CN106115668A - The process for dispersing of a kind of Graphene and graphene composite material - Google Patents
The process for dispersing of a kind of Graphene and graphene composite material Download PDFInfo
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- CN106115668A CN106115668A CN201610445561.1A CN201610445561A CN106115668A CN 106115668 A CN106115668 A CN 106115668A CN 201610445561 A CN201610445561 A CN 201610445561A CN 106115668 A CN106115668 A CN 106115668A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/02—Processes for applying liquids or other fluent materials performed by spraying
- B05D1/12—Applying particulate materials
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
- B22F1/16—Metallic particles coated with a non-metal
Abstract
The invention provides process for dispersing and the graphene composite material of a kind of Graphene, comprise the following steps, make hard material particle be in vibratory liquefaction and irregular movement state, graphene oxide solution is uniformly sprayed at hard material particle surface, obtains homodisperse graphene composite material.The graphene composite material that the present invention provides, including the dispersed compound graphene layer of hard material particle and surface thereof；The particle diameter of described hard material particle is 10～5000 mesh.The process for dispersing that the present invention provides is in existing solution mixing method, Graphene mixes uneven disadvantage in the solution, and the defect that the pollutant that can result in of other mixed and disorderly material introducings such as dispersant are to the negative effect of actual effect, effectively solve the problem that Graphene is easily reunited, ensure that the dispersed of Graphene, preferably play its premium properties, and obtained a kind of graphene composite material, be more widely applied for later stage Graphene and lay the foundation.
Description
Technical field
The invention belongs to material with carbon element technical field, particularly relate to process for dispersing and the Graphene composite wood of a kind of Graphene
Material.
Background technology
Graphene (Graphene) is the new material of a kind of monolayer laminated structure being made up of carbon atom.It is a kind of by carbon
Atom is with the flat film that sp2 hybrid orbital composition hexangle type is honeycomb lattice, the two-dimensional material of only one of which carbon atom thickness.
As the two dimensional crystal of a kind of only one layer of atomic thickness being made up of carbon atom, it be enter in application at present the thinnest
Material and the most tough material, fracture strength taller 200 times than steel, also have the most elastic, stretch range can reach certainly
The 20% of body size；Graphene has huge theoretical specific surface area simultaneously, and physicochemical properties are stable, can be at high working voltage
With keep good structural stability under big electric current fast charging and discharging, meanwhile, Graphene also have excellence electric conductivity, can drop
Low internal resistance, improves the cyclical stability of ultracapacitor；And Graphene is if able to manufacture superminiature transistor, it is used for producing
Following supercomputer.Replacing silicon with Graphene, the speed of service of computer processor will hundreds times soon；It addition, graphite
Alkene is almost fully transparent, only absorbs the light of 2.3%.And the finest and close, even the gas atom of minimum (helium atom)
Also cannot penetrate.These features make it be highly suitable as the raw material of transparent electron product, such as transparent touch display screen, send out
Tabula rasa and solar panel.Having above-mentioned many excellent physical chemical property just because of Graphene, it is at energy storage material,
Environmental project, sensing sensitive aspect is widely used, and is referred to as " dark fund " or " king of new material ", and before potential application
Scape is vast, has the most become global focus and study hotspot.
But in actual applications, Graphene there is also many problems and restraining factors, Graphene is just easily reunited
It is restriction Graphene research and a major obstacle of application.There is stronger model ylid bloom action power each other to make due to Graphene
It can not stable dispersion in a solvent, also easily again reunite after dispersion and be difficult to open together.According to reported literature, numerous studies
By the way of adding different types of dispersant or modification, improve the dispersion effect of Graphene, but Graphene at water or
Other liquid solutions are difficult to ensure that dispersed；And use the mode adding dispersant to improve the degree of scatter of Graphene, though
It is so the main method currently solving scattering problem, but which is readily incorporated other impurity, subsequent result is produced impact；Or
Person becomes graphene roll, it is simply that graphene platelet is rolled up, and is formed and a kind of is similar to carbon between a peacekeeping two dimension
The web-like nano-carbon material of nanotube, its edge non-close, footpath spacing easily regulates and controls, and has higher specific surface area etc.；But also
The performance of Graphene can be affected, limit its application, also can increase processing cost.
Therefore, how to find a kind of can the method for dispersed Graphene, solve the problem that Graphene is easily reunited, become
For the major issue that the downstream application field of Graphene production firm and Graphene is urgently to be resolved hurrily.
Summary of the invention
In view of this, the technical problem to be solved in the present invention is to provide the process for dispersing of a kind of Graphene and Graphene multiple
Condensation material, the process for dispersing of the Graphene that the present invention provides can effective dispersed graphite alkene, the problem solving its easy reunion, for
Later stage Graphene is more widely applied and lays the foundation.
The invention provides the process for dispersing of a kind of Graphene, comprise the following steps:
A) make hard material particle be in vibratory liquefaction and irregular movement state, graphene oxide solution is uniformly sprayed
On hard material particle surface, obtain the composite with homodisperse Graphene.
Preferably, the particle diameter of described hard material particle is 10～5000 mesh；
Described hard material includes metal, nonmetal, alloy, metal-oxide, nonmetal oxide and nonmetallic mineral
In one or more.
Preferably, described hard material includes zinc, ferrum, aluminium alloy, magnesium alloy, copper, sandstone, aluminium oxide, pottery and diatom
One or more in soil.
Preferably, the concentration of described graphene oxide solution is 0.01%～20%；
The solvent of described graphene oxide solution is the one in water, dehydrated alcohol, acetone, dimethylbenzene and n-butyl alcohol or many
Kind.
Preferably, the speed of described sprinkling is 1～100mL/min；
The equipment of described sprinkling is rotary spray gun.
Preferably, the temperature of described vibratory liquefaction is 50～120 DEG C；
The time of described vibratory liquefaction is 0.1～10h；The frequency of described vibratory liquefaction is 5～99Hz.
Preferably, described step A) particularly as follows:
A1) hard material particle is placed in vibrated fluidized bed, makes hard material particle be in vibratory liquefaction and irregular
Kinestate, then it is aided with stirring；
A2) graphene oxide solution is uniformly sprayed at the hard material particle surface of above-mentioned state, obtains dispersed
Graphene composite material.
Preferably, described step A2) particularly as follows:
A21) under conditions of ventilating, graphene oxide solution is uniformly sprayed at the hard material particle table of above-mentioned state
Face；
A22), after stopping spraying, gradually reduce vibratory liquefaction degree, improve ventilation volume, treat the graphite on hard particles surface
Alkene is dried, obtains homodisperse graphene composite material.
The invention provides a kind of graphene composite material, dispersed compound including hard material particle and surface thereof
Graphene layer；
The particle diameter of described hard material particle is 10～5000 mesh.
Preferably, the thickness of described graphene layer is 0.01～10 μm.
The invention provides the process for dispersing of a kind of Graphene, comprise the following steps, make hard material particle be in vibration
Fluidisation and irregular movement state, be uniformly sprayed at graphene oxide solution hard material particle surface, obtain dispersed
Graphene composite material.Compared with prior art, the present invention uses the method for vibratory liquefaction, makes material to be sprayed present and does not advise
Then kinestate, then use the graphene coated powder body of mode of spray coating, the available Graphene hard that can uniformly coat
Granule, the most homodisperse Graphene.The process for dispersing that the present invention provides is in existing solution mixing method, and Graphene is molten
Liquid mixes uneven disadvantage, and the pollutant that other mixed and disorderly material introducings such as dispersant can result in are to actual effect
The defect of negative effect, effectively solve the problem that Graphene is easily reunited, it is possible to ensure the dispersed, more preferably of Graphene
Ground plays its premium properties, and is more widely applied lays the foundation for later stage Graphene.Test result indicate that, the present invention provides
Process for dispersing be capable of Graphene being uniformly distributed on hard particles surface.
Accompanying drawing explanation
Fig. 1 is the transmission electron microscope contrast of the Graphene prepared by the embodiment of the present invention 1/zinc composite and zinc granule-morphology
Figure；
Fig. 2 is the macro morphology comparison diagram of the Graphene/iron composite material prepared by the embodiment of the present invention 2 and iron powder；
Fig. 3 is the macro morphology comparison diagram of the Graphene prepared by the embodiment of the present invention 4/mark sand composite and mark sand.
Detailed description of the invention
In order to be further appreciated by the present invention, below in conjunction with embodiment, the preferred embodiment of the invention is described, but
Should be appreciated that these descriptions are intended merely to further illustrate the features and advantages of the present invention rather than to invention claim
Limit.
The all raw materials of the present invention, are not particularly limited its source, that commercially buy or according to people in the art
Prepared by the conventional method known to Yuan.
The all raw materials of the present invention, are not particularly limited its purity, present invention preferably employs analytical pure or composite neck
The conventional purity that territory uses.
The invention provides the process for dispersing of a kind of Graphene, comprise the following steps:
A) make hard material particle be in vibratory liquefaction and irregular movement state, graphene oxide solution is uniformly sprayed
On hard material particle surface, obtain the composite with homodisperse Graphene.
The specifically chosen of described hard material is not particularly limited by the present invention, with hard well known to those skilled in the art
Material granule, those skilled in the art can select according to practical condition, product requirement and prescription
And adjustment, hard material particle of the present invention preferably includes metal, nonmetal, alloy, metal-oxide, nonmetal oxide
With one or more in nonmetallic mineral, more preferably metal, nonmetal, alloy, metal-oxide, nonmetal oxide or
Nonmetallic mineral, most preferably metal, nonmetal, alloy, metal-oxide or nonmetal oxide；Or specifically preferably include
One or more in zinc, ferrum, aluminium alloy, magnesium alloy, copper, sandstone, aluminium oxide, pottery and kieselguhr, more preferably zinc, ferrum,
Aluminium alloy, magnesium alloy, copper, sandstone, aluminium oxide, pottery or kieselguhr.The present invention is the most special to the particle diameter of described hard material
Limiting, with the particle diameter of hard material particle well known to those skilled in the art, those skilled in the art can be according to reality
The condition of production, product requirement and prescription select and adjust, and the particle diameter of hard material particle of the present invention is preferred
It is 10～5000 mesh, more preferably 100～4500 mesh, more preferably 300～4000 mesh, most preferably 500～3000 mesh.
The present invention uses sprinkling paint-on technique, Graphene, macroscopical or micron-sized hard material particle is combined closely
Together, it is possible to effective solution graphene dispersion problem of non-uniform, preferably play its premium properties, and can also obtain uniformly
The hard particles material of graphene coated material, makes Graphene become a reality the coating of microcosmic hard particles initiatively.
The concentration of described graphene oxide solution is not particularly limited by the present invention, with oxygen well known to those skilled in the art
The concentration of functionalized graphene solution, those skilled in the art can want according to practical condition, product requirement and quality
Asking and select and adjust, the concentration of graphene oxide solution of the present invention is preferably 0.01%～20%, more preferably
0.05%～5%, most preferably 0.1%～1%.The solvent of described graphene oxide solution is not particularly limited by the present invention,
With the Conventional solvents for graphene oxide solution well known to those skilled in the art, those skilled in the art can basis
Practical condition, product requirement and prescription select and adjust, graphene oxide solution of the present invention molten
Agent is preferably one or more in water, dehydrated alcohol, acetone, dimethylbenzene and n-butyl alcohol, more preferably water, dehydrated alcohol, third
Ketone, dimethylbenzene or n-butyl alcohol, more preferably water, dehydrated alcohol, acetone or dimethylbenzene.
The present invention is for preferably to combine closely Graphene and hard particles, and improves the dispersing uniformity of Graphene, institute
State the speed of sprinkling and be preferably 1～100mL/min, more preferably 10～90mL/min, more preferably 30～70mL/min, optimum
Elect 40～60mL/min as；The mode of described sprinkling is not particularly limited by the present invention, and those skilled in the art can be according to reality
The border condition of production, product requirement and prescription select and adjust, can be spray, coat, brush, spary or injection
In one or more, the present invention for improve spray effect, the mode of described sprinkling preferably rotates sprinkling；Setting of described sprinkling
Standby preferably rotary spray gun.
The present invention is for preferably to combine closely Graphene and hard particles, and improves the dispersing uniformity of Graphene, institute
The temperature stating vibratory liquefaction is preferably 50～120 DEG C, more preferably 60～110 DEG C, more preferably 70～100 DEG C, most preferably
80～90 DEG C；The time of described vibratory liquefaction is preferably 0.1～10h, more preferably 1～9h, more preferably 3～7h, most preferably
It is 4～6h；The frequency of described vibratory liquefaction is preferably 5～99Hz, more preferably 10～90Hz, more preferably 30～70Hz,
It is preferably 40～60Hz.The equipment of described vibratory liquefaction is not particularly limited by the present invention, and those skilled in the art can basis
Practical condition, product requirement and prescription select and adjust, and the present invention is for improving homodisperse effect, institute
The equipment stating vibratory liquefaction is preferably vibrated fluidized bed.
The present invention is for preferably to combine closely Graphene and hard particles, and improves the dispersing uniformity of Graphene, institute
State step A) it is particularly preferred as:
A1) hard material particle is placed in vibrated fluidized bed, makes hard material particle be in vibratory liquefaction and irregular
Kinestate, then it is aided with stirring；
A2) graphene oxide solution is uniformly sprayed at the hard material particle surface of above-mentioned state, obtains dispersed
Graphene composite material.
The condition of described stirring is not particularly limited by the present invention, with the condition of stirring well known to those skilled in the art is
Can, those skilled in the art can select according to practical condition, product requirement and prescription and adjust, so that
It is preferred version that hard material particle is in irregular movement state.The present invention is to the technological parameter of above-mentioned concrete steps and behaviour
Make, in addition to consistent with the optimum principle of aforesaid technical scheme and selection, do not have other to limit especially, with those skilled in the art
Known to aforesaid operations and technological parameter, those skilled in the art can according to practical condition, product requirement and
Prescription selects and adjusts.
The present invention is for preferably to combine closely Graphene and hard particles, and improves the dispersing uniformity of Graphene, institute
State step A2) more specifically it is preferably:
A21) under conditions of ventilating, graphene oxide solution is uniformly sprayed at the hard material particle table of above-mentioned state
Face；
A22), after stopping spraying, gradually reduce vibratory liquefaction degree, improve ventilation volume, treat the graphite on hard particles surface
Alkene is dried, obtains homodisperse graphene composite material.
The present invention particularly, under conditions of existing without protective gas, carries out aforesaid operations, thus the production stream simplified
Journey, production equipment and decrease production consume.The process for dispersing technique that the present invention provides is simple, mild condition, safety and environmental protection,
It is more suitable for the big production of technology.The present invention to the technological parameter of above-mentioned concrete steps and operation, except and aforesaid technical scheme
Optimum principle with select consistent outside, do not have other to limit especially, with aforesaid operations well known to those skilled in the art and technique
Parameter, those skilled in the art can select according to practical condition, product requirement and prescription and adjust
Whole.
Present invention also offers a kind of graphene composite material, dispersed compound including hard material particle and surface thereof
Graphene layer.
