CN106109256B - CC frost - Google Patents

Abstract

The invention discloses a kind of CC frosts, it includes the ingredient of following mass parts: the particle size range of the titanium dioxide of 2.0 ~ 2.5 parts of ethylhexyl palmitate total 0.6 ~ 1.0 portion of colorant, 15 ~ 20 parts of emollient, 0.5 ~ 0.6 portion of thickener, 0.2 ~ 0.4 part of preservative, 4.0 ~ 5.0 part first of emulsifier, 3 ~ 5 part second of sunscreen composition, 2 ~ 3 parts of sunscreen composition, 3 ~ 4 parts of slip agents, 0.8 ~ 1.5 part of sodium chloride, 50 ~ 60 parts of water, 8 ~ 12 parts of glycerol, 0.2 ~ 0.6 part of skin conditioning agent, 0.2 ~ 0.3 part of Phenoxyethanol, 0.1 ~ 0.3 part first of essence sunscreen compositions and the second sunscreen composition is 5 ~ 50 μm, have the effect of improving sun protection.

Description

CC frost

Technical field

The present invention relates to cosmetic field, in particular to a kind of CC frost.

Background technique

After naked adornment comes into fashion, natural adornment sense has become the big demand for the women that likes to be beautiful, but natural adornment sense does not have The BB frost for the effects of auxiliary of make up artist is difficult to realize again, then collects bottoming, isolation, concealing and whitening just becomes most of women Liberator.In current makeups circle, each famous brand in the whole world is also proposed the vanishing cream main products such as respective BB frost, and oath is flourishing at this The vanishing cream of development is taken a share in the market.BB frost is as a very high vanishing cream of routine use frequency, and consumer is to it The requirement used is also higher and higher.BB frost on the market, although integrating multiple functions, but does not put various functions Greatly to optimum efficiency, and BB frost is thick and heavy, poor air permeability, has gray tone, and becoming influences adornment sense naturally maximum obstruction.CC frost Vanishing cream as a new generation comes into being.

CC frost, the i.e. abbreviation of Color Control Cream, Chinese are that color regulates and controls Quan Xiaoxiu appearance frost.CC frost is It is promoted on the basic components of BB frost, it may be said that be the strengthening version of BB frost.CC frost had both remained the original concealing of BB frost, guarantor Wet, isolation sun-proof, whitening, repairs the functions such as face, and has carried out abundant amplification to each details characteristic, so CC frost is in whole adornment It is more more natural than BB frost, more clear in sense, the colour of skin mildly lightened also unlike BB frost adornment sense it is thick and heavy, Lian Xiang how, Lancome this One line of sample is famous, all has launched the CC frost product of oneself, can see the popular degree of CC frost completely.

The Chinese patent that application publication number is CN103735444A, data of publication of application is on April 23rd, 2014 discloses one Kind Multifunctional CC cream, the Multifunctional CC cream add silicone oil emulsification agent, grease, hydrophobic pigment, sun-screening agent, polyalcohols moisturizing Agent, electrolyte, auxiliary material and both effectiveness raw material compound, by the way that oily phase, Aqueous Phase Raw Material are separately heated to 75-80 DEG C, oily phase, water Phase raw material carries out the stirring and emulsification of certain time, water/silicone oil emulsification body is made by filter.

Similar with above-mentioned patent, the CC frost of most of prior art has the following problems: mentioning when by the amount of sun-screening agent When rising to SPF30 or more, needs to improve sun-screening agent dosage or select high-performance sun-screening agent, sun-screening agent cannot under both of these case It is dispersed in system well, causes CC frost viscosity uneven, so CC frost sun-proof result most on the market is not special at present It is not ideal.

Summary of the invention

The object of the present invention is to provide a kind of CC frosts, and which solve the undesirable problems of sun-proof result, have raising sun-proof The effect of property.

