CN106085077A - A kind of photo frame scrubbing resistance high tack metallized coating - Google Patents
A kind of photo frame scrubbing resistance high tack metallized coating Download PDFInfo
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- CN106085077A CN106085077A CN201610417137.6A CN201610417137A CN106085077A CN 106085077 A CN106085077 A CN 106085077A CN 201610417137 A CN201610417137 A CN 201610417137A CN 106085077 A CN106085077 A CN 106085077A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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Abstract
The invention discloses a kind of photo frame scrubbing resistance high tack metallized coating, its raw material includes by weight: hydroxy acryl acid resin 35 45 parts, aqueous polyester resin 5 15 parts, ternary chlorine vinegar resin 26 parts, 36 parts of amino resins, dimethylethanolamine 14 parts, aqueous polyurethane 39 parts, polyurethane dispersant 26 parts, butyl glycol ether 14 parts, modified acetylbutyrylcellulose 28 parts, aluminium powder 39 parts, antimony oxide 14 parts, titanium dioxide 39 parts, superfine heavy calcium carbonate 49 parts, ultrafine kaolin 25 parts, 14 parts of micro-plastic crystal particle, 36 parts of firming agent, levelling agent 14 parts, wetting agent 25 parts, defoamer 15 parts, thickening agent 26 parts.The metallized coating of the present invention has the scrubbing resistance height adhesion property of excellence.
Description
Technical field
The present invention relates to flash coating material, particularly relate to a kind of photo frame scrubbing resistance high tack metallized coating.
Background technology
At present, present in metal flash paint, flakey aluminium powder forms the arranged in parallel of multilamellar in film, it is possible to purple
Outside line, infrared ray and visible ray effectively reflect, and delay its aging damage to film, it is also possible to effectively stop water, gas and
The infiltration of ion, because of decoration and the antiseptic effect of its this uniqueness, in photo frame surface coating, application is more and more.
Need when the scrubbing resistance height adhesion property of metallized coating the most of the prior art cannot meet actually used
Ask, demand when therefore needing the metallized coating designing a kind of excellent scrubbing resistance height adhesion property badly to meet actually used.
Summary of the invention
For solving technical problem present in background technology, the present invention proposes a kind of photo frame scrubbing resistance high tack metal
Flash coating material, has the scrubbing resistance of excellence and high adhesion property.
A kind of photo frame scrubbing resistance high tack metallized coating that the present invention proposes, its raw material includes by weight:
Hydroxy acryl acid resin 35-45 part, aqueous polyester resin 5-15 part, ternary chlorine vinegar resin 2-6 part, amino resins 3-6 part, two
Methylethanolamine 1-4 part, aqueous polyurethane 3-9 part, polyurethane dispersant 2-6 part, butyl glycol ether 1-4 part, modified acetic acid fourth
Acid cellulose 2-8 part, aluminium powder 3-9 part, antimony oxide 1-4 part, titanium dioxide 3-9 part, superfine heavy calcium carbonate 4-9 part, ultra-fine
Kaolin 2-5 part, micro-plastic crystal particle 1-4 part, firming agent 3-6 part, levelling agent 1-4 part, wetting agent 2-5 part, defoamer 1-5 part,
Thickening agent 2-6 part.
Preferably, modified acetylbutyrylcellulose is prepared by following technique: by ethyl acetate, butyl glycol ether and carboxylic
Acid cellulose butyrate mix homogeneously, is warming up to 50-70 DEG C, stirs 20-50min, is subsequently adding butyl methacrylate and benzene second
Alkene, is warming up to 75-95 DEG C, is incubated 30-50min, is cooled to room temperature and obtains modified acetylbutyrylcellulose.
Preferably, in the preparation technology of modified acetylbutyrylcellulose, ethyl acetate, butyl glycol ether, carboxylic acid butanoic acid are fine
Dimension element, butyl methacrylate and cinnamic weight ratio are 2-5:1-4:3-9:2-5:1-3.
Preferably, in the preparation technology of modified acetylbutyrylcellulose, acid cellulose butyrate, butyl methacrylate and benzene
The weight ratio of ethylene is 4-8:3-4:1.5-2.5.
Preferably, the degree of neutralization of described hydroxy acryl acid resin is 84-86%, and hydroxy radical content is 3.6-4.2%, viscosity
For 1800-2200mpa s, vitrification point is 8-12 DEG C, and solidification amount is 42-47%.
