CN106079690A - A kind of aerosil felt of strong weatherability and preparation method thereof - Google Patents

A kind of aerosil felt of strong weatherability and preparation method thereof Download PDF

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Publication number
CN106079690A
CN106079690A CN201610410115.7A CN201610410115A CN106079690A CN 106079690 A CN106079690 A CN 106079690A CN 201610410115 A CN201610410115 A CN 201610410115A CN 106079690 A CN106079690 A CN 106079690A
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CN
China
Prior art keywords
tack coat
aerogel blanket
nano silicon
layer
enhancement layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610410115.7A
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Chinese (zh)
Inventor
徐斌
刘汉东
钊文科
柏莹莹
任斌
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JIANGSU DEWN ENERGY SAVING CO Ltd
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JIANGSU DEWN ENERGY SAVING CO Ltd
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Priority to CN201610410115.7A priority Critical patent/CN106079690A/en
Publication of CN106079690A publication Critical patent/CN106079690A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/20Layered products comprising a layer of metal comprising aluminium or copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/06Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/06Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer characterised by a fibrous or filamentary layer mechanically connected, e.g. by needling to another layer, e.g. of fibres, of paper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/10Interconnection of layers at least one layer having inter-reactive properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B9/047Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material made of fibres or filaments
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • B32B2262/0261Polyamide fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • B32B2262/0276Polyester fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10Inorganic fibres
    • B32B2262/101Glass fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/712Weather resistant

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  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Laminated Bodies (AREA)

Abstract

The present invention relates to aerosil felt of a kind of strong weatherability and preparation method thereof; including nano silicon aerogel blanket body, pre-enhancement layer, tack coat and protective layer; described tack coat is located at the surface of nano silicon aerogel blanket body; described protective layer sets the top of tack coat, and described pre-enhancement layer is between nano silicon aerogel blanket body and tack coat.By at dewatering nano aerosil felt surface pre-add enhancement layer and strengthening in advance with aerosil felt; then hot melt adhesive film is applied; the protective layers such as aluminium foil are laid again on hot melt adhesive film; avoid contacting of aerosil felt and air, moisture etc.; slow down the efflorescence speed of surface gel; simultaneously; existence due to pre-enhancement layer; the strength and stability that tack coat is combined with aerogel blanket is greatly enhanced; coordinate different protective layers, the stability and persistency being combined with different materials can be met.

Description

A kind of aerosil felt of strong weatherability and preparation method thereof
Technical field
The present invention relates to a kind of aerosil felt, particularly relate to the aerosil felt of a kind of strong weatherability And preparation method thereof.
Background technology
Along with becoming increasingly conspicuous of current energy source problem, energy-saving and emission-reduction have become as the focus of current research.Silicon dioxide gas Gel rubber material is due to the heat-insulating capability of its excellence, and the use in field of thermal insulation about comes about extensive, uses nano silicon airsetting Glue material, not only can greatly reduce insulation layer thickness, and owing to silica aerogel material is substantially all by dioxy SiClx and glass fibre composition, do not have any harmful pollution for environment.It it is preferable insulation material succedaneum.
But, the aerosil felt currently used needs to be used in combination with other material in use process mostly, Especially at building field, with using time lengthening, surface gel can be because contacting gradually efflorescence, with contactant with sky, moisture etc. The cohesive force of body dies down, and affects the serviceability of product, uses the manufacture method of VIP plate at present, is sealed by aerogel blanket aluminum film After dress, evacuation can slow down problems to a certain extent, but after still suffering from extending gas leakage in time, aluminium foil is combined with aeroge Power dies down and is difficult to make the problem of coiled material, limits the expansion of nanometer titanium dioxide silica aerogel range.
Summary of the invention
It is an object of the invention to: for the defect of prior art, it is proposed that the silicon dioxide airsetting of a kind of strong weatherability Rubber mat and preparation method thereof.
The technical solution adopted in the present invention is: the aerosil felt of a kind of strong weatherability, including nano-silica SiClx aerogel blanket body, pre-enhancement layer, tack coat and protective layer, described tack coat is located at nano silicon aerogel blanket The surface of body, described protective layer sets the top of tack coat, and described pre-enhancement layer is positioned at nano silicon aerogel blanket Between body and tack coat, described protective layer is that polyamide fibre cloth, woven dacron, macromolecule membrane or aluminum foil material are constituted, described Pre-enhancement layer is that glass fiber material is constituted, and described tack coat is pressure sensitive adhesive or hot melt adhesive material composition.
In the present invention: the thickness of described protective layer is 0.1 1.5mm.
In the present invention: the thickness of described pre-enhancement layer is 0.1 0.5mm.
In the present invention: described tack coat is 0.15 0.35mm.
A kind of method of aerosil felt preparing strong weatherability, comprises the steps:
(1), after nano silicon aerogel blanket body completes, before hydrophobic treatment or pre-on its surface after hydrophobic treatment Lay one layer of pre-enhancement layer being made up of glass fiber material, then by needle-punching method with nano silicon aerogel blanket originally Body strengthens in advance;
(2), on pre-enhancement layer, one layer of tack coat being made up of pressure sensitive adhesive or hot melt adhesive material is laid;
(3), by pre-thermo-compression bonding layer, then its surface hot pressing one layer by polyamide fibre cloth, woven dacron, macromolecule membrane or aluminium foil The protective layer that material is constituted, can be steady in a long-term after preparing aerosil felt external application mortar.
After using technique scheme, the invention have the benefit that by dewatering nano aerosil felt Surface pre-add enhancement layer also strengthens in advance with aerosil felt, then applies hot melt adhesive film, then lays on hot melt adhesive film The protective layers such as aluminium foil, it is to avoid aerosil felt contacts with air, moisture etc., slow down the efflorescence speed of surface gