CN106117788A - A kind of frosted electrification line thermoplastic elastomer (TPE) and preparation method thereof - Google Patents
A kind of frosted electrification line thermoplastic elastomer (TPE) and preparation method thereof Download PDFInfo
- Publication number
- CN106117788A CN106117788A CN201610510563.4A CN201610510563A CN106117788A CN 106117788 A CN106117788 A CN 106117788A CN 201610510563 A CN201610510563 A CN 201610510563A CN 106117788 A CN106117788 A CN 106117788A
- Authority
- CN
- China
- Prior art keywords
- frosted
- thermoplastic elastomer
- tpe
- electrification line
- good
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
- C08L53/025—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/22—Halogen free composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to technical field of polymer materials, specifically disclose a kind of frosted electrification line thermoplastic elastomer (TPE), percentage includes: SBC 15 35%, dynamic perduren TPV10 35%, poly terephthalic acid Isosorbide-5-Nitrae cyclohexanedimethanoester ester PCT 10 25%, polyolefin 6 18%, plasticizer 6 14%, polymethyl methacrylate 5 10%, polyacetals vinyl acetate 5 10%, fire retardant 3 8%, auxiliary agent 1 3%.The invention also discloses aforementioned frosted electrification line process for preparation of thermoplastic elastomer.Compared with prior art, the present invention has features such as frosted finish effect is good, resilience is good, good, the good hand touch of low cost, outward appearance, and hardness is high, intensity is good, the excellent combination property such as durability, shock resistance, stretch-resistance.
Description
Technical field
The present invention relates to technical field of polymer materials, particularly to a kind of frosted electrification line thermoplastic elastomer (TPE) and
Preparation method.
Background technology
Along with the rise of i Phone, the demand for frosted sense charger for mobile phone line is increasing, but i Phone
Charger line is typically to use thermoplastic polyester elastomer TPEE material, and its shortcoming is that hardness is high, price is high, tearing strength is poor, holds
Easily inhaling ash etc., thermoplastic elastomer (TPE) (TPE) has the features such as good processability, feel exquisiteness, hardness range width, fire resistance are good
Being widely used in field of consumer electronics, such as data wire, earphone cord etc., but thermoplastic elastomer (TPE) (TPE) is used as charger for mobile phone
Line outward appearance is the most smooth, has not yet to see and reported the thermoplastic elastomer (TPE) with frosted sense.
It addition, the frosted sense of current material is often through adding the auxiliary agent such as frosting agent, frosting powder, particulate matter is at matrix resin
In poor dispersion, uneven, the problems such as frosted finish effect is the best.
Summary of the invention
It is an object of the invention to, for the above-mentioned deficiency of prior art, it is provided that a kind of frosted electrification line thermoplastic elastomehc
Gonosome, has the features such as frosted finish effect is good, resilience is good, good, the good hand touch of low cost, outward appearance, and hardness, intensity are good, durability, anti-
The excellent combination properties such as impact, stretch-resistance.
The present invention be the technical scheme is that by reaching above-mentioned purpose
A kind of frosted electrification line thermoplastic elastomer (TPE), percentage, including: SBC
15-35%, dynamic perduren TPV 10-35%, poly terephthalic acid-1,4 cyclohexane dimethanol ester PCT 10-25%, poly-
Alkene 6-18%, plasticizer 6-14%, polymethyl methacrylate 5-10%, polyacetals vinyl acetate 5-10%, fire retardant 3-
8%, auxiliary agent 1-3%.
Preferably, described SBC is styrene-ethylene-butylene-styrene block copolymer
Any one in SEBS, styrene ethylene-propylene-styrene type block copolymer SEPS.
Preferably, described polyolefin is linear low density polyethylene.
Preferably, described plasticizer is paraffinic base white mineral oil.
Preferably, described fire retardant be melamine cyanurate with organic hypophosphites by any mass ratio compounding and
Become.
Preferably, described auxiliary agent includes antioxidant, and antioxidant is antioxidant 1076 with irgasfos 168 by any mass ratio
Compound and form.
Styrene-ethylene-butylene-styrene block copolymer SEBS, is with polystyrene as end segment, with polybutadiene
The linear three embedding copolymers that ethylene-butene copolymer is middle spring block that hydrogenation obtains.SEBS does not contains unsaturated double-bond, tool
There are good stability and resistance to ag(e)ing, both there is plasticity, there is again high resiliency, will not produce anaphylaxis, thermostability, resistance to
Compression is excellent.
Dynamic perduren TPV refers to the analog thermoplastic elastomer obtained by rubber plastic blend and dynamic vulcanization, TPV
Not only possessed the elasticity of crosslinking rubber but also there is the characteristic of the easy machine-shaping of thermoplastic, with PP as hard segment, EPDM be soft chain
During Duan Jinhang melt blending, add and make its cross-linking agent vulcanized, utilize the strength that the mechanical height such as banbury, screw machine is sheared,
Make the particle of the EPDM crosslinking rubber of complete cure, be well dispersed among PP matrix with micron order size (less than 1 micron) and obtain
The thermoplastic elastomer arrived, have compression resistant morphotropism, high tenacity, high resilience, resistance to environment, resistance to ag(e)ing, mobility high,
The advantages such as shrinkage factor is little, surface class height, good hand touch.
Linear low density polyethylene is linearly nontoxic, tasteless, the milky white granules of odorless, have higher softening temperature and
Melt temperature, has the advantages such as intensity is big, good toughness, rigidity are big, heat-resisting, tolerance to cold is good, also has good environmental stress resistance and open
Fragility, the performance such as impact strength, tear-resistant intensity, and can acid and alkali resistance, organic solvent etc..
Poly terephthalic acid-1,4 cyclohexane dimethanol ester PCT is a kind of thermoplastic polyester material high temperature resistant, hemicrystalline
Material.
Compared with prior art, the outward appearance of the frosted electrification line thermoplastic elastomer (TPE) of the present invention is good, and frosted finish effect is good, adopts
It is main body with SBC, dynamic perduren TPV, poly terephthalic acid-1,4 cyclohexane dimethanol ester PCT
Resin, the polymethyl methacrylate of interpolation, the compatibility between polyacetals vinyl acetate and matrix resin form the most not
Granular it is uniformly distributed in matrix resin, and forms frosted structure at finished surface, simultaneously by the polyolefin added, plasticising
Between agent, fire retardant, auxiliary agent and matrix resin and polymethyl methacrylate, polyacetals vinyl acetate, each molecule segment can be mutual
Tangle, " can be locked " together each other by covalent bond effect, enhance blended effect, it is to avoid component migration, scattered, from
And having ensured that elastomer cable material produces more preferable frosted feel or frosted cloudy surface sense, surface frosted particle effect is good, has refreshing
Sliding frosted feel.
Present invention also offers a kind of frosted electrification line process for preparation of thermoplastic elastomer, comprise the following steps:
S1: weigh each raw material components according to percentage by weight: SBC, dynamic perduren TPV, poly-
P-phthalic acid-1,4 cyclohexane dimethanol ester PCT, polyolefin, plasticizer, polymethyl methacrylate, polyacetals vinyl acetate,
Fire retardant, auxiliary agent；
S2: by SBC, dynamic perduren TPV, poly terephthalic acid-1,4 cyclohexane dimethanol
Ester PCT, polyolefin, plasticizer, polymethyl methacrylate, polyacetals vinyl acetate, fire retardant, auxiliary agent add in mixer, high
Stop stirring after speed stirring 10-30min, obtain mixture；
S3: pour the mixture into and carry out melt kneading in double screw extruder and extrude, extruder die head is extruded
Melted output carries out water cooling, packs, get product after pelletize.
Preferably, extrusion temperature is 180-230 DEG C, and screw speed is 300-600rpm.
Compared with prior art, the frosted electrification line process for preparation of thermoplastic elastomer of the present invention, technique is accurate, letter
Clean, product quality is high, and its frosted electrification line prepared has frosted feel with thermoplastic elastomers, is applicable to charger for mobile phone
Electric wire, can compare favourably with i Phone charger line, and price is low, excellent combination property, halogen-free environmental, fully meets mobile phone charging
The requirement of device line.
Above-mentioned is the general introduction of inventive technique scheme, and below in conjunction with detailed description of the invention, the present invention will be further described.
Detailed description of the invention:
In order to make the purpose of the present invention and technical scheme and advantage clearer, make specifically below in conjunction with embodiment
Bright.Should be appreciated that specific embodiment described herein, only in order to explain the present invention, is not intended to limit the present invention.
Embodiment 1: the frosted electrification line thermoplastic elastomer (TPE) that the present embodiment provides, percentage, including:
Wherein, fire retardant is that melamine cyanurate is compounding with organic hypophosphites 1:1 in mass ratio to be formed, You Jici
Phosphate can be organic hypophosphorous acid zinc salt；Antioxidant is that antioxidant 1076 is compounding with irgasfos 168 2:1 in mass ratio to be formed.
The present embodiment also provides for above-mentioned frosted electrification line process for preparation of thermoplastic elastomer, comprises the following steps:
S1: weigh each raw material components according to percentage by weight；
S2: by SBC, dynamic perduren TPV, poly terephthalic acid-1,4 cyclohexane dimethanol
Ester PCT, polyolefin, plasticizer, polymethyl methacrylate, polyacetals vinyl acetate, fire retardant, auxiliary agent add in mixer, high
Stop stirring after speed stirring 30min, obtain mixture；
S3: pour the mixture into and carry out melt kneading in double screw extruder and extrude, extrusion temperature is 230 DEG C, screw rod
Rotating speed is 600rpm, and the melted output being extruded extruder die head carries out water cooling, packs, get product after pelletize.
Embodiment 2: frosted electrification line thermoplastic elastomer (TPE) that the present embodiment provides and preparation method thereof, itself and embodiment
1 is essentially identical, and difference is: a kind of frosted electrification line thermoplastic elastomer (TPE), percentage, including:
Wherein, to be melamine cyanurate compounding with organic hypophosphites 1:3 in mass ratio forms for fire retardant；Antioxidant
Form for antioxidant 1076 is compounding with irgasfos 168 2:1 in mass ratio.
In its preparation process: mix and blend 10min, extrusion temperature is 220 DEG C, and screw speed is 300rpm.
Other are same as in Example 1, the most burdensome at this.
Embodiment 3: frosted electrification line thermoplastic elastomer (TPE) that the present embodiment provides and preparation method thereof, itself and embodiment
1 is essentially identical, and difference is: a kind of frosted electrification line thermoplastic elastomer (TPE), percentage, including:
Wherein, to be melamine cyanurate compounding with organic hypophosphites 2:1 in mass ratio forms for fire retardant；Antioxidant
Form for antioxidant 1076 is compounding with irgasfos 168 3:1 in mass ratio.
In its preparation process: mix and blend 20min, extrusion temperature is 180 DEG C, and screw speed is 600rpm.
Other are same as in Example 1, the most burdensome at this.
Embodiment 4: frosted electrification line thermoplastic elastomer (TPE) that the present embodiment provides and preparation method thereof, itself and embodiment
1 is essentially identical, and difference is: a kind of frosted electrification line thermoplastic elastomer (TPE), percentage, including:
Wherein, to be melamine cyanurate compounding with organic hypophosphites 1:5 in mass ratio forms for fire retardant；Antioxidant
Form for antioxidant 1076 is compounding with irgasfos 168 4:1 in mass ratio.
In its preparation process: mix and blend 26min, extrusion temperature is 190 DEG C, and screw speed is 450rpm.
Other are same as in Example 1, the most burdensome at this.
Embodiment 5: frosted electrification line thermoplastic elastomer (TPE) that the present embodiment provides and preparation method thereof, itself and embodiment
1 is essentially identical, and difference is: a kind of frosted electrification line thermoplastic elastomer (TPE), percentage, including:
Wherein, to be melamine cyanurate compounding with organic hypophosphites 3:2 in mass ratio forms for fire retardant；Antioxidant
Form for antioxidant 1076 is compounding with irgasfos 168 3:4 in mass ratio.
In its preparation process: mix and blend 17min, extrusion temperature is 200 DEG C, and screw speed is 400rpm.
Other are same as in Example 1, the most burdensome at this.
The performance test results record of above-described embodiment 1-5 refers to table 1, it is known that, the frosted electrification line that the present invention prepares is used
The excellent combination property of thermoplastic elastomer (TPE).
Table 1 is the performance test results of embodiment products obtained therefrom:
Above the present invention is described in detail, its object is to allow those skilled in the art will appreciate that the present invention's
Content is also carried out, but can not limit the scope of the invention with this, and the invention is not restricted to above-described embodiment, all bases
The equivalence that the spirit of the present invention is made changes or modifies, and all should contain within protection scope of the present invention.
Claims (8)
1. a frosted electrification line thermoplastic elastomer (TPE), it is characterised in that percentage, including:
Frosted electrification line thermoplastic elastomer (TPE) the most according to claim 1, it is characterised in that described phenylethylene is embedding
Section copolymer is styrene-ethylene-butylene-styrene block copolymer SEBS, styrene ethylene-propylene-styrene type block
Any one in copolymer SEPS.
Frosted electrification line thermoplastic elastomer (TPE) the most according to claim 1, it is characterised in that described polyolefin is line
Property Low Density Polyethylene.
Frosted electrification line thermoplastic elastomer (TPE) the most according to claim 1, it is characterised in that described plasticizer is stone
Cerul white mineral oil.
Frosted electrification line thermoplastic elastomer (TPE) the most according to claim 1, it is characterised in that described fire retardant is three
Poly cyanamid cyanurate forms by any mass ratio is compounding with organic hypophosphites.
Frosted electrification line thermoplastic elastomer (TPE) the most according to claim 1, it is characterised in that described auxiliary agent includes resisting
Oxygen agent, antioxidant is that antioxidant 1076 forms by any mass ratio is compounding with irgasfos 168.
7. the frosted electrification line process for preparation of thermoplastic elastomer that one of claim 1-6 is described, it is characterised in that
Comprise the following steps:
S1: weigh each raw material components according to percentage by weight: SBC, dynamic perduren TPV, poly-to benzene
Dioctyl phthalate-1,4 cyclohexane dimethanol ester PCT, polyolefin, plasticizer, polymethyl methacrylate, polyacetals vinyl acetate, fire-retardant
Agent, auxiliary agent；
S2: by SBC, dynamic perduren TPV, poly terephthalic acid-1,4 cyclohexane dimethanol ester
PCT, polyolefin, plasticizer, polymethyl methacrylate, polyacetals vinyl acetate, fire retardant, auxiliary agent add in mixer, at a high speed
Stop stirring after stirring 10-30min, obtain mixture；
S3: pour the mixture into and carry out melt kneading in double screw extruder and extrude, that is extruded extruder die head is melted
Output carries out water cooling, packs, get product after pelletize.
Frosted electrification line process for preparation of thermoplastic elastomer the most according to claim 7, it is characterised in that extrusion temperature
Degree is for 180-230 DEG C, and screw speed is 300-600rpm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610510563.4A CN106117788B (en) | 2016-06-30 | 2016-06-30 | A kind of frosted electrification line thermoplastic elastomer (TPE) and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610510563.4A CN106117788B (en) | 2016-06-30 | 2016-06-30 | A kind of frosted electrification line thermoplastic elastomer (TPE) and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106117788A true CN106117788A (en) | 2016-11-16 |
| CN106117788B CN106117788B (en) | 2018-07-31 |
Family
ID=57469093
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610510563.4A Active CN106117788B (en) | 2016-06-30 | 2016-06-30 | A kind of frosted electrification line thermoplastic elastomer (TPE) and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106117788B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107189319A (en) * | 2017-05-16 | 2017-09-22 | 浙江大学 | Electric wire flexible halogen-free flame-retardant thermoplastic elastomer PP Pipe Compound of the full cloudy surface of high frosted and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010126855A2 (en) * | 2009-04-29 | 2010-11-04 | Polyone Corporation | Flame retardant thermoplastic elastomers |
| WO2011062809A1 (en) * | 2009-11-20 | 2011-05-26 | Dow Global Technologies Inc. | Thermoplastic elastomer for cold and wet applications |
| CN102268170A (en) * | 2011-06-09 | 2011-12-07 | 厦门雄基高分子合金股份有限公司 | High performance thermoplastic elastomer and use thereof |
| CN104387715A (en) * | 2014-10-29 | 2015-03-04 | 苏州新区枫盛塑料制品厂 | TPE (thermal plastic elastomer) plastic formula and preparation method thereof |
| CN105623180A (en) * | 2016-01-12 | 2016-06-01 | 安徽中鼎橡塑制品有限公司 | Halogen-free flame retardant thermoplastic elastomer material for electric wires and cables and preparation method thereof |
-
2016
- 2016-06-30 CN CN201610510563.4A patent/CN106117788B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010126855A2 (en) * | 2009-04-29 | 2010-11-04 | Polyone Corporation | Flame retardant thermoplastic elastomers |
| WO2011062809A1 (en) * | 2009-11-20 | 2011-05-26 | Dow Global Technologies Inc. | Thermoplastic elastomer for cold and wet applications |
| CN102268170A (en) * | 2011-06-09 | 2011-12-07 | 厦门雄基高分子合金股份有限公司 | High performance thermoplastic elastomer and use thereof |
| CN104387715A (en) * | 2014-10-29 | 2015-03-04 | 苏州新区枫盛塑料制品厂 | TPE (thermal plastic elastomer) plastic formula and preparation method thereof |
| CN105623180A (en) * | 2016-01-12 | 2016-06-01 | 安徽中鼎橡塑制品有限公司 | Halogen-free flame retardant thermoplastic elastomer material for electric wires and cables and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107189319A (en) * | 2017-05-16 | 2017-09-22 | 浙江大学 | Electric wire flexible halogen-free flame-retardant thermoplastic elastomer PP Pipe Compound of the full cloudy surface of high frosted and preparation method thereof |
| CN107189319B (en) * | 2017-05-16 | 2019-01-15 | 浙江大学 | Wire and cable full cloudy surface flexibility halogen-free flame-retardant thermoplastic elastomer PP Pipe Compound of high frosted and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106117788B (en) | 2018-07-31 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101676327B (en) | Thermoplastic elastomer for sucking with polypropylene material | |
| CN100463942C (en) | Thermoplastic elastomer for injection adhering nylon material | |
| CN103725027A (en) | High-resilience TPE (thermoplastic elastomer) material and preparation method thereof | |
| CN105367987A (en) | Low-emission low-odor thermoplastic elastomer and preparation method therefor | |
| CN111607236B (en) | High-fluidity low-gloss styrene-based thermoplastic elastomer material and preparation method thereof | |
| CN105255092A (en) | SBC thermoplastic elastic material and preparation technology thereof | |
| CN104744825A (en) | Thermoplastic vulcanizate elastomer composition and preparation method thereof | |
| CN103172963B (en) | Thermoplastic elastic material of a kind of high welding strength and preparation method thereof | |
| CN103509239A (en) | Scratch-resistant polypropylene material and preparation method thereof | |
| CN107151356A (en) | The composition for thermoplastic elastomer being made up of elastomer, non-elastomeric polyolefin and polyolefin block copolymer analog thermoplastic elastomer | |
| CN101796127A (en) | Flame retardant thermoplastic elastomers | |
| CN107434913A (en) | A kind of strong bonding PA cover materials of the anti-UV of halogen-free flameproof and preparation method thereof | |
| CN110072930A (en) | Polymer composition | |
| CN109354773A (en) | The nucleating agent application tackiness in the precipitation for reducing PP composite material | |
| CN107646045A (en) | Adjusted by the hardness of combined thermoplastic plastics and the composition for thermoplastic elastomer of thermoplastic elastomer (TPE) | |
| CN104109332A (en) | Antimicrobial thermoplastic elastomer, and preparation method and application thereof | |
| CN105778387B (en) | A kind of 125 DEG C of halogen-free flame retarding elastomer material of thermoplasticity and preparation method thereof | |
| CN103619932A (en) | Epoxidised natural rubber based blend for antistatic footwear application | |
| CN103649193A (en) | Epoxidised natural rubber-based blend with reversible electrical behaviour | |
| CN105542376A (en) | Thermoplastic elastic complex, preparation method thereof, and application thereof in production of automobile bottom guard board | |
| CN112795172B (en) | PVC-coated thermoplastic elastomer composition and preparation method and application thereof | |
| CN107189319A (en) | Electric wire flexible halogen-free flame-retardant thermoplastic elastomer PP Pipe Compound of the full cloudy surface of high frosted and preparation method thereof | |
| CN106117788B (en) | A kind of frosted electrification line thermoplastic elastomer (TPE) and preparation method thereof | |
| CN107541004B (en) | Load-resistant and fatigue-resistant TPE (thermoplastic elastomer) and preparation method thereof | |
| CN112080062A (en) | Graphene multifunctional master batch using elastomer as carrier and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |