CN106079847B - The preparation method of wear-resisting puncture-resistant halftone - Google Patents

The preparation method of wear-resisting puncture-resistant halftone Download PDF

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Publication number
CN106079847B
CN106079847B CN201610418029.0A CN201610418029A CN106079847B CN 106079847 B CN106079847 B CN 106079847B CN 201610418029 A CN201610418029 A CN 201610418029A CN 106079847 B CN106079847 B CN 106079847B
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layer
emulsion layer
parts
pattern
emulsion
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Expired - Fee Related
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CN201610418029.0A
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Chinese (zh)
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CN106079847A (en
Inventor
戴晓晨
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BRAVE C & H SUPPLY Co Ltd
CANGHE PRECISION INDUSTRY (SUZHOU) Co Ltd
Original Assignee
BRAVE C & H SUPPLY Co Ltd
CANGHE PRECISION INDUSTRY (SUZHOU) Co Ltd
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Priority to CN201610418029.0A priority Critical patent/CN106079847B/en
Publication of CN106079847A publication Critical patent/CN106079847A/en
Application granted granted Critical
Publication of CN106079847B publication Critical patent/CN106079847B/en
Expired - Fee Related legal-status Critical Current
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41CPROCESSES FOR THE MANUFACTURE OR REPRODUCTION OF PRINTING SURFACES
    • B41C1/00Forme preparation
    • B41C1/14Forme preparation for stencil-printing or silk-screen printing
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02Organic and inorganic ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/17Amines; Quaternary ammonium compounds
    • C08K5/18Amines; Quaternary ammonium compounds with aromatically bound amino groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/18Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
    • C08L23/20Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
    • C08L23/22Copolymers of isobutene; Butyl rubber ; Homo- or copolymers of other iso-olefins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/26Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
    • C08L23/28Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or compounds containing halogen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/06Copolymers with styrene
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/20Adhesives in the form of films or foils characterised by their carriers
    • C09J7/22Plastics; Metallised plastics
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • General Chemical & Material Sciences (AREA)
  • Printing Plates And Materials Therefor (AREA)

Abstract

The invention discloses a kind of preparation methods of wear-resisting puncture-resistant halftone, include the following steps:1)Screen cloth is fixed on screen frame;2)Using emulsion as raw material, one layer of first emulsion layer is covered on the patch print face of screen cloth;3)Using emulsion as raw material, one layer of second emulsion layer is covered in above-mentioned first emulsion layer surface;4)It is bonded one layer of endless rubber belt layer in the second emulsion layer surface;The endless rubber belt layer is made of the adhesive tape for being fitted in the second emulsion layer surface;Adhesive tape printing along the second emulsion layer is arranged with area of the pattern outer, and surrounds the printing area of the pattern.Halftone prepared by the present invention has the endless rubber belt layer of wear-resisting puncture-resistant, can effectively improve the wear-resisting puncture resistance in halftone patch print face, improve the service life of halftone.

Description

The preparation method of wear-resisting puncture-resistant halftone
Technical field
The present invention relates to the preparation methods of wear-resisting puncture-resistant halftone.
Background technology
Halftone is the common tool of printing, and halftone includes screen frame and screen cloth, and the patch print face of screen cloth is equipped with band printing and schemes The emulsion layer of case, emulsion layer will recline object to be printed when printing, and emulsion layer is easy to be worn and puncture, to seriously affect printing quality Amount, therefore emulsion layer needs to carry out effective protection.
Invention content
The purpose of the present invention is to provide a kind of preparation method of wear-resisting puncture-resistant halftone, the halftone prepared has wear-resisting The endless rubber belt layer of puncture-resistant can effectively improve the wear-resisting puncture resistance in halftone patch print face, improve the service life of halftone.
To achieve the above object, the technical scheme is to design a kind of preparation method of wear-resisting puncture-resistant halftone, packets Include following steps:
1)Screen cloth is fixed on screen frame;
2)Using emulsion as raw material, coating, drying, exposure, imaging, baking operation are passed sequentially through, is printed in the patch of screen cloth One layer of first emulsion layer is covered on face, which is equipped with printing area of the pattern, is equipped in printing area of the pattern If dry printing pattern;
3)Using emulsion as raw material, coating, drying, exposure, imaging, baking operation are passed sequentially through, in above-mentioned first breast Oxidant layer surface covers one layer of second emulsion layer, and first emulsion layer is located between screen cloth patch print face and the second emulsion layer;Second Emulsion layer also is provided with printing area of the pattern, if also being provided with dry printing pattern in printing area of the pattern;Second emulsion layer Printing corresponded with area of the pattern with area of the pattern with the printing of the first emulsion layer, and on the second emulsion layer respectively printing scheme Case is corresponded with each printing on the first emulsion layer with pattern;
4)It is bonded one layer of endless rubber belt layer in the second emulsion layer surface, second emulsion layer is located at the first emulsion layer and ring Between shape adhesive tape layer;The endless rubber belt layer is made of the adhesive tape for being fitted in the second emulsion layer surface;The adhesive tape is along the second breast Printing is arranged with area of the pattern outer in oxidant layer, and surrounds the printing area of the pattern.
Preferably, the thickness of the endless rubber belt layer is 0.01~0.012mm.
Preferably, the width of the endless rubber belt layer is 10~15mm.
Preferably, one layer of endless rubber belt layer is bonded in the second emulsion layer surface by adhesive-tape application machine.
Preferably, the adhesive-tape application machine is equipped with CCD para-position system, which controls the bonding position of adhesive tape.
Preferably, the adhesive-tape application machine is equipped with displacement mechanism, which moves adhesive tape and supreme state bonding position.
Preferably, the adhesive-tape application machine is equipped with rubber roll, which is pressed on the second emulsion layer surface by adhesive tape, Adhesive tape is set to combine closely with the second emulsion layer.
Preferably, institute's displacement mechanism includes servo motor, precise guide rail and precise ball screw;The precise guide rail packet Include orthogonal X-axis guide rail and Y-axis guide rail.
Preferably, the adhesive tape is macromolecule compound adhesive tape.
Preferably, the adhesive tape includes substrate layer and adhesive layer;By weight, the substrate layer is by following components group At:
9.8 parts of chlorinated polypropylenes,
14.2 parts of butadiene-styrene rubber,
7.9 parts of butyl rubbers,
6.5 parts of emulsion polymerized styrene butadiene rubbers,
3.2 parts of vinyl bis-stearamides,
1.1 parts of zirconium oxides,
1.3 parts of calcium sulfate,
0.7 part of silicon carbide,
1.4 parts of 4- methoxyl group -3,5- dimethyl -2- hydroxymethylpyridines,
2.1 parts of γ-mercaptopropyl trimethoxysilanes,
1.7 parts of vinyltrimethoxysilanes,
0.9 part of diethyl thiourea,
1.3 parts of phenyl silicone oils,
1.6 parts of N- phenyl-1-naphthylamines,
2.1 parts of polyvinylpyrrolidones.
The advantages of the present invention are:A kind of preparation method of wear-resisting puncture-resistant halftone is provided, is prepared Halftone has the endless rubber belt layer of wear-resisting puncture-resistant, can effectively improve the wear-resisting puncture resistance in halftone patch print face, improve halftone Service life.
Halftone patch print of the present invention face is equipped with the second emulsion layer, and the second emulsion layer can play a protective role to the first emulsion layer.
Halftone of the present invention patch print face is additionally provided with endless rubber belt layer, and endless rubber belt layer is located at object surface to be printed and second when printing Between emulsion layer, it can play a protective role to the second emulsion layer;And endless rubber belt layer of the present invention is made of wear-resisting puncture-resistant adhesive tape, The wear-resisting puncture resistance in halftone patch print face can be effectively improved.The substrate layer of adhesive tape of the present invention is made by specific components with specific proportioning At with higher wear-resisting puncture resistance.
