CN106106500A - A kind of containing double third ring worm esters and the composite insecticide of ethofenprox and application - Google Patents

A kind of containing double third ring worm esters and the composite insecticide of ethofenprox and application Download PDF

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Publication number
CN106106500A
CN106106500A CN201610473464.3A CN201610473464A CN106106500A CN 106106500 A CN106106500 A CN 106106500A CN 201610473464 A CN201610473464 A CN 201610473464A CN 106106500 A CN106106500 A CN 106106500A
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CN
China
Prior art keywords
ethofenprox
ring worm
insecticide
double
composite
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CN201610473464.3A
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Chinese (zh)
Inventor
赵来成
***
张建华
陈源
姚克兵
束兆林
缪康
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Jiangsu Lvdun Plant Protection Agrochemlcal Experimental Co Ltd
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Jiangsu Lvdun Plant Protection Agrochemlcal Experimental Co Ltd
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Priority to CN201610473464.3A priority Critical patent/CN106106500A/en
Publication of CN106106500A publication Critical patent/CN106106500A/en
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N53/00Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N31/00Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
    • A01N31/08Oxygen or sulfur directly attached to an aromatic ring system
    • A01N31/14Ethers

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a kind of containing double third ring worm esters and the composite insecticide of ethofenprox and application, life physiological habit for Bemisia tabaci, and the different insecticidal mechanisms of various medicament, its perfect adaptation is got up, it is aided with suitable auxiliary agent and carrier, seek most suitable proportioning Bemisia tabaci is prevented and treated, have the advantage that a) this kind has obvious potentiation to Bemisia tabaci compared with single dose, is remarkably improved prevention effect compared with the prevention and controls of tradition water;B) dosage can be reduced with poison insecticide high in Substitute For Partial, reduces environmental pollution and the residual of agricultural product;C) Bemisia tabaci Drug resistance to single insecticide can be delayed;The advantage d) with lasting period length, compared with single medicament, it is possible to decrease cost.

Description

A kind of containing double third ring worm esters and the composite insecticide of ethofenprox and application
Technical field
The present invention relates to the prevention and control field of insect, particularly relate to a kind of containing double third ring worm ester and composite insecticidals of ethofenprox Agent and application thereof.
Background technology
Bemisia tabaci is a kind of quarantine pest, has started since coastal area from 2003, and area expands rapidly, danger Evil degree increases the weight of year by year.Bemisia tabaci has become the restriction yield of commercial crops such as booth Capsicum annuum L., Fructus Solani melongenae and quality improves one hinders greatly Hinder.Bemisia tabaci is mainly manifested in 3 aspects to the hazardness of crops: one is to inhale plant juice by sucking mouth parts thorn and make Killed plant leaf chlorisis, turning yellow, wilt, even Herb is withered;Two is the viral disease that spreads disease, and Bemisia tabaci can be propagated and plant virus more 30 Disease, causes virosis extension to spread;Three be Bemisia tabaci adults, nymph secretion honeydew can induce the fungal diseases such as sooty mould, press down Fabrication photosynthesis, reduces yield and quality, and the most due to illness the field that insect density is high is ruined Seedling, even had no harvest.
For a long time, the preventing and treating of Bemisia tabaci relies primarily on imidacloprid, avilamycin, Buprofezin, pymetrozine, Nitenpyram etc. Single insecticide, has produced obvious Drug resistance, and prevention effect drastically declines, and therefore, research and development efficiently prevent and treat Bemisia tabaci Composite insecticide kind is to tackle its drug-fast problem, it has also become the task of top priority.
Currently also there is the research of some composite insecticides, but be both for the broad spectrum insecticide of various pests, actual The insecticidal effect of upper special reply Bemisia tabaci is not very well, according to life habit and the medicine resistance ability of Bemisia tabaci, specializes in Go out a kind of worth discussion of composite insecticide for Bemisia tabaci with good result.
Summary of the invention
Goal of the invention: in order to overcome the preventing and treating of Bemisia tabaci present in prior art to there is obvious Drug resistance, preventing and treating effect The problem that drastically declines of fruit, the present invention propose a kind of Bemisia tabaci is controlled effective, reduce dosage, reduce environmental pollution and The residual of agricultural product, lasting period length and delay drug-fast containing double third ring worm ester and ethofenprox to single insecticide of Bemisia tabaci Composite insecticide and application.
Technical scheme: in order to solve above-mentioned technical problem, the technical solution adopted in the present invention is: a kind of containing double third rings Worm ester and the composite insecticide of ethofenprox, by weight by the auxiliary agent of main component, 5%~30% of 5%~60% and remaining The carrier composition of amount;Wherein said main component includes double third ring worm ester and mixing of ethofenprox that weight ratio is 1:50~50:1 Thing.
Being more highly preferred to, the dosage form of described composite insecticide is in water dispersible granules, wettable powder, aqueous emulsion Kind.
Being more highly preferred to, described auxiliary agent is emulsifying agent, wetting agent, stabilizer, dispersant, thickening agent, defoamer, ph regulation Agent, filler.
Being more highly preferred to, the dosage form of described composite insecticide is water dispersible granules, and main component percentage by weight is 24%, Concrete component is: 8g double third ring worm ester, 16g ethofenprox, 4g sodium lauryl sulphate, 2g polyoxyethylene lauryl ether, 2g is wooden Element sulfonate, 2g sulfonic acid polyformaldehyde condensation substance, 2g Polyethylene Glycol, 4g ammonium sulfate, 10g sodium carboxymethyl cellulose, Kaolin are mended extremely 100g。
Being more highly preferred to, the dosage form of described composite insecticide is wettable powder, and main component percentage by weight is 36%, Concrete component is: the double third ring worm ester of 12g, 24g ethofenprox, 4g sodium lauryl sulphate, 4g sodium lignin sulfonate, 2g pull open powder, Kieselguhr complements to 100g.
Being more highly preferred to, the dosage form of described composite insecticide is aqueous emulsion, and main component percentage by weight is 24%, specifically Component is: 8g double third ring worm ester, 16g ethofenprox, 10g dimethylbenzene, 5gN-methyl pyrrolidone, 2g alkyl benzene calcium sulfonate, 6g benzene Ethyl phenol mela mine-formaldehyde resin polyoxyethyl ether, 4g ethylene glycol, 0.4g silicone compound, 0.1g xanthan gum, 0.8g aluminium-magnesium silicate, water Mend to 100g.
