404A
CN106120404A CN201610466482.9A CN201610466482A CN106120404A CN 106120404 A CN106120404 A CN 106120404A CN 201610466482 A CN201610466482 A CN 201610466482A CN 106120404 A CN106120404 A CN 106120404A
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dyeing
fiber
situ
mineralising
protein fibre
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CN106120404B (en
Inventor
邢建伟
徐成书
沈兰萍
曹贻儒
欧阳磊
苏广召
赵航
周梦宇
刘刚中
李世朋
王培�
***
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Xian Polytechnic University
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Xian Polytechnic University
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/02—After-treatment
    • D06P5/04—After-treatment with organic compounds
    • D06P5/08—After-treatment with organic compounds macromolecular
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/02—Material containing basic nitrogen
    • D06P3/04—Material containing basic nitrogen containing amide groups
    • D06P3/10—Material containing basic nitrogen containing amide groups using reactive dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/02—Material containing basic nitrogen
    • D06P3/04—Material containing basic nitrogen containing amide groups
    • D06P3/14—Wool
    • D06P3/148—Wool using reactive dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/02—After-treatment
    • D06P5/10—After-treatment with compounds containing metal

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Coloring (AREA)

Abstract

In protein fibre disclosed by the invention mineralising dyeing in situ, dyestuff separates used additives and application with fiber, wherein in protein fibre mineralising dyeing in situ, dyestuff separates used additives by polyacrylamide with fiber, aliphatic amine polyoxyethylene ether, sodium hydroxide, sodium carbonate and pure water are prepared from: the present invention further discloses dyestuff in protein fibre mineralising dyeing in situ and separates the preparation method of used additives with fiber and utilize dyestuff in protein fibre mineralising dyeing in situ to separate the method that dyestuff in protein fibre in situ mineralising dyeing is separated with fiber by used additives with fiber.In the mineralising dyeing in situ of the protein fibre of the present invention, dyestuff separates used additives and application with fiber, Colour Difference can not only be made to avoid follow-up soaping and washing processing, residual bath of dyeing after original position mineralising processes can also re-apply in follow-up Colour Difference, makes being greatly decreased with water and pollutant emission of whole Colour Difference.

Description

In protein fibre mineralising dyeing in situ, dyestuff separates used additives and application with fiber
Technical field
The invention belongs to textile dyeing and finishing technical field, be specifically related to dyestuff in the mineralising dyeing in situ of a kind of protein fibre Separate used additives with fiber, the invention still further relates to the preparation method of above-mentioned separation used additives and utilize above-mentioned separation used additives pair The method that in protein fibre mineralising dyeing in situ, dyestuff carries out separating with fiber.
Background technology
The residual bath of dyeing after natural protein fibre is dyed often also exists a number of residual dye and remnants Dyeing assistant, and also there is a number of residual dye on the fiber after dyeing.At natural protein fibre traditional dyeing In the course of processing, the residual bath of above-mentioned dyeing must be discharged, and thus causes higher modifying porcelain expense, also exists simultaneously The hidden danger of environmental pollution.Additionally, in order to ensure to be contaminated the dyeing color fastness of fiber, it is necessary to carry out removing loose colour as main purpose Soap and wash processing.Generally, including dyeing, soaping and wash, natural protein fibre Colour Difference institute The water yield consumed is to be contaminated 40～100 times of fiber quality.Therefore, the dyeing processing technique of traditional natural protein fibre is deposited In a large amount of water consumptions and the problem of a large amount of blowdown, it is unfavorable for the sustainable development of the sector.
In order to solve the problems referred to above, home and abroad research worker proposes solution below and technology:
1.CO2Supercritical dyeing technology: CO2Supercritical dyeing technology is domestic and international textile fabric dyeing from 1988 The new dyeing technology that boundary is widely studied, the research in dyeing polyester fibers field is more.In recent years, have research worker for Wool fiber has carried out CO2The research of supercritical dyeing technology, in research process, first wool fiber is carried out low temperature etc. from Daughter processes, and uses reactive dye to carry out CO afterwards2Supercritical dyeing is processed.Owing to this processing cost is high and link is complicated, It is difficult in actual production application.
2. dyeing post processing processing link: the problem many in order to reduce natural protein fibre Colour Difference water consumption, some Enterprise carries out alkali cleaning by being directly added into alkaline agent in residual bath of dyeing, and makes the residual dye that set does not occurs on fiber enter dyeing Residual bath, carries out twice washing after this residual bath discharge, makes dyeing last handling process decrease water consumption, but Colour Difference is total Water consumption is still up to by 30～40 times of dye fiber quality, it is impossible to fundamentally solve natural protein fibre Colour Difference high Water consumption, the problem of high pollution.
In sum, for natural protein fibre Colour Difference, home and abroad does not finds a kind of practicable yet The new dyeing technology of degree of depth water-saving and emission-reducing.