Preferably, its raw material includes by weight: hydroxy acryl acid resin 38-42 part, aqueous polyester resin 8-12 part,
Ternary chlorine vinegar resin 3-5 part, amino resins 4-5 part, dimethylethanolamine 2-3 part, aqueous polyurethane 4-8 part, they
Agent 3-5 part, butyl glycol ether 2-3 part, modified acetylbutyrylcellulose 3-7 part, aluminium powder 4-8 part, antimony oxide 2-3 part, titanium
White lead 4-8 part, superfine heavy calcium carbonate 5-8 part, ultrafine kaolin 3-4 part, micro-plastic crystal particle 2-3 part, firming agent 4-5 part, stream
Flat agent 2-3 part, wetting agent 3-4 part, defoamer 2-4 part, thickening agent 3-5 part.
Preferably, its raw material includes by weight: hydroxy acryl acid resin 40 parts, aqueous polyester resin 10 parts, ternary
Vinyl chloride-vinyl acetate resin 4 parts, 4.5 parts of amino resins, dimethylethanolamine 2.5 parts, aqueous polyurethane 6 parts, polyurethane dispersant 4 parts, second
Glycol butyl ether 2.5 parts, modified acetylbutyrylcellulose 5 parts, aluminium powder 6 parts, antimony oxide 2.5 parts, titanium dioxide 6 parts, ultra-fine heavy
Matter calcium carbonate 6.5 parts, ultrafine kaolin 3.5 parts, 2.5 parts of micro-plastic crystal particle, 4.5 parts of firming agent, levelling agent 2.5 parts, wetting agent
3.5 parts, defoamer 3 parts, thickening agent 4 parts.
A kind of photo frame scrubbing resistance high tack metallized coating of the present invention, its raw material includes hydroxy acryl acid tree
Fat, aqueous polyester resin, ternary chlorine vinegar resin, amino resins, aqueous polyurethane, dimethylethanolamine, polyurethane dispersant, second
Glycol butyl ether, modified acetylbutyrylcellulose, aluminium powder, antimony oxide, titanium dioxide, superfine heavy calcium carbonate, ultrafine kaolin,
Micro-plastic crystal particle, firming agent, levelling agent, wetting agent, defoamer and thickening agent；Add hydroxy acryl acid resin, waterborne polyester
Resin, ternary chlorine vinegar resin, amino resins and aqueous polyurethane are base material, wherein with hydroxy acryl acid resin as major ingredient, auxiliary
Help interpolation aqueous polyester resin, ternary chlorine vinegar resin, amino resins and aqueous polyurethane, be effectively improved hydroxy acryl acid resin
Waterproof, wear-resisting and adhesion property；The aluminium powder action effect pigment added, under the effect of modified acetylbutyrylcellulose, makes
Obtain aluminium powder to align in film, impart the flash effect of film metallic luster and changeable colors along with angle；And modified acetic acid
Cellulose butyrate with ethyl acetate, butyl glycol ether, carboxylic acid cellulose butyrate, butyl methacrylate and styrene as raw material,
Owing to methyl methacrylate copolymer time space steric hindrance is little, after graft modification, acetylbutyrylcellulose is in solvent resistance, hardness etc.
Effectively improve in performance；Make acetylbutyrylcellulose aluminium powder align effect more preferably, overlap of reuniting occurs
Phenomenon is less；The antimony oxide, titanium dioxide, superfine heavy calcium carbonate, ultrafine kaolin and the micro-plastic crystal particle that add are as filling out
Material, effectively imparts the excellent scrub performance of metallized coating of the present invention and water resistance, and tack have also been obtained effectively
Improve.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in detail, it should be appreciated that embodiment is served only for this is described
Bright rather than be used for limiting the invention, any made on the basis of the present invention amendment, equivalent etc. is all at this
In bright protection domain.
In detailed description of the invention, the weight portion of hydroxy acryl acid resin can be 35 parts, 36 parts, 37 parts, 38 parts, 39
Part, 40 parts, 41 parts, 42 parts, 43 parts, 44 parts, 45 parts；The weight portion of aqueous polyester resin can be 5 parts, 6 parts, 7 parts, 8 parts, 9
Part, 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts；The weight portion of ternary chlorine vinegar resin can be 2 parts, 2.5 parts, 3 parts, 3.5
Part, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；The weight portion of amino resins can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5
Part, 6 parts；The weight portion of dimethylethanolamine can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；Aqueous polyurethane
Weight portion can be 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts；The weight portion of polyurethane dispersant can be 2 parts, 3 parts, 4
Part, 5 parts, 6 parts；The weight portion of butyl glycol ether can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；Modified acetic acid
The weight portion of cellulose butyrate can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts；The weight portion of aluminium powder can be 3 parts, 4
Part, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts；The weight portion of antimony oxide can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts,
4 parts；The weight portion of titanium dioxide can be 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts；The weight portion of superfine heavy calcium carbonate can
Think 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts, 8.5 parts, 9 parts；The weight portion of ultrafine kaolin
It can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The weight portion of micro-plastic crystal particle can be 1 part, 1.5 parts, 2
Part, 2.5 parts, 3 parts, 3.5 parts, 4 parts；The weight portion of firming agent can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；
The weight portion of levelling agent can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；The weight portion of wetting agent can be 2
Part, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The weight portion of defoamer can be 1 part, 2 parts, 3 parts, 4 parts, 5 parts；Thickening
The weight portion of agent can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts.
