CN106086481B - 一种回收含锗废液中锗的方法 - Google Patents
一种回收含锗废液中锗的方法 Download PDFInfo
- Publication number
- CN106086481B CN106086481B CN201610713310.7A CN201610713310A CN106086481B CN 106086481 B CN106086481 B CN 106086481B CN 201610713310 A CN201610713310 A CN 201610713310A CN 106086481 B CN106086481 B CN 106086481B
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- Prior art keywords
- germanium
- resin
- germanic
- solution
- waste liquid
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- 229910052732 germanium Inorganic materials 0.000 title claims abstract description 119
- 238000000034 method Methods 0.000 title claims abstract description 34
- 239000007788 liquid Substances 0.000 title claims abstract description 23
- 239000002699 waste material Substances 0.000 title claims abstract description 17
- 238000004064 recycling Methods 0.000 title claims abstract description 12
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 title claims abstract 22
- 239000000243 solution Substances 0.000 claims abstract description 50
- 239000011347 resin Substances 0.000 claims abstract description 45
- 229920005989 resin Polymers 0.000 claims abstract description 45
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 39
- 239000002253 acid Substances 0.000 claims abstract description 26
- IEXRMSFAVATTJX-UHFFFAOYSA-N tetrachlorogermane Chemical compound Cl[Ge](Cl)(Cl)Cl IEXRMSFAVATTJX-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000012670 alkaline solution Substances 0.000 claims abstract description 19
- 238000004821 distillation Methods 0.000 claims abstract description 19
- 239000012141 concentrate Substances 0.000 claims abstract description 17
- 238000010521 absorption reaction Methods 0.000 claims abstract description 12
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims abstract description 11
- VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical compound C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000013307 optical fiber Substances 0.000 claims abstract description 7
- 239000005049 silicon tetrachloride Substances 0.000 claims abstract description 7
- 239000007921 spray Substances 0.000 claims abstract description 7
- -1 germanic acid radical ion Chemical class 0.000 claims description 33
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 16
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 9
- 239000003957 anion exchange resin Substances 0.000 claims description 9
- 230000008569 process Effects 0.000 claims description 9
- 239000004593 Epoxy Substances 0.000 claims description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- 238000004140 cleaning Methods 0.000 claims description 6
- 150000002500 ions Chemical class 0.000 claims description 6
- 238000005660 chlorination reaction Methods 0.000 claims description 3
- 230000003472 neutralizing effect Effects 0.000 claims description 2
- 125000003011 styrenyl group Chemical class [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims 2
- XCNHXROWMVKLEB-UHFFFAOYSA-N [Ge+2].[O-2].[O-2].[Ti+4] Chemical compound [Ge+2].[O-2].[O-2].[Ti+4] XCNHXROWMVKLEB-UHFFFAOYSA-N 0.000 claims 1
- YBMRDBCBODYGJE-UHFFFAOYSA-N germanium dioxide Chemical compound O=[Ge]=O YBMRDBCBODYGJE-UHFFFAOYSA-N 0.000 abstract description 11
- 238000011084 recovery Methods 0.000 abstract description 8
- 238000004519 manufacturing process Methods 0.000 abstract description 7
- 238000001179 sorption measurement Methods 0.000 abstract description 7
- 229940119177 germanium dioxide Drugs 0.000 abstract description 5
- 238000007796 conventional method Methods 0.000 abstract description 3
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 abstract description 3
- 238000003912 environmental pollution Methods 0.000 abstract description 2
- 230000007062 hydrolysis Effects 0.000 abstract 1
- 238000006460 hydrolysis reaction Methods 0.000 abstract 1
- VGRFVJMYCCLWPQ-UHFFFAOYSA-N germanium Chemical compound [Ge].[Ge] VGRFVJMYCCLWPQ-UHFFFAOYSA-N 0.000 description 81
- 239000007789 gas Substances 0.000 description 19
- FNIHDXPFFIOGKL-UHFFFAOYSA-N disodium;dioxido(oxo)germane Chemical compound [Na+].[Na+].[O-][Ge]([O-])=O FNIHDXPFFIOGKL-UHFFFAOYSA-N 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 6
- 239000002994 raw material Substances 0.000 description 4
- 239000001648 tannin Substances 0.000 description 4
- 235000018553 tannin Nutrition 0.000 description 4
- 229920001864 tannin Polymers 0.000 description 4
- 230000008859 change Effects 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229910020218 Pb—Zn Inorganic materials 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 241000790917 Dioxys <bee> Species 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000003077 lignite Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001698 pyrogenic effect Effects 0.000 description 1
- FDNAPBUWERUEDA-UHFFFAOYSA-N silicon tetrachloride Chemical compound Cl[Si](Cl)(Cl)Cl FDNAPBUWERUEDA-UHFFFAOYSA-N 0.000 description 1
- 230000000192 social effect Effects 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B41/00—Obtaining germanium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/006—Wet processes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
Claims (4)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201610713310.7A CN106086481B (zh) | 2016-08-23 | 2016-08-23 | 一种回收含锗废液中锗的方法 |
Applications Claiming Priority (1)
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CN201610713310.7A CN106086481B (zh) | 2016-08-23 | 2016-08-23 | 一种回收含锗废液中锗的方法 |
Publications (2)
Publication Number | Publication Date |
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CN106086481A CN106086481A (zh) | 2016-11-09 |
CN106086481B true CN106086481B (zh) | 2018-08-24 |
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Family Applications (1)
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CN201610713310.7A Active CN106086481B (zh) | 2016-08-23 | 2016-08-23 | 一种回收含锗废液中锗的方法 |
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CN (1) | CN106086481B (zh) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109055760A (zh) * | 2018-09-28 | 2018-12-21 | 郴州丰越环保科技有限公司 | 一种高锌高砷锗料回收锗的方法 |
CN110921905A (zh) * | 2019-12-12 | 2020-03-27 | 四川高锗再生资源有限公司 | 一种高纯二氧化锗生产中含锗液的回收***及方法 |
CN111254286A (zh) * | 2020-03-24 | 2020-06-09 | 中天科技精密材料有限公司 | 低浓度锗废液中锗的回收方法 |
CN112760497B (zh) * | 2021-01-26 | 2022-09-09 | 云南东昌金属加工有限公司 | 提锗尾气净化处理的吸收碱液中锗的回收方法 |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102828054A (zh) * | 2012-09-03 | 2012-12-19 | 四川长虹电器股份有限公司 | 酸浸-阳离子交换树脂吸附工艺从废液晶板回收铟的方法 |
CN104357688B (zh) * | 2014-11-19 | 2016-06-22 | 辽宁大学 | 萃淋树脂吸萃分离锗的方法 |
CN104593611A (zh) * | 2014-12-30 | 2015-05-06 | 郴州丰越环保科技有限公司 | 一种高效回收锗的方法 |
CN105567986B (zh) * | 2015-12-31 | 2018-01-02 | 郴州丰越环保科技有限公司 | 一种用树脂从锌粉置换镓锗渣中回收镓锗的方法 |
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2016
- 2016-08-23 CN CN201610713310.7A patent/CN106086481B/zh active Active
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CN106086481A (zh) | 2016-11-09 |
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TR01 | Transfer of patent right |
Effective date of registration: 20240312 Address after: 314000 No. 1658, Hongxing Road, Xiuzhou District, Jiaxing City, Zhejiang Province Patentee after: Liu Bo Country or region after: China Address before: 310013 No. 38, Zhejiang Road, Hangzhou, Zhejiang, Xihu District Patentee before: Wang Peng Country or region before: China |
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Effective date of registration: 20240624 Address after: 235199 Inside No. 8 Bahe Road, Suixi Economic Development Zone, Suixi County, Huaibei City, Anhui Province Patentee after: Huaibei Leisaike New Energy Technology Co.,Ltd. Country or region after: China Address before: 314000 No. 1658, Hongxing Road, Xiuzhou District, Jiaxing City, Zhejiang Province Patentee before: Liu Bo Country or region before: China |
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