Application No. 201510107510.3, the mineralising water-saving and emission-reducing dyeing post processing in situ of entitled natural protein fibre The colouring method and a kind of native protein that disclose a kind of degree of depth water-saving and emission-reducing in the application for a patent for invention of method and auxiliary agent are fine Dimension dyeing after treatment aid XAM, the major function of natural protein fibre dyeing after treatment aid XAM is by reactive dye for wool Dye fixing is sufficiently separated by the discarded dyestuff on dye fiber with by dye fiber and isolates after terminating, and is trapped in dye bath, with It is easy in the original position mineralization process carried out later use natural protein fibre dyeing after treatment aid XBM by above-mentioned discarded dye Material and discarded dyeing assistant are decomposed into CO2And water；And the group of natural protein fibre dyeing after treatment aid XAM disclosed in wherein Become: polyacrylamide 0.001%～5%, polyaluminium sulfate or aluminium polychlorid 0.001%～2.5%, dimethyl Base benzyl ammonium chloride 5.0%～40%, double octadecyl-methyl-benzyl ammonium chloride 0.1%～5.0%, double hexadecyldimethylamine Ammonium chloride 0.05%～2.0%, fatty alcohol-polyoxyethylene ether 10%～30% and pure water 15.5%～84.848%.Upper During stating separation and isolating discarded dyestuff, the various ingredients in natural protein fibre dyeing after treatment aid XAM is in dye System can affect during dark product the colorfastness to rubbing of dye product, thus affect the mass effect of final products.Above-mentioned in order to solve Problem, be highly desirable to research and develop a kind of discarded dye separation being applied in natural protein fibre mineralising dyeing course in situ and Release aid, makes to be decomposed into CO smoothly in the original position mineralization process that discarded dyestuff the most directly carries out2And water.Based on this, grind Study carefully the novel discarded dye separation and release aid right and wrong being developed to replace natural protein fibre dyeing after treatment aid XAM The most important.
Summary of the invention
It is an object of the invention to provide dyestuff in the mineralising dyeing in situ of a kind of protein fibre and separate used additives with fiber, Using and separate used additives Colour Difference can not only be made to avoid follow-up soaping and washing processing, the dyeing after original position mineralising processes is residual Bath can also re-apply in follow-up Colour Difference, makes being greatly decreased with water and pollutant emission of whole Colour Difference.
The second object of the present invention is to provide dyestuff in protein fibre mineralising dyeing in situ to separate used additives with fiber Preparation method.
The third object of the present invention is that offer utilizes dyestuff in protein fibre mineralising dyeing in situ to separate use with fiber The method that dyestuff in protein fibre in situ mineralising dyeing is separated by auxiliary agent with fiber.
The first technical scheme of the present invention is, in protein fibre mineralising dyeing in situ, dyestuff separates with fiber Used additives XFL, is prepared from the following materials according to mass percent:
Polyacrylamide 0～5%, aliphatic amine polyoxyethylene ether 0～10%, sodium hydroxide 0.01%～10%, sodium carbonate 0%～10%, pure water 65%～99.99%, the content summation of above component is 100%.
The feature of the first technical scheme of the present invention also resides in:
Polyacrylamide uses nonionic, anion, cation or amphoteric polyacrylamide；Aliphatic amine polyoxyethylene ether Using coco amine polyoxyethylene ether or tallow amine polyoxyethylene ether, wherein oxygen ethylene unit number is 2～20.
The second technical scheme of the present invention is, in protein fibre mineralising dyeing in situ, dyestuff separates with fiber The preparation method of used additives, specifically implements according to following steps:
Step 1, weigh following raw material respectively according to mass percent:
Polyacrylamide 0～5%, aliphatic amine polyoxyethylene ether 0～10%, sodium hydroxide 0.01%～10%, sodium carbonate 0%～10%, pure water 65%～99.99%, the content summation of above component is 100%；
Step 2, the pure water weighed in step 1 is heated to 25 DEG C～50 DEG C；
Step 3, polyacrylamide, aliphatic amine polyoxyethylene ether, sodium hydroxide and sodium carbonate by weighing in step 1 are together Add in the pure water that temperature is 25 DEG C～50 DEG C that step 2 processes, after stirring, obtain protein fibre ore deposit in situ Change dyestuff in dyeing and separate used additives XFL with fiber.
The feature of the second technical scheme of the present invention also resides in:
Polyacrylamide uses nonionic, anion, cation or amphoteric polyacrylamide；Aliphatic amine polyoxyethylene ether Using coco amine polyoxyethylene ether or tallow amine polyoxyethylene ether, wherein oxygen ethylene unit number is 2～20.
The third technical scheme of the present invention is, utilizes dyestuff and fiber in protein fibre mineralising dyeing in situ Separate the method that dyestuff in protein fibre in situ mineralising dyeing is separated by used additives with fiber, specifically according to following steps Implement:
Step 1, fiber to be contaminated or textile to be contaminated are placed in dyeing installation, and in dyeing installation, add dyeing use Water, keeps dye bath circulation；
Step 2, after step 1, according to general natural protein fibre colouring method treat dye fiber or treat dye weaving Product carry out Colour Difference, and dyeing does not discharge dyeing residual liquid after terminating；
Step 3, dyestuff in protein fibre in situ mineralising dyeing is utilized to separate used additives XFL, native protein with fiber Stock-dye after treatment aid XBM and natural protein fibre dyeing after treatment aid XYM is to the fibre after dye residual bath and dyeing Dimension or textile carry out mineralising in situ and process；
Step 4, residual for the dyeing after step 3 mineralising processes bath is stored, as follow-up dyeing with water, and will be after dyeing Fiber or textile carry out being dehydrated, drying, finally realize dyestuff in protein fibre in situ mineralising dyeing and separate with fiber.
The feature of the third technical scheme of the present invention also resides in:
Step 1 is specifically implemented according to following steps:
Step 1.1, fiber to be contaminated or textile to be contaminated are placed in dyeing installation；
Step 1.2, after step 1.1, adding temperature in dyeing installation is the dyeing soft water of 25 DEG C～35 DEG C, is added The dyeing soft water added is 7～11:1 with the mass ratio of fiber to be contaminated or textile to be contaminated, and keeps dye bath fully to circulate.
The dyeing installation used in step 1 is stock dyeing machine, top dyeing machine, yarn package dyeing machine, bundle dyeing Machine, garment dyeing machine, dye jigger, overflow dyeing machine or air flow dyeing machine.