Above-mentioned technical purpose of the invention has the technical scheme that

A kind of CC frost, the ingredient including following mass parts:

2.0~2.5 parts of ethylhexyl palmitate；

Total 0.6~1.0 part of colorant；

15~20 parts of emollient；

0.5~0.6 part of thickener；

0.2~0.4 part of preservative；

4.0~5.0 parts of emulsifier；

By the talcum powder of 10~80wt%, the titanium dioxide of 10~80wt%, the first colorant of 0~30wt% and 0~ 3~5 parts of the first sunscreen composition of the dimethyl silicone polymer composition of 10wt%；

By the titanium dioxide of 75~85wt%, the dimethyl siloxane of the silica of 10~20wt% and 5~10wt% 2~3 parts of the second sunscreen composition of composition；

3~4 parts of slip agents；

0.8~1.5 part of sodium chloride；

50~60 parts of water；

8~12 parts of glycerol；

0.2~0.6 part of skin conditioning agent；

0.2~0.3 part of Phenoxyethanol；

0.1~0.3 part of essence；

Wherein, the particle size range of the titanium dioxide of the first sunscreen composition and the second sunscreen composition weight is 5~50 μm.

All raw materials and its dosage of the application meet international cosmetic raw material standard.

By adopting the above technical scheme, firstly, the particle size range of titanium dioxide is 5~50 μm and titanium dioxide is made first The form of sunscreen composition and the second sunscreen composition, further increases sun-proof result, is ground according to the evaluation of the area UVB sun-proof result Study carefully discovery, the CC frost of the application is suitable for outwork, summer sunburst irradiation condition；Secondly, the CC frost of the application passes through The interaction of emulsifier, slip agents, sodium chloride, water and glycerol and other substances, the dispersibility of Lai Tigao product, further mentions The clear property of high CC frost；In addition, the CC frost of the application passes through emollient, total colorant, sodium chloride, water, glycerol and skin conditioning agent The effects of, it had not only fundamentally improved skin and skin carries out moisturizing, moistens, but also concealing effect is provided.

Further preferably are as follows: second sunscreen composition is prepared by the following method: using titanium dioxide as kernel, in It is successively applied on kernel and is covered with silica and dimethyl siloxane.

By adopting the above technical scheme, the second sunscreen composition viscosity of this form is low, dispersibility and redispersibility compared with Good, suitable for this clear property of CC frost vanishing cream；It is good with the compatibility of emollient, emulsifier simultaneously, can further mention The effect of Gao Qiyu skin.

Further preferably are as follows: the CC frost is prepared by the following method:

Step 1: the ethylhexyl palmitate of formula ratio being opened into homogeneous, is slowly added to total colorant of formula ratio, by total colorant It is completely dispersed, transfers them in reaction kettle；

Step 2: in through step 1 treated reaction kettle, emollient, thickener, preservative and the cream of formula ratio is added Agent is stirred；70~75 DEG C are heated to, the first sunscreen composition of formula ratio, the second sunscreen composition is added and helps cunning Agent, homogeneous make it be completely dispersed no particle；

Step 3: in sodium chloride, water and glycerol that formula ratio is added in water phase pot, it is stirred, is warming up to 70~75 DEG C, Obtain aqueous mixture；

Step 4: in through step 2 treated reaction kettle, the aqueous mixture of step 3 is slowly added to, in adition process It is stirred；

Step 5: will be cooling through step 4 treated reaction kettle, in the skin tune of wherein addition formula ratio when to≤45 DEG C Manage agent, Phenoxyethanol and essence, be uniformly mixed to get.

By adopting the above technical scheme, each ingredient is uniformly dispersed, and obtained CC frost can disperse and more clear at once；Meanwhile Skin conditioning agent etc. is put at relatively low temperature, is able to maintain its activity.

Further preferably are as follows: the emollient include cetanol ethylhexoate, dormant oil, phenyl trimethicone, Diisooctadecanol malate, horse fat, stearic oxygroup dimethione；And by mass, the cetanol ethylhexoate, Dormant oil, phenyl trimethicone, diisooctadecanol malate, horse fat, stearic oxygroup dimethione amount ratio For 1:0.5~0.6:0.5~0.6:0.4~0.5:0.4~0.5:0.2~0.3.

