CN106085205A - A kind of saponification steel alloy anticorrosive paint and preparation method thereof - Google Patents
A kind of saponification steel alloy anticorrosive paint and preparation method thereof Download PDFInfo
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- CN106085205A CN106085205A CN201610543376.6A CN201610543376A CN106085205A CN 106085205 A CN106085205 A CN 106085205A CN 201610543376 A CN201610543376 A CN 201610543376A CN 106085205 A CN106085205 A CN 106085205A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D179/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen, with or without oxygen, or carbon only, not provided for in groups C09D161/00 - C09D177/00
- C09D179/02—Polyamines
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/02—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using non-aqueous solutions
- C23C22/03—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using non-aqueous solutions containing phosphorus compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical Kinetics & Catalysis (AREA)
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- Metallurgy (AREA)
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Abstract
The invention discloses a kind of saponification steel alloy anticorrosive paint, it is made up of the raw material of following weight parts；Aluminium triphosphate 12, myristic acid soda soap 35, aniline 50 60, pyrroles 30 40, sulfosalicylic acid 79, epoxy resin E513 4, Ammonium persulfate. 1.3 2, molybdic acid 46, polyamide 35, n-butyl alcohol 160 170, butyl glycol ether 20 30, chlorine dimethyl phthalate 0.2 0.4, aphthenic acids lithium 0.1 0.2, diisopropyl ethanolamine 0.8 1, Cera Flava 12, dithio-salicylic acid 12, thiol-butyl tin 0.3 1, tetramethylolmethane 67.The myristic acid soda soap etc. that the present invention adds can effectively improve the pliability of finished product coating.
Description
Technical field
The present invention relates to anticorrosive paint technical field, particularly relate to a kind of saponification steel alloy anticorrosive paint and preparation side thereof
Method.
Background technology
Polyaniline increasingly causes the attention of people as a kind of novel conducting polymer composite in recent years.It synthesizes work
Skill is simple, environmentally safe, low cost have the features such as stable thermodynamic property and chemical property and make it lead at each
Territory is all widely used.Particularly its excellent antiseptic property makes it the most extensive in the application of corrosion-resistant field.But its paint film
Fragile adhesive force and slightly solubility are applied to create the biggest restriction.If by chemical corrosion resistance excellent for polyaniline and ring
The adhesive force of epoxy resins excellence and mechanical property combine prepares blended coating, and this will be greatly improved epoxy coating
Antiseptic power, also overcomes the weakness of polyaniline paint simultaneously, thus is greatly improved its range of application and antiseptic property；
Polyaniline film can carry out protection in acid medium to ferrous materials makes its surface soul and the erosion medium resistance that is not corroded,
This discovery starts so that polyaniline is shown up prominently at corrosion-resistant field.Showed through the substantial amounts of experimental data of research worker later, poly-
Aniline has scratch resistance and the effect of anti-spot corrosion of uniqueness, and after it mixes with epoxy resin, Xu is overlying on the anticorrosion of metal surface
Having exceeded during performance-based only coated with resins and got well all times of even an order of magnitude, it is harsh that it also can be suitably used for ocean and Aero-Space etc.
Condition makes this material increasingly be taken seriously.Additionally also there is polyaniline in fields such as microelectronics packaging and electronic package
Figure；
Polyaniline bad dispersibility in polyaniline/cold coating and poor adhesive force etc. the most all greatly reduce the anti-of polyaniline
Rotten performance, the physics impermeabilisation ability of polyaniline does not reaches the most far away the use condition requirement of harshness simultaneously.So how improve
The insoluble energy of polyaniline, dispersive property and impermeabilisation ability are to improve the key of anticorrosive polyaniline ability, are also to promote it
Practical, the key of extensiveization；.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of saponification steel alloy anticorrosive paint and system thereof
Preparation Method.