The particle diameter of hard material particle of the present invention is preferably 10～5000 mesh, and more preferably 100～4500 mesh are more excellent
Elect 300～4000 mesh, most preferably 500～3000 mesh as.The thickness of described graphene layer is not particularly limited by the present invention, this
Skilled person can select according to practical condition, product requirement and prescription and adjust, to realize stone
Ink alkene material is dispersed for preferred version, and the THICKNESS CONTROL of graphene layer of the present invention is in 0.01～10 μm, preferred thickness
Can regulate and control according to the actual requirements.
Above-mentioned steps of the present invention provides process for dispersing and a kind of graphene composite material, the present invention of a kind of Graphene
The method using dither fluidisation, makes hard particles present irregular movement state, then uses the mode rotating sprinkling by stone
Ink alkene powder body is coated in hard particles surface, has obtained homodisperse Graphene, and by Graphene with macroscopical or micron-sized
Hard material particle is closely linked；The effective Graphene that solves mixes uneven disadvantage, and graphite in the solution
Alkene disperses uneven problem in containing macroscopic view or microcosmic hard particles material, also will not be drawn by other mixed and disorderly materials such as dispersant
Enter, preferably play the premium properties of grapheme material, and the hard particles thing of grapheme material can also be obtain a uniformly coated
Material, makes Graphene become a reality the coating of microcosmic hard particles initiatively, and is more widely applied for later stage Graphene
Lay the foundation.Test result indicate that, the process for dispersing that the present invention provides is capable of uniform on hard particles surface of Graphene
Distribution.
In order to further illustrate the present invention, below in conjunction with the process for dispersing of a kind of Graphene that the present invention is provided by embodiment
And graphene composite material is described in detail, but it is to be understood that these embodiments are to be with technical solution of the present invention
Implement under premise, give detailed embodiment and concrete operating process, simply for further illustrate the present invention's
Feature and advantage rather than limiting to the claimed invention, protection scope of the present invention is also not necessarily limited to following embodiment.
Embodiment 1
1) taking 5000g 500 mesh zinc particle, be placed in vibrated fluidized bed, open stirring, making powder body is irregular movement
State；
2) graphene aqueous solution taking a certain amount of 1% content is placed in special automatic rotary spray gun, opens rotational automatic rotation
Turning spray gun, coutroi velocity is 30ml/min, and constant speed is added to (1) material；
3) in vibration processes, fluidized-bed temperature is maintained at 90 DEG C, enables the moisture in the Graphene of entrance fluid bed to protect
Hold evaporating state, and open separate ventilation device, steam is detached the most intermittently；
4), after step 1～3 persistently carries out 30min, stop adding Graphene, increase ventilation dynamics, and gradually reduce vibration
Frequency, being drying regime to powder, finally obtains the Graphene/zinc composite with homodisperse Graphene.
5) Graphene/iron composite material preparing above-mentioned steps of the present invention carries out macroscopic analysis, and after coating, zinc powder is relatively coated with
Obvious color burn before covering.
The Graphene preparing above-mentioned steps of the present invention/zinc composite carries out transmission electron microscope micro analysis, sees Fig. 1,
Fig. 1 is the transmission electron microscope comparison diagram of the Graphene/iron composite material prepared by the embodiment of the present invention 1 and zinc granule-morphology.Wherein
Upper figure is single metallic particles shape appearance figure, and figure below is Graphene/zinc composite shape appearance figure, and as shown in Figure 1, the present invention is at zinc
Granule top layer defines graphene film layer, and the attachment of graphene film layer is uniformly, there is no agglomeration, and thickness is about 60nm.