The ring protection layer that the present invention is arranged in the second emulsion layer surface(Endless rubber belt layer), by being fitted in the second emulsion Layer surface printing constitutes with the adhesive tape of area of the pattern outer, and ring protection is prepared using emulsion for raw material without being to continue with Layer, can remove from again be coated with, dry, exposure, imaging, drying and etc., enormously simplify process, reduce energy consumption.And this Invention prepares ring protection layer using adhesive tape, prepares ring protection layer as raw material relative to using emulsion, was printing The abrasion resistance of adhesive tape and paracentesis resistance are stronger in journey, can preferably improve halftone service life.
The present invention can be by adhesive-tape application machine in the second emulsion layer surface automatic attaching ring protection layer(Endless rubber belt layer), can The precision that adhesive tape gluing position is controlled by CCD para-position system avoids the inaccurate problem manually aligned, while utilizing machine Joint adhesive band reduces multiple working procedure relative to manual operation, greatly shortens the production time of every halftone, improves Production capacity and efficiency can reduce to artificial use using machine joint adhesive band, reduce cost of labor.
Specific implementation mode
With reference to embodiment, the specific embodiment of the present invention is further described.Following embodiment is only used for more Add and clearly demonstrate technical scheme of the present invention, and not intended to limit the protection scope of the present invention.
The technical solution that the present invention embodies is:
A kind of preparation method of wear-resisting puncture-resistant halftone, includes the following steps:
1)Screen cloth is fixed on screen frame;
2)Using emulsion as raw material, coating, drying, exposure, imaging, baking operation are passed sequentially through, is printed in the patch of screen cloth One layer of first emulsion layer is covered on face, which is equipped with printing area of the pattern, is equipped in printing area of the pattern If dry printing pattern;
3)Using emulsion as raw material, coating, drying, exposure, imaging, baking operation are passed sequentially through, in above-mentioned first breast Oxidant layer surface covers one layer of second emulsion layer, and first emulsion layer is located between screen cloth patch print face and the second emulsion layer;Second Emulsion layer also is provided with printing area of the pattern, if also being provided with dry printing pattern in printing area of the pattern;Second emulsion layer Printing corresponded with area of the pattern with area of the pattern with the printing of the first emulsion layer, and on the second emulsion layer respectively printing scheme Case is corresponded with each printing on the first emulsion layer with pattern;
4)It is bonded one layer of endless rubber belt layer in the second emulsion layer surface, second emulsion layer is located at the first emulsion layer and ring Between shape adhesive tape layer;The endless rubber belt layer is made of the adhesive tape for being fitted in the second emulsion layer surface;The adhesive tape is along the second breast Printing is arranged with area of the pattern outer in oxidant layer, and surrounds the printing area of the pattern.
The thickness of the endless rubber belt layer is 0.01~0.012mm.
The width of the endless rubber belt layer is 10~15mm.
Step 4)In by adhesive-tape application machine the second emulsion layer surface be bonded one layer of endless rubber belt layer.
The adhesive-tape application machine is equipped with CCD para-position system, which controls the bonding position of adhesive tape.
The adhesive-tape application machine is equipped with displacement mechanism, which moves adhesive tape and supreme state bonding position.
The adhesive-tape application machine is equipped with rubber roll, which is pressed on the second emulsion layer surface by adhesive tape, makes adhesive tape It combines closely with the second emulsion layer.
Institute's displacement mechanism includes servo motor, precise guide rail and precise ball screw;The precise guide rail includes mutual Vertical X-axis guide rail and Y-axis guide rail.
The adhesive tape is macromolecule compound adhesive tape.
The adhesive tape includes substrate layer and adhesive layer;By weight, the substrate layer is composed of the following components:
9.8 parts of chlorinated polypropylenes,
14.2 parts of butadiene-styrene rubber,
7.9 parts of butyl rubbers,
6.5 parts of emulsion polymerized styrene butadiene rubbers,
3.2 parts of vinyl bis-stearamides,
1.1 parts of zirconium oxides,
1.3 parts of calcium sulfate,
0.7 part of silicon carbide,
1.4 parts of 4- methoxyl group -3,5- dimethyl -2- hydroxymethylpyridines,
2.1 parts of γ-mercaptopropyl trimethoxysilanes,
1.7 parts of vinyltrimethoxysilanes,
0.9 part of diethyl thiourea,
1.3 parts of phenyl silicone oils,
1.6 parts of N- phenyl-1-naphthylamines,
2.1 parts of polyvinylpyrrolidones.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For member, without departing from the technical principles of the invention, several improvements and modifications can also be made, these improvements and modifications Also it should be regarded as protection scope of the present invention.