The present invention is achieved by the following technical solutions:
A kind of saponification steel alloy anticorrosive paint, it is made up of the raw material of following weight parts；
Aluminium triphosphate 1-2, myristic acid soda soap 3-5, aniline 50-60, pyrroles 30-40, sulfosalicylic acid 7-9, epoxy resin
E513-4, Ammonium persulfate. 1.3-2, molybdic acid 4-6, polyamide 3-5, n-butyl alcohol 160-170, butyl glycol ether 20-30, chlorine phthalein
Dimethyl phthalate 0.2-0.4, aphthenic acids lithium 0.1-0.2, diisopropyl ethanolamine 0.8-1, Cera Flava 1-2, dithio-salicylic acid 1-2,
Thiol-butyl tin 0.3-1, tetramethylolmethane 6-7.
The preparation method of a kind of described saponification steel alloy anticorrosive paint, comprises the following steps:
(1) Ammonium persulfate. is joined in its weight 21-25 times deionized water, stir, obtain initiator solution；
(2) above-mentioned Cera Flava is joined in tetramethylolmethane, rise high-temperature and be 76-80 DEG C, add aphthenic acids lithium, insulated and stirred 7-10
Minute, add above-mentioned epoxy resin, rise high-temperature and be 86-90 DEG C, add the 10-15% of above-mentioned n-butyl alcohol weight, insulated and stirred 4-
8 minutes, it is cooled to room temperature, obtains modified epoxy alcohol liquid；
(3) above-mentioned aluminium triphosphate is joined in the deionized water of its weight 17-20 times, stir, add above-mentioned lima bean
Cool acid soda soap, rises high-temperature and is 50-60 DEG C, and insulated and stirred 6-9 minute adds thiol-butyl tin, and stirring, to room temperature, obtains saponification breast
Liquid；
(4) above-mentioned sulfosalicylic acid is joined in the deionized water of its weight 47-50 times, magnetic agitation 20-30 minute, add
Aniline, stirs, and drips the 47-50% of above-mentioned initiator solution weight, regulates temperature and be 20-25 DEG C after dropping, stirring
React 10-12 hour, add above-mentioned saponification emulsion, stir, filter, precipitation acetone, distilled water are washed 3-4 successively
Secondary, it is dried 10-12 hour at 60-65 DEG C, obtains acid doped polyaniline；
(5) by molybdic acid, the mixing of aphthenic acids lithium, join in the deionized water of compound weight 60-65 times, stir, add
Above-mentioned pyrroles, magnetic agitation 50-60 minute, drip remaining initiator solution, regulate temperature after dropping and be 0-5 DEG C, stir
Mix reaction 6-7 hour, filter, the ethanol of precipitation 30-35% is washed 2-3 time, be dried 6-8 hour at 70-85 DEG C, obtain sour mixing
Heteromeric pyrroles；
(6) by remaining n-butyl alcohol, butyl glycol ether mixing, stir, obtain mixed solvent；
(7) take the 50-60% of above-mentioned mixed solvent weight, add above-mentioned acid doped polyaniline, ultrasonic 10-15 minute, add above-mentioned
Modified epoxy alcohol liquid, stirring reaction 40-50 minute, obtain epoxy emulsion；
(8) above-mentioned acid doping polypyrrole is joined in remaining mixed solvent, stir, add polyamide, ultrasonic
30-40 minute, obtain polyamide emulsion；
(9) by above-mentioned epoxy emulsion, the mixing of polyamide emulsion, add the dimethicone of compound weight 1-2%, stir,
Add and remain each raw material, be passed through the steam of 80-90 DEG C, heat aging 30-40 minute, cool down, obtain described coating.
A kind of saponification steel alloy anticorrosive paint and preparation method thereof, the using method of described coating is:
Be applied to paint brush of the present invention to clean up, dried alloy steel material working electrode surface, control coating thickness one
Cause, as in baking oven, be dried 20-25 hour at 60-70 DEG C,.
