CN106084841A - A kind of modified bamboo fiber reinforcement PBT resin base cabinet slab and preparation method thereof - Google Patents

A kind of modified bamboo fiber reinforcement PBT resin base cabinet slab and preparation method thereof Download PDF

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Publication number
CN106084841A
CN106084841A CN201610546579.0A CN201610546579A CN106084841A CN 106084841 A CN106084841 A CN 106084841A CN 201610546579 A CN201610546579 A CN 201610546579A CN 106084841 A CN106084841 A CN 106084841A
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China
Prior art keywords
bamboo fiber
modified bamboo
pbt resin
fiber reinforcement
resin base
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CN201610546579.0A
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Chinese (zh)
Inventor
夏大庆
孔令根
王平
王安勇
戚明永
王丹
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Zhibang Kitchen Cabinet Co Ltd
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Zhibang Kitchen Cabinet Co Ltd
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Priority to CN201610546579.0A priority Critical patent/CN106084841A/en
Publication of CN106084841A publication Critical patent/CN106084841A/en
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L97/00—Compositions of lignin-containing materials
    • C08L97/02—Lignocellulosic material, e.g. wood, straw or bagasse
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/10—Other agents for modifying properties
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/10—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one other macromolecular compound obtained by reactions only involving carbon-to-carbon unsaturated bonds as constituent
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/14—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/425—Cellulose series
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4382—Stretched reticular film fibres; Composite fibres; Mixed fibres; Ultrafine fibres; Fibres for artificial leather
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/44—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
    • D04H1/46—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic System
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic System; Titanates; Zirconates; Stannates; Plumbates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/61—Polyamines polyimines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16—Fibres; Fibrils
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic

Abstract

The invention discloses a kind of modified bamboo fiber reinforcement PBT resin base cabinet slab, this Bamboo plastic plate material is made up of the raw material of following weight portion: modified bamboo fiber 50 60, PBT resin 20 25, hydroxy silicon oil 12, maleic anhydride grafted polyester 35, asphaltic base MCMB 23, antioxidant 0.1 0.2, ionic liquid 58, zinc methacrylate 12.

