CN106098389A - The preparation method containing platinum electrode that automobile batteries uses - Google Patents
The preparation method containing platinum electrode that automobile batteries uses Download PDFInfo
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- CN106098389A CN106098389A CN201610535846.4A CN201610535846A CN106098389A CN 106098389 A CN106098389 A CN 106098389A CN 201610535846 A CN201610535846 A CN 201610535846A CN 106098389 A CN106098389 A CN 106098389A
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/20—Light-sensitive devices
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
- H01G9/00—Electrolytic capacitors, rectifiers, detectors, switching devices, light-sensitive or temperature-sensitive devices; Processes of their manufacture
- H01G9/20—Light-sensitive devices
- H01G9/2059—Light-sensitive devices comprising an organic dye as the active light absorbing material, e.g. adsorbed on an electrode or dissolved in solution
- H01G9/2063—Light-sensitive devices comprising an organic dye as the active light absorbing material, e.g. adsorbed on an electrode or dissolved in solution comprising a mixture of two or more dyes
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/542—Dye sensitized solar cells
Abstract
The preparation method containing platinum electrode that a kind of automobile batteries uses: step 1: (FTO electro-conductive glass is the SnO2 transparent conducting glass (SnO2:F) of doped with fluorine at FTO conducting glass substrate by ion sputtering process, referred to as FTO) the upper Aurum metallicum thin film coating a layer, the instrument used is HitachiE 1010 ion sputtering instrument, the parameter arranged is pressure 12 Pa, electric current 14 mA, time 25 s, the purpose of one layer of gold thin film of spray is to make follow-up platinum deposition can start growth from the surface of FTO as seed gold.
Description
Technical field
The present invention relates to a kind of battery electrode, be particularly applied to the preparation method containing platinum electrode of automobile batteries.
Background technology
Metal platinum has the strongest corrosion resistance, after covering on electrode, can promote battery performance and life-span, but existing
Preparation containing the complex process of platinum electrode, power consumption height, be unfavorable for heavy industrialization.
Summary of the invention
The technical problem to be solved in the present invention is to propose a kind of brand-new preparation method, and simplification of flowsheet improves preparation
Efficiency.
The preparation method containing platinum electrode that a kind of automobile batteries uses:
Step 1: (FTO electro-conductive glass is the SnO2 electrically conducting transparent glass of doped with fluorine at FTO conducting glass substrate by ion sputtering process
Glass (SnO2:F), referred to as FTO) the upper Aurum metallicum thin film coating a layer, the instrument used is that HitachiE-1010 ion spatters
Penetrating instrument, the parameter of setting is pressure 12 Pa, electric current 14 mA, time 25 s, and the purpose of one layer of gold thin film of spray is as planting using gold
Son makes follow-up platinum deposition can start growth from the surface of FTO；
Step 2: by 1.1 mL chloroplatinic acids (concentration is 20 mg/mL), 0.4g polyethylene adjoins pyrrolidone, 0.2 mL methylamine solution
(concentration is 20 mg/mL) mixs homogeneously with 20 mL dimethyl methyl phthalein amine (concentration is 10 mg/mL), and solution is by water white transparency gradually
Fade to yellow turbid solution；
Step 3: in the autoclave of the polytetrafluoroethylsubstrate substrate that above-mentioned mixed liquor is put into 60 mL, that step 1 is prepared contains simultaneously
The FTO substrate of glass having gold grain faces up and puts into autoclave so that it is be completely submerged in reactant liquor；
Step 4: the autoclave of sealing is positioned over constant temperature in 1500C baking oven and keeps 2 hours, thus prepare primary platiniferous electricity
Pole.
Step 5: by 1.0 mL chloroplatinic acids (concentration is 20 mg/mL), 0.6g tri-Phosphoric acid monohexadecyl ester, 0.2g polypropylene
Ketopyrrolidine, 0.2 mL methylamine solution (concentration is 20 mg/mL) mixes with 20 mL dimethyl methyl phthalein amine (concentration is 10 mg/mL)
Closing uniformly, solution is graduated into yellow turbid solution by water white transparency；
Step 6: in the autoclave of the polytetrafluoroethylsubstrate substrate that above-mentioned mixed liquor is put into 70 mL, prepared by step 4 simultaneously at the beginning of
Level faces up containing platinum electrode and puts into autoclave so that it is be completely submerged in reactant liquor；
Step 7: the autoclave of sealing is positioned over constant temperature in 1800C baking oven and keeps 1 hour, thus prepare finished product platiniferous electricity
Pole.
Detailed description of the invention
Embodiment 1:
The preparation method containing platinum electrode that a kind of automobile batteries uses:
Step 1: (FTO electro-conductive glass is the SnO2 electrically conducting transparent glass of doped with fluorine at FTO conducting glass substrate by ion sputtering process
Glass (SnO2:F), referred to as FTO) the upper Aurum metallicum thin film coating a layer, the instrument used is that HitachiE-1010 ion spatters
Penetrating instrument, the parameter of setting is pressure 12 Pa, electric current 14 mA, time 25 s, and the purpose of one layer of gold thin film of spray is as planting using gold
Son makes follow-up platinum deposition can start growth from the surface of FTO；
Step 2: by 1.1 mL chloroplatinic acids (concentration is 20 mg/mL), 0.4g polyethylene adjoins pyrrolidone, 0.2 mL methylamine solution
(concentration is 20 mg/mL) mixs homogeneously with 20 mL dimethyl methyl phthalein amine (concentration is 10 mg/mL), and solution is by water white transparency gradually
Fade to yellow turbid solution；
Step 3: in the autoclave of the polytetrafluoroethylsubstrate substrate that above-mentioned mixed liquor is put into 60 mL, that step 1 is prepared contains simultaneously
The FTO substrate of glass having gold grain faces up and puts into autoclave so that it is be completely submerged in reactant liquor；
Step 4: the autoclave of sealing is positioned over constant temperature in 1500C baking oven and keeps 2 hours, thus prepare primary platiniferous electricity
Pole.
Step 5: by 1.0 mL chloroplatinic acids (concentration is 20 mg/mL), 0.6g tri-Phosphoric acid monohexadecyl ester, 0.2g polypropylene
Ketopyrrolidine, 0.2 mL methylamine solution (concentration is 20 mg/mL) mixes with 20 mL dimethyl methyl phthalein amine (concentration is 10 mg/mL)
Closing uniformly, solution is graduated into yellow turbid solution by water white transparency；
Step 6: in the autoclave of the polytetrafluoroethylsubstrate substrate that above-mentioned mixed liquor is put into 70 mL, prepared by step 4 simultaneously at the beginning of
Level faces up containing platinum electrode and puts into autoclave so that it is be completely submerged in reactant liquor；
Step 7: the autoclave of sealing is positioned over constant temperature in 1800C baking oven and keeps 1 hour, thus prepare finished product platiniferous electricity
Pole.
Embodiment 2:
The preparation method containing platinum electrode that a kind of automobile batteries uses:
Step 1: (FTO electro-conductive glass is the SnO2 electrically conducting transparent glass of doped with fluorine at FTO conducting glass substrate by ion sputtering process
Glass (SnO2:F), referred to as FTO) the upper Aurum metallicum thin film coating a layer, the instrument used is that HitachiE-1010 ion spatters
Penetrating instrument, the parameter of setting is pressure 12 Pa, electric current 14 mA, time 25 s, and the purpose of one layer of gold thin film of spray is as planting using gold
Son makes follow-up platinum deposition can start growth from the surface of FTO；
Step 2: by 1.2 mL chloroplatinic acids (concentration is 20 mg/mL), 0.4g polyethylene adjoins pyrrolidone, 0.2 mL methylamine solution
(concentration is 20 mg/mL) mixs homogeneously with 20 mL dimethyl methyl phthalein amine (concentration is 10 mg/mL), and solution is by water white transparency gradually
Fade to yellow turbid solution；
Step 3: in the autoclave of the polytetrafluoroethylsubstrate substrate that above-mentioned mixed liquor is put into 60 mL, that step 1 is prepared contains simultaneously
The FTO substrate of glass having gold grain faces up and puts into autoclave so that it is be completely submerged in reactant liquor；
Step 4: the autoclave of sealing is positioned over constant temperature in 1500C baking oven and keeps 2 hours, thus prepare primary platiniferous electricity
Pole.
Step 5: by 1.0 mL chloroplatinic acids (concentration is 20 mg/mL), 0.6g tri-Phosphoric acid monohexadecyl ester, 0.2g polypropylene
Ketopyrrolidine, 0.2 mL methylamine solution (concentration is 20 mg/mL) mixes with 20 mL dimethyl methyl phthalein amine (concentration is 10 mg/mL)
Closing uniformly, solution is graduated into yellow turbid solution by water white transparency；
Step 6: in the autoclave of the polytetrafluoroethylsubstrate substrate that above-mentioned mixed liquor is put into 70 mL, prepared by step 4 simultaneously at the beginning of
Level faces up containing platinum electrode and puts into autoclave so that it is be completely submerged in reactant liquor；
Step 7: the autoclave of sealing is positioned over constant temperature in 1800C baking oven and keeps 1 hour, thus prepare finished product platiniferous electricity
Pole.
Embodiment 3:
The preparation method containing platinum electrode that a kind of automobile batteries uses:
Step 1: (FTO electro-conductive glass is the SnO2 electrically conducting transparent glass of doped with fluorine at FTO conducting glass substrate by ion sputtering process
Glass (SnO2:F), referred to as FTO) the upper Aurum metallicum thin film coating a layer, the instrument used is that HitachiE-1010 ion spatters
Penetrating instrument, the parameter of setting is pressure 12 Pa, electric current 14 mA, time 25 s, and the purpose of one layer of gold thin film of spray is as planting using gold
Son makes follow-up platinum deposition can start growth from the surface of FTO；
Step 2: by 1.3 mL chloroplatinic acids (concentration is 20 mg/mL), 0.4g polyethylene adjoins pyrrolidone, 0.2 mL methylamine solution
(concentration is 20 mg/mL) mixs homogeneously with 20 mL dimethyl methyl phthalein amine (concentration is 10 mg/mL), and solution is by water white transparency gradually
Fade to yellow turbid solution；
Step 3: in the autoclave of the polytetrafluoroethylsubstrate substrate that above-mentioned mixed liquor is put into 60 mL, that step 1 is prepared contains simultaneously
The FTO substrate of glass having gold grain faces up and puts into autoclave so that it is be completely submerged in reactant liquor；
Step 4: the autoclave of sealing is positioned over constant temperature in 1500C baking oven and keeps 2 hours, thus prepare primary platiniferous electricity
Pole.
Step 5: by 1.0 mL chloroplatinic acids (concentration is 20 mg/mL), 0.6g tri-Phosphoric acid monohexadecyl ester, 0.2g polypropylene
Ketopyrrolidine, 0.2 mL methylamine solution (concentration is 20 mg/mL) mixes with 20 mL dimethyl methyl phthalein amine (concentration is 10 mg/mL)
Closing uniformly, solution is graduated into yellow turbid solution by water white transparency；
Step 6: in the autoclave of the polytetrafluoroethylsubstrate substrate that above-mentioned mixed liquor is put into 70 mL, prepared by step 4 simultaneously at the beginning of
Level faces up containing platinum electrode and puts into autoclave so that it is be completely submerged in reactant liquor；
Step 7: the autoclave of sealing is positioned over constant temperature in 1800C baking oven and keeps 1 hour, thus prepare finished product platiniferous electricity
Pole.
Embodiment 4:
The preparation method containing platinum electrode that a kind of automobile batteries uses:
Step 1: (FTO electro-conductive glass is the SnO2 electrically conducting transparent glass of doped with fluorine at FTO conducting glass substrate by ion sputtering process
Glass (SnO2:F), referred to as FTO) the upper Aurum metallicum thin film coating a layer, the instrument used is that HitachiE-1010 ion spatters
Penetrating instrument, the parameter of setting is pressure 12 Pa, electric current 14 mA, time 25 s, and the purpose of one layer of gold thin film of spray is as planting using gold
Son makes follow-up platinum deposition can start growth from the surface of FTO；
Step 2: by 1.0 mL chloroplatinic acids (concentration is 20 mg/mL), 0.4g polyethylene adjoins pyrrolidone, 0.2 mL methylamine solution
(concentration is 20 mg/mL) mixs homogeneously with 20 mL dimethyl methyl phthalein amine (concentration is 10 mg/mL), and solution is by water white transparency gradually
Fade to yellow turbid solution；
Step 3: in the autoclave of the polytetrafluoroethylsubstrate substrate that above-mentioned mixed liquor is put into 60 mL, that step 1 is prepared contains simultaneously
The FTO substrate of glass having gold grain faces up and puts into autoclave so that it is be completely submerged in reactant liquor；
Step 4: the autoclave of sealing is positioned over constant temperature in 1500C baking oven and keeps 2 hours, thus prepare primary platiniferous electricity
Pole.