The invention have the advantage that the doped polypyrrole of the present invention is conduction, during as anti-corrosion material protection metal, always
Be first with surface metal generation partial reaction, make surface metal corrode purification, corrosion potential presents and generally reduces, molybdic acid official's energy
Group, as a kind of anti-corrosion function functional group, may depart from also faster when touching metal material from polypyrrole strand
React with metal, make metal surface protected and be passivated, and use being total to of the sulfosalisylic acid doping of bigger organic group
Polymers is embedded in copolymer molecule interchain because of large scale counter ion, it is possible to increases the extension degree of polymer chain and expands interchain
Away from, organic macromolecule sulfonic acid group has strong surface-active action, makes the dissolubility of subject polymer be improved, simultaneously
Have both good electrical conductivity, can be formed different electric field, the direction of the electric field of formation and corrosion when it acts on metal surface
When reaction occurs, electronics flowing is in opposite direction, and therefore this electric field is equal to being applied with a counteracting force to corrosion reaction, hinders
Electronics, to the movement of metal surface, makes corrosion reaction by a definite limitation, the polyphenyl that this sulfosalisylic acid doping is formed simultaneously
Amine is blended with polypyrrole so that the grain diameter of copolymer diminishes, and granule is uniform, careful, piles up more tight, agglomeration
Basic disappear, the coating of the present invention can effectively improve the ability of passive metal so that steel alloy Surface Creation one floor height
The oxide-film of consistency, preferably isolating metal base material and corrosive medium, enhance the ability of its suppression anode reaction, show
Preferably corrosion resistance；The myristic acid soda soap etc. that the present invention adds can effectively improve the pliability of finished product coating.
Detailed description of the invention
A kind of saponification steel alloy anticorrosive paint, it is made up of the raw material of following weight parts；
Aluminium triphosphate 1, myristic acid soda soap 3, aniline 50, pyrroles 30, sulfosalicylic acid 7, epoxy resin E513, Ammonium persulfate.
1.3, molybdic acid 4, polyamide 3, n-butyl alcohol 160, butyl glycol ether 20, chlorine dimethyl phthalate 0.2, aphthenic acids lithium 0.1, two are different
Propyl group ethanolamine 0.8, Cera Flava 1, dithio-salicylic acid 1, thiol-butyl tin 0.3, tetramethylolmethane 6.
The preparation method of a kind of described saponification steel alloy anticorrosive paint, comprises the following steps:
(1) Ammonium persulfate. is joined in 21 times of deionized waters of its weight, stir, obtain initiator solution；
(2) joining in tetramethylolmethane by above-mentioned Cera Flava, rising high-temperature is 76 DEG C, addition aphthenic acids lithium, insulated and stirred 7 minutes,
Adding above-mentioned epoxy resin, rising high-temperature is 86 DEG C, adds the 10% of above-mentioned n-butyl alcohol weight, and insulated and stirred 4 minutes is cooled to
Room temperature, obtains modified epoxy alcohol liquid；
(3) above-mentioned aluminium triphosphate is joined in the deionized water of its weight 17 times, stir, add above-mentioned myristic acid
Soda soap, rising high-temperature is 50 DEG C, insulated and stirred 6 minutes, adds thiol-butyl tin, and stirring, to room temperature, obtains saponification emulsion；
(4) above-mentioned sulfosalicylic acid is joined in the deionized water of its weight 47 times, magnetic agitation 20 minutes, add aniline,
Stirring, drip the 47% of above-mentioned initiator solution weight, regulating temperature after dropping is 20 DEG C, stirring reaction 10 hours,
Add above-mentioned saponification emulsion, stir, filter, precipitation acetone, distilled water are washed successively 3 times, at 60 DEG C, be dried 10
Hour, obtain acid doped polyaniline；
(5) by molybdic acid, the mixing of aphthenic acids lithium, join in the deionized water of compound weight 60 times, stir, add above-mentioned
Pyrroles, magnetic agitation 50 minutes, drip remaining initiator solution, regulating temperature after dropping is 0 DEG C, and stirring reaction 6 is little
Time, filter, precipitation is washed 2 times with the ethanol of 30%, be dried 6 hours at 70 DEG C, obtain acid doping polypyrrole；
(6) by remaining n-butyl alcohol, butyl glycol ether mixing, stir, obtain mixed solvent；
(7) take the 50% of above-mentioned mixed solvent weight, add above-mentioned acid doped polyaniline, ultrasonic 10 minutes, add above-mentioned modified ring
Oxygen alcohol liquid, stirring reaction 40 minutes, obtain epoxy emulsion；
(8) above-mentioned acid doping polypyrrole is joined in remaining mixed solvent, stir, add polyamide, ultrasonic
30 minutes, obtain polyamide emulsion；
(9) by above-mentioned epoxy emulsion, the mixing of polyamide emulsion, add the dimethicone of compound weight 1%, stir, add
Enter and remain each raw material, be passed through the steam of 80 DEG C, heat aging 30 minutes, cool down, obtain described coating.