By adopting the above technical scheme, these emollients also have following effect other than the moisturizing effect of itself respectively:

Cetanol ethylhexoate has water-repellancy, after can acting on other emollients, forms ventilated membrane, further mentions The clear property of the CC frost of high the application；

Dormant oil has antistatic property, and external environment can be isolated to the electrostatic interaction of skin, further protect skin；

Phenyl trimethicone has antistatic property, moreover it is possible to reduce surface tension, keep the CC frost of the application salubrious good It smears, does not stick greasy；

Diisooctadecanol malate has moisturizing effect, carries out skin care effect；

Horse fat, which has, improves looks and the dermopathic effect for the treatment of part；

Above-mentioned emollient comprehensive function does not occur side reaction or comprehensive allergic reaction between each other, fundamentally moistens skin Skin simultaneously above improves skin from multi-level, and the effect of skin care is further functioned as while clear.

It is found in dispersed evaluation test, when the emulsifier includes sorbitan sesquioleate and cetyl PEG/ PPG-10/1 dimethyl silicone polymer；And by mass, the sorbitan sesquioleate and cetyl PEG/PPG-10/1 are poly- The amount ratio of dimethyl siloxane is 1:0.3~0.5, and the CC frost of the application disperses at once and is uniformly dispersed, is clear.

It is found in dispersed evaluation test, when the slip agents include bismuth oxychloride, magnesium stearate and poly- methyl silicon times Half oxygen alkane；And by mass, the amount ratio of the bismuth oxychloride, magnesium stearate and polymethylsilsesquioxane be 1:0.4~ The CC frost of 0.5:0.5~0.6, the application disperses at once and is uniformly dispersed, is clear.

Further preferably are as follows: total colorant and the first colorant are selected from one of CI 77007, CI 77891 or more Kind；

The thickener is bentonite；The preservative is selected from one of methyl hydroxybenzoate, Nipasol or a variety of.

Further preferably are as follows: the skin conditioning agent is selected from aloe barbadensis Miller leaf extract, Flos persicae extract, rose and mentions Take one of object, tomato extract or a variety of.

By adopting the above technical scheme, the allergic population of these skin conditioning agents is less, and the case where can improve skin aging, Moisturizing moisturizing.

Further preferably are as follows: the skin conditioning agent is prepared by the following method:

Step i, it takes raw material to be screened, clean, infrared sterilizing, eliminating moisture in -20~0 DEG C of freeze-drying；

Step ii, Extraction solvent is added in the raw material handled through step i, is warming up to reflux, distillation is extracted Object；

Step iii, extract is crossed into chromatographic column, obtains purity >=99wt% skin conditioning agent.

By adopting the above technical scheme, the activity of raw material is maintained in extraction process, while the utilization of raw material can be improved Rate, the purity is high of product are suitable for cosmetics this kind high request field；According to safety evaluatio the study found that by above-mentioned The CC frost that mode obtains does not occur skin adverse reaction, can antiallergy；In addition, first with freeze-drying to raw material in step i Handled so that raw material moment dehydration and also held its shape substantially state originally, so after Extraction solvent is added, Extraction solvent The dissolution to accelerate the effective component in raw material can be quickly acted on the raw material of dehydration.

The study found that when the Extraction solvent includes the ethyl alcohol of 0~20wt% and the water of 80~100wt%；In mass, The dosage of the Extraction solvent is 1~5 times of raw material dry weight, and the utilization rate and recovery rate of raw material reach balance.

In conclusion the invention has the following advantages:

1, the sun-proof result of the CC frost of the application is to protect ultraviolet light effect completely, and the CC frost of the application is suitable for outdoor work Make, summer sunburst irradiation condition.

2, the CC frost antiallergy of the skin conditioning agent added with the application preparation, safely and effectively；

3, after by improving the preparation process of the application, the selecting of optimizing raw material, the CC frost of the application is naturally clear, disperses Property and concealing are good, are the ideal choses of naked adornment.