Claims (1)

1. the preparation method of wear-resisting puncture-resistant halftone, which is characterized in that include the following steps:
1)Screen cloth is fixed on screen frame;
2)Using emulsion as raw material, coating, drying, exposure, imaging, baking operation are passed sequentially through, on the patch print face of screen cloth One layer of first emulsion layer is covered, which is equipped with printing area of the pattern, is equipped in the printing area of the pattern several Printing pattern;
3)Using emulsion as raw material, coating, drying, exposure, imaging, baking operation are passed sequentially through, in above-mentioned first emulsion layer Surface covers one layer of second emulsion layer, and first emulsion layer is located between screen cloth patch print face and the second emulsion layer;Second emulsion Layer also is provided with printing area of the pattern, if also being provided with dry printing pattern in printing area of the pattern;The print of second emulsion layer Brush is corresponded with area of the pattern with the printing of the first emulsion layer with area of the pattern, and on the second emulsion layer respectively printing pattern with Each printing is corresponded with pattern on first emulsion layer;
4)It is bonded one layer of endless rubber belt layer in the second emulsion layer surface by adhesive-tape application machine, second emulsion layer is located at the first breast Between oxidant layer and endless rubber belt layer;The endless rubber belt layer is made of the adhesive tape for being fitted in the second emulsion layer surface;The adhesive tape Printing is arranged with area of the pattern outer along the second emulsion layer, and surrounds the printing area of the pattern;The endless rubber belt layer Thickness is 0.01~0.012mm;The width of the endless rubber belt layer is 10~15mm;The adhesive-tape application machine is equipped with CCD para-position system System, the CCD para-position system control the bonding position of adhesive tape;The adhesive-tape application machine is equipped with displacement mechanism, and the displacement mechanism is by adhesive tape It is moved to above-mentioned bonding position;Institute's displacement mechanism includes servo motor, precise guide rail and precise ball screw;The precision is led Rail includes orthogonal X-axis guide rail and Y-axis guide rail;The adhesive-tape application machine is equipped with rubber roll, and the rubber roll is by adhesive tape pressure Tightly in the second emulsion layer surface, adhesive tape is made to combine closely with the second emulsion layer;
The adhesive tape is macromolecule compound adhesive tape;The adhesive tape includes substrate layer and adhesive layer;
By weight, the substrate layer is composed of the following components:
9.8 parts of chlorinated polypropylenes,
14.2 parts of butadiene-styrene rubber,
7.9 parts of butyl rubbers,
6.5 parts of emulsion polymerized styrene butadiene rubbers,
3.2 parts of vinyl bis-stearamides,
1.1 parts of zirconium oxides,
1.3 parts of calcium sulfate,
0.7 part of silicon carbide,
1.4 parts of 4- methoxyl group -3,5- dimethyl -2- hydroxymethylpyridines,
2.1 parts of γ-mercaptopropyl trimethoxysilanes,
1.7 parts of vinyltrimethoxysilanes,
0.9 part of diethyl thiourea,
1.3 parts of phenyl silicone oils,
1.6 parts of N- phenyl-1-naphthylamines,
2.1 parts of polyvinylpyrrolidones.
CN201610418029.0A 2016-06-13 2016-06-13 The preparation method of wear-resisting puncture-resistant halftone Expired - Fee Related CN106079847B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610418029.0A CN106079847B (en) 2016-06-13 2016-06-13 The preparation method of wear-resisting puncture-resistant halftone

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610418029.0A CN106079847B (en) 2016-06-13 2016-06-13 The preparation method of wear-resisting puncture-resistant halftone

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CN106079847B true CN106079847B (en) 2018-09-04

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Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU833458A1 (en) * 1979-10-05 1981-05-30 Рязанский Проектно-Технологическийинститут Stencil plate making method
JP4488589B2 (en) * 2000-05-29 2010-06-23 株式会社 旺電舎 Manufacturing method of mesh and pattern integrated screen mask for precision printing
CN101570078A (en) * 2009-05-11 2009-11-04 大连崇达电子有限公司 Treatment method to reduce screen damage by screen printing
CN202640954U (en) * 2012-05-25 2013-01-02 苏州优尔嘉电子有限公司 Screen painting plate
CN203142008U (en) * 2013-01-21 2013-08-21 天之域电子工业(厦门)有限公司 Silk-screen printing board structure of touch screen
CN103753989B (en) * 2013-12-20 2016-08-24 深圳市裕同包装科技股份有限公司 A kind of method for printing screen
CN103777268B (en) * 2014-01-22 2016-05-04 福州大学 A kind of method that improves LGP half tone press resistance rate and permeability
CN105050330B (en) * 2015-07-02 2018-05-01 江门崇达电路技术有限公司 A kind of production method for thickening halftone and the method using thickening halftone silk-screen indigo plant glue
CN105346213B (en) * 2015-09-15 2018-01-09 赫日光电(苏州)有限公司 Composite halftone with choana and preparation method thereof

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