CN106117942B - A kind of construction material of heat-insulation and heat-preservation and preparation method thereof - Google Patents

A kind of construction material of heat-insulation and heat-preservation and preparation method thereof Download PDF

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CN106117942B
CN106117942B CN201610505289.1A CN201610505289A CN106117942B CN 106117942 B CN106117942 B CN 106117942B CN 201610505289 A CN201610505289 A CN 201610505289A CN 106117942 B CN106117942 B CN 106117942B
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heat
sodium tetraborate
ethylparaben
diatomite
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CN106117942A (en
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石鸿娟
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Hebei Zhibo insulation materials manufacturing Co. Ltd.
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Taizhou Venture Capital Environmental Protection & Technology Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/04—Ingredients characterised by their shape and organic or inorganic ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/346—Clay
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/38—Boron-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/098—Metal salts of carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/02—Fibres or whiskers
    • C08K7/04—Fibres or whiskers inorganic
    • C08K7/06—Elements
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/265—Calcium, strontium or barium carbonate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/38—Boron-containing compounds
    • C08K2003/387—Borates

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Abstract

The invention discloses a kind of construction materials of heat-insulation and heat-preservation and preparation method thereof, are prepared by the raw material of following parts by weight：Carbon fiber, 20~30 parts；Powdered whiting, 15~25 parts；Diatomite, 15~25 parts；Titanium dioxide, 10~20 parts；Calcium oxide, 5~10 parts；Magnesium stearate, 1~3 part；Dioctyl phthalate, 7~9 parts；Diethylene glycol (DEG), 6~8 parts；Polyacrylamide, 1~3 part；Calgon, 4~6 parts；Totally 5~7 parts of ethylparaben and sodium tetraborate, ethylparaben and sodium tetraborate weight part ratio are 4~6:1.Construction material provided by the invention has excellent thermal and insulating performance.And preparation method is simple, and manufacture is at low cost, and suit large area to popularize use, low-carbon environment-friendly.