The invention allows for above-mentioned containing double third ring worm esters with the application of the composite insecticide of ethofenprox, specifically for cigarette The preventing and treating of aleyrodid.
It is more highly preferred to, above-mentioned containing double third ring worm esters with the application of the composite insecticide of ethofenprox, for every mu of crop, The consumption of composite insecticide is 25g/ mu.
Beneficial effect: it is a kind of containing double third ring worm esters and the composite insecticide of ethofenprox and application that the present invention provides, For the life physiological habit of Bemisia tabaci, and the different insecticidal mechanisms of various medicament, its perfect adaptation is got up, it is suitable to be aided with Auxiliary agent and carrier, seek most suitable proportioning and Bemisia tabaci prevented and treated, with tradition water prevention and controls compared with have following Advantage: a) this kind has obvious potentiation to Bemisia tabaci compared with single dose, is remarkably improved prevention effect;B) can replace For poison insecticide high in part, reduce dosage, reduce environmental pollution and the residual of agricultural product;C) Bemisia tabaci can be delayed single The Drug resistance of insecticide;The advantage d) with lasting period length, compared with single medicament, it is possible to decrease cost.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is described in further detail:
A kind of containing double third ring worm ester and composite insecticides of ethofenprox, by weight by 5%~60% main component, The auxiliary agent of 5%~30% and the carrier composition of surplus;Wherein said main component includes that weight ratio is the double of 1:50~50:1 Third ring worm ester and the mixture of ethofenprox.
Embodiment 1:
36% pair of the third ring worm ester ethofenprox water dispersible granules, the concrete proportioning of each component is as follows: 12g double third ring worm ester, 24g Ethofenprox, 4g sodium lauryl sulphate, 2g polyoxyethylene lauryl ether, 2g lignosulfonates, 2g sulfonic acid polyformaldehyde condensation substance (NNO), 2g Polyethylene Glycol, 4g ammonium sulfate, 10g sodium carboxymethyl cellulose, Kaolin are mended to 100g.
Preparation method is as follows: by effective ingredient, auxiliary agent, carrier mixing, after stirring, be grinding to obtain female powder, by mother Powder is mixed homogeneously with binding agent, then pelletize, dries, sieves, and can be prepared by 36% pair of the third ring worm ester ethofenprox water-dispersible grain Agent.
Embodiment 2:
24% pair of the third ring worm ester ethofenprox water dispersible granules, the concrete proportioning of each component is as follows: 8g double third ring worm ester, 16g Ethofenprox, 4g sodium lauryl sulphate, 2g polyoxyethylene lauryl ether, 2g lignosulfonates, 2g sulfonic acid polyformaldehyde condensation substance (NNO), 2g Polyethylene Glycol, 4g ammonium sulfate, 10g sodium carboxymethyl cellulose, Kaolin are mended to 100g.
Preparation method is as follows: by effective ingredient, auxiliary agent, carrier mixing, after stirring, be grinding to obtain female powder, by mother Powder is mixed homogeneously with binding agent, then pelletize, dries, sieves, and can be prepared by 24% pair of the third ring worm ester ethofenprox water-dispersible grain Agent.
Embodiment 3:
36% pair of the third ring worm ester ethofenprox wettable powder, the concrete proportioning of each component is as follows: 12g double third ring worm ester, 24g Ethofenprox, 4g sodium lauryl sulphate, 4g sodium lignin sulfonate, 2g pull open powder (BX), kieselguhr supplies 100g.
Preparation method is as follows: effective ingredient, auxiliary agent, carrier are added together, after comminution by gas stream, mixed in cone-type mixer Close stirring 30 minutes, can be prepared by 36% pair of the third ring worm ester ethofenprox wettable powder.
Embodiment 4:
24% pair of the third ring worm ester ethofenprox wettable powder, the concrete proportioning of each component is as follows: 8g double third ring worm ester, 16g Ethofenprox, 6g sodium lauryl sulphate, 5g sodium lignin sulfonate, 4g pull open powder (BX), kieselguhr supplies 100g.
Preparation method is as follows: effective ingredient, auxiliary agent, carrier are added together, after comminution by gas stream, mixed in cone-type mixer Close stirring 30 minutes, can be prepared by 24% pair of the third ring worm ester ethofenprox wettable powder.
Embodiment 5:
36% pair of the third ring worm ester ethofenprox aqueous emulsion, the concrete proportioning of each component is as follows: 12g double third ring worm ester, 24g ether chrysanthemum Ester, 10g dimethylbenzene, 5gN-methyl pyrrolidone, 2g alkyl benzene calcium sulfonate, 6g phenethyl phenol mela mine-formaldehyde resin polyoxyethyl ether, 4g Ethylene glycol, 0.4g silicone compound, 0.1g xanthan gum, 0.8g aluminium-magnesium silicate, water are mended to 100g.