The fiber to be contaminated or the textile to be contaminated that use in step 1 are wool fiber, cashmere fibres, camel wool fiber, yak Down Fiber, mohair yarn fiber, Alpaca fiber, rabbit fur fibre, fox Down Fiber, silk fiber and by above-mentioned fibre spinning Any one in the fabric of yarn and weaving.
Step 3 is specifically implemented according to following steps:
Step 3.1, residual for the dyeing in step 2 bath is cooled to 70 DEG C～90 DEG C, and is incubated at a temperature of this；
Step 3.2, first weigh dyestuff in protein fibre in situ mineralising dyeing and separate used additives XFL, protein with fiber In fiber mineralising dyeing in situ, dyestuff separates the consumption of used additives XFL with fiber is 0.001%owf～50%owf；
Then with fiber, dyestuff in the protein fibre weighed in situ mineralising dyeing is separated used additives XFL to add to through step In the residual bath of dyeing after rapid 3.1 process, and under the temperature conditions of 70 DEG C～90 DEG C, soak cycles 1min～50min；
Step 3.3, first weigh natural protein fibre dyeing after treatment aid XBM, natural protein fibre dyeing after locate The consumption of reason auxiliary agent XBM is 0.001%owf～8%owf；
Then the natural protein fibre weighed dyeing after treatment aid XBM is added to dye after step 3.2 processes In the residual bath of color, and under the temperature conditions of 70 DEG C～90 DEG C, soak cycles 1min～5min；
Step 3.4, first weigh natural protein fibre dyeing after treatment aid XYM, natural protein fibre dyeing after locate The consumption of reason auxiliary agent XYM is 0.001%owf～30%owf；
Then the natural protein fibre weighed dyeing after treatment aid XYM is added to dye after step 3.3 processes In the residual bath of color, and under the temperature conditions of 70 DEG C～90 DEG C, soak cycles 1min～50min, it is finally completed residual bath of dyeing Mineralising processes.
The beneficial effects of the present invention is:
1. utilize dyestuff in the protein fibre mineralising dyeing in situ of the present invention to separate used additives with fiber, in hair activity After dyeing terminates, discarded dyestuff can be made to occur sufficiently separate and isolate with by dye fiber, for follow-up with bathing carry out former Position mineralising link lays the foundation.
2. the discarded dyestuff after dyeing terminates with after by dye, fiber separates and isolates, fine at the native protein added Dimension dyeing after treatment aid XBM and natural protein fibre dyeing after treatment aid XYM jointly act on down, above-mentioned discarded dyestuff with There is mineralising in situ in remaining dyeing assistant, main decomposition is CO simultaneously2And water.
3. in the dyeing of the protein fibre of the present invention of the present invention in situ mineralising, dyestuff separates used additives with fiber and has system The advantage that standby technique is simple, raw material is easy to get, preparation cost is low, is especially suitable for dyeing and finishing industry application, has wide market prospect.
Accompanying drawing explanation
Fig. 1 is natural protein fibre mineralising dyeing heating curve in situ.
Detailed description of the invention
The present invention is described in detail with specific implementation method below in conjunction with the accompanying drawings.
In the mineralising dyeing in situ of present protein fiber, dyestuff separates used additives XFL, according to mass percent with fiber It is prepared from the following materials:
Polyacrylamide 0～5%, aliphatic amine polyoxyethylene ether 0～10%, sodium hydroxide 0.01%～10%, sodium carbonate 0%～10%, pure water 65%～99.99%, the content summation of above component is 100%.
Polyacrylamide uses nonionic, anion, cation or amphoteric polyacrylamide；Aliphatic amine polyoxyethylene ether Using coco amine polyoxyethylene ether or tallow amine polyoxyethylene ether, wherein oxygen ethylene unit number is 2～20.
In the mineralising dyeing in situ of present protein fiber, dyestuff separates the preparation method of used additives XFL with fiber, specifically Implement according to following steps:
Step 1, weigh following raw material respectively according to mass percent:
Polyacrylamide 0～5%, aliphatic amine polyoxyethylene ether 0～10%, sodium hydroxide 0.01%～10%, sodium carbonate 0%～10%, pure water 65%～99.99%, the content summation of above component is 100%；
Step 2, the pure water weighed in step 1 is heated to 25 DEG C～50 DEG C；
Step 3, polyacrylamide, aliphatic amine polyoxyethylene ether, sodium hydroxide and sodium carbonate by weighing in step 1 are together Add in the pure water that temperature is 25 DEG C～50 DEG C that step 2 processes, after stirring, obtain protein fibre ore deposit in situ Change dyestuff in dyeing and separate used additives XFL with fiber.
Polyacrylamide uses nonionic, anion, cation or amphoteric polyacrylamide；Aliphatic amine polyoxyethylene ether Using coco amine polyoxyethylene ether or tallow amine polyoxyethylene ether, wherein oxygen ethylene unit number is 2～20.
Dyestuff in protein fibre mineralising dyeing in situ is utilized to separate used additives with fiber to protein fibre mineralising in situ In dyeing, dyestuff carries out the method separated with fiber, as it is shown in figure 1, specifically implement according to following steps:
Step 1, fiber to be contaminated or textile to be contaminated are placed in dyeing installation, and in dyeing installation, add dyeing use Water, keeps dye bath circulation, specifically implements according to following steps:
Step 1.1, fiber to be contaminated or textile to be contaminated are placed in dyeing installation；
Step 1.2, after step 1.1, adding temperature in dyeing installation is the dyeing soft water of 25 DEG C～35 DEG C, is added The dyeing soft water added is 7～11:1 with the mass ratio of fiber to be contaminated or textile to be contaminated, and keeps dye bath fully to circulate.