Embodiment 2
1) taking 5000g 200 mesh iron powder, be placed in vibrated fluidized bed, open strong stirring, making powder body is irregular movement
State；
2) the Graphene ethanol solution taking a certain amount of 5% content is placed in special automatic rotary spray gun, opens rotational automatic
Rotary spray gun, coutroi velocity is 40ml/min, and constant speed is added to (1) material；
3) in vibration processes, fluidized-bed temperature is maintained at 100 DEG C, makes the dehydrated alcohol energy in the Graphene of entrance fluid bed
Enough keep evaporating state, and open separate ventilation device, steam is detached the most intermittently；
4) after step 1-3 persistently carries out 40min, stop adding Graphene, increase ventilation dynamics, and gradually reduce vibration frequency
Rate, being drying regime to powder.
5) Graphene/iron composite material preparing above-mentioned steps of the present invention carries out macroscopic analysis, and after coating, iron powder is relatively coated with
Obvious color burn before covering.Seeing Fig. 2, Fig. 2 is the Graphene/iron composite material prepared by the embodiment of the present invention 2 and iron powder
Macro morphology comparison diagram.
Graphene/the iron composite material preparing above-mentioned steps of the present invention carries out transmission electron microscope micro analysis, graphene film
Uniformly, thickness is about 120nm in layer attachment.
Embodiment 3
1) taking 3000g alumina particle, be placed in vibrated fluidized bed, open stirring, making powder body is irregular movement state；
2) the Graphene acetone soln taking a certain amount of 0.5% content is placed in special automatic rotary spray gun, and unlatching rotates from
Dynamic rotary spray gun, coutroi velocity is 60ml/min, and constant speed is added to (1) material；
3) in vibration processes, fluidized-bed temperature is maintained at 60 DEG C, enables the moisture in the Graphene of entrance fluid bed to protect
Hold evaporating state, and open separate ventilation device, steam is detached the most intermittently；
4), after step 1～3 persistently carries out 120min, stop adding Graphene, increase ventilation dynamics, and gradually reduce vibration
Frequency, being drying regime to powder.
5) the graphene/aluminum composite preparing above-mentioned steps of the present invention carries out macroscopic analysis, and after coating, aluminium powder is relatively coated with
Obvious color burn before covering.
The graphene/aluminum composite preparing above-mentioned steps of the present invention carries out transmission electron microscope micro analysis, graphene film
Uniformly, thickness is about 60nm in layer attachment.
Embodiment 4
1) taking 1000g normal sand granule, be placed in vibrated fluidized bed, open stirring, making powder body is irregular movement state；
2) the Graphene acetone soln taking a certain amount of 0.1% content is placed in special automatic rotary spray gun, and unlatching rotates from
Dynamic rotary spray gun, coutroi velocity is 30ml/min, and constant speed is added to (1) material；
3) in vibration processes, fluidized-bed temperature is maintained at 100 DEG C, enables the moisture in the Graphene of entrance fluid bed to protect
Hold evaporating state, and open separate ventilation device, steam is detached the most intermittently；
4), after step 1～3 persistently carries out 90min, stop adding Graphene, increase ventilation dynamics, and gradually reduce vibration
Frequency, being drying regime to powder.
5) Graphene preparing above-mentioned steps of the present invention/mark sand composite carries out macroscopic analysis, marks sand relatively after coating
Obvious color burn before coating.Seeing Fig. 3, Fig. 3 is the Graphene prepared by the embodiment of the present invention 4/mark sand composite and mark
The macro morphology comparison diagram of sand.
The graphene/aluminum composite preparing above-mentioned steps of the present invention carries out transmission electron microscope micro analysis, graphene film
Uniformly, thickness is about 50nm in layer attachment.
Process for dispersing and graphene composite material to a kind of Graphene that the present invention provides have carried out detailed above
Introducing, principle and the embodiment of the present invention are set forth by specific case used herein, the explanation of above example
It is only intended to help to understand method and the core concept thereof of the present invention, including best mode, and also makes any of this area
Technical staff can put into practice the present invention, including manufacturing and using any device or system, and the method implementing any combination.Should
When pointing out, for those skilled in the art, under the premise without departing from the principles of the invention, it is also possible to this
Invention carries out some improvement and modification, and these improve and modify in the protection domain also falling into the claims in the present invention.The present invention
The scope of patent protection is defined by the claims, and those skilled in the art can be included it is conceivable that other embodiments.