Preparation method is as follows: effective ingredient, solvent, emulsifying agent are added together, and are dissolved into homogeneous oil phase;By water, antifreeze, Thickening agent, defoamer mix, and become homogeneous aqueous phase.Under high velocity agitation, aqueous phase is added oil phase, can be prepared by 36% pair Third ring worm ester ethofenprox aqueous emulsion.
Embodiment 6:
24% pair of the third ring worm ester ethofenprox aqueous emulsion, the concrete proportioning of each component is as follows: 8g double third ring worm ester, 16g ether chrysanthemum Ester, 10g dimethylbenzene, 5gN-methyl pyrrolidone, 2g alkyl benzene calcium sulfonate, 6g phenethyl phenol mela mine-formaldehyde resin polyoxyethyl ether, 4g Ethylene glycol, 0.4g silicone compound, 0.1g xanthan gum, 0.8g aluminium-magnesium silicate, water are mended to 100g.
Preparation method is as follows: effective ingredient, solvent, emulsifying agent are added together, and are dissolved into homogeneous oil phase;By water, antifreeze, Thickening agent, defoamer mix, and become homogeneous aqueous phase.Under high velocity agitation, aqueous phase is added oil phase, can be prepared by 24% pair Third ring worm ester ethofenprox aqueous emulsion.
Embodiment 7:
Material to be tested: 36% pair of the third ring worm ester ethofenprox wettable powder of embodiment 3 preparation, embodiment 6 preparation 24% pair of the third ring worm ester ethofenprox aqueous emulsion, subjects is the crops that Bemisia tabaci is broken out.
Test processes and arranges: 36% pair of the third ring worm ester ethofenprox wettable powder every mu arranging embodiment 3 is used 25g, 24% pair of third ring worm ester ethofenprox aqueous emulsion every mu of embodiment 6 is used two test group of 25g, is arranged 5% pair simultaneously Third ring worm ester dispersible agent every mu uses 67g, and 10% ethofenprox suspending agent every mu uses 60g and blank group three comparison Group.
Test method and statistical effect: five process test group+matched group random alignment, often process and be repeated 3 times, face, community Long-pending 50m2, contain phase spray medicine in Bemisia tabaci Nymph, use the Changjiang river-10 type aerosol apparatus slightly to spray, by reason low concentration at EXPERIMENTAL DESIGN To high concentration successively dispenser, amount of liquid medicine 750kg/hm2, spray medicine before and spray medicine after 1,3,7d, the parallel jump method in every community sample, often Point investigation 2 caves, amount to investigation 20 cave Bemisia tabaci insect population radixes, and whether checkout facility medicament has poisoning to crop simultaneously, records medicine The type of evil and the extent of injury, calculate prevention effect with check plot Bemisia tabaci nature insect population gradient.
Concrete result of the test is as shown in table 1:
Table 1: the composite insecticide prevention effect to Bemisia tabaci
Relatively above table data, the composite insecticide of the embodiment of the present invention 3 and 6 has for Bemisia tabaci and preferably controls effect Really, and at medication 3,7d, embodiment 3 shows that obvious advantage, especially more traditional on consumption insecticide have compared with remaining matched group Minimizing more than half amount.
Additionally, the different dosage form of other embodiments and the composite insecticide of proportioning are also carried out the test of little area, equally Each process decreases usage amount all have excellent control effect to Bemisia tabaci on the premise of.
To sum up, what the present invention provided contains double third ring worm esters and the composite insecticide of ethofenprox and application thereof, for tobacco powder The life physiological habit of louse, and the different insecticidal mechanisms of various medicament, get up its perfect adaptation, be aided with suitable auxiliary agent and Carrier, seeks most suitable proportioning and prevents and treats Bemisia tabaci, with tradition water prevention and controls compared with have the advantage that a) with Single dose is compared this kind and is had obvious potentiation to Bemisia tabaci, is remarkably improved prevention effect;B) can be with in Substitute For Partial High poison insecticide, reduces dosage, reduces environmental pollution and the residual of agricultural product;C) Bemisia tabaci can be delayed single insecticide Drug resistance;The advantage d) with lasting period length, compared with single medicament, it is possible to decrease cost.
It should be pointed out that, that above detailed description of the invention is merely to illustrate the present invention rather than limits the scope of the present invention, After having read the present invention, the amendment of the various equivalent form of values of the present invention is all fallen within and weighs appended by the application by those skilled in the art Profit requires limited range.