The dyeing installation used in step 1 is stock dyeing machine, top dyeing machine, yarn package dyeing machine, bundle dyeing Machine, garment dyeing machine, dye jigger, overflow dyeing machine or air flow dyeing machine.
The fiber to be contaminated or the textile to be contaminated that use in step 1 are wool fiber, cashmere fibres, camel wool fiber, yak Down Fiber, mohair yarn fiber, Alpaca fiber, rabbit fur fibre, fox Down Fiber, silk fiber and by above-mentioned fibre spinning Any one in the fabric of yarn and weaving.
Step 2, after step 1, according to general natural protein fibre colouring method treat dye fiber or treat dye weaving Product carry out Colour Difference, and dyeing does not discharge dyeing residual liquid after terminating.
Step 3, dyestuff in protein fibre in situ mineralising dyeing is utilized to separate used additives XFL, native protein with fiber Stock-dye after treatment aid XBM and natural protein fibre dyeing after treatment aid XYM is to the fibre after dye residual bath and dyeing Dimension or textile carry out mineralising in situ and process, and specifically implement according to following steps:
Step 3.1, residual for the dyeing in step 2 bath is cooled to 70 DEG C～90 DEG C, and is incubated at a temperature of this；
Step 3.2, first weigh dyestuff in protein fibre in situ mineralising dyeing and separate used additives XFL, protein with fiber In fiber mineralising dyeing in situ, dyestuff separates the consumption of used additives XFL with fiber is 0.001%owf～50%owf；
Then with fiber, dyestuff in the protein fibre weighed in situ mineralising dyeing is separated used additives XFL to add to through step In the residual bath of dyeing after rapid 3.1 process, and under the temperature conditions of 70 DEG C～90 DEG C, soak cycles 1min～50min；
Step 3.3, first weigh natural protein fibre dyeing after treatment aid XBM, natural protein fibre dyeing after locate The consumption of reason auxiliary agent XBM is 0.001%owf～8%owf；
Then the natural protein fibre weighed dyeing after treatment aid XBM is added to dye after step 3.2 processes In the residual bath of color, and under the temperature conditions of 70 DEG C～90 DEG C, soak cycles 1min～5min；
Step 3.4, first weigh natural protein fibre dyeing after treatment aid XYM, natural protein fibre dyeing after locate The consumption of reason auxiliary agent XYM is 0.001%owf～30%owf；
Then the natural protein fibre weighed dyeing after treatment aid XYM is added to dye after step 3.3 processes In the residual bath of color, and under the temperature conditions of 70 DEG C～90 DEG C, soak cycles 1min～50min, it is finally completed residual bath of dyeing Mineralising processes.
Natural protein fibre dyeing after treatment aid XBM in step 3.3 and the natural protein fibre in step 3.4 After treatment aid XYM is in Application No. in dyeing: 201510107510.3, invention entitled: natural protein fibre is in situ Disclosed in mineralising water-saving and emission-reducing dyeing post-processing approach and auxiliary agent.
Step 4, residual for the dyeing after step 3 mineralising processes bath is stored, as follow-up dyeing with water, and will be after dyeing Fiber or textile carry out being dehydrated, drying, finally realize dyestuff in protein fibre in situ mineralising dyeing and separate with fiber.
Embodiment 1
In protein fibre mineralising dyeing in situ, dyestuff separates used additives XFL, according to mass percent by following with fiber Raw material is prepared from:
Polyacrylamide 1%, aliphatic amine polyoxyethylene ether 3%, sodium hydroxide 5%, sodium carbonate 2%, pure water 89%, with The content summation of upper component is 100%；
In protein fibre mineralising dyeing in situ, dyestuff separates the preparation method of used additives with fiber, specific as follows:
Following raw material is weighed respectively according to mass percent:
Polyacrylamide 1%, aliphatic amine polyoxyethylene ether 3%, sodium hydroxide 5%, sodium carbonate 2%, pure water 89%, with The content summation of upper component is 100%；
The pure water weighed is heated to 40 DEG C；
Adding the polyacrylamide weighed, aliphatic amine polyoxyethylene ether, sodium hydroxide and sodium carbonate to temperature together is In the pure water of 40 DEG C, after stirring, obtain dyestuff in protein fibre mineralising dyeing in situ and separate used additives with fiber XFL；
Dyestuff in protein fibre mineralising dyeing in situ is utilized to separate used additives with fiber to protein fibre mineralising in situ In dyeing, dyestuff carries out the method separated with fiber, specific as follows:
Wool top is inserted top dyeing machine；The dyeing soft water that temperature is 25 DEG C, institute is added in top dyeing machine The dyeing soft water added is 9:1 with the mass ratio of wool top, opens top dyeing machine, keeps dye bath fully to circulate；
According to general natural protein fibre colouring method, wool top is carried out Colour Difference, method particularly includes: to Dye bath adds Abegal B 2.0g/l, acetic acid 4.0%owf and Lanasol CE dyestuff 6.5%owf, to dye bath by 1.0 DEG C/heating rate of min heats up, and carries out being incubated 90min under the temperature conditions of 98 DEG C；Dyeing does not discharge dye after terminating Color residual liquid；
Residual for dyeing bath is cooled to 80 DEG C, and is incubated at a temperature of this；Weigh in protein fibre mineralising dyeing in situ and contaminate Material separates used additives XFL with fiber, and in protein fibre mineralising dyeing in situ, dyestuff separates the consumption of used additives XFL and is with fiber 30%owf, and dyestuff in the protein fibre weighed in situ mineralising dyeing is separated used additives XFL with fiber add temperature to and be In the residual bath of dyeing of 80 DEG C, and under the temperature conditions of 80 DEG C, soak cycles 35min；After weighing natural protein fibre dyeing Processing auxiliary agent XBM, the consumption of natural protein fibre dyeing after treatment aid XBM is 5%owf, and the native protein that will weigh Matter stock-dye after treatment aid XBM is also added to dye in residual bath, continues under the temperature conditions of 80 DEG C, soak cycles 5min；Weigh natural protein fibre dyeing after treatment aid XYM, the use of natural protein fibre dyeing after treatment aid XYM Amount is 6%owf, and is again added to dye in residual bath by the natural protein fibre weighed dyeing after treatment aid XYM, and in Under the temperature conditions of 80 DEG C, soak cycles 40min, it is finally completed the mineralising to residual bath of dyeing and processes；
Residual for dyeing after mineralising processes bath is stored, as follow-up dyeing with water, and by the wool top after dyeing Carry out being dehydrated, drying, finally realize dyestuff in protein fibre mineralising dyeing in situ and separate with fiber.