Description

A kind of modified bamboo fiber reinforcement PBT resin base cabinet slab and preparation method thereof
Technical field
The present invention relates to bamboo moulding material technical field, particularly relate to a kind of modified bamboo fiber reinforcement PBT resin base cupboard board Material and preparation method thereof.
Background technology
Cabinet is a class storage closet the most common in daily household, is also the material that in household building materials, market is quite varied Material, along with the change of the demand property of consumer's age level, the requirement to cabinet is the most durable, the environmental protection of product Property, texture etc. are increasingly becoming consumer's focus of attention, make rational use of resources, it is achieved the sustainable development of industry simultaneously Also it is the developing direction producing industry.
Cabinet slab is a ring particularly important in cabinet assembly, directly influences consumer and buys selection, current cabinet Sheet material mainly has solid wood board, particieboard, density board etc., and wherein solid wood board is expensive, needs frequent maintaining, and resistance to water Not enough；Though particieboard low cost, its intensity is low, and content of formaldehyde is high；Density board is smashed after mainly being soaked by timber etc. High pressure compacting forms, and combination property is the most excellent, but its quality is still waited to improve, and uses the non-renewable resources such as timber.
Bamboo fibre has that draw ratio is big, specific strength is high, specific surface area is big, inexpensive, renewable etc. advantage, can use it for Strengthen polymer matrix composite, under industry Sustainable Development Trend, will be a kind of green material with broad prospect of application Material, especially in terms of cabinet production, the exclusive advantage of bamboo fiber material can improve the experience of conventional cabinet product, changes The household of philanthropists is experienced.Produce the primary of Bamboo Fiber Reinforced Polymer based composites it is important that bamboo fibre to be modified place Reason, improves the compatibility of itself and fluoropolymer resin body, to obtain the product of high comprehensive performance." surface of bamboo fibre can be analyzed And strengthen the mechanical property of PP composite " literary composition is as a example by PP, after bamboo fibre carries out alkali process-silane coupler process Molded with PP compound thermal, although the compatible wellability that this method processes bamboo fibre and the PP obtained is improved, but high Fiber can be caused damage by the aqueous slkali of concentration, destroys the mechanical strength of material, does not reaches gratifying reinforced effects..
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of modified bamboo fiber reinforcement PBT resin base Cabinet slab and preparation method thereof.
The present invention is achieved by the following technical solutions:
A kind of modified bamboo fiber reinforcement PBT resin base cabinet slab, this sheet material is made up of the raw material of following weight portion: modified Bamboo fibre 50-60, PBT resin 20-25, hydroxy silicon oil 1-2, maleic anhydride grafted polyester 3-5, asphaltic base MCMB 2- 3, antioxidant 0.1-0.2, ionic liquid 5-8, zinc methacrylate 1-2.
The preparation method of described modified bamboo fiber is: bamboo fibre first puts into the sodium hydroxide solution leaching that concentration is 5% Bubble process 30-40min, then pass through filter, be washed to neutrality after be completely dried, products therefrom input concentration be the metatitanic acid of 1-5% Ester coupling agent/ethanol solution mixes immersion treatment 2-5h, and process is filtered after terminating, gained drying materials, then is put into concentration For in the aq. polyethyleneimine of 1-5%, it is heated to 80-90 DEG C, confined reaction 10-15h, react and filter after terminating, gained Material 2-3 post-drying of washing, obtains described modified bamboo fiber, wherein bamboo fibre and sodium hydroxide solution, titanate esters coupling Agent/ethanol solution, the bath raio of aq. polyethyleneimine are 1:10-20:5-10:10-15.
Described length of bamboo fibre is 40-50mm, a diameter of 50-100 μm.
The preparation method of described a kind of modified bamboo fiber reinforcement PBT resin base cabinet slab is:
(1) first by PBT resin, maleic anhydride grafted polyester, asphaltic base MCMB, ionic liquid and except modification Melt spinning after other leftover materials high-speed stirred mix homogeneously outside bamboo fibre, makes a length of 50-80mm, a diameter of 50- The composite fibre of 100 μm is standby；
(2) shredding 2-3 again after mixing after composite fibre shredding respectively prepared by modified bamboo fiber and step (1) Secondary, make composite fibrofelt by combing, needling process subsequently, the fiber felt parallel layers of gained is spread, 200-230 DEG C of temperature Under, hot-pressing processing 15-30min under 15-20MPa pressure, obtain described sheet material.
The invention have the advantage that
(1) bamboo fibre is processed first with traditional alkali treatment method, remove its surface impurity, improve its surface The reactivity of group, subsequently under titanate coupling agent and polymine act on jointly, at bamboo fibre surface graft, Improve bamboo fibre intensity and with the compatibility of resin material, thus improve the mechanical property of composite, this modified at Reason method not only improves tradition alkali treatment method and weakens the shortcoming of bamboo fibre intensity, improves bamboo fibre the most further compatible Property.
(2) PBT resin is mixed as resin binder with maleic anhydride grafted polyester, be simultaneously introduced ionic liquid, Colophonium Base MCMB, prepares and has superior tensile toughness and high reaction activity, the resin fibre of response strength, has with bamboo fibre There is good compatible associativity.
To sum up, bamboo fibre is introduced resin material by composite board efficiently that prepare with inventive formulation and technique In, to mould at relatively Gao Zhu and than under the conditions of obtain the product that comprehensive mechanical property is excellent, greatly reduce production cost, product is good Good mechanical property makes its advantage in terms of making cabinet slab highlight, the most certain adsorptivity, it is possible to purify kitchen space, Itself, without volatile harmful material, has a good application prospect in terms of making environmental protection cabinet.
Detailed description of the invention
A kind of modified bamboo fiber reinforcement PBT resin base cabinet slab, this fibrous plate is made up of the raw material of following weight portion: Modified bamboo fiber 50, PBT resin 20, hydroxy silicon oil 1, maleic anhydride grafted polyester 3, asphaltic base MCMB 2, antioxidant 0.1, ionic liquid 5, zinc methacrylate 1.
Wherein the preparation method of modified bamboo fiber is: bamboo fibre first puts into the sodium hydroxide solution that concentration is 5% and soaks Process 30min, then pass through filter, be washed to neutrality after be completely dried, products therefrom input concentration be 1% titanate esters coupling Agent/ethanol solution mixing immersion treatment 2h, process filters after terminating, gained drying materials, then to be put into concentration be 1% gather In aziridine aqueous solution, it is heated to 80 DEG C, confined reaction 10h, react and filter after terminating, gained material 2 post-dryings of washing, Obtain described modified bamboo fiber, wherein bamboo fibre and sodium hydroxide solution, titanate coupling agent/ethanol solution, polyethyleneimine The bath raio of amine aqueous solution is 1:10:5:10.
Wherein length of bamboo fibre is 40mm, a diameter of 50 μm.
This preparation of plates method is:
(1) first by PBT resin, maleic anhydride grafted polyester, asphaltic base MCMB, ionic liquid and except modification Melt spinning after other leftover materials high-speed stirred mix homogeneously outside bamboo fibre, makes a length of 50mm, a diameter of 50 μm Composite fibre is standby；
(2) shredding 2 again after mixing after composite fibre shredding respectively prepared by modified bamboo fiber and step (1) Secondary, make composite fibrofelt by combing, needling process subsequently, the fiber felt parallel layers of gained is spread, at a temperature of 200 DEG C, Hot-pressing processing 30min under 15MPa pressure, makes standard specimen.
The above-mentioned standard specimen prepared is carried out performance test, and test result is:
Hot strength: 82.5MPa；Stretch modulus: 0.85GPa；Bending strength: 65.2MPa；Bending modulus: 0.92GPa； Elongation at break: 5.2%；Fracture load by bending retention rate after aging 2000h: 106.