If these other embodiments have the structural element being not different from claim character express, if or they include with
The character express of claim is without the equivalent structural elements of essence difference, then these other embodiments also should be included in right and want
In the range of asking.
Claims (10)
1. the process for dispersing of a Graphene, it is characterised in that comprise the following steps:
A) make hard material particle be in vibratory liquefaction and irregular movement state, graphene oxide solution is uniformly sprayed at hard
Material particle surface, obtains the composite with homodisperse Graphene.
Process for dispersing the most according to claim 1, it is characterised in that the particle diameter of described hard material particle is 10～5000
Mesh；
Described hard material includes in metal, nonmetal, alloy, metal-oxide, nonmetal oxide and nonmetallic mineral
One or more.
Process for dispersing the most according to claim 2, it is characterised in that described hard material includes zinc, ferrum, aluminium alloy, magnesium
One or more in alloy, copper, sandstone, aluminium oxide, pottery and kieselguhr.
Process for dispersing the most according to claim 1, it is characterised in that the concentration of described graphene oxide solution is 0.01%
～20%；
The solvent of described graphene oxide solution is one or more in water, dehydrated alcohol, acetone, dimethylbenzene and n-butyl alcohol.
Process for dispersing the most according to claim 1, it is characterised in that the speed of described sprinkling is 1～100mL/min；
The equipment of described sprinkling is rotary spray gun.
Process for dispersing the most according to claim 1, it is characterised in that the temperature of described vibratory liquefaction is 50～120 DEG C；
The time of described vibratory liquefaction is 0.1～10h；The frequency of described vibratory liquefaction is 5～99Hz.
Process for dispersing the most according to claim 1, it is characterised in that described step A) particularly as follows:
A1) hard material particle is placed in vibrated fluidized bed, makes hard material particle be in vibratory liquefaction and irregular movement
State, then it is aided with stirring；
A2) graphene oxide solution is uniformly sprayed at the hard material particle surface of above-mentioned state, obtains homodisperse stone
Ink alkene composite.
Process for dispersing the most according to claim 7, it is characterised in that described step A2) particularly as follows:
A21) under conditions of ventilating, graphene oxide solution is uniformly sprayed at the hard material particle surface of above-mentioned state；
A22) after stopping spraying, gradually reduce vibratory liquefaction degree, improve ventilation volume, treat that the Graphene on hard particles surface is done
After dry, obtain homodisperse graphene composite material.
9. a graphene composite material, it is characterised in that include the dispersed compound stone of hard material particle and surface thereof
Ink alkene layer；
The particle diameter of described hard material particle is 10～5000 mesh.
Composite the most according to claim 1, it is characterised in that the thickness of described graphene layer is 0.01～10 μm.