Described a kind of saponification steel alloy anticorrosive paint and preparation method thereof, the using method of described coating is:
Be applied to paint brush of the present invention to clean up, dried alloy steel material working electrode surface, control coating thickness one
Cause, as in baking oven, be dried 20 hours at 60 DEG C,.
Performance test with the coating formation film of the present invention:
Impact strength: 51kg.cm；
Hardness: 3H.
Claims (3)
1. a saponification steel alloy anticorrosive paint, it is characterised in that it is made up of the raw material of following weight parts；
Aluminium triphosphate 1-2, myristic acid soda soap 3-5, aniline 50-60, pyrroles 30-40, sulfosalicylic acid 7-9, epoxy resin
E513-4, Ammonium persulfate. 1.3-2, molybdic acid 4-6, polyamide 3-5, n-butyl alcohol 160-170, butyl glycol ether 20-30, chlorine phthalein
Dimethyl phthalate 0.2-0.4, aphthenic acids lithium 0.1-0.2, diisopropyl ethanolamine 0.8-1, Cera Flava 1-2, dithio-salicylic acid 1-2,
Thiol-butyl tin 0.3-1, tetramethylolmethane 6-7.
2. the preparation method of a saponification steel alloy anticorrosive paint as claimed in claim 1, it is characterised in that include following step
Rapid:
(1) Ammonium persulfate. is joined in its weight 21-25 times deionized water, stir, obtain initiator solution；
(2) above-mentioned Cera Flava is joined in tetramethylolmethane, rise high-temperature and be 76-80 DEG C, add aphthenic acids lithium, insulated and stirred 7-10
Minute, add above-mentioned epoxy resin, rise high-temperature and be 86-90 DEG C, add the 10-15% of above-mentioned n-butyl alcohol weight, insulated and stirred 4-
8 minutes, it is cooled to room temperature, obtains modified epoxy alcohol liquid；
(3) above-mentioned aluminium triphosphate is joined in the deionized water of its weight 17-20 times, stir, add above-mentioned lima bean
Cool acid soda soap, rises high-temperature and is 50-60 DEG C, and insulated and stirred 6-9 minute adds thiol-butyl tin, and stirring, to room temperature, obtains saponification breast
Liquid；
(4) above-mentioned sulfosalicylic acid is joined in the deionized water of its weight 47-50 times, magnetic agitation 20-30 minute, add
Aniline, stirs, and drips the 47-50% of above-mentioned initiator solution weight, regulates temperature and be 20-25 DEG C after dropping, stirring
React 10-12 hour, add above-mentioned saponification emulsion, stir, filter, precipitation acetone, distilled water are washed 3-4 successively
Secondary, it is dried 10-12 hour at 60-65 DEG C, obtains acid doped polyaniline；
(5) by molybdic acid, the mixing of aphthenic acids lithium, join in the deionized water of compound weight 60-65 times, stir, add
Above-mentioned pyrroles, magnetic agitation 50-60 minute, drip remaining initiator solution, regulate temperature after dropping and be 0-5 DEG C, stir
Mix reaction 6-7 hour, filter, the ethanol of precipitation 30-35% is washed 2-3 time, be dried 6-8 hour at 70-85 DEG C, obtain sour mixing
Heteromeric pyrroles；
(6) by remaining n-butyl alcohol, butyl glycol ether mixing, stir, obtain mixed solvent；
(7) take the 50-60% of above-mentioned mixed solvent weight, add above-mentioned acid doped polyaniline, ultrasonic 10-15 minute, add above-mentioned
Modified epoxy alcohol liquid, stirring reaction 40-50 minute, obtain epoxy emulsion；
(8) above-mentioned acid doping polypyrrole is joined in remaining mixed solvent, stir, add polyamide, ultrasonic
30-40 minute, obtain polyamide emulsion；
(9) by above-mentioned epoxy emulsion, the mixing of polyamide emulsion, add the dimethicone of compound weight 1-2%, stir,
Add and remain each raw material, be passed through the steam of 80-90 DEG C, heat aging 30-40 minute, cool down, obtain described coating.