Claims (4)

1. a modified bamboo fiber reinforcement PBT resin base cabinet slab, it is characterised in that this sheet material is by the raw material of following weight portion Make: in the middle of modified bamboo fiber 50-60, PBT resin 20-25, hydroxy silicon oil 1-2, maleic anhydride grafted polyester 3-5, asphaltic base Phase carbon microspheres 2-3, antioxidant 0.1-0.2, ionic liquid 5-8, zinc methacrylate 1-2.
2. a kind of modified bamboo fiber reinforcement PBT resin base cabinet slab as claimed in claim 1, it is characterised in that described The preparation method of modified bamboo fiber is: bamboo fibre first puts into sodium hydroxide solution immersion treatment 30-40min that concentration is 5%, Then pass through filter, be washed to neutrality after be completely dried, it is the titanate coupling agent/ethanol solution of 1-5% that products therefrom puts into concentration Mixing immersion treatment 2-5h, process is filtered after terminating, gained drying materials, then is put into the polymine that concentration is 1-5% In aqueous solution, it is heated to 80-90 DEG C, confined reaction 10-15h, react and filter after terminating, gained material 2-3 post-drying of washing, Obtain described modified bamboo fiber, wherein bamboo fibre and sodium hydroxide solution, titanate coupling agent/ethanol solution, polyethyleneimine The bath raio of amine aqueous solution is 1:10-20:5-10:10-15.
3. a kind of modified bamboo fiber reinforcement PBT resin base cabinet slab as claimed in claim 2, it is characterised in that described Length of bamboo fibre is 40-50mm, a diameter of 50-100 μm.
The preparation method of a kind of modified bamboo fiber reinforcement PBT resin base cabinet slab the most as claimed in claim 2, its feature exists In, its preparation method is:
(1) first by PBT resin, maleic anhydride grafted polyester, asphaltic base MCMB, ionic liquid and except modified bamboo is fine Melt spinning after other leftover materials high-speed stirred mix homogeneously outside dimension, makes a length of 50-80mm, a diameter of 50-100 μm Composite fibre standby；
(2) shredding 2-3 time again after mixing after composite fibre shredding respectively prepared by modified bamboo fiber and step (1), Make composite fibrofelt by combing, needling process subsequently, the fiber felt parallel layers of gained is spread, at a temperature of 200-230 DEG C, Hot-pressing processing 15-30min under 15-20MPa pressure, obtains described sheet material.
CN201610546579.0A 2016-07-12 2016-07-12 A kind of modified bamboo fiber reinforcement PBT resin base cabinet slab and preparation method thereof Pending CN106084841A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106751554A (en) * 2016-11-10 2017-05-31 上海纳米技术及应用国家工程研究中心有限公司 A kind of sisal hemp reinforced polyester master batch and preparation method thereof
CN106751558A (en) * 2016-11-18 2017-05-31 无锡明盛纺织机械有限公司 A kind of engineering plastic materials and preparation method containing bamboo fibre
CN109553933A (en) * 2017-09-27 2019-04-02 南通星辰合成材料有限公司 A kind of composite material of thermoplastic macromolecule and the preparation method and application thereof that nail-holding ability is high

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102134367A (en) * 2010-01-25 2011-07-27 王广武 Polymer alloy with added wood (bamboo) powder and flake material and preparation method thereof
CN104448567A (en) * 2014-12-22 2015-03-25 河北科技大学 Method for improving mechanical performance of composite material by grafting hyperbranched polyamide on plant fiber surface

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102134367A (en) * 2010-01-25 2011-07-27 王广武 Polymer alloy with added wood (bamboo) powder and flake material and preparation method thereof
CN104448567A (en) * 2014-12-22 2015-03-25 河北科技大学 Method for improving mechanical performance of composite material by grafting hyperbranched polyamide on plant fiber surface

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
刘西文编著: "《塑料注射成型技术实用教程》", 31 October 2013, 印刷工业出版社 *
王春红等: ""碱处理对竹纤维及竹纤维增强聚丙烯复合材料性能的影响"", 《复合材料学报》 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106751554A (en) * 2016-11-10 2017-05-31 上海纳米技术及应用国家工程研究中心有限公司 A kind of sisal hemp reinforced polyester master batch and preparation method thereof
CN106751558A (en) * 2016-11-18 2017-05-31 无锡明盛纺织机械有限公司 A kind of engineering plastic materials and preparation method containing bamboo fibre
CN109553933A (en) * 2017-09-27 2019-04-02 南通星辰合成材料有限公司 A kind of composite material of thermoplastic macromolecule and the preparation method and application thereof that nail-holding ability is high
CN109553933B (en) * 2017-09-27 2021-04-27 南通星辰合成材料有限公司 Thermoplastic polymer composite material with high nail-holding power and preparation method and application thereof

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