Embodiment 2
In protein fibre mineralising dyeing in situ, dyestuff separates used additives XFL, according to mass percent by following with fiber Raw material is prepared from:
Polyacrylamide 2%, aliphatic amine polyoxyethylene ether 8%, sodium hydroxide 9%, sodium carbonate 6%, pure water 75%, with The content summation of upper component is 100%；
In protein fibre mineralising dyeing in situ, dyestuff separates the preparation method of used additives with fiber, specific as follows:
Following raw material is weighed respectively according to mass percent:
Polyacrylamide 2%, aliphatic amine polyoxyethylene ether 8%, sodium hydroxide 9%, sodium carbonate 6%, pure water 75%, with The content summation of upper component is 100%；
The pure water weighed is heated to 45 DEG C；
Adding the polyacrylamide weighed, aliphatic amine polyoxyethylene ether, sodium hydroxide and sodium carbonate to temperature together is In the pure water of 45 DEG C, after stirring, obtain dyestuff in protein fibre mineralising dyeing in situ and separate used additives with fiber XFL；
Dyestuff in protein fibre mineralising dyeing in situ is utilized to separate used additives with fiber to protein fibre mineralising in situ In dyeing, dyestuff carries out the method separated with fiber, specific as follows:
Cashmere loose fiber is inserted stock dyeing machine；In stock dyeing machine, add the dyeing that temperature is 30 DEG C use Soft water, the dyeing soft water added is 10:1 with the mass ratio of cashmere loose fiber, opens stock dyeing machine, keeps dye bath Fully circulation；
According to general natural protein fibre colouring method, cashmere loose fiber is carried out Colour Difference, concrete grammar For: add Abegal B 2.0g/l, acetic acid 2.5%owf and Lanasol dyestuff 3.5%owf, to dye bath by 0.8 DEG C/min Heating rate heat up, and carry out under the temperature conditions of 95 DEG C be incubated 40min, dyeing terminate after do not discharge dyeing residual Liquid；
Residual for dyeing bath is cooled to 70 DEG C, and is incubated at a temperature of this；Weigh in protein fibre mineralising dyeing in situ and contaminate Material separates used additives XFL with fiber, and in protein fibre mineralising dyeing in situ, dyestuff separates the consumption of used additives XFL and is with fiber 40%owf, and the auxiliary agent XFL weighed is added in the residual bath of dyeing that temperature is 70 DEG C, and under the temperature conditions of 70 DEG C, protect Temperature circulation 40min；Weigh natural protein fibre dyeing after treatment aid XBM, natural protein fibre dyeing after treatment aid The consumption of XBM is 3%owf, and the natural protein fibre weighed dyeing after treatment aid XBM is also added to residual bath of dyeing In, continue under the temperature conditions of 70 DEG C, soak cycles 4min；Weigh natural protein fibre dyeing after treatment aid XYM, sky So the consumption of protein fibre dyeing after treatment aid XYM is 8%owf, and locates after the natural protein fibre dyeing that will weigh Reason auxiliary agent XYM is again added to dye in residual bath, and under the temperature conditions of 70 DEG C, soak cycles 45min, it is finally completed dye The mineralising of the residual bath of color processes；
Residual for dyeing after mineralising processes bath is stored, as follow-up dyeing with water, and the cashmere after dyeing is dissipated Fiber carries out being dehydrated, drying, and finally realizes dyestuff in protein fibre mineralising dyeing in situ and separates with fiber.
