CN106084842A - A kind of polystyrene-based bamboo with graphene oxide grafted metallocene polyethylene capacity increasing modifying moulds cabinet slab and preparation method thereof - Google Patents

A kind of polystyrene-based bamboo with graphene oxide grafted metallocene polyethylene capacity increasing modifying moulds cabinet slab and preparation method thereof Download PDF

Info

Publication number
CN106084842A
CN106084842A CN201610546854.9A CN201610546854A CN106084842A CN 106084842 A CN106084842 A CN 106084842A CN 201610546854 A CN201610546854 A CN 201610546854A CN 106084842 A CN106084842 A CN 106084842A
Authority
CN
China
Prior art keywords
graphene oxide
bamboo
polystyrene
metallocene polyethylene
grafted metallocene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610546854.9A
Other languages
Chinese (zh)
Inventor
夏大庆
孔令根
王平
王安勇
戚明永
王丹
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhibang Kitchen Cabinet Co Ltd
Original Assignee
Zhibang Kitchen Cabinet Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhibang Kitchen Cabinet Co Ltd filed Critical Zhibang Kitchen Cabinet Co Ltd
Priority to CN201610546854.9A priority Critical patent/CN106084842A/en
Publication of CN106084842A publication Critical patent/CN106084842A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L97/00—Compositions of lignin-containing materials
    • C08L97/02—Lignocellulosic material, e.g. wood, straw or bagasse
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/32—Component parts, details or accessories; Auxiliary operations
    • B29C43/58—Measuring, controlling or regulating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/32—Component parts, details or accessories; Auxiliary operations
    • B29C43/58—Measuring, controlling or regulating
    • B29C2043/5808—Measuring, controlling or regulating pressure or compressing force
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/32—Component parts, details or accessories; Auxiliary operations
    • B29C43/58—Measuring, controlling or regulating
    • B29C2043/5816—Measuring, controlling or regulating temperature
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2007/00—Flat articles, e.g. films or sheets
    • B29L2007/002—Panels; Plates; Sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/08—Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/18—Spheres

Abstract

The invention discloses a kind of polystyrene-based bamboo with graphene oxide grafted metallocene polyethylene capacity increasing modifying and mould cabinet slab, this Bamboo plastic plate material is made up of the raw material of following weight portion: bamboo powder 60 80, waste high impact polystyrene particle 20 30, ten dihydroxystearic acid 12, polymine 45, hydroxyl polydimethylsiloxane 15, dehydrated alcohol are appropriate, silane coupler 12, antioxidant 0.1 0.2, graphene oxide grafted metallocene polyethylene bulking agent 46, nanometer fusing assistants 45.

Description

A kind of polystyrene-based with graphene oxide grafted metallocene polyethylene capacity increasing modifying Bamboo moulds cabinet slab and preparation method thereof
Technical field
The present invention relates to bamboo moulding material technical field, particularly relate to a kind of with the increasing of graphene oxide grafted metallocene polyethylene Hold modified polystyrene-based bamboo and mould cabinet slab and preparation method thereof.
Background technology
Cabinet is a class storage closet the most common in daily household, is also the material that in household building materials, market is quite varied Material, along with the change of the demand property of consumer's age level, the requirement to cabinet is the most durable, the environmental protection of product Property, texture etc. are increasingly becoming consumer's focus of attention, make rational use of resources, it is achieved the sustainable development of industry simultaneously Also it is the developing direction producing industry.
Cabinet slab is a ring particularly important in cabinet assembly, directly influences consumer and buys selection, current cabinet Sheet material mainly has solid wood board, particieboard, density board etc., and wherein solid wood board is expensive, needs frequent maintaining, and resistance to water Not enough；Though particieboard low cost, its intensity is low, and content of formaldehyde is high；Density board is smashed after mainly being soaked by timber etc. High pressure compacting forms, and combination property is the most excellent, but its quality is still waited to improve, and uses the non-renewable resources such as timber.
China has extremely abundant bamboo resource, and bamboo wood has a good mechanical property, fast growth, uniqueness attractive in appearance, Being the important substitution material of timber, be the sustainable resource of a kind of environment-friendly and green, it is come by more as a kind of emerging building materials The most concerns.Bamboo moulding material is that bamboo powder is obtained by a class with plastics mixing co-extrusion, its texture having solid wood concurrently and plastics anti- Water, water-fast, advantage, the performance requirement of cabinet slab of especially fitting such as be unlikely to deform.In actual production process, due to bamboo powder with The compatibility of plastics is poor, and the requirement to production technology and auxiliary agent is very strict, is directly connected to the mechanical property of composite, Also it is the key factor of restriction bamboo molding product quality." heat pressing process of bamboo powder/high density polyethylene (HDPE) (HDPE) composite grinds Study carefully " literary composition is with maleic anhydride grafted polyethylene as compatilizer, and under the conditions of 180 DEG C, hot-pressing processing has obtained a kind of bamboo and has moulded proportioning relatively High material, but the material comprehensive mechanical property obtained is poor, still is apparent not enough in processing characteristics as cabinet slab..
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of poly-with graphene oxide grafting metallocene The polystyrene-based bamboo of ethylene capacity increasing modifying moulds cabinet slab and preparation method thereof.
The present invention is achieved by the following technical solutions:
A kind of polystyrene-based bamboo with graphene oxide grafted metallocene polyethylene capacity increasing modifying moulds cabinet slab, this bamboo Mould sheet material to be made up of the raw material of following weight portion: bamboo powder 60-80, waste high impact polystyrene particle 20-30, ten dihydroxy are hard Fat acid 1-2, polymine 4-5, hydroxyl polydimethylsiloxane 1-5, dehydrated alcohol are appropriate, silane coupler 1-2, antioxidation Agent 0.1-0.2, graphene oxide grafted metallocene polyethylene bulking agent 4-6, nanometer fusing assistants 4-5.
Described graphene oxide grafted metallocene polyethylene bulking agent is prepared by the raw material of following weight portion: oxidation Graphene 1-2, maleic anhydride 1-2, metallocene PE 10-15, cumyl peroxide 0.1-0.5, Silane coupling agent KH550 0.1-0.2, dehydrated alcohol 5-8, preparation method is: first puts in dehydrated alcohol by Silane coupling agent KH550, is uniformly mixed Rear addition graphene oxide, system is heated to 60-80 DEG C, and ultrasonic disperse 1.5-2h, and reaction terminates rear sucking filtration, products therefrom water It is dried after washing, obtains modified graphene oxide, then by modified graphene oxide and metallocene PE, maleic anhydride, peroxidating Diisopropylbenzene (DIPB) puts in high-speed mixer together, puts into melt blending pelletize in double screw extruder, i.e. after being uniformly mixed Graphene oxide grafted metallocene polyethylene bulking agent described in.
Described nanometer fusing assistants is nanoscale polystyrene microsphere.
Described a kind of polystyrene-based bamboo with graphene oxide grafted metallocene polyethylene capacity increasing modifying moulds cupboard board The preparation method of material is:
(1) first bamboo powder is processed through dehydrate, put into by silane coupler, ten dihydroxystearic acids subsequently, gather Aziridine, dehydrated alcohol mixed preparing solution in soak reaction 2-3h, then pass through filter, dried obtain modified bamboo powder standby With；
(2) after waste high impact polystyrene particle being mixed homogeneously with hydroxyl polydimethylsiloxane, nanometer fusing assistants Melt pelletization, obtains MPS particle standby；
(3) modification bamboo powder, MPS particle are put in high-speed mixer and be preheated to 50-60 DEG C, mix and blend 20-30min, adds other leftover materials subsequently, is warming up to 80-100 DEG C, continues mix and blend 1-2min, after mix homogeneously Preparing sheet material by die pressing, wherein molding preheating time is 20-30min, and molding temperature is 180-200 DEG C, and the dwell time is 4-5min, pressure is 8-12MPa, and cold pressing time 3-5min, and cold pressing pressure 10-15MPa, obtains described Bamboo plastic plate material.
Bamboo moulding material feature prepared by the present invention is:
(1) bamboo powder is put into after processed silane coupler, ten dihydroxystearic acids, polymine mixed preparing Ethanol solution in modification, organic group is introduced bamboo powder surface, improves the compatibility of bamboo powder and resin, simultaneously Improve intensity and the heat stability of bamboo powder.
(2) being prepared for a kind of graphene oxide grafted metallocene polyethylene bulking agent, this bulking agent utilizes graphite oxide Unique amphipathic of alkene, is blended with organic facies for bamboo powder and puts up a bridge, reduce interface-potential, improve the adhesion of storeroom, than biography The maleic anhydride grafting bulking agent compatibilization effect of system meaning is more preferably.
(3) in advance by polystyrene and polysiloxane compound and pelletize of nanometer fusing assistants, it is thus achieved that degree of crystallinity The resin binder that higher, comprehensive mechanical property is the most excellent.
To sum up, the bamboo molding product prepared with present invention process has of a relatively high bamboo and moulds ratio, reduces product Production cost, has good intensity and toughness concurrently simultaneously, and durable, anti-corruption is water-fast, environment-protecting asepsis, has in terms of making cabinet There is good application prospect.
Detailed description of the invention
This embodiment Bamboo plastic plate material is made up of the raw material of following weight portion: bamboo powder 60, waste high impact polystyrene particle 20, ten dihydroxystearic acids 1, polymine 4, hydroxyl polydimethylsiloxane 1, dehydrated alcohol be appropriate, silane coupler 1, Antioxidant 0.1, graphene oxide grafted metallocene polyethylene bulking agent 4, nanometer fusing assistants 4.
Wherein graphene oxide grafted metallocene polyethylene bulking agent is prepared by the raw material of following weight portion: oxidation stone Ink alkene 1, maleic anhydride 1, metallocene PE 10, cumyl peroxide 0.1, Silane coupling agent KH550 0.1, dehydrated alcohol 5, preparation method is: first put in dehydrated alcohol by Silane coupling agent KH550, adds graphene oxide after being uniformly mixed, System is heated to 60 DEG C, and ultrasonic disperse 1.5h, and reaction terminates rear sucking filtration, is dried, obtains modified oxidized stone after products therefrom washing Ink alkene, then puts into the most mixed together with metallocene PE, maleic anhydride, cumyl peroxide by modified graphene oxide In conjunction machine, after being uniformly mixed, put into melt blending pelletize in double screw extruder, obtain described graphene oxide grafting Metallocene PE bulking agent.
Wherein nanometer fusing assistants is nanoscale polystyrene microsphere.
This embodiment preparation of plates method is:
(1) first bamboo powder is processed through dehydrate, put into by silane coupler, ten dihydroxystearic acids subsequently, gather Aziridine, dehydrated alcohol mixed preparing solution in soak reaction 2h, then pass through filter, dried obtain modified bamboo powder standby；
(2) after waste high impact polystyrene particle being mixed homogeneously with hydroxyl polydimethylsiloxane, nanometer fusing assistants Melt pelletization, obtains MPS particle standby；
(3) modification bamboo powder, MPS particle are put in high-speed mixer and be preheated to 50 DEG C, mix and blend 20min, adds other leftover materials subsequently, is warming up to 80 DEG C, continues mix and blend 1min, passes through die pressing after mix homogeneously Prepare sheet material, wherein mold preheating time be 20min, molding temperature is 180 DEG C, and the dwell time is 4min, and pressure is 8MPa, cold Pressure time 3min, cold pressing pressure 10MPa, obtains described Bamboo plastic plate material.
Above-mentioned prepared Bamboo plastic plate material is made test strip and is carried out performance measurement, and test result is as follows:
Detection project Testing result
Hot strength (MPa) 52.6
Bending strength (MPa) 64.3
Elongation at break (%) 22.5
Bending modulus (GPa) 3.05
24h thickness swelling rate (%) ≤1.5
Impact strength (KJ/m<sup>2</sup>) 14.2