Embodiment 1
A kind of photo frame scrubbing resistance high tack metallized coating that the present invention proposes, its raw material includes by weight:
Hydroxy acryl acid resin 40 parts, aqueous polyester resin 10 parts, ternary chlorine vinegar resin 4 parts, 4.5 parts of amino resins, dimethyl second
Hydramine 2.5 parts, aqueous polyurethane 6 parts, polyurethane dispersant 4 parts, butyl glycol ether 2.5 parts, modified acetylbutyrylcellulose 5
Part, aluminium powder 6 parts, antimony oxide 2.5 parts, titanium dioxide 6 parts, superfine heavy calcium carbonate 6.5 parts, ultrafine kaolin 3.5 parts, micro-mould
Crystal grain 2.5 parts, 4.5 parts of firming agent, levelling agent 2.5 parts, wetting agent 3.5 parts, defoamer 3 parts, thickening agent 4 parts.
Wherein, the degree of neutralization of hydroxy acryl acid resin is 85%, and hydroxy radical content is 3.9%, and viscosity is 2000mpa s,
Vitrification point is 10 DEG C, and solidification amount is 44.5%.
Modified acetylbutyrylcellulose is prepared by following technique: by weight by 3.5 parts of ethyl acetate, 2.5 parts of second
Glycol butyl ether and 6 parts of carboxylic acid cellulose butyrate mix homogeneously, be warming up to 60 DEG C, stirs 35min, is subsequently adding 3.5 parts of methyl-prop
Olefin(e) acid butyl ester and 2 parts of styrene, be warming up to 85 DEG C, is incubated 40min, is cooled to room temperature and obtains modified acetylbutyrylcellulose.
Embodiment 2
A kind of photo frame scrubbing resistance high tack metallized coating that the present invention proposes, its raw material includes by weight:
Hydroxy acryl acid resin 35 parts, aqueous polyester resin 15 parts, ternary chlorine vinegar resin 2 parts, 6 parts of amino resins, dimethyl ethanol
Amine 1 part, aqueous polyurethane 9 parts, polyurethane dispersant 2 parts, butyl glycol ether 4 parts, modified acetylbutyrylcellulose 2 parts, aluminium powder 9
Part, antimony oxide 1 part, titanium dioxide 9 parts, superfine heavy calcium carbonate 4 parts, ultrafine kaolin 5 parts, 1 part of micro-plastic crystal particle, solidification
Agent 6 parts, levelling agent 1 part, wetting agent 5 parts, defoamer 1 part, thickening agent 6 parts.
Wherein, the degree of neutralization of hydroxy acryl acid resin is 84%, and hydroxy radical content is 4.2%, and viscosity is 1800mpa s,
Vitrification point is 12 DEG C, and solidification amount is 42%.
Modified acetylbutyrylcellulose is prepared by following technique: by weight by 2 parts of ethyl acetate, 4 parts of ethylene glycol
Butyl ether and 3 parts of carboxylic acid cellulose butyrate mix homogeneously, be warming up to 70 DEG C, stirs 20min, is subsequently adding 5 parts of methacrylic acid fourths
Ester and 1 part of styrene, be warming up to 95 DEG C, is incubated 30min, is cooled to room temperature and obtains modified acetylbutyrylcellulose.
Embodiment 3
A kind of photo frame scrubbing resistance high tack metallized coating that the present invention proposes, its raw material includes by weight:
Hydroxy acryl acid resin 45 parts, aqueous polyester resin 5 parts, ternary chlorine vinegar resin 6 parts, 3 parts of amino resins, dimethylethanolamine
4 parts, aqueous polyurethane 3 parts, polyurethane dispersant 6 parts, butyl glycol ether 1 part, modified acetylbutyrylcellulose 8 parts, aluminium powder 3
Part, antimony oxide 4 parts, titanium dioxide 3 parts, superfine heavy calcium carbonate 9 parts, ultrafine kaolin 2 parts, 4 parts of micro-plastic crystal particle, solidification
Agent 3 parts, levelling agent 4 parts, wetting agent 2 parts, defoamer 5 parts, thickening agent 2 parts.
Wherein, the degree of neutralization of hydroxy acryl acid resin is 86%, and hydroxy radical content is 3.6%, and viscosity is 2200mpa s,
Vitrification point is 8 DEG C, and solidification amount is 47%.
Modified acetylbutyrylcellulose is prepared by following technique: by weight by 5 parts of ethyl acetate, 1 part of ethylene glycol
Butyl ether and 9 parts of carboxylic acid cellulose butyrate mix homogeneously, be warming up to 50 DEG C, stirs 50min, is subsequently adding 2 parts of methacrylic acid fourths
Ester and 3 parts of styrene, be warming up to 75 DEG C, is incubated 50min, is cooled to room temperature and obtains modified acetylbutyrylcellulose.
Embodiment 4
A kind of photo frame scrubbing resistance high tack metallized coating that the present invention proposes, its raw material includes by weight:
Hydroxy acryl acid resin 38 parts, aqueous polyester resin 12 parts, ternary chlorine vinegar resin 3 parts, 5 parts of amino resins, dimethyl ethanol
Amine 2 parts, aqueous polyurethane 8 parts, polyurethane dispersant 3 parts, butyl glycol ether 3 parts, modified acetylbutyrylcellulose 3 parts, aluminium powder 8
Part, antimony oxide 2 parts, titanium dioxide 8 parts, superfine heavy calcium carbonate 5 parts, ultrafine kaolin 4 parts, 2 parts of micro-plastic crystal particle, solidification
Agent 5 parts, levelling agent 2 parts, wetting agent 4 parts, defoamer 2 parts, thickening agent 5 parts.
Wherein, the degree of neutralization of hydroxy acryl acid resin is 84.5%, and hydroxy radical content is 4.1%, and viscosity is 1900mpa
S, vitrification point is 11 DEG C, and solidification amount is 43%.
Modified acetylbutyrylcellulose is prepared by following technique: by weight by 3 parts of ethyl acetate, 3 parts of ethylene glycol
Butyl ether and 4 parts of carboxylic acid cellulose butyrate mix homogeneously, be warming up to 65 DEG C, stirs 25min, is subsequently adding 4 parts of methacrylic acid fourths
Ester and 1.5 parts of styrene, be warming up to 92 DEG C, is incubated 35min, is cooled to room temperature and obtains modified acetylbutyrylcellulose.
Embodiment 5
A kind of photo frame scrubbing resistance high tack metallized coating that the present invention proposes, its raw material includes by weight:
Hydroxy acryl acid resin 42 parts, aqueous polyester resin 8 parts, ternary chlorine vinegar resin 5 parts, 4 parts of amino resins, dimethylethanolamine
3 parts, aqueous polyurethane 4 parts, polyurethane dispersant 5 parts, butyl glycol ether 2 parts, modified acetylbutyrylcellulose 7 parts, aluminium powder 4
Part, antimony oxide 3 parts, titanium dioxide 4 parts, superfine heavy calcium carbonate 8 parts, ultrafine kaolin 3 parts, 3 parts of micro-plastic crystal particle, solidification
Agent 4 parts, levelling agent 3 parts, wetting agent 3 parts, defoamer 4 parts, thickening agent 3 parts.
Wherein, the degree of neutralization of hydroxy acryl acid resin is 85.5%, and hydroxy radical content is 3.7%, and viscosity is 2100mpa
S, vitrification point is 9 DEG C, and solidification amount is 46%.
Modified acetylbutyrylcellulose is prepared by following technique: by weight by 4 parts of ethyl acetate, 2 parts of ethylene glycol
Butyl ether and 8 parts of carboxylic acid cellulose butyrate mix homogeneously, be warming up to 55 DEG C, stirs 45min, is subsequently adding 3 parts of methacrylic acid fourths
Ester and 2.5 parts of styrene, be warming up to 78 DEG C, is incubated 45min, is cooled to room temperature and obtains modified acetylbutyrylcellulose.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention is not limited thereto,
Any those familiar with the art in the technical scope that the invention discloses, according to technical scheme and
Inventive concept equivalent or change in addition, all should contain within protection scope of the present invention.