Embodiment 3
In protein fibre mineralising dyeing in situ, dyestuff separates used additives XFL, according to mass percent by following with fiber Raw material is prepared from:
Aliphatic amine polyoxyethylene ether 15%, sodium hydroxide 10%, pure water 75%, the content summation of above component is 100%；
In protein fibre mineralising dyeing in situ, dyestuff separates the preparation method of used additives with fiber, specific as follows:
Following raw material is weighed respectively according to mass percent:
Aliphatic amine polyoxyethylene ether 15%, sodium hydroxide 10%, pure water 75%, the content summation of above component is 100%；
The pure water weighed is heated to 35 DEG C；
The aliphatic amine polyoxyethylene ether weighed is added to together with sodium hydroxide in the pure water that temperature is 35 DEG C, stirring After Jun Yun, obtain dyestuff in protein fibre mineralising dyeing in situ and separate used additives XFL with fiber；
Dyestuff in protein fibre mineralising dyeing in situ is utilized to separate used additives with fiber to protein fibre mineralising in situ In dyeing, dyestuff carries out the method separated with fiber, specific as follows:
Loose wool fiber is inserted stock dyeing machine；Adding temperature in stock dyeing machine is that the dyeing of 33 DEG C is with soft Water, the dyeing soft water added is 8:1 with the mass ratio of cashmere loose fiber, opens stock dyeing machine, keeps dye bath to fill Divide circulation；
According to general natural protein fibre colouring method, loose wool fiber is carried out Colour Difference, method particularly includes: Add Abegal B 2.0g/l, acetic acid 2.0%owf and reactive dye for wool 6.5%owf, to dye bath by 1.0 DEG C/min's Heating rate heats up, and carries out being incubated 80min under the temperature conditions of 98 DEG C, and dyeing does not discharge dyeing residual liquid after terminating；
Residual for dyeing bath is cooled to 85 DEG C, and is incubated at a temperature of this；Weigh in protein fibre mineralising dyeing in situ and contaminate Material separates used additives XFL with fiber, and in protein fibre mineralising dyeing in situ, dyestuff separates the consumption of used additives XFL and is with fiber 18%owf, and the auxiliary agent XFL weighed is added in the residual bath of dyeing that temperature is 85 DEG C, and under the temperature conditions of 85 DEG C, protect Temperature circulation 35min；Weigh natural protein fibre dyeing after treatment aid XBM, natural protein fibre dyeing after treatment aid The consumption of XBM is 4%owf, and the natural protein fibre weighed dyeing after treatment aid XBM is also added to residual bath of dyeing In, continue under the temperature conditions of 85 DEG C, soak cycles 5min；Weigh natural protein fibre dyeing after treatment aid XYM, sky So the consumption of protein fibre dyeing after treatment aid XYM is 7%owf, and locates after the natural protein fibre dyeing that will weigh Reason auxiliary agent XYM is again added to dye in residual bath, and under the temperature conditions of 85 DEG C, soak cycles 35min, it is finally completed dye The mineralising of the residual bath of color processes；
Residual for dyeing after mineralising processes bath is stored, as follow-up dyeing with water, and the Pilus Caprae seu Ovis after dyeing is dissipated fibre Dimension carries out being dehydrated, drying, and finally realizes dyestuff in protein fibre mineralising dyeing in situ and separates with fiber.
Embodiment 4
In protein fibre mineralising dyeing in situ, dyestuff separates used additives XFL, according to mass percent by following with fiber Raw material is prepared from:
Polyacrylamide 3%, sodium carbonate 10%, pure water 87%, the content summation of above component is 100%；
In protein fibre mineralising dyeing in situ, dyestuff separates the preparation method of used additives with fiber, specific as follows:
Following raw material is weighed respectively according to mass percent:
Polyacrylamide 3%, sodium carbonate 10%, pure water 87%, the content summation of above component is 100%；
The pure water weighed is heated to 30 DEG C；
The aliphatic amine polyoxyethylene ether weighed is added to together with sodium hydroxide in the pure water that temperature is 30 DEG C, stirring After Jun Yun, obtain dyestuff in protein fibre mineralising dyeing in situ and separate used additives XFL with fiber；
Dyestuff in protein fibre mineralising dyeing in situ is utilized to separate used additives with fiber to protein fibre mineralising in situ In dyeing, dyestuff carries out the method separated with fiber, specific as follows:
Goat nap sliver is inserted top dyeing machine；The dyeing soft water that temperature is 33 DEG C, institute is added in top dyeing machine The dyeing soft water added is 11:1 with the mass ratio of goat nap sliver, opens top dyeing machine, keeps dye bath fully to circulate；
According to general natural protein fibre colouring method, goat nap sliver is carried out Colour Difference, method particularly includes: add Enter Abegal B 2.0g/l, acetic acid 2.5%owf and reactive dye for wool 5.5%owf, to dye bath by the liter of 1.0 DEG C/min Temperature speed heats up, and carries out being incubated 80min under the temperature conditions of 95 DEG C, and dyeing does not discharge dyeing residual liquid after terminating；
Residual for dyeing bath is cooled to 90 DEG C, and is incubated at a temperature of this；Weigh in protein fibre mineralising dyeing in situ and contaminate Material separates used additives XFL with fiber, and in protein fibre mineralising dyeing in situ, dyestuff separates the consumption of used additives XFL and is with fiber 50%owf, and the auxiliary agent XFL weighed is added in the residual bath of dyeing that temperature is 90 DEG C, and under the temperature conditions of 90 DEG C, protect Temperature circulation 15min；Weigh natural protein fibre dyeing after treatment aid XBM, natural protein fibre dyeing after treatment aid The consumption of XBM is 2.5%owf, and the natural protein fibre weighed dyeing after treatment aid XBM is also added to residual bath of dyeing In, continue under the temperature conditions of 90 DEG C, soak cycles 3min；Weigh natural protein fibre dyeing after treatment aid XYM, sky So the consumption of protein fibre dyeing after treatment aid XYM is 9%owf, and locates after the natural protein fibre dyeing that will weigh Reason auxiliary agent XYM is again added to dye in residual bath, and under the temperature conditions of 90 DEG C, soak cycles 45min, it is finally completed dye The mineralising of the residual bath of color processes；
Residual for dyeing after mineralising processes bath is stored, as follow-up dyeing with water, and by the goat nap sliver after dyeing Carry out being dehydrated, drying, finally realize dyestuff in protein fibre mineralising dyeing in situ and separate with fiber.