Step 5: by 1.4 mL chloroplatinic acids (concentration is 20 mg/mL), 0.6g tri-Phosphoric acid monohexadecyl ester, 0.2g polypropylene
Ketopyrrolidine, 0.2 mL methylamine solution (concentration is 20 mg/mL) mixes with 20 mL dimethyl methyl phthalein amine (concentration is 10 mg/mL)
Closing uniformly, solution is graduated into yellow turbid solution by water white transparency；
Step 6: in the autoclave of the polytetrafluoroethylsubstrate substrate that above-mentioned mixed liquor is put into 70 mL, prepared by step 4 simultaneously at the beginning of
Level faces up containing platinum electrode and puts into autoclave so that it is be completely submerged in reactant liquor；
Step 7: the autoclave of sealing is positioned over constant temperature in 1800C baking oven and keeps 1 hour, thus prepare finished product platiniferous electricity
Pole.
Embodiment 5:
The preparation method containing platinum electrode that a kind of automobile batteries uses:
Step 1: (FTO electro-conductive glass is the SnO2 electrically conducting transparent glass of doped with fluorine at FTO conducting glass substrate by ion sputtering process
Glass (SnO2:F), referred to as FTO) the upper Aurum metallicum thin film coating a layer, the instrument used is that HitachiE-1010 ion spatters
Penetrating instrument, the parameter of setting is pressure 12 Pa, electric current 14 mA, time 25 s, and the purpose of one layer of gold thin film of spray is as planting using gold
Son makes follow-up platinum deposition can start growth from the surface of FTO；
Step 2: by 1.5 mL chloroplatinic acids (concentration is 20 mg/mL), 0.4g polyethylene adjoins pyrrolidone, 0.2 mL methylamine solution
(concentration is 20 mg/mL) mixs homogeneously with 20 mL dimethyl methyl phthalein amine (concentration is 10 mg/mL), and solution is by water white transparency gradually
Fade to yellow turbid solution；
Step 3: in the autoclave of the polytetrafluoroethylsubstrate substrate that above-mentioned mixed liquor is put into 60 mL, that step 1 is prepared contains simultaneously
The FTO substrate of glass having gold grain faces up and puts into autoclave so that it is be completely submerged in reactant liquor；
Step 4: the autoclave of sealing is positioned over constant temperature in 1500C baking oven and keeps 2 hours, thus prepare primary platiniferous electricity
Pole.
Step 5: by 1.0 mL chloroplatinic acids (concentration is 20 mg/mL), 0.6g tri-Phosphoric acid monohexadecyl ester, 0.2g polypropylene
Ketopyrrolidine, 0.2 mL methylamine solution (concentration is 20 mg/mL) mixes with 20 mL dimethyl methyl phthalein amine (concentration is 10 mg/mL)
Closing uniformly, solution is graduated into yellow turbid solution by water white transparency；
Step 6: in the autoclave of the polytetrafluoroethylsubstrate substrate that above-mentioned mixed liquor is put into 70 mL, prepared by step 4 simultaneously at the beginning of
Level faces up containing platinum electrode and puts into autoclave so that it is be completely submerged in reactant liquor；
Step 7: the autoclave of sealing is positioned over constant temperature in 1800C baking oven and keeps 1 hour, thus prepare finished product platiniferous electricity
Pole.