Specific embodiment

Raw material used herein meets international cosmetic raw material standard, therefore single component is not specified in this application Source.This specific embodiment is only explanation of the invention, is not limitation of the present invention, and those skilled in the art exist It can according to need the modification that not creative contribution is made to the present embodiment after reading this specification, but as long as in the present invention Scope of the claims in all by the protection of Patent Law.

Embodiment 1-4: skin conditioning agent is prepared by the following method:

Step i, it takes raw material to be screened, water cleaning, infrared sterilizing, eliminates moisture in -20~0 DEG C of freeze-drying；

Step ii, it is taken at the raw material 100g handled through step i, Extraction solvent is added, is warming up to reflux, distillation obtains Extract；

Step iii, extract is crossed into chromatographic column, obtains purity >=99wt% skin conditioning agent；

The material information of embodiment 1-4 is as shown in table 1.

The material information of 1 embodiment 1-4 of table counts

The 5-7: the first sunscreen composition of embodiment, is prepared by the following method:

Step i, all raw materials are crushed to particle size range respectively is 10~50 μm；

Step ii, smashed raw material is stirred, and crushed again, obtain first that particle size range is 5~50 μm Sunscreen composition；

The raw material information of embodiment 5-7 is as shown in table 2.

The raw material information of 2 embodiment 5-7 of table counts

The 8-10: the second sunscreen composition of embodiment, is prepared by the following method:

Step i, titanium dioxide is taken, being crushed to particle size range is 5~50 μm；

Step ii, silica is taken to crush, it is 5~50 μm that water ultrasound to particle size range, which is added, and spray drying is to through step i The outer layer of treated titanium dioxide；

Step iii, dimethyl siloxane is taken to crush, it is 5~50 μm that water ultrasound to particle size range, which is added, spray drying to warp The outer layer of step ii treated silica obtains the second sunscreen composition that particle size range is 5~50 μm；

The raw material information of embodiment 8-10 is as shown in table 3.

The raw material information of 3 embodiment 8-10 of table counts

Embodiment 11-13:CC frost, is prepared by the following method:

Step 1: ethylhexyl palmitate being opened into homogeneous, is slowly added to total colorant, total colorant is completely dispersed, is shifted To reaction kettle；

Step 2: in through step 1 treated reaction kettle, emollient, thickener, preservative and emulsifier, stirring is added Mixing；70~75 DEG C are heated to, the first sunscreen composition, the second sunscreen composition and slip agents, homogeneous, which is added, divides it completely It dissipates without particle；

Step 3: in sodium chloride, water and glycerol are added in water phase pot, being stirred, be warming up to 70~75 DEG C, obtain water phase Mixture；

Step 4: in through step 2 treated reaction kettle, the aqueous mixture of step 3 is slowly added to, in adition process It is stirred；

Step 5: will be cooling through step 4 treated reaction kettle, in the skin tune of wherein addition formula ratio when to≤45 DEG C Agent, Phenoxyethanol and essence are managed, is uniformly mixed to get CC frost；

The raw material information of embodiment 11-13 is as shown in table 4.

The raw material information of 4 embodiment 11-13 of table counts

Embodiment 14:CC frost, the difference with embodiment 11 are that skin conditioning agent is limited by Xi'an Tian Feng biotechnology Company provides.

Embodiment 15:CC frost, the difference with embodiment 11 be, preparation process are as follows: by all raw materials directly 70~ Mixed at 75 DEG C, be subsequently cooled to≤45 DEG C to get.

Embodiment 16:CC frost, the difference with embodiment 11 be, preparation process are as follows: by all raw materials directly 20~ At 30 DEG C mix to get.

Embodiment 17:CC frost, the difference with embodiment 11 is, does not add cetanol ethylhexoate, dormant oil and phenyl Poly- trimethicone.

Embodiment 18:CC frost, the difference with embodiment 11 be, does not add diisooctadecanol malate, horse fat and hard Rouge oxygroup dimethione.

Embodiment 19:CC frost, the difference with embodiment 11 is, does not add sorbitan sesquioleate.

Embodiment 20:CC frost, the difference with embodiment 11 is, does not add cetyl PEG/PPG-10/1 poly dimethyl silicon Oxygen alkane.

Embodiment 21:CC frost, the difference with embodiment 11 is, does not add bismuth oxychloride and magnesium stearate.

Embodiment 22:CC frost, the difference with embodiment 11 is, does not add polymethylsilsesquioxane.

Embodiment 23:CC frost, the difference with embodiment 11 is, replaces the first sunscreen composition with commercially available titanium dioxide With the second sunscreen composition.

The evaluation of the area embodiment 24:UVB sun-proof result

Subjects: using the CC frost of embodiment 11-22 as test specimen, using the CC frost of embodiment 23 as control sample.

Content of the test: the evaluation of the area UVB sun-proof result is carried out referring to QB/T 2410-1998, according to the sun-proof result of table 5 Comprehensive evaluation form evaluates the sun-proof result of subjects, and each experimental subjects is measured in parallel 10 times.

Test result: as shown in table 6.As shown in Table 6, the sun-proof result of embodiment 11-22 is complete protection ultraviolet light The CC frost of effect, the application is suitable for outwork, summer sunburst irradiation condition.

5 sun-proof result comprehensive evaluation form of table

Absorbance A	Sun-proof result	Use condition
			0.5~1.0	Minimum protects ultraviolet light effect	Winter sunlight, morning and evening in summer sunlight and cloudy day
1.1~1.5	The medium ultraviolet light effect of protection	The irradiation of moderate strength sunlight
			1.6~2.0	The ultraviolet light effect of high efficient protected	Outwork, the irradiation of summer sunburst
2.1	Ultraviolet light effect is protected completely	Outwork, the irradiation of summer sunburst

6 area UVB sun-proof result evaluation result of table

Embodiment 25: safety evaluatio

Subjects: using the CC frost of embodiment 11-13 as test specimen, using the CC frost of embodiment 14 as control sample.

Content of the test: take 400 ages between 20~50 years old, skin health and the women without skin disease allergies, 4 groups are randomly divided into, one subjects of every group of receiving；Safety evaluatio uses human skin patch, method particularly includes: 20~25mg subjects are taken to be dispersed in qualified spot tester, external application special adhesive tape is overlying on subject back, goes after 24 hours 0hr, 1hr, 6hr, 12hr, the dermoreaction of r, 48hr observation for 24 hours except tested material, after removal.

Test result: 0 there is skin adverse reaction in embodiment 11-13, and has 15 in embodiment 14 and skin occur Adverse reaction.

Embodiment 26: dispersibility evaluation

Subjects: being pair with the CC frost of embodiment 15-16,19-22 using the CC frost of embodiment 11-13 as test specimen Product in the same old way.

Content of the test: it takes 20~25mg subjects on the back of the hand, is gently rubbed with hand, observe the dispersion of subjects.

Test result: as shown in table 7.As shown in Table 7, embodiment 11-13 disperses at once and is uniformly dispersed, is clear.

The dispersed evaluation result of table 7

Claims (7)

1. a kind of CC frost, which is characterized in that the ingredient including following mass parts:

2.0 ~ 2.5 parts of ethylhexyl palmitate；

Total 0.6 ~ 1.0 part of colorant；

15 ~ 20 parts of emollient；

0.5 ~ 0.6 part of thickener；

0.2 ~ 0.4 part of preservative；

4.0 ~ 5.0 parts of emulsifier；

By the talcum powder of 10 ~ 80wt%, the titanium dioxide of 10 ~ 80wt%, the first colorant of 0 ~ 30wt% and 0 ~ 10wt% poly- diformazan 3 ~ 5 parts of the first sunscreen composition of radical siloxane composition；

Second be made of the dimethyl siloxane of the titanium dioxide of 75 ~ 85wt%, the silica of 10 ~ 20wt% and 5 ~ 10wt% 2 ~ 3 parts of sunscreen composition；