Description

A kind of construction material of heat-insulation and heat-preservation and preparation method thereof
Technical field
The invention belongs to building material fields, and in particular to a kind of construction material of heat-insulation and heat-preservation and preparation method thereof.
Background technology
Building energy consumption proportion in the entire energy consumption of the mankind is very high, therefore building energy conservation is to solve energy problem of China Fundamental way, and the most directly effective method of building energy conservation is to use heat preserving and insulating material.Rationally using heat preservation in building Heat-barrier material, it is possible to reduce the dosage of construction material improves the industrialization degree of construction, accompanied by substantial power saving.Originally The heat preserving and insulating material used under construction, being mainly based upon improves comfortable for living degree, nowadays has been transferred to above energy saving.Make It is of great significance with building heat preservation heat-barrier material to the residential level of alleviating energy crisis and the raising people.
Good heat preserving and insulating material is developed and promoted and applied, not only contributes to improve the insulation of building sides Property, improve indoor living environment, while can be energy saving, the use cost of building is reduced, is had a very important significance.
The content of the invention
It is an object of the invention to provide a kind of construction materials of heat-insulation and heat-preservation and preparation method thereof.
The above-mentioned purpose of the present invention is achieved by following technical solution：
A kind of construction material of heat-insulation and heat-preservation, is prepared by the raw material of following parts by weight：Carbon fiber, 20~30 parts； Powdered whiting, 15~25 parts；Diatomite, 15~25 parts；Titanium dioxide, 10~20 parts；Calcium oxide, 5~10 parts；Magnesium stearate, 1 ~3 parts；Dioctyl phthalate, 7~9 parts；Diethylene glycol (DEG), 6~8 parts；Polyacrylamide, 1~3 part；Calgon, 4~6 Part；Totally 5~7 parts of ethylparaben and sodium tetraborate, ethylparaben and sodium tetraborate weight part ratio are 4~6:1.
Further, the construction material of the heat-insulation and heat-preservation is prepared by the raw material of following parts by weight：Carbon fiber, 25 parts；Powdered whiting, 20 parts；Diatomite, 20 parts；Titanium dioxide, 15 parts；Calcium oxide, 7 parts；Magnesium stearate, 2 parts；O-phthalic Dioctyl phthalate, 8 parts；Diethylene glycol (DEG), 7 parts；Polyacrylamide, 2 parts；Calgon, 5 parts；Ethylparaben and sodium tetraborate totally 6 Part, ethylparaben and sodium tetraborate weight part ratio are 5:1.
Further, the construction material of the heat-insulation and heat-preservation is prepared by the raw material of following parts by weight：Carbon fiber, 20 parts；Powdered whiting, 15 parts；Diatomite, 15 parts；Titanium dioxide, 10 parts；Calcium oxide, 5 parts；Magnesium stearate, 1 part；O-phthalic Dioctyl phthalate, 7 parts；Diethylene glycol (DEG), 6 parts；Polyacrylamide, 1 part；Calgon, 4 parts；Ethylparaben and sodium tetraborate totally 5 Part, ethylparaben and sodium tetraborate weight part ratio are 4:1.
Further, the construction material of the heat-insulation and heat-preservation is prepared by the raw material of following parts by weight：Carbon fiber, 30 parts；Powdered whiting, 25 parts；Diatomite, 25 parts；Titanium dioxide, 20 parts；Calcium oxide, 10 parts；Magnesium stearate, 3 parts；Adjacent benzene two Formic acid dioctyl ester, 9 parts；Diethylene glycol (DEG), 8 parts；Polyacrylamide, 3 parts；Calgon, 6 parts；Ethylparaben and sodium tetraborate Totally 7 parts, ethylparaben and sodium tetraborate weight part ratio are 6:1.
The preparation method of above-mentioned construction material, includes the following steps：
Step S1 mixes carbon fiber, powdered whiting, diatomite, titanium dioxide, calcium oxide and magnesium stearate, in 120~ 140 DEG C are stirred 20~30 minutes；
It is pungent to add phthalic acid two when temperature is reduced to 80~90 DEG C, in the mixture prepared to step S1 by step S2 Ester, diethylene glycol (DEG), polyacrylamide, calgon, ethylparaben and sodium tetraborate, when 80~90 DEG C of stirrings 1~2 are small；
