CN106083210A - Using method for the titanium oxide sol of ceramic tile - Google Patents

Using method for the titanium oxide sol of ceramic tile Download PDF

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Publication number
CN106083210A
CN106083210A CN201610469161.4A CN201610469161A CN106083210A CN 106083210 A CN106083210 A CN 106083210A CN 201610469161 A CN201610469161 A CN 201610469161A CN 106083210 A CN106083210 A CN 106083210A
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CN
China
Prior art keywords
ceramic tile
titanium oxide
tile surface
hydrosol
weight portion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610469161.4A
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Chinese (zh)
Inventor
王赞
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Individual
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Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Individual filed Critical Individual
Priority to CN201610469161.4A priority Critical patent/CN106083210A/en
Publication of CN106083210A publication Critical patent/CN106083210A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5025Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with ceramic materials
    • C04B41/5041Titanium oxide or titanates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/85Coating or impregnation with inorganic materials
    • C04B41/87Ceramics

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Catalysts (AREA)

Abstract

The invention discloses the using method of a kind of titanium oxide sol for ceramic tile, relate to building materials technical field.This using method for the titanium oxide sol of ceramic tile is first to make the titanium oxide hydrosol with anatase titanium dioxide, sodium alginate, calcium chloride, sodium lauryl sulphate and water, is then coated with the ceramic tile surface in cleaning, is finally dried.The present invention solves the problem solving ceramic tile antibiotic and sterilizing with minimal amount of anatase titanium dioxide, and step is few, simple to operate, provides cost savings, antibiotic and sterilizing excellent effect.

Description

Using method for the titanium oxide sol of ceramic tile
Technical field
The present invention relates to building materials technical field, the using method of a kind of titanium oxide sol for ceramic tile.
Background technology
Ceramic tile is as the decorative material for wall surface closely bound up with people's productive life, along with the growth of the time of use, its table Face inevitably grows many pathogenic bacterias, easily spreads disease, and serious also can endanger the healthy of people.Existing frequently-used Method for disinfection have microwave, ray, high temperature, formaldehyde or ethanol etc., be not all suitable for the sterilization of wall tile.
Anatase titanium dioxide is as a kind of novel antibacterial, under light illumination, produces the most active hydroxyl radical free radical (HO), make that Organic substance is oxidized resolves into H2O and CO2, S that Organic substance initially contains, P, atom N etc. are changed into respectively SO4 2-、PO4 2-And NO3 -Deng inorganic salts, thus reach suppression or the effect of sterilization.Have performance quickly, efficiently, wide spectrum, hold For a long time, will not be consumed, the advantage such as have no drug resistance, and solves conventional inorganic antiseptic sterilization speed slow, easy to change and and organic Antibacterial poor heat resistance, the shortcomings such as effective time is short.
But how by combination stable to itself and ceramic tile, reach anatase titanium dioxide consumption few, but antibiotic and sterilizing effect The best purpose, does not record at present in open source literature.
Summary of the invention
The present invention provides the using method of a kind of titanium oxide sol for ceramic tile, and it can solve with minimal amount of sharp titanium The problem that type titanium dioxide solves ceramic tile antibiotic and sterilizing.
In order to solve the problems referred to above, the technical solution adopted in the present invention is: this titanium oxide sol for ceramic tile Using method, comprises the steps of:
A, the making titanium oxide hydrosol, this Zinc oxide water colloidal sol comprises the anatase titanium dioxide titanium dioxide that particle diameter is 5~200 nm Titanium 0.1~3 weight portion, sodium alginate 2~4 weight portion, calcium chloride 2~10 weight portion, sodium lauryl sulphate 0.4~0.7 weight Amount part.
B, clean ceramic tile surface to be coated;
C, the step A gained titanium oxide hydrosol being coated in by Spray painting tool the ceramic tile surface of step B gained, coating thickness is 25~150nm;
D, by step C gained at 80~180 DEG C be dried 1~2h.
In technique scheme, more specifically technical scheme is it may also is that the spraying of step C is the glass using cloth parcel Water is scraped uniformly to be coated with the speed of 10~50cm/s at ceramic tile surface and is scraped the titanium oxide hydrosol described in last layer, described bath of glass scrape with The angle of described ceramic tile surface is 20~80 °;Or, use air compressor or airless sprayer to coordinate 0.3~1.0mm bore The spray gun of nozzle at described ceramic tile surface with Zinc oxide water colloidal sol described in the speed even application last layer of 20~100cm/s, institute State ceramic tile 10~50cm described in the nozzle distance of spray gun;Or, use automatic film applicator to coat last layer at described ceramic tile surface The described titanium oxide hydrosol.
Owing to have employed technique scheme, the present invention compared with prior art has the advantages that
1, the present invention solves the problem of ceramic tile antibiotic and sterilizing with minimal amount of anatase titanium dioxide, provides cost savings, antibacterial kills Bacterium excellent effect, reaches 98.6 more than % to the sterilizing rate of staphylococcus aureus, colibacillary sterilizing rate is reached 99.5 More than %.
2, step of the present invention is few, simple to operate.
Detailed description of the invention
Below in conjunction with specific embodiment, the invention will be further described:
Embodiment one:
The using method of this titanium oxide sol for ceramic tile, comprises the steps of:
A, the making titanium oxide hydrosol: this titanium oxide hydrosol comprises the anatase titanium dioxide that particle diameter is 5~200 nm 0.1kg, sodium alginate 2 kg, calcium chloride 2 kg, sodium lauryl sulphate 0.4 kg and 100kg water;During making, first take 10 kg Sodium alginate described in the water dissolution of 60~70 DEG C, then in 60~70 DEG C of water-baths, add anatase titanium dioxide, calcium chloride, Sodium lauryl sulphate and remaining water, stir 5~10min, is fully placed on 3~5min cooling in room temperature environment after mixing, The filtrate filtered is i.e. the titanium oxide hydrosol;
B, clean ceramic tile surface to be coated;
C, use the bath of glass of cloth parcel to scrape the ceramic tile surface in step B gained to be uniformly coated with the speed of 50cm/s and scrape last layer step The rapid A gained titanium oxide hydrosol, it is 20 ° that described bath of glass scrapes the angle with described ceramic tile surface, and being coated with and scraping thickness is 25nm;
D, by step C gained at 80 DEG C be dried 2h.
Embodiment two:
The using method of this titanium oxide sol for ceramic tile, comprises the steps of:
A, the making titanium oxide hydrosol: this titanium oxide hydrosol particle diameter is anatase titanium dioxide 3 kg of 5~200 nm, sea Sodium alginate 4 kg, calcium chloride 10 kg, sodium lauryl sulphate 0.7 kg, manufacture method is with embodiment one;
B, clean ceramic tile surface to be coated;
C, employing automatic film applicator coat the last layer step A gained titanium oxide hydrosol, coating in the ceramic tile surface of step B gained Thickness is 150nm;
D, by step C gained at 180 DEG C be dried 2h.