3 ~ 4 parts of slip agents；

0.8 ~ 1.5 part of sodium chloride；

50 ~ 60 parts of water；

8 ~ 12 parts of glycerol；

0.2 ~ 0.6 part of skin conditioning agent；

0.2 ~ 0.3 part of Phenoxyethanol；

0.1 ~ 0.3 part of essence；

Wherein, the particle size range of the first sunscreen composition and the titanium dioxide in the second sunscreen composition is 5 ~ 50 μm；

The thickener is bentonite；

The preservative is methyl hydroxybenzoate and Nipasol；

The emollient includes cetanol ethylhexoate, dormant oil, phenyl trimethicone, two isooctadecanol malic acid Ester, horse fat, stearic oxygroup dimethione；And by mass, the cetanol ethylhexoate, dormant oil, the poly- front three of phenyl Radical siloxane, diisooctadecanol malate, horse fat, stearic oxygroup dimethione amount ratio be 1:0.5 ~ 0.6:0.5 ~ 0.6:0.4 ~ 0.5:0.4 ~ 0.5:0.2 ~ 0.3；

The emulsifier includes sorbitan sesquioleate and cetyl PEG/PPG-10/1 dimethyl silicone polymer；And press matter The amount ratio of meter, the sorbitan sesquioleate and cetyl PEG/PPG-10/1 dimethyl silicone polymer be 1:0.3 ~ 0.5；

The CC frost is prepared by the following method:

Step 1: the ethylhexyl palmitate of formula ratio is opened into homogeneous, is slowly added to total colorant of formula ratio, total colorant is complete Dispersion, transfers them in reaction kettle；

Step 2: in through step 1 treated reaction kettle, emollient, thickener, preservative and the emulsifier of formula ratio is added, It is stirred；70 ~ 75 DEG C are heated to, the first sunscreen composition, the second sunscreen composition and slip agents of formula ratio, homogeneous is added It is set to be completely dispersed no particle；

Step 3: in sodium chloride, water and glycerol that formula ratio is added in water phase pot, being stirred, be warming up to 70 ~ 75 DEG C, obtain water Phase mixture；

Step 4: in through step 2 treated reaction kettle, being slowly added to the aqueous mixture of step 3, stirred in adition process Mixing；

Step 5: will be cooling through step 4 treated reaction kettle, when to≤45 DEG C in the wherein skin conditioning agent of addition formula ratio, Phenoxyethanol and essence, be uniformly mixed to get.

2. CC frost according to claim 1, which is characterized in that second sunscreen composition is prepared by the following method It arrives: using titanium dioxide as kernel, being covered with silica and dimethyl siloxane in successively applying on kernel.

3. CC frost according to claim 1, which is characterized in that the slip agents include bismuth oxychloride, magnesium stearate and gather Methyl silsesquioxane；And by mass, the amount ratio of the bismuth oxychloride, magnesium stearate and polymethylsilsesquioxane is 1: 0.4 ~ 0.5:0.5 ~ 0.6.

4. CC according to claim 1 frost, which is characterized in that total colorant and the first colorant be selected from CI 77007, One of CI 77891 or a variety of.

5. CC frost according to claim 1, which is characterized in that the skin conditioning agent is extracted selected from Aloe Barbadensis Miller One of object, Flos persicae extract, Flos Rosae Rugosae extract, tomato extract are a variety of.

6. CC frost according to claim 5, which is characterized in that the skin conditioning agent is prepared by the following method:

Step i, it takes raw material to be screened, clean, infrared sterilizing, eliminating moisture in -20 ~ 0 DEG C of freeze-drying；

Step ii, Extraction solvent is added in the raw material handled through step i, is warming up to reflux, distillation obtains extract；

Step iii, extract is crossed into chromatographic column, obtains purity >=99wt% skin conditioning agent.

7. CC frost according to claim 6, which is characterized in that ethyl alcohol and 80 of the Extraction solvent including 0 ~ 20wt% ~ The water of 100wt%；In mass, the dosage of the Extraction solvent is 1 ~ 5 times of raw material dry weight.