Claims (8)

1. one kind contains double third ring worm ester and composite insecticides of ethofenprox, it is characterised in that by weight by 5%~60% The auxiliary agent of main component, 5%~30% and the carrier composition of surplus;Wherein said main component include weight ratio be 1:50~ Double third ring worm ester and mixture of ethofenprox of 50:1.
It is the most according to claim 1 containing double third ring worm ester and composite insecticides of ethofenprox, it is characterised in that: described multiple The dosage form closing insecticide is the one in water dispersible granules, wettable powder, aqueous emulsion.
The most according to claim 1 containing double third ring worm ester and composite insecticides of ethofenprox, it is characterised in that to help described in: Agent is emulsifying agent, wetting agent, stabilizer, dispersant, thickening agent, defoamer, ph regulator, filler.
It is the most according to claim 1 containing double third ring worm ester and composite insecticides of ethofenprox, it is characterised in that: described multiple The dosage form closing insecticide is water dispersible granules, and main component percentage by weight is 24%, and concrete component is: the double third ring worm ester of 8g, 16g ethofenprox, 4g sodium lauryl sulphate, 2g polyoxyethylene lauryl ether, 2g lignosulfonates, 2g sulfonic acid polyformaldehyde are condensed Thing, 2g Polyethylene Glycol, 4g ammonium sulfate, 10g sodium carboxymethyl cellulose, Kaolin are mended to 100g.
It is the most according to claim 1 containing double third ring worm ester and composite insecticides of ethofenprox, it is characterised in that: described multiple The dosage form closing insecticide is wettable powder, and main component percentage by weight is 36%, and concrete component is: the double third ring worm ester of 12g, 24g ethofenprox, 4g sodium lauryl sulphate, 4g sodium lignin sulfonate, 2g pull open powder, kieselguhr complements to 100g.
It is the most according to claim 1 containing double third ring worm ester and composite insecticides of ethofenprox, it is characterised in that: described multiple The dosage form closing insecticide is aqueous emulsion, and main component percentage by weight is 24%, and concrete component is: 8g double third ring worm ester, 16g ether Chrysanthemum ester, 10g dimethylbenzene, 5gN-methyl pyrrolidone, 2g alkyl benzene calcium sulfonate, 6g phenethyl phenol mela mine-formaldehyde resin polyoxyethyl ether, 4g ethylene glycol, 0.4g silicone compound, 0.1g xanthan gum, 0.8g aluminium-magnesium silicate, water are mended to 100g.
A kind of containing double third ring worm esters with the application of the composite insecticide of ethofenprox, its feature exists In the preventing and treating for Bemisia tabaci.
It is the most according to claim 7 containing double third ring worm esters with the application of the composite insecticide of ethofenprox, it is characterised in that For every mu of crop, the consumption of composite insecticide is 25g/ mu.
CN201610473464.3A 2016-06-24 2016-06-24 A kind of containing double third ring worm esters and the composite insecticide of ethofenprox and application Pending CN106106500A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115886007A (en) * 2022-11-02 2023-04-04 上海沪联生物药业(夏邑)股份有限公司 Pesticide composition, application thereof and pesticide preparation containing same

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102905528A (en) * 2010-05-28 2013-01-30 巴斯夫欧洲公司 Pesticidal mixtures
CN103814909A (en) * 2014-02-11 2014-05-28 深圳诺普信农化股份有限公司 Synergistic pesticidal composition
WO2014079724A1 (en) * 2012-11-22 2014-05-30 Basf Se Pesticidal mixtures

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102905528A (en) * 2010-05-28 2013-01-30 巴斯夫欧洲公司 Pesticidal mixtures
WO2014079724A1 (en) * 2012-11-22 2014-05-30 Basf Se Pesticidal mixtures
CN103814909A (en) * 2014-02-11 2014-05-28 深圳诺普信农化股份有限公司 Synergistic pesticidal composition

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115886007A (en) * 2022-11-02 2023-04-04 上海沪联生物药业(夏邑)股份有限公司 Pesticide composition, application thereof and pesticide preparation containing same
CN115886007B (en) * 2022-11-02 2024-05-28 上海沪联生物药业(夏邑)股份有限公司 Pesticide composition, application thereof and pesticide preparation containing pesticide composition

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Application publication date: 20161116