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| CN201610445561.1A CN106115668A (en) | 2016-06-20 | 2016-06-20 | The process for dispersing of a kind of Graphene and graphene composite material |
| PCT/CN2017/088992 WO2017219945A1 (en) | 2016-06-20 | 2017-06-19 | Graphene dispersion method and graphene composite material |
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| CN107163775A (en) * | 2017-04-28 | 2017-09-15 | 山东欧铂新材料有限公司 | A kind of resin anti-corrosive paint containing graphene/ferric oxide composite material and preparation method thereof |
| CN107225237A (en) * | 2017-06-21 | 2017-10-03 | 山东欧铂新材料有限公司 | A kind of graphene is modified the preparation method and application of zinc powder |
| WO2017219945A1 (en) * | 2016-06-20 | 2017-12-28 | 山东欧铂新材料有限公司 | Graphene dispersion method and graphene composite material |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103183353A (en) * | 2011-12-29 | 2013-07-03 | 中国科学院成都有机化学有限公司 | Conductive mica powder and preparation method thereof |
| CN103261563A (en) * | 2010-10-29 | 2013-08-21 | 贝克休斯公司 | Graphene-coated diamond particles, compositions and intermediate structures comprising same, and methods of forming graphene-coated diamond particles and polycrystalline compacts |
| CN104475316A (en) * | 2014-12-03 | 2015-04-01 | 林前锋 | Preparing method of graphene coating |
| CN105215353A (en) * | 2015-11-09 | 2016-01-06 | 山东大学 | A kind of Metal/grapheme composite and preparation method thereof |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8691441B2 (en) * | 2010-09-07 | 2014-04-08 | Nanotek Instruments, Inc. | Graphene-enhanced cathode materials for lithium batteries |
| US9558860B2 (en) * | 2010-09-10 | 2017-01-31 | Samsung Electronics Co., Ltd. | Graphene-enhanced anode particulates for lithium ion batteries |
| CN102764724A (en) * | 2012-07-23 | 2012-11-07 | 贵州新碳高科有限责任公司 | Method for spraying graphene coat, and graphene coat prepared by same |
| CN106115668A (en) * | 2016-06-20 | 2016-11-16 | 山东欧铂新材料有限公司 | The process for dispersing of a kind of Graphene and graphene composite material |
-
2016
- 2016-06-20 CN CN201610445561.1A patent/CN106115668A/en active Pending
-
2017
- 2017-06-19 WO PCT/CN2017/088992 patent/WO2017219945A1/en active Application Filing
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103261563A (en) * | 2010-10-29 | 2013-08-21 | 贝克休斯公司 | Graphene-coated diamond particles, compositions and intermediate structures comprising same, and methods of forming graphene-coated diamond particles and polycrystalline compacts |
| CN103183353A (en) * | 2011-12-29 | 2013-07-03 | 中国科学院成都有机化学有限公司 | Conductive mica powder and preparation method thereof |
| CN104475316A (en) * | 2014-12-03 | 2015-04-01 | 林前锋 | Preparing method of graphene coating |
| CN105215353A (en) * | 2015-11-09 | 2016-01-06 | 山东大学 | A kind of Metal/grapheme composite and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 程峰 等: ""振动流化床造粒特性的实验研究"", 《四川大学学报(工程科学版)》 * |
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| CN108285681A (en) * | 2017-03-13 | 2018-07-17 | 宁波市北仑区振古装饰设计研究院有限公司 | A kind of zinc powder incremental agent and its preparation method and application |
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| CN107585763A (en) * | 2017-10-23 | 2018-01-16 | 南京旭羽睿材料科技有限公司 | A kind of graphene particles and preparation method thereof |
| CN107585763B (en) * | 2017-10-23 | 2018-10-19 | 南京旭羽睿材料科技有限公司 | A kind of graphene particles and preparation method thereof |
| CN110385432A (en) * | 2018-04-17 | 2019-10-29 | 中国科学院宁波材料技术与工程研究所 | A kind of graphene/copper powder body material and preparation method thereof |
| CN110391035A (en) * | 2018-04-17 | 2019-10-29 | 中国科学院宁波材料技术与工程研究所 | A kind of graphene/copper contact material and preparation method thereof |
| CN110391035B (en) * | 2018-04-17 | 2022-08-02 | 中国科学院宁波材料技术与工程研究所 | Graphene/copper electric contact material and preparation method thereof |
| CN111485128A (en) * | 2020-05-28 | 2020-08-04 | 山东海科创新研究院有限公司 | Graphene aluminum alloy and preparation method thereof |
| CN112457548A (en) * | 2020-11-26 | 2021-03-09 | 四川六九一二科技有限公司 | Preparation method of super-wear-resistant, flame-retardant, high-strength and mould-resistant graphene composite material |
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