3. according to a kind of saponification steel alloy anticorrosive paint described in claim 1-2 and preparation method thereof, it is characterised in that described
The using method of coating be:
Be applied to paint brush of the present invention to clean up, dried alloy steel material working electrode surface, control coating thickness one
Cause, as in baking oven, be dried 20-25 hour at 60-70 DEG C,.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610543376.6A CN106085205A (en) | 2016-07-12 | 2016-07-12 | A kind of saponification steel alloy anticorrosive paint and preparation method thereof |
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| CN201610543376.6A CN106085205A (en) | 2016-07-12 | 2016-07-12 | A kind of saponification steel alloy anticorrosive paint and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107312428A (en) * | 2017-07-24 | 2017-11-03 | 杨洁磊 | A kind of preparation method of hard saponification water paint |
| CN108753141A (en) * | 2018-06-25 | 2018-11-06 | 合肥艾飞新材料有限公司 | A kind of environment-friendly epoxy water paint and preparation method thereof |
| CN109666377A (en) * | 2018-12-31 | 2019-04-23 | 方少章 | A kind of heat-resisting emulsified epoxy coating and preparation method thereof |
| CN111454658A (en) * | 2019-12-31 | 2020-07-28 | 江苏拓展新材料科技有限公司 | Wear-resistant scratch-resistant modified alloy and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105001759A (en) * | 2015-07-21 | 2015-10-28 | 中国科学院金属研究所 | Molybdate doped polypyrrole/epoxy resin self-healing coating, preparation method thereof and application thereof |
| CN105368304A (en) * | 2015-09-23 | 2016-03-02 | 航天科工防御技术研究试验中心 | Anticorrosive paint and preparation method thereof |
-
2016
- 2016-07-12 CN CN201610543376.6A patent/CN106085205A/en not_active Withdrawn
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105001759A (en) * | 2015-07-21 | 2015-10-28 | 中国科学院金属研究所 | Molybdate doped polypyrrole/epoxy resin self-healing coating, preparation method thereof and application thereof |
| CN105368304A (en) * | 2015-09-23 | 2016-03-02 | 航天科工防御技术研究试验中心 | Anticorrosive paint and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107312428A (en) * | 2017-07-24 | 2017-11-03 | 杨洁磊 | A kind of preparation method of hard saponification water paint |
| CN108753141A (en) * | 2018-06-25 | 2018-11-06 | 合肥艾飞新材料有限公司 | A kind of environment-friendly epoxy water paint and preparation method thereof |
| CN109666377A (en) * | 2018-12-31 | 2019-04-23 | 方少章 | A kind of heat-resisting emulsified epoxy coating and preparation method thereof |
| CN111454658A (en) * | 2019-12-31 | 2020-07-28 | 江苏拓展新材料科技有限公司 | Wear-resistant scratch-resistant modified alloy and preparation method thereof |
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