Embodiment 6:
The preparation method containing platinum electrode that a kind of automobile batteries uses:
Step 1: (FTO electro-conductive glass is the SnO2 electrically conducting transparent glass of doped with fluorine at FTO conducting glass substrate by ion sputtering process
Glass (SnO2:F), referred to as FTO) the upper Aurum metallicum thin film coating a layer, the instrument used is that HitachiE-1010 ion spatters
Penetrating instrument, the parameter of setting is pressure 12 Pa, electric current 14 mA, time 25 s, and the purpose of one layer of gold thin film of spray is as planting using gold
Son makes follow-up platinum deposition can start growth from the surface of FTO；
Step 2: by 1.6 mL chloroplatinic acids (concentration is 20 mg/mL), 0.4g polyethylene adjoins pyrrolidone, 0.2 mL methylamine solution
(concentration is 20 mg/mL) mixs homogeneously with 20 mL dimethyl methyl phthalein amine (concentration is 10 mg/mL), and solution is by water white transparency gradually
Fade to yellow turbid solution；
Step 3: in the autoclave of the polytetrafluoroethylsubstrate substrate that above-mentioned mixed liquor is put into 60 mL, that step 1 is prepared contains simultaneously
The FTO substrate of glass having gold grain faces up and puts into autoclave so that it is be completely submerged in reactant liquor；
Step 4: the autoclave of sealing is positioned over constant temperature in 1500C baking oven and keeps 2 hours, thus prepare primary platiniferous electricity
Pole.
Step 5: by 1.0 mL chloroplatinic acids (concentration is 20 mg/mL), 0.6g tri-Phosphoric acid monohexadecyl ester, 0.2g polypropylene
Ketopyrrolidine, 0.2 mL methylamine solution (concentration is 20 mg/mL) mixes with 20 mL dimethyl methyl phthalein amine (concentration is 10 mg/mL)
Closing uniformly, solution is graduated into yellow turbid solution by water white transparency；
Step 6: in the autoclave of the polytetrafluoroethylsubstrate substrate that above-mentioned mixed liquor is put into 70 mL, prepared by step 4 simultaneously at the beginning of
Level faces up containing platinum electrode and puts into autoclave so that it is be completely submerged in reactant liquor；
Step 7: the autoclave of sealing is positioned over constant temperature in 1800C baking oven and keeps 1 hour, thus prepare finished product platiniferous electricity
Pole.
Embodiment 7:
The preparation method containing platinum electrode that a kind of automobile batteries uses:
Step 1: (FTO electro-conductive glass is the SnO2 electrically conducting transparent glass of doped with fluorine at FTO conducting glass substrate by ion sputtering process
Glass (SnO2:F), referred to as FTO) the upper Aurum metallicum thin film coating a layer, the instrument used is that HitachiE-1010 ion spatters
Penetrating instrument, the parameter of setting is pressure 12 Pa, electric current 14 mA, time 25 s, and the purpose of one layer of gold thin film of spray is as planting using gold
Son makes follow-up platinum deposition can start growth from the surface of FTO；
Step 2: by 1.7 mL chloroplatinic acids (concentration is 20 mg/mL), 0.4g polyethylene adjoins pyrrolidone, 0.2 mL methylamine solution
(concentration is 20 mg/mL) mixs homogeneously with 20 mL dimethyl methyl phthalein amine (concentration is 10 mg/mL), and solution is by water white transparency gradually
Fade to yellow turbid solution；
Step 3: in the autoclave of the polytetrafluoroethylsubstrate substrate that above-mentioned mixed liquor is put into 60 mL, that step 1 is prepared contains simultaneously
The FTO substrate of glass having gold grain faces up and puts into autoclave so that it is be completely submerged in reactant liquor；
Step 4: the autoclave of sealing is positioned over constant temperature in 1500C baking oven and keeps 2 hours, thus prepare primary platiniferous electricity
Pole.
Step 5: by 1.0 mL chloroplatinic acids (concentration is 20 mg/mL), 0.6g tri-Phosphoric acid monohexadecyl ester, 0.2g polypropylene
Ketopyrrolidine, 0.2 mL methylamine solution (concentration is 20 mg/mL) mixes with 20 mL dimethyl methyl phthalein amine (concentration is 10 mg/mL)
Closing uniformly, solution is graduated into yellow turbid solution by water white transparency；
Step 6: in the autoclave of the polytetrafluoroethylsubstrate substrate that above-mentioned mixed liquor is put into 70 mL, prepared by step 4 simultaneously at the beginning of
Level faces up containing platinum electrode and puts into autoclave so that it is be completely submerged in reactant liquor；
Step 7: the autoclave of sealing is positioned over constant temperature in 1800C baking oven and keeps 1 hour, thus prepare finished product platiniferous electricity
Pole.