Step S3, cooling are got product.
Advantages of the present invention：
Construction material provided by the invention has excellent thermal and insulating performance, and preparation method is simple, at low cost.
Specific embodiment
The essentiality content further illustrated the present invention with reference to embodiment, but present invention protection model is not limited with this It encloses.Although being explained in detail with reference to preferred embodiment to the present invention, it will be understood by those of ordinary skill in the art that, it can be right Technical scheme is modified or replaced equivalently, without departing from the spirit and scope of technical solution of the present invention.
Embodiment 1：The preparation of construction material
Parts by weight of raw materials ratio：
Carbon fiber, 25 parts；Powdered whiting, 20 parts；Diatomite, 20 parts；Titanium dioxide, 15 parts；Calcium oxide, 7 parts；Stearic acid Magnesium, 2 parts；Dioctyl phthalate, 8 parts；Diethylene glycol (DEG), 7 parts；Polyacrylamide, 2 parts；Calgon, 5 parts；Nipalgin second Totally 6 parts of ester and sodium tetraborate, ethylparaben and sodium tetraborate weight part ratio are 5:1.
Preparation method：
Step S1 mixes carbon fiber, powdered whiting, diatomite, titanium dioxide, calcium oxide and magnesium stearate, in 120~ 140 DEG C are stirred 20~30 minutes；
It is pungent to add phthalic acid two when temperature is reduced to 80~90 DEG C, in the mixture prepared to step S1 by step S2 Ester, diethylene glycol (DEG), polyacrylamide, calgon, ethylparaben and sodium tetraborate, when 80~90 DEG C of stirrings 1~2 are small；
Step S3, cooling are got product.
Embodiment 2：The preparation of construction material
Parts by weight of raw materials ratio：
Carbon fiber, 20 parts；Powdered whiting, 15 parts；Diatomite, 15 parts；Titanium dioxide, 10 parts；Calcium oxide, 5 parts；Stearic acid Magnesium, 1 part；Dioctyl phthalate, 7 parts；Diethylene glycol (DEG), 6 parts；Polyacrylamide, 1 part；Calgon, 4 parts；Nipalgin second Totally 5 parts of ester and sodium tetraborate, ethylparaben and sodium tetraborate weight part ratio are 4:1.
Preparation method：
Step S1 mixes carbon fiber, powdered whiting, diatomite, titanium dioxide, calcium oxide and magnesium stearate, in 120~ 140 DEG C are stirred 20~30 minutes；
It is pungent to add phthalic acid two when temperature is reduced to 80~90 DEG C, in the mixture prepared to step S1 by step S2 Ester, diethylene glycol (DEG), polyacrylamide, calgon, ethylparaben and sodium tetraborate, when 80~90 DEG C of stirrings 1~2 are small；
Step S3, cooling are got product.
Embodiment 3：The preparation of construction material
Parts by weight of raw materials ratio：
Carbon fiber, 30 parts；Powdered whiting, 25 parts；Diatomite, 25 parts；Titanium dioxide, 20 parts；Calcium oxide, 10 parts；It is stearic Sour magnesium, 3 parts；Dioctyl phthalate, 9 parts；Diethylene glycol (DEG), 8 parts；Polyacrylamide, 3 parts；Calgon, 6 parts；Nipalgin Totally 7 parts of ethyl ester and sodium tetraborate, ethylparaben and sodium tetraborate weight part ratio are 6:1.
Preparation method：
Step S1 mixes carbon fiber, powdered whiting, diatomite, titanium dioxide, calcium oxide and magnesium stearate, in 120~ 140 DEG C are stirred 20~30 minutes；
It is pungent to add phthalic acid two when temperature is reduced to 80~90 DEG C, in the mixture prepared to step S1 by step S2 Ester, diethylene glycol (DEG), polyacrylamide, calgon, ethylparaben and sodium tetraborate, when 80~90 DEG C of stirrings 1~2 are small；
Step S3, cooling are got product.
Embodiment 4：The preparation of construction material
Parts by weight of raw materials ratio：
Carbon fiber, 25 parts；Powdered whiting, 20 parts；Diatomite, 20 parts；Titanium dioxide, 15 parts；Calcium oxide, 7 parts；Stearic acid Magnesium, 2 parts；Dioctyl phthalate, 8 parts；Diethylene glycol (DEG), 7 parts；Polyacrylamide, 2 parts；Calgon, 5 parts；Nipalgin second Totally 6 parts of ester and sodium tetraborate, ethylparaben and sodium tetraborate weight part ratio are 4:1.
Preparation method：
Step S1 mixes carbon fiber, powdered whiting, diatomite, titanium dioxide, calcium oxide and magnesium stearate, in 120~ 140 DEG C are stirred 20~30 minutes；
