CN106117917A - Synergistic flame retardant type cable material formula - Google Patents

Synergistic flame retardant type cable material formula Download PDF

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Publication number
CN106117917A
CN106117917A CN201610735469.9A CN201610735469A CN106117917A CN 106117917 A CN106117917 A CN 106117917A CN 201610735469 A CN201610735469 A CN 201610735469A CN 106117917 A CN106117917 A CN 106117917A
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CN
China
Prior art keywords
parts
flame retardant
synergistic flame
fire retardant
type cable
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610735469.9A
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Chinese (zh)
Inventor
朱树范
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
DEQING BAISHENG PLASTIC Co Ltd
Original Assignee
DEQING BAISHENG PLASTIC Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by DEQING BAISHENG PLASTIC Co Ltd filed Critical DEQING BAISHENG PLASTIC Co Ltd
Priority to CN201610735469.9A priority Critical patent/CN106117917A/en
Publication of CN106117917A publication Critical patent/CN106117917A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06Homopolymers or copolymers of vinyl chloride
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/443Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from vinylhalogenides or other halogenoethylenic compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/202Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The present invention relates to CABLE MATERIALS technical field, specifically, relate to a kind of synergistic flame retardant type cable material formula.It includes following components by weight: Corvic 40~65 parts, environment-friendly plasticizer 10~30 parts, filler 5~15 parts, stabilizer 3~7 parts, processing aid 2~10 parts, synergistic flame retardant 4~40 parts.The CABLE MATERIALS prepared according to inventive formulation can possess preferably fire resistance.

Description

Synergistic flame retardant type cable material formula
Technical field
The present invention relates to CABLE MATERIALS technical field, specifically, relate to a kind of synergistic flame retardant type cable material formula.
Background technology
Electric wire, cable insulation and sheath plastics are commonly called as CABLE MATERIALS, which includes the multiple product such as rubber, plastics, nylon Kind.CABLE MATERIALS manufacturing enterprise is with electric wire, cable manufacturing enterprise as user, as long as live wire, cabling requirements just have CABLE MATERIALS Market.Electric wire, cable product nearly all need insulating barrier mouth in addition to the bare wire product such as steel-cored aluminium strand, electromagnetic wire.At present I State-owned electric wire manufacturing enterprise nearly ten thousand, has again upgrading urban and rural power grids, development of the West Regions and the upgrading of communications facility large area to change Make electric wire, the great demand of cable product, thus from the point of view of a period of time, CABLE MATERIALS has market development widely in China Prospect.
Owing to if electric wire, cable consequence on fire are hardly imaginable, therefore whether CABLE MATERIALS possesses preferably fire resistance pole It is important.Existing CABLE MATERIALS does not the most possess good flame retardant effect.
Summary of the invention
The invention provides a kind of synergistic flame retardant type cable material formula, it can overcome certain or some of prior art to lack Fall into.
Synergistic flame retardant type cable material formula according to the present invention, it includes following components by weight: polrvinyl chloride Resin 40~65 parts, environment-friendly plasticizer 10~30 parts, filler 5~15 parts, stabilizer 3~7 parts, processing aid 2~10 parts, synergistic Fire retardant 4~40 parts.
In the present invention, Corvic is the base material of CABLE MATERIALS, environment-friendly plasticizer can preferably improve processing characteristics, Reduce processing temperature and the cryogenic property of CABLE MATERIALS can be improved, stabilizer can preferably improve CABLE MATERIALS heat stability, Ageing resistace, improve processing characteristics and the cable glossiness produced, filler can increase CABLE MATERIALS intensity and can Reducing cost, processing aid can improve processing characteristics, reduces processing cost and improve yield rate, and synergistic flame retardant can be with Lower cost carries out bigger lifting to the fire resistance of CABLE MATERIALS.
As preferably, also include following components by weight, lubricant 0.1~2 parts, antioxidant 0.5~2 parts.Profit Lubrication prescription can preferably reduce add man-hour equipment produce shearing heat thus improve yield rate, antioxidant can preferably improve sheath The ageing resistace of material.
As preferably, synergistic flame retardant includes following components by weight, fire retardant A1~10 parts, fire retardant B2~ 10 parts, fire retardant C1~10 parts.Fire retardant A, fire retardant B and fire retardant C can carry out fire-retardant by synergistic such that it is able to improve fire-retardant Performance, reduction cost of material.
As preferably, fire retardant A uses chlorine-containing flame retardant, and fire retardant B uses the fire retardant in antimony, and fire retardant C uses brominated Fire retardant.
As preferably, environment-friendly plasticizer uses epoxy plasticiser.
As preferably, filler uses glass fibre.
As preferably, processing aid is resinae toughener.
Present invention also offers a kind of synergistic flame retardant formula prepared for CABLE MATERIALS, it can overcome prior art Certain or some defect.
According to the synergistic flame retardant formula prepared for CABLE MATERIALS of the present invention, it includes following group by weight Point: fire retardant A1~10 parts, fire retardant B2~10 parts, fire retardant C1~10 parts.
As preferably, fire retardant A uses chlorine-containing flame retardant, and fire retardant B uses the fire retardant in antimony, and fire retardant C uses brominated Fire retardant.
As preferably, fire retardant A uses hexacholorocyclopentadiene, and fire retardant B uses antimony oxide, and fire retardant C uses bromine Change polystyrene.
The synergistic flame retardant formula prepared for CABLE MATERIALS of the present invention, it is possible to obtain higher with relatively low production cost Flame retardant effect.
Detailed description of the invention
For further appreciating that present disclosure, the present invention is described in detail in conjunction with the embodiments.It should be appreciated that it is real Execute example be only the present invention explained and and non-limiting.
Embodiment 1
Present embodiments providing a kind of synergistic flame retardant formula, it includes following components by weight: fire retardant A10 Part, fire retardant B2 part, fire retardant C10 part.
In the present embodiment, fire retardant A uses chlorine-containing flame retardant, and fire retardant B uses the fire retardant in antimony, and fire retardant C uses and contains Bromine flame retardant.Wherein, fire retardant A uses hexacholorocyclopentadiene, and fire retardant B uses antimony oxide, and fire retardant C uses bromination to gather Styrene.
Embodiment 2
The present embodiment also provides a kind of synergistic flame retardant formula, and it is with the difference of embodiment 1: fire retardant A1 part, Fire retardant B10 part, fire retardant C1 part.
Embodiment 3
The present embodiment also provides a kind of synergistic flame retardant formula, and it is with the difference of embodiment 1: fire retardant A5 part, Fire retardant B4 part, fire retardant C7 part.
Embodiment 4
Present embodiments providing a kind of synergistic flame retardant type cable material formula, it includes following components by weight: poly- Vinyl chloride resin 55 parts, environment-friendly plasticizer 15 parts, filler 10 parts, stabilizer 5 parts, processing aid 6 parts, synergistic flame retardant 25 parts, Lubricant 1 part, 1.5 parts of antioxidant.
In the present embodiment, the formula of synergistic flame retardant uses the synergistic flame retardant formula in embodiment 1.
In the present embodiment, environment-friendly plasticizer uses epoxy plasticiser, and filler uses glass fibre, and processing aid is resin Class toughener, remaining component such as lubricant, antioxidant etc. are existing conventional raw material.
Embodiment 5
The present embodiment also provides a kind of synergistic flame retardant type cable material formula, and it is with the difference of embodiment 4: polychlorostyrene second Olefine resin 65 parts, environment-friendly plasticizer 30 parts, filler 5 parts, stabilizer 3 parts, processing aid 2 parts, synergistic flame retardant 40 parts, lubricant 2 parts, 0.5 part of antioxidant;The formula of synergistic flame retardant uses the synergistic flame retardant formula in embodiment 2.
Embodiment 6
The present embodiment also provides a kind of synergistic flame retardant type cable material formula, and it is with the difference of embodiment 4: polychlorostyrene second Olefine resin 40 parts, environment-friendly plasticizer 10 parts, filler 15 parts, stabilizer 7 parts, processing aid 10 parts, synergistic flame retardant 4 parts, lubrication Agent 0.1 part, 2 parts of antioxidant;The formula of synergistic flame retardant uses the synergistic flame retardant formula in embodiment 3.
Below being schematically described the present invention and embodiment thereof, this description is the most restricted.So, if Those of ordinary skill in the art is enlightened by it, in the case of without departing from the invention objective, without creatively designing Go out the scheme similar to this technical scheme and embodiment, protection scope of the present invention all should be belonged to.