Embodiment 8:
The preparation method containing platinum electrode that a kind of automobile batteries uses:
Step 1: (FTO electro-conductive glass is the SnO2 electrically conducting transparent glass of doped with fluorine at FTO conducting glass substrate by ion sputtering process
Glass (SnO2:F), referred to as FTO) the upper Aurum metallicum thin film coating a layer, the instrument used is that HitachiE-1010 ion spatters
Penetrating instrument, the parameter of setting is pressure 12 Pa, electric current 14 mA, time 25 s, and the purpose of one layer of gold thin film of spray is as planting using gold
Son makes follow-up platinum deposition can start growth from the surface of FTO；
Step 2: by 1.8 mL chloroplatinic acids (concentration is 20 mg/mL), 0.4g polyethylene adjoins pyrrolidone, 0.2 mL methylamine solution
(concentration is 20 mg/mL) mixs homogeneously with 20 mL dimethyl methyl phthalein amine (concentration is 10 mg/mL), and solution is by water white transparency gradually
Fade to yellow turbid solution；
Step 3: in the autoclave of the polytetrafluoroethylsubstrate substrate that above-mentioned mixed liquor is put into 60 mL, that step 1 is prepared contains simultaneously
The FTO substrate of glass having gold grain faces up and puts into autoclave so that it is be completely submerged in reactant liquor；
Step 4: the autoclave of sealing is positioned over constant temperature in 1500C baking oven and keeps 2 hours, thus prepare primary platiniferous electricity
Pole.
Step 5: by 1.0 mL chloroplatinic acids (concentration is 20 mg/mL), 0.6g tri-Phosphoric acid monohexadecyl ester, 0.2g polypropylene
Ketopyrrolidine, 0.2 mL methylamine solution (concentration is 20 mg/mL) mixes with 20 mL dimethyl methyl phthalein amine (concentration is 10 mg/mL)
Closing uniformly, solution is graduated into yellow turbid solution by water white transparency；
Step 6: in the autoclave of the polytetrafluoroethylsubstrate substrate that above-mentioned mixed liquor is put into 70 mL, prepared by step 4 simultaneously at the beginning of
Level faces up containing platinum electrode and puts into autoclave so that it is be completely submerged in reactant liquor；
Step 7: the autoclave of sealing is positioned over constant temperature in 1800C baking oven and keeps 1 hour, thus prepare finished product platiniferous electricity
Pole.
Embodiment 9:
The preparation method containing platinum electrode that a kind of automobile batteries uses:
Step 1: (FTO electro-conductive glass is the SnO2 electrically conducting transparent glass of doped with fluorine at FTO conducting glass substrate by ion sputtering process
Glass (SnO2:F), referred to as FTO) the upper Aurum metallicum thin film coating a layer, the instrument used is that HitachiE-1010 ion spatters
Penetrating instrument, the parameter of setting is pressure 12 Pa, electric current 14 mA, time 25 s, and the purpose of one layer of gold thin film of spray is as planting using gold
Son makes follow-up platinum deposition can start growth from the surface of FTO；
Step 2: by 1.9 mL chloroplatinic acids (concentration is 20 mg/mL), 0.4g polyethylene adjoins pyrrolidone, 0.2 mL methylamine solution
(concentration is 20 mg/mL) mixs homogeneously with 20 mL dimethyl methyl phthalein amine (concentration is 10 mg/mL), and solution is by water white transparency gradually
Fade to yellow turbid solution；
Step 3: in the autoclave of the polytetrafluoroethylsubstrate substrate that above-mentioned mixed liquor is put into 60 mL, that step 1 is prepared contains simultaneously
The FTO substrate of glass having gold grain faces up and puts into autoclave so that it is be completely submerged in reactant liquor；
Step 4: the autoclave of sealing is positioned over constant temperature in 1500C baking oven and keeps 2 hours, thus prepare primary platiniferous electricity
Pole.
Step 5: by 1.0 mL chloroplatinic acids (concentration is 20 mg/mL), 0.6g tri-Phosphoric acid monohexadecyl ester, 0.2g polypropylene
Ketopyrrolidine, 0.2 mL methylamine solution (concentration is 20 mg/mL) mixes with 20 mL dimethyl methyl phthalein amine (concentration is 10 mg/mL)
Closing uniformly, solution is graduated into yellow turbid solution by water white transparency；
Step 6: in the autoclave of the polytetrafluoroethylsubstrate substrate that above-mentioned mixed liquor is put into 70 mL, prepared by step 4 simultaneously at the beginning of
Level faces up containing platinum electrode and puts into autoclave so that it is be completely submerged in reactant liquor；
Step 7: the autoclave of sealing is positioned over constant temperature in 1800C baking oven and keeps 1 hour, thus prepare finished product platiniferous electricity
Pole.