Embodiment 5
In protein fibre mineralising dyeing in situ, dyestuff separates used additives XFL, according to mass percent by following with fiber Raw material is prepared from:
Sodium hydroxide 10%, pure water 90%, the content summation of above component is 100%；
In protein fibre mineralising dyeing in situ, dyestuff separates the preparation method of used additives with fiber, specific as follows:
Following raw material is weighed respectively according to mass percent:
Sodium hydroxide 10%, pure water 90%, the content summation of above component is 100%；
The pure water weighed is heated to 28 DEG C；
The aliphatic amine polyoxyethylene ether weighed is added to together with sodium hydroxide in the pure water that temperature is 28 DEG C, stirring After Jun Yun, obtain dyestuff in protein fibre mineralising dyeing in situ and separate used additives XFL with fiber；
Dyestuff in protein fibre mineralising dyeing in situ is utilized to separate used additives with fiber to protein fibre mineralising in situ In dyeing, dyestuff carries out the method separated with fiber, specific as follows:
Loose wool fiber is inserted stock dyeing machine；Adding temperature in stock dyeing machine is that the dyeing of 30 DEG C is with soft Water, the dyeing soft water added is 7:1 with the mass ratio of goat nap sliver, opens stock dyeing machine, keeps dye bath fully to follow Ring；
According to general natural protein fibre colouring method, goat nap sliver is carried out Colour Difference, method particularly includes: add Enter Abegal B 2.0g/l, acetic acid 3.0%owf and reactive dye for wool 6.5%owf, to dye bath by the liter of 1.0 DEG C/min Temperature speed heats up, and carries out being incubated 80min under the temperature conditions of 98 DEG C, and dyeing does not discharge dyeing residual liquid after terminating；
Residual for dyeing bath is cooled to 85 DEG C, and is incubated at a temperature of this；Weigh in protein fibre mineralising dyeing in situ and contaminate Material separates used additives XFL with fiber, and in protein fibre mineralising dyeing in situ, dyestuff separates the consumption of used additives XFL and is with fiber 18%owf, and the auxiliary agent XFL weighed is added in the residual bath of dyeing that temperature is 85 DEG C, and under the temperature conditions of 85 DEG C, protect Temperature circulation 35min；Weigh natural protein fibre dyeing after treatment aid XBM, natural protein fibre dyeing after treatment aid The consumption of XBM is 2.8%owf, and the natural protein fibre weighed dyeing after treatment aid XBM is also added to residual bath of dyeing In, continue under the temperature conditions of 85 DEG C, soak cycles 5min；Weigh natural protein fibre dyeing after treatment aid XYM, sky So the consumption of protein fibre dyeing after treatment aid XYM is 3%owf, and locates after the natural protein fibre dyeing that will weigh Reason auxiliary agent XYM is again added to dye in residual bath, and under the temperature conditions of 85 DEG C, soak cycles 40min, it is finally completed dye The mineralising of the residual bath of color processes；
Residual for dyeing after mineralising processes bath is stored, as follow-up dyeing with water, and the Pilus Caprae seu Ovis after dyeing is dissipated fibre Dimension carries out being dehydrated, drying, and finally realizes dyestuff in protein fibre mineralising dyeing in situ and separates with fiber.
In the mineralising dyeing in situ of invention protein fibre, dyestuff separates used additives and application with fiber, can not only Making Colour Difference avoid follow-up soaping and washing processing, the residual bath of dyeing after original position mineralising processes can also re-apply in follow-up Colour Difference, make being greatly decreased with water and pollutant emission of whole Colour Difference.

Claims (9)

1. in protein fibre mineralising dyeing in situ, dyestuff separates used additives XFL with fiber, it is characterised in that according to percent mass Ratio is prepared from the following materials:
Polyacrylamide 0～5%, aliphatic amine polyoxyethylene ether 0～10%, sodium hydroxide 0.01%～10%, sodium carbonate 0%～ 10%, pure water 65%～99.99%, the content summation of above component is 100%.
In protein fibre the most according to claim 1 mineralising dyeing in situ, dyestuff separates used additives XFL with fiber, and it is special Levying and be, described polyacrylamide uses nonionic, anion, cation or amphoteric polyacrylamide；
Described aliphatic amine polyoxyethylene ether uses coco amine polyoxyethylene ether or tallow amine polyoxyethylene ether, wherein oxygen ethylene unit Number is 2～20.
3. in a protein fibre as claimed in claim 1 mineralising dyeing in situ, dyestuff separates used additives XFL's with fiber Preparation method, it is characterised in that specifically implement according to following steps:
Step 1, weigh following raw material respectively according to mass percent:
Polyacrylamide 0～5%, aliphatic amine polyoxyethylene ether 0～10%, sodium hydroxide 0.01%～10%, sodium carbonate 0%～ 10%, pure water 65%～99.99%, the content summation of above component is 100%；
Step 2, the pure water weighed in step 1 is heated to 25 DEG C～50 DEG C；
Step 3, the polyacrylamide weighed in step 1, aliphatic amine polyoxyethylene ether, sodium hydroxide and sodium carbonate are added together In the pure water that the temperature processed through step 2 is 25 DEG C～50 DEG C, after stirring, obtain protein fibre mineralising dye in situ In color, dyestuff separates used additives XFL with fiber.
In protein fibre the most according to claim 3 mineralising dyeing in situ, dyestuff separates the system of used additives XFL with fiber Preparation Method, it is characterised in that described polyacrylamide uses nonionic, anion, cation or amphoteric polyacrylamide；
Described aliphatic amine polyoxyethylene ether uses coco amine polyoxyethylene ether or tallow amine polyoxyethylene ether, wherein oxygen ethylene unit Number is 2～20.