Claims (7)

1. synergistic flame retardant type cable material formula, it includes following components by weight: Corvic 40~65 parts, ring Protect plasticizer 10~30 parts, filler 5~15 parts, stabilizer 3~7 parts, processing aid 2~10 parts, synergistic flame retardant 4~40 parts.
Synergistic flame retardant type cable material formula the most according to claim 1, it is characterised in that: also include by weight with Lower component, lubricant 0.1~2 parts, antioxidant 0.5~2 parts.
Synergistic flame retardant type cable material formula the most according to claim 1, it is characterised in that: synergistic flame retardant includes by weight The following components of part meter, fire retardant A1~10 parts, fire retardant B2~10 parts, fire retardant C1~10 parts.
Synergistic flame retardant type cable material formula the most according to claim 2, it is characterised in that: fire retardant A uses chloride fire-retardant Agent, fire retardant B uses the fire retardant in antimony, and fire retardant C uses brominated flame-retardant.
Synergistic flame retardant type cable material formula the most according to claim 1, it is characterised in that: environment-friendly plasticizer uses epoxies Plasticizer.
Synergistic flame retardant type cable material formula the most according to claim 1, it is characterised in that: filler uses glass fibre.
Synergistic flame retardant type cable material formula the most according to claim 1, it is characterised in that: processing aid is that resinae is toughness reinforcing Agent.
CN201610735469.9A 2016-08-26 2016-08-26 Synergistic flame retardant type cable material formula Pending CN106117917A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610735469.9A CN106117917A (en) 2016-08-26 2016-08-26 Synergistic flame retardant type cable material formula

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106633519A (en) * 2016-12-16 2017-05-10 安徽建筑大学 Combustible non-dripping polyvinyl chloride plastic
CN106832656A (en) * 2016-12-28 2017-06-13 滁州品之达电器科技有限公司 A kind of Special material for flame-retardant polyvinyl chloride switch holder and preparation method thereof
CN107674347A (en) * 2017-11-15 2018-02-09 湖州荣吴索道运输服务有限公司 A kind of preparation method of high temperature resistant weather-resistance flame-retardant cable jacket material
CN107987414A (en) * 2017-11-22 2018-05-04 新宇电缆集团股份有限公司 A kind of PVC cable insulations CABLE MATERIALS
CN108034159A (en) * 2017-11-22 2018-05-15 新宇电缆集团股份有限公司 A kind of industry fire-resistant cable material
CN112194864A (en) * 2020-09-29 2021-01-08 富通集团(天津)超导技术应用有限公司 Superconducting cable sheath material and preparation method thereof
CN113861586A (en) * 2021-09-18 2021-12-31 上海起帆电线电缆技术有限公司 Noctilucent PVC insulating material and BV wire

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101475724A (en) * 2008-12-04 2009-07-08 王一群 Highly flame-retardant environment friendly sheath material and co-axial cable composed thereof
CN104031329A (en) * 2014-04-30 2014-09-10 中广核三角洲(江苏)塑化有限公司 High-flame-retardation low-smoke composite cable material for boosting communication light cables, and preparation technology thereof
CN104817788A (en) * 2015-05-07 2015-08-05 邹文君 High-flame-retarding low-smoke modified polyvinyl ethylene cable material and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101475724A (en) * 2008-12-04 2009-07-08 王一群 Highly flame-retardant environment friendly sheath material and co-axial cable composed thereof
CN104031329A (en) * 2014-04-30 2014-09-10 中广核三角洲(江苏)塑化有限公司 High-flame-retardation low-smoke composite cable material for boosting communication light cables, and preparation technology thereof
CN104817788A (en) * 2015-05-07 2015-08-05 邹文君 High-flame-retarding low-smoke modified polyvinyl ethylene cable material and preparation method thereof

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106633519A (en) * 2016-12-16 2017-05-10 安徽建筑大学 Combustible non-dripping polyvinyl chloride plastic
CN106832656A (en) * 2016-12-28 2017-06-13 滁州品之达电器科技有限公司 A kind of Special material for flame-retardant polyvinyl chloride switch holder and preparation method thereof
CN107674347A (en) * 2017-11-15 2018-02-09 湖州荣吴索道运输服务有限公司 A kind of preparation method of high temperature resistant weather-resistance flame-retardant cable jacket material
CN107987414A (en) * 2017-11-22 2018-05-04 新宇电缆集团股份有限公司 A kind of PVC cable insulations CABLE MATERIALS
CN108034159A (en) * 2017-11-22 2018-05-15 新宇电缆集团股份有限公司 A kind of industry fire-resistant cable material
CN112194864A (en) * 2020-09-29 2021-01-08 富通集团(天津)超导技术应用有限公司 Superconducting cable sheath material and preparation method thereof
CN113861586A (en) * 2021-09-18 2021-12-31 上海起帆电线电缆技术有限公司 Noctilucent PVC insulating material and BV wire

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Application publication date: 20161116

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