Claims (4)

1. mould a cabinet slab with the polystyrene-based bamboo of graphene oxide grafted metallocene polyethylene capacity increasing modifying, its feature Being, this Bamboo plastic plate material is made up of the raw material of following weight portion: bamboo powder 60-80, waste high impact polystyrene particle 20-30, Ten dihydroxystearic acid 1-2, polymine 4-5, hydroxyl polydimethylsiloxane 1-5, dehydrated alcohol are appropriate, silane coupler 1-2, antioxidant 0.1-0.2, graphene oxide grafted metallocene polyethylene bulking agent 4-6, nanometer fusing assistants 4-5.
A kind of polystyrene-based bamboo with graphene oxide grafted metallocene polyethylene capacity increasing modifying Mould cabinet slab, it is characterised in that former by following weight portion of described graphene oxide grafted metallocene polyethylene bulking agent Material prepares: graphene oxide 1-2, maleic anhydride 1-2, metallocene PE 10-15, cumyl peroxide 0.1-0.5, Silane coupling agent KH550 0.1-0.2, dehydrated alcohol 5-8, preparation method is: first Silane coupling agent KH550 is put into dehydrated alcohol In, adding graphene oxide after being uniformly mixed, system is heated to 60-80 DEG C, and ultrasonic disperse 1.5-2h, after reaction terminates Sucking filtration, is dried after products therefrom washing, obtains modified graphene oxide, then by modified graphene oxide and metallocene PE, Maleic anhydride, cumyl peroxide put in high-speed mixer together, put in double screw extruder after being uniformly mixed Melt blending pelletize, obtains described graphene oxide grafted metallocene polyethylene bulking agent.
A kind of polystyrene-based bamboo with graphene oxide grafted metallocene polyethylene capacity increasing modifying Mould cabinet slab, it is characterised in that described nanometer fusing assistants is nanoscale polystyrene microsphere.
A kind of polystyrene-based bamboo with graphene oxide grafted metallocene polyethylene capacity increasing modifying Mould the preparation method of cabinet slab, it is characterised in that its preparation method is:
(1) first bamboo powder is processed through dehydrate, put into subsequently by silane coupler, ten dihydroxystearic acids, polyethylene Imines, dehydrated alcohol mixed preparing solution in soak reaction 2-3h, then pass through filter, dried obtain modified bamboo powder standby；
(2) melt after waste high impact polystyrene particle being mixed homogeneously with hydroxyl polydimethylsiloxane, nanometer fusing assistants Pelletize, obtains MPS particle standby；
(3) modification bamboo powder, MPS particle are put in high-speed mixer and be preheated to 50-60 DEG C, mix and blend 20- 30min, adds other leftover materials subsequently, is warming up to 80-100 DEG C, continues mix and blend 1-2min, passes through after mix homogeneously Die pressing prepares sheet material, wherein mold preheating time be 20-30min, molding temperature is 180-200 DEG C, and the dwell time is 4- 5min, pressure is 8-12MPa, and cold pressing time 3-5min, and cold pressing pressure 10-15MPa, obtains described Bamboo plastic plate material.
CN201610546854.9A 2016-07-12 2016-07-12 A kind of polystyrene-based bamboo with graphene oxide grafted metallocene polyethylene capacity increasing modifying moulds cabinet slab and preparation method thereof Pending CN106084842A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610546854.9A CN106084842A (en) 2016-07-12 2016-07-12 A kind of polystyrene-based bamboo with graphene oxide grafted metallocene polyethylene capacity increasing modifying moulds cabinet slab and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610546854.9A CN106084842A (en) 2016-07-12 2016-07-12 A kind of polystyrene-based bamboo with graphene oxide grafted metallocene polyethylene capacity increasing modifying moulds cabinet slab and preparation method thereof

Publications (1)

Publication Number Publication Date
CN106084842A true CN106084842A (en) 2016-11-09

Family

ID=57221262

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610546854.9A Pending CN106084842A (en) 2016-07-12 2016-07-12 A kind of polystyrene-based bamboo with graphene oxide grafted metallocene polyethylene capacity increasing modifying moulds cabinet slab and preparation method thereof

Country Status (1)

Country Link
CN (1) CN106084842A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106496424A (en) * 2016-11-11 2017-03-15 杭州师范大学 A kind of preparation method of maleic anhydride melt grafting polyolefine material
CN106496425A (en) * 2016-11-11 2017-03-15 杭州师范大学 The preparation method of glycidyl methacrylate fusion-grafting polyolefine material
CN108976837A (en) * 2018-07-24 2018-12-11 王晚秀 A kind of flame-proof anti-aging packaging pallet and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102153877A (en) * 2011-02-22 2011-08-17 中国科学技术大学 Graphene composite material and preparation method thereof
CN103588991A (en) * 2013-11-20 2014-02-19 桂林理工大学 Method for preparing hyperdispersant by adopting oxidized graphene and application thereof
CN104448567A (en) * 2014-12-22 2015-03-25 河北科技大学 Method for improving mechanical performance of composite material by grafting hyperbranched polyamide on plant fiber surface