Claims (7)
1. a photo frame scrubbing resistance high tack metallized coating, it is characterised in that its raw material includes by weight: containing hydroxyl
Base acrylic resin 35-45 part, aqueous polyester resin 5-15 part, ternary chlorine vinegar resin 2-6 part, amino resins 3-6 part, dimethyl
Ethanolamine 1-4 part, aqueous polyurethane 3-9 part, polyurethane dispersant 2-6 part, butyl glycol ether 1-4 part, modified acetate butyrate fibre
Dimension element 2-8 part, aluminium powder 3-9 part, antimony oxide 1-4 part, titanium dioxide 3-9 part, superfine heavy calcium carbonate 4-9 part, ultra-fine kaolinite
Soil 2-5 part, micro-plastic crystal particle 1-4 part, firming agent 3-6 part, levelling agent 1-4 part, wetting agent 2-5 part, defoamer 1-5 part, thickening
Agent 2-6 part.
Photo frame scrubbing resistance high tack metallized coating the most according to claim 1, it is characterised in that modified acetic acid
Cellulose butyrate is prepared by following technique: by ethyl acetate, butyl glycol ether and carboxylic acid cellulose butyrate mix homogeneously, rises
Temperature, to 50-70 DEG C, stirs 20-50min, is subsequently adding butyl methacrylate and styrene, is warming up to 75-95 DEG C, is incubated 30-
50min, is cooled to room temperature and obtains modified acetylbutyrylcellulose.
Photo frame scrubbing resistance high tack metallized coating the most according to claim 1 and 2, it is characterised in that modified
In the preparation technology of acetylbutyrylcellulose, ethyl acetate, butyl glycol ether, carboxylic acid cellulose butyrate, butyl methacrylate
It is 2-5:1-4:3-9:2-5:1-3 with cinnamic weight ratio.
4. according to the scrubbing resistance high tack metallized coating of the photo frame described in any one of claim 1-3, it is characterised in that
In the preparation technology of modified acetylbutyrylcellulose, acid cellulose butyrate, butyl methacrylate and cinnamic weight ratio are
4-8:3-4:1.5-2.5.
5. according to the scrubbing resistance high tack metallized coating of the photo frame described in any one of claim 1-4, it is characterised in that
The degree of neutralization of described hydroxy acryl acid resin is 84-86%, and hydroxy radical content is 3.6-4.2%, and viscosity is 1800-
2200mpa s, vitrification point is 8-12 DEG C, and solidification amount is 42-47%.
6. according to the scrubbing resistance high tack metallized coating of the photo frame described in any one of claim 1-5, it is characterised in that
Its raw material includes by weight: hydroxy acryl acid resin 38-42 part, aqueous polyester resin 8-12 part, ternary chlorine vinegar resin 3-5
Part, amino resins 4-5 part, dimethylethanolamine 2-3 part, aqueous polyurethane 4-8 part, polyurethane dispersant 3-5 part, ethylene glycol fourth
Ether 2-3 part, modified acetylbutyrylcellulose 3-7 part, aluminium powder 4-8 part, antimony oxide 2-3 part, titanium dioxide 4-8 part, ultra-fine heavy
Matter calcium carbonate 5-8 part, ultrafine kaolin 3-4 part, micro-plastic crystal particle 2-3 part, firming agent 4-5 part, levelling agent 2-3 part, wetting agent
3-4 part, defoamer 2-4 part, thickening agent 3-5 part.
7. according to the scrubbing resistance high tack metallized coating of the photo frame described in any one of claim 1-6, it is characterised in that
Its raw material includes by weight: hydroxy acryl acid resin 40 parts, aqueous polyester resin 10 parts, ternary chlorine vinegar resin 4 parts, amino
Resin 4.5 parts, dimethylethanolamine 2.5 parts, aqueous polyurethane 6 parts, polyurethane dispersant 4 parts, butyl glycol ether 2.5 parts, change
Property acetylbutyrylcellulose 5 parts, aluminium powder 6 parts, antimony oxide 2.5 parts, titanium dioxide 6 parts, superfine heavy calcium carbonate 6.5 parts, super
Thin Kaolin 3.5 parts, 2.5 parts of micro-plastic crystal particle, 4.5 parts of firming agent, levelling agent 2.5 parts, wetting agent 3.5 parts, defoamer 3 parts,
Thickening agent 4 parts.
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| CN114539863A (en) * | 2022-04-06 | 2022-05-27 | 卡秀万辉(无锡)高新材料有限公司 | Coating with excellent adhesion to PEEK material and preparation method thereof |
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