5. utilize dyestuff in the mineralising dyeing in situ of the protein fibre in claim 1 or 2 to separate used additives to albumen with fiber The method that in the mineralising dyeing in situ of matter fiber, dyestuff carries out separating with fiber, it is characterised in that specifically implement according to following steps:
Step 1, fiber to be contaminated or textile to be contaminated are placed in dyeing installation, and in dyeing installation, add dyeing water, protect Hold dye bath circulation；
Step 2, after step 1, according to general natural protein fibre colouring method treat dye fiber or textile to be contaminated enter Row Colour Difference, dyeing does not discharge dyeing residual liquid after terminating；
Step 3, dyestuff in protein fibre in situ mineralising dyeing is utilized to separate used additives XFL, natural protein fibre with fiber Dyeing after treatment aid XBM and natural protein fibre dyeing after treatment aid XYM to dye residual bath and dyeing after fiber or Textile carries out mineralising in situ and processes；
Step 4, residual for the dyeing after step 3 mineralising processes bath is stored, as follow-up dyeing with water, and by the fibre after dyeing Dimension or textile carry out being dehydrated, drying, and finally realize dyestuff in protein fibre mineralising dyeing in situ and separate with fiber.
The most according to claim 5 dyestuff in protein fibre in situ mineralising dyeing is utilized to separate used additives to egg with fiber The method that in white matter fiber in situ mineralising dyeing, dyestuff carries out separating with fiber, it is characterised in that described step 1 specifically according to Lower step is implemented:
Step 1.1, fiber to be contaminated or textile to be contaminated are placed in dyeing installation；
Step 1.2, after step 1.1, adding temperature in dyeing installation is the dyeing soft water of 25 DEG C～35 DEG C, is added Dyeing soft water is 7～11:1 with the mass ratio of fiber to be contaminated or textile to be contaminated, and keeps dye bath fully to circulate.
The most according to claim 6 dyestuff in protein fibre in situ mineralising dyeing is utilized to separate used additives to egg with fiber The method that in white matter fiber mineralising dyeing in situ, dyestuff carries out separating with fiber, it is characterised in that the dye used in described step 1 Color equipment is stock dyeing machine, top dyeing machine, yarn package dyeing machine, hank-dyeing machine, garment dyeing machine, dye jigger, overflows Stream staining machine or air flow dyeing machine.
The most according to claim 6 dyestuff in protein fibre in situ mineralising dyeing is utilized to separate used additives to egg with fiber The method that in white matter fiber mineralising dyeing in situ, dyestuff carries out separating with fiber, it is characterised in that use in described step 1 treats Dye fiber or textile to be contaminated are wool fiber, cashmere fibres, camel wool fiber, yakwool fiber, mohair yarn fiber, alpaca fibre Dimension, rabbit fur fibre, fox Down Fiber, silk fiber and by the yarn of above-mentioned fibre spinning and the fabric of weaving Any one.
The most according to claim 5 dyestuff in protein fibre in situ mineralising dyeing is utilized to separate used additives to egg with fiber The method that in white matter fiber in situ mineralising dyeing, dyestuff carries out separating with fiber, it is characterised in that described step 3 specifically according to Lower step is implemented:
Step 3.1, residual for the dyeing in step 2 bath is cooled to 70 DEG C～90 DEG C, and is incubated at a temperature of this；
Step 3.2, first weigh dyestuff in protein fibre in situ mineralising dyeing and separate used additives XFL, protein fibre with fiber In mineralising dyeing, dyestuff separates the consumption of used additives XFL with fiber in situ is 0.001%owf～50%owf；
Then with fiber, dyestuff in the protein fibre weighed in situ mineralising dyeing is separated used additives XFL to add to through step In the residual bath of dyeing after 3.1 process, and under the temperature conditions of 70 DEG C～90 DEG C, soak cycles 1min～50min；
Step 3.3, first weigh natural protein fibre dyeing after treatment aid XBM, natural protein fibre dyeing post processing help The consumption of agent XBM is 0.001%owf～8%owf；
Then the natural protein fibre weighed dyeing after treatment aid XBM is added to dyeing after step 3.2 processes residual In bath, and under the temperature conditions of 70 DEG C～90 DEG C, soak cycles 1min～5min；
Step 3.4, first weigh natural protein fibre dyeing after treatment aid XYM, natural protein fibre dyeing post processing help The consumption of agent XYM is 0.001%owf～30%owf；
Then the natural protein fibre weighed dyeing after treatment aid XYM is added to dyeing after step 3.3 processes residual In bath, and under the temperature conditions of 70 DEG C～90 DEG C, soak cycles 1min～50min, it is finally completed the mineralising to residual bath of dyeing Process.
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CN110761092A (en) * 2019-11-05 2020-02-07 西安工程大学 In-situ mineralization dyeing method for natural protein fiber high-color-fastness dye
CN115142279A (en) * 2022-07-29 2022-10-04 内蒙古鄂尔多斯资源股份有限公司 Fiber energy-saving dyeing method

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CN104711872A (en) * 2015-03-11 2015-06-17 西安工程大学 In-situ mineralization and water-saving emission-reduction dyeing post-treatment method for natural protein fibers and auxiliary agents
CN105347455A (en) * 2015-10-28 2016-02-24 杨洋 Printing and dyeing wastewater purification powder and preparation method thereof

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CN104088174A (en) * 2014-06-18 2014-10-08 桐乡市濮院毛针织技术服务中心 Wool-fabric dye-fixing agent
CN104711872A (en) * 2015-03-11 2015-06-17 西安工程大学 In-situ mineralization and water-saving emission-reduction dyeing post-treatment method for natural protein fibers and auxiliary agents
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CN106638055A (en) * 2016-12-28 2017-05-10 江苏申洲毛纺有限公司 In-situ mineralization auxiliary agents and after backwashing method used in dyed slubbing after backwashing
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CN110761092A (en) * 2019-11-05 2020-02-07 西安工程大学 In-situ mineralization dyeing method for natural protein fiber high-color-fastness dye
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