Embodiment 10:
The preparation method containing platinum electrode that a kind of automobile batteries uses:
Step 1: (FTO electro-conductive glass is the SnO2 electrically conducting transparent glass of doped with fluorine at FTO conducting glass substrate by ion sputtering process
Glass (SnO2:F), referred to as FTO) the upper Aurum metallicum thin film coating a layer, the instrument used is that HitachiE-1010 ion spatters
Penetrating instrument, the parameter of setting is pressure 12 Pa, electric current 14 mA, time 25 s, and the purpose of one layer of gold thin film of spray is as planting using gold
Son makes follow-up platinum deposition can start growth from the surface of FTO；
Step 2: by 2.0 mL chloroplatinic acids (concentration is 20 mg/mL), 0.4g polyethylene adjoins pyrrolidone, 0.2 mL methylamine solution
(concentration is 20 mg/mL) mixs homogeneously with 20 mL dimethyl methyl phthalein amine (concentration is 10 mg/mL), and solution is by water white transparency gradually
Fade to yellow turbid solution；
Step 3: in the autoclave of the polytetrafluoroethylsubstrate substrate that above-mentioned mixed liquor is put into 60 mL, that step 1 is prepared contains simultaneously
The FTO substrate of glass having gold grain faces up and puts into autoclave so that it is be completely submerged in reactant liquor；
Step 4: the autoclave of sealing is positioned over constant temperature in 1500C baking oven and keeps 2 hours, thus prepare primary platiniferous electricity
Pole.
Step 5: by 1.0 mL chloroplatinic acids (concentration is 20 mg/mL), 0.6g tri-Phosphoric acid monohexadecyl ester, 0.2g polypropylene
Ketopyrrolidine, 0.2 mL methylamine solution (concentration is 20 mg/mL) mixes with 20 mL dimethyl methyl phthalein amine (concentration is 10 mg/mL)
Closing uniformly, solution is graduated into yellow turbid solution by water white transparency；
Step 6: in the autoclave of the polytetrafluoroethylsubstrate substrate that above-mentioned mixed liquor is put into 70 mL, prepared by step 4 simultaneously at the beginning of
Level faces up containing platinum electrode and puts into autoclave so that it is be completely submerged in reactant liquor；
Step 7: the autoclave of sealing is positioned over constant temperature in 1800C baking oven and keeps 1 hour, thus prepare finished product platiniferous electricity
Pole.
Embodiment 11:
The preparation method containing platinum electrode that a kind of automobile batteries uses:
Step 1: (FTO electro-conductive glass is the SnO2 electrically conducting transparent glass of doped with fluorine at FTO conducting glass substrate by ion sputtering process
Glass (SnO2:F), referred to as FTO) the upper Aurum metallicum thin film coating a layer, the instrument used is that HitachiE-1010 ion spatters
Penetrating instrument, the parameter of setting is pressure 12 Pa, electric current 14 mA, time 25 s, and the purpose of one layer of gold thin film of spray is as planting using gold
Son makes follow-up platinum deposition can start growth from the surface of FTO；
Step 2: 1.0 mL(can also be selected from following amounts: 1.1ml, 1.2ml, 1.3ml, 1.4ml, 1.5ml,
1.6ml.1.7ml, 1.8ml, 1.9ml, 2.0ml) chloroplatinic acid (concentration is 20 mg/mL), 0.4g polyethylene adjoins pyrrolidone, and 0.2
ML methylamine solution (concentration is 20 mg/mL) is mixed homogeneously with 20 mL dimethyl methyl phthalein amine (concentration is 10 mg/mL), solution by
Water white transparency graduates into yellow turbid solution；
Step 3: in the autoclave of the polytetrafluoroethylsubstrate substrate that above-mentioned mixed liquor is put into 60 mL, that step 1 is prepared contains simultaneously
The FTO substrate of glass having gold grain faces up and puts into autoclave so that it is be completely submerged in reactant liquor；
Step 4: the autoclave of sealing is positioned over constant temperature in 1500C baking oven and keeps 2 hours, thus prepare primary platiniferous electricity
Pole.
Step 5: 1.0 mL(can also be selected from following amounts: 1.1ml, 1.2ml, 1.3ml, 1.4ml, 1.5ml,
1.6ml.1.7ml, 1.8ml, 1.9ml, 2.0ml) chloroplatinic acid (concentration is 20 mg/mL), 0.6g tri-Phosphoric acid monohexadecyl ester,
0.2g polyvinyl pyrilodone, (concentration is for 0.2 mL methylamine solution (concentration is 20 mg/mL) and 20 mL dimethyl methyl phthalein amine
10 mg/mL) mix homogeneously, solution is graduated into yellow turbid solution by water white transparency；
Step 6: in the autoclave of the polytetrafluoroethylsubstrate substrate that above-mentioned mixed liquor is put into 70 mL, prepared by step 4 simultaneously at the beginning of
Level faces up containing platinum electrode and puts into autoclave so that it is be completely submerged in reactant liquor；
Step 7: the autoclave of sealing is positioned over constant temperature in 1800C baking oven and keeps 1 hour, thus prepare finished product platiniferous electricity
Pole.
Claims (2)
1. the preparation method containing platinum electrode that an automobile batteries uses:
Step 1: (FTO electro-conductive glass is the SnO2 electrically conducting transparent glass of doped with fluorine at FTO conducting glass substrate by ion sputtering process
Glass (SnO2:F), referred to as FTO) the upper Aurum metallicum thin film coating a layer, the instrument used is that HitachiE-1010 ion spatters
Penetrating instrument, the parameter of setting is pressure 12 Pa, electric current 14 mA, time 25 s, and the purpose of one layer of gold thin film of spray is as planting using gold
Son makes follow-up platinum deposition can start growth from the surface of FTO；
Step 2: by 1.1 mL chloroplatinic acids (concentration is 20 mg/mL), 0.4g polyethylene adjoins pyrrolidone, 0.2 mL methylamine solution
(concentration is 20 mg/mL) mixs homogeneously with 20 mL dimethyl methyl phthalein amine (concentration is 10 mg/mL), and solution is by water white transparency gradually
Fade to yellow turbid solution；
Step 3: in the autoclave of the polytetrafluoroethylsubstrate substrate that above-mentioned mixed liquor is put into 60 mL, that step 1 is prepared contains simultaneously
The FTO substrate of glass having gold grain faces up and puts into autoclave so that it is be completely submerged in reactant liquor；
Step 4: the autoclave of sealing is positioned over constant temperature in 1500C baking oven and keeps 2 hours, thus prepare primary platiniferous electricity
Pole；Step 5: by 1.0 mL chloroplatinic acids (concentration is 20 mg/mL), 0.6g tri-Phosphoric acid monohexadecyl ester, 0.2g polypropylene pyrrolidine
Ketone, 0.2 mL methylamine solution (concentration is 20 mg/mL) mixes all with 20 mL dimethyl methyl phthalein amine (concentration is 10 mg/mL)
Even, solution is graduated into yellow turbid solution by water white transparency；
Step 6: in the autoclave of the polytetrafluoroethylsubstrate substrate that above-mentioned mixed liquor is put into 70 mL, prepared by step 4 simultaneously at the beginning of
Level faces up containing platinum electrode and puts into autoclave so that it is be completely submerged in reactant liquor；
Step 7: the autoclave of sealing is positioned over constant temperature in 1800C baking oven and keeps 1 hour, thus prepare finished product platiniferous electricity
Pole.
2. present invention can apply to electric automobile field.
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| CN102166518A (en) * | 2011-03-21 | 2011-08-31 | 天津大学 | Method for preparing electrocatalytic noble metal nanomaterial with three-dimensional network structure |
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| CN102166518A (en) * | 2011-03-21 | 2011-08-31 | 天津大学 | Method for preparing electrocatalytic noble metal nanomaterial with three-dimensional network structure |
| CN102189267A (en) * | 2011-04-26 | 2011-09-21 | 浙江理工大学 | Method for preparing highly-dispersed regular octahedral platinum nano particles |
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| CN107895650A (en) * | 2017-11-27 | 2018-04-10 | 王瑞明 | The preparation method containing platinum electrode that automobile batteries uses |
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