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102153877A (en) * 2011-02-22 2011-08-17 中国科学技术大学 Graphene composite material and preparation method thereof
CN103588991A (en) * 2013-11-20 2014-02-19 桂林理工大学 Method for preparing hyperdispersant by adopting oxidized graphene and application thereof
CN104448567A (en) * 2014-12-22 2015-03-25 河北科技大学 Method for improving mechanical performance of composite material by grafting hyperbranched polyamide on plant fiber surface

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106496424A (en) * 2016-11-11 2017-03-15 杭州师范大学 A kind of preparation method of maleic anhydride melt grafting polyolefine material
CN106496425A (en) * 2016-11-11 2017-03-15 杭州师范大学 The preparation method of glycidyl methacrylate fusion-grafting polyolefine material
CN108976837A (en) * 2018-07-24 2018-12-11 王晚秀 A kind of flame-proof anti-aging packaging pallet and preparation method thereof

Similar Documents

Publication Publication Date Title
CN102140255B (en) Hot-press type wood plastic composite for toy and preparation method thereof
CN103087400B (en) A kind of wood plastic composite and preparation method thereof
CN102492305B (en) Formula for preparing wood-plastic composite material from papermaking solid wastes and method thereof
CN104479223A (en) Wood-plastic composite prepared by use of short fiber and preparation method thereof
CN105713403A (en) Wood-plastic composite and preparation method for special-shape molded member thereof
CN103709519A (en) Modified polypropylene material and preparation method thereof
CN102558679A (en) Novel bamboo fiber/polypropylene composite material and method for preparing same
CN103044944A (en) Method for preparing high-performance wood-plastic composite material
CN106084842A (en) A kind of polystyrene-based bamboo with graphene oxide grafted metallocene polyethylene capacity increasing modifying moulds cabinet slab and preparation method thereof
CN105566937A (en) Fiberglass reinforced wood-plastic composite material and preparation method thereof
CN109081955A (en) A kind of starch-based bio degradable bionic fish bait adding modified nano calcium carbonate
CN106084846A (en) A kind of modified bamboo TRPP base high-strength fire-retarding cabinet slab and preparation method thereof
CN106147268A (en) A kind of bamboo modified with graphene oxide graft phenylethene acrylonitrile copolymer bulking agent moulds cabinet slab and preparation method thereof
CN103333513A (en) Wood-plastic composite material and preparation method thereof
CN102020814A (en) Recycled polypropylene modified polrvinyl chloride sectional material and preparation method thereof
CN106189304A (en) A kind of antimicrobial form high-density polyethylene thiazolinyl bamboo blending nano-metallic copper moulds cabinet slab and preparation method thereof
CN111117106A (en) Wood-plastic composite floor and preparation method thereof
CN101906219A (en) Completely biodegradable bamboo microstructure unit and polylactic acid biomass composite and preparation method thereof
CN106084845A (en) A kind of light heat-resisting flame-retardant modified chlorinated polyethylene thiazolinyl bamboo moulds cabinet slab and preparation method thereof
CN106084844A (en) A kind of modification phenolic resin-based bamboo of high temperature resistant heat insulation moulds cabinet slab and preparation method thereof
CN101787153B (en) Environmentally-friendly EPE pearl wool foaming master batch and preparation method thereof
CN102181167A (en) Amino mold reinforcement polyvinyl chloride (PVC) base wood plastics composite and preparation method thereof
CN104530738B (en) PP/ABS wood-plastic composite plate and manufacturing method thereof
CN106189307A (en) A kind of high-strength polyethylene base bamboo containing carbon nano-fiber moulds cabinet slab and preparation method thereof
CN106084843A (en) The ethylene vinyl acetate copolymer base bamboo of a kind of high tenacity moulds cabinet slab and preparation method thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20161109