Claims (2)

1. the using method for the titanium oxide sol of ceramic tile, it is characterised in that comprise the steps of: A, making titanium oxide The hydrosol, this Zinc oxide water colloidal sol comprises anatase titanium dioxide 0.1~3 weight portion that particle diameter is 5~200 nm, sea Sodium alginate 2~4 weight portion, calcium chloride 2~10 weight portion, sodium lauryl sulphate 0.4~0.7 weight portion;
B, clean ceramic tile surface to be coated;
C, the step A gained titanium oxide hydrosol being coated in by Spray painting tool the ceramic tile surface of step B gained, coating thickness is 25~150nm;
D, by step C gained at 80~180 DEG C be dried 1~2h.
The using method of the titanium oxide sol for ceramic tile the most according to claim 1, it is characterised in that: the spray of step C Painting is to use the bath of glass of cloth parcel to scrape at ceramic tile surface to be uniformly coated with the speed of 10~50cm/s to scrape titanium oxide described in last layer The hydrosol, it is 20~80 ° that described bath of glass scrapes the angle with described ceramic tile surface;Or, use air compressor or without gas blowout Painting machine coordinates the spray gun of 0.3~1.0mm bore nozzle at described ceramic tile surface with on the speed even application of 20~100cm/s one The described Zinc oxide water colloidal sol of layer, ceramic tile 10~50cm described in the nozzle distance of described spray gun;Or, use automatic film applicator in institute State titanium oxide hydrosol glue described in ceramic tile surface coating last layer.
CN201610469161.4A 2016-06-25 2016-06-25 Using method for the titanium oxide sol of ceramic tile Pending CN106083210A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610469161.4A CN106083210A (en) 2016-06-25 2016-06-25 Using method for the titanium oxide sol of ceramic tile

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610469161.4A CN106083210A (en) 2016-06-25 2016-06-25 Using method for the titanium oxide sol of ceramic tile

Publications (1)

Publication Number Publication Date
CN106083210A true CN106083210A (en) 2016-11-09

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610469161.4A Pending CN106083210A (en) 2016-06-25 2016-06-25 Using method for the titanium oxide sol of ceramic tile

Country Status (1)

Country Link
CN (1) CN106083210A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109016098A (en) * 2018-06-27 2018-12-18 清远市简陶瓷有限公司 A kind of antibiotic ceramic tile and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102641731A (en) * 2011-02-22 2012-08-22 上海华明高技术(集团)有限公司 Active carbon fiber load calcium-doping titanium dioxide (TiO2) photocatalyst and preparation method of photocatalyst
JP2014204867A (en) * 2013-04-15 2014-10-30 国立大学法人信州大学 Biological implant and production method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102641731A (en) * 2011-02-22 2012-08-22 上海华明高技术(集团)有限公司 Active carbon fiber load calcium-doping titanium dioxide (TiO2) photocatalyst and preparation method of photocatalyst
JP2014204867A (en) * 2013-04-15 2014-10-30 国立大学法人信州大学 Biological implant and production method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109016098A (en) * 2018-06-27 2018-12-18 清远市简陶瓷有限公司 A kind of antibiotic ceramic tile and preparation method thereof

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Application publication date: 20161109