It is pungent to add phthalic acid two when temperature is reduced to 80~90 DEG C, in the mixture prepared to step S1 by step S2 Ester, diethylene glycol (DEG), polyacrylamide, calgon, ethylparaben and sodium tetraborate, when 80~90 DEG C of stirrings 1~2 are small；
Step S3, cooling are got product.
Embodiment 5：The preparation of construction material
Parts by weight of raw materials ratio：
Carbon fiber, 25 parts；Powdered whiting, 20 parts；Diatomite, 20 parts；Titanium dioxide, 15 parts；Calcium oxide, 7 parts；Stearic acid Magnesium, 2 parts；Dioctyl phthalate, 8 parts；Diethylene glycol (DEG), 7 parts；Polyacrylamide, 2 parts；Calgon, 5 parts；Nipalgin second Totally 6 parts of ester and sodium tetraborate, ethylparaben and sodium tetraborate weight part ratio are 6:1.
Preparation method：
Step S1 mixes carbon fiber, powdered whiting, diatomite, titanium dioxide, calcium oxide and magnesium stearate, in 120~ 140 DEG C are stirred 20~30 minutes；
It is pungent to add phthalic acid two when temperature is reduced to 80~90 DEG C, in the mixture prepared to step S1 by step S2 Ester, diethylene glycol (DEG), polyacrylamide, calgon, ethylparaben and sodium tetraborate, when 80~90 DEG C of stirrings 1~2 are small；
Step S3, cooling are got product.
Embodiment 6：Comparative example, ethylparaben and sodium tetraborate weight part ratio are 3:1
Parts by weight of raw materials ratio：
Carbon fiber, 25 parts；Powdered whiting, 20 parts；Diatomite, 20 parts；Titanium dioxide, 15 parts；Calcium oxide, 7 parts；Stearic acid Magnesium, 2 parts；Dioctyl phthalate, 8 parts；Diethylene glycol (DEG), 7 parts；Polyacrylamide, 2 parts；Calgon, 5 parts；Nipalgin second Totally 6 parts of ester and sodium tetraborate, ethylparaben and sodium tetraborate weight part ratio are 3:1.
Preparation method：
Step S1 mixes carbon fiber, powdered whiting, diatomite, titanium dioxide, calcium oxide and magnesium stearate, in 120~ 140 DEG C are stirred 20~30 minutes；
It is pungent to add phthalic acid two when temperature is reduced to 80~90 DEG C, in the mixture prepared to step S1 by step S2 Ester, diethylene glycol (DEG), polyacrylamide, calgon, ethylparaben and sodium tetraborate, when 80~90 DEG C of stirrings 1~2 are small；
Step S3, cooling are got product.
Embodiment 7：Comparative example, ethylparaben and sodium tetraborate weight part ratio are 7:1
Parts by weight of raw materials ratio：
Carbon fiber, 25 parts；Powdered whiting, 20 parts；Diatomite, 20 parts；Titanium dioxide, 15 parts；Calcium oxide, 7 parts；Stearic acid Magnesium, 2 parts；Dioctyl phthalate, 8 parts；Diethylene glycol (DEG), 7 parts；Polyacrylamide, 2 parts；Calgon, 5 parts；Nipalgin second Totally 6 parts of ester and sodium tetraborate, ethylparaben and sodium tetraborate weight part ratio are 7:1.
Preparation method：
Step S1 mixes carbon fiber, powdered whiting, diatomite, titanium dioxide, calcium oxide and magnesium stearate, in 120~ 140 DEG C are stirred 20~30 minutes；
It is pungent to add phthalic acid two when temperature is reduced to 80~90 DEG C, in the mixture prepared to step S1 by step S2 Ester, diethylene glycol (DEG), polyacrylamide, calgon, ethylparaben and sodium tetraborate, when 80~90 DEG C of stirrings 1~2 are small；
Step S3, cooling are got product.
Embodiment 8：Effect example
The performance of construction material prepared by testing example 1~7 respectively.
Wherein, Measured Results of Thermal Conductivity result is as follows：
Thermal conductivity factor ((W/mk))
Embodiment 1 0.032
Embodiment 4 0.037
Embodiment 5 0.035
Embodiment 6 0.093
Embodiment 7 0.098
Embodiment 2,3 measurement results and embodiment 4,5 are basically identical.
The above results show that construction material provided by the invention has excellent thermal and insulating performance.And preparation method Simply, manufacture is at low cost, and suit large area to popularize use, low-carbon environment-friendly.
The effect of above-described embodiment indicates that the essentiality content of the present invention, but the protection of the present invention is not limited with this Scope.It will be understood by those of ordinary skill in the art that technical scheme can be modified or replaced equivalently, Without departing from the essence and protection domain of technical solution of the present invention.

Claims (5)

1. a kind of construction material of heat-insulation and heat-preservation, which is characterized in that be prepared by the raw material of following parts by weight：Carbon fiber, 20~30 parts；Powdered whiting, 15~25 parts；Diatomite, 15~25 parts；Titanium dioxide, 10~20 parts；Calcium oxide, 5~10 parts； Magnesium stearate, 1~3 part；Dioctyl phthalate, 7~9 parts；Diethylene glycol (DEG), 6~8 parts；Polyacrylamide, 1~3 part；Six partially Sodium phosphate, 4~6 parts；Totally 5~7 parts of ethylparaben and sodium tetraborate, ethylparaben and sodium tetraborate weight part ratio for 4~ 6:1。
2. the construction material of heat-insulation and heat-preservation according to claim 1, which is characterized in that pass through the raw material system of following parts by weight It is standby to form：Carbon fiber, 25 parts；Powdered whiting, 20 parts；Diatomite, 20 parts；Titanium dioxide, 15 parts；Calcium oxide, 7 parts；Stearic acid Magnesium, 2 parts；Dioctyl phthalate, 8 parts；Diethylene glycol (DEG), 7 parts；Polyacrylamide, 2 parts；Calgon, 5 parts；Nipalgin second Totally 6 parts of ester and sodium tetraborate, ethylparaben and sodium tetraborate weight part ratio are 5:1.
3. the construction material of heat-insulation and heat-preservation according to claim 1, which is characterized in that pass through the raw material system of following parts by weight It is standby to form：Carbon fiber, 20 parts；Powdered whiting, 15 parts；Diatomite, 15 parts；Titanium dioxide, 10 parts；Calcium oxide, 5 parts；Stearic acid Magnesium, 1 part；Dioctyl phthalate, 7 parts；Diethylene glycol (DEG), 6 parts；Polyacrylamide, 1 part；Calgon, 4 parts；Nipalgin second Totally 5 parts of ester and sodium tetraborate, ethylparaben and sodium tetraborate weight part ratio are 4:1.
4. the construction material of heat-insulation and heat-preservation according to claim 1, which is characterized in that pass through the raw material system of following parts by weight It is standby to form：Carbon fiber, 30 parts；Powdered whiting, 25 parts；Diatomite, 25 parts；Titanium dioxide, 20 parts；Calcium oxide, 10 parts；Stearic acid Magnesium, 3 parts；Dioctyl phthalate, 9 parts；Diethylene glycol (DEG), 8 parts；Polyacrylamide, 3 parts；Calgon, 6 parts；Nipalgin second Totally 7 parts of ester and sodium tetraborate, ethylparaben and sodium tetraborate weight part ratio are 6:1.
5. the preparation method of any construction material of Claims 1 to 4, which is characterized in that include the following steps：
Step S1 mixes carbon fiber, powdered whiting, diatomite, titanium dioxide, calcium oxide and magnesium stearate, in 120~140 DEG C stirring 20~30 minutes；
When temperature is reduced to 80~90 DEG C, dioctyl phthalate, two are added in the mixture prepared to step S1 by step S2 Glycol, polyacrylamide, calgon, ethylparaben and sodium tetraborate, when 80~90 DEG C of stirrings 1~2 are small；
Step S3, cooling are got product.
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014080564A (en) * 2012-01-30 2014-05-08 Toray Ind Inc Carbon fiber-reinforced flame-retardant polycarbonate-based resin composition, and molded article
CN103130478A (en) * 2013-02-28 2013-06-05 四川省长源建筑工程有限责任公司 Environmentally-friendly building heat insulation material
JP2015131952A (en) * 2013-12-13 2015-07-23 王子ホールディングス株式会社 Sheet for fiber-reinforced plastic molding
CN105622032A (en) * 2014-10-31 2016-06-01 胡耀青 Thermal insulation building material
CN104402511A (en) * 2014-11-27 2015-03-11 太仓顺如成建筑材料有限公司 Composite wall of fiber cement board
CN104496519A (en) * 2014-11-27 2015-04-08 太仓顺如成建筑材料有限公司 Heat insulation building material
CN105131524A (en) * 2015-08-31 2015-12-09 苏州凯欧曼新材料科技有限公司 High-tenacity environment-friendly building material and preparing method thereof
CN105542324A (en) * 2016-01-21 2016-05-04 上海馨来建筑装饰设计有限公司 Thermal insulation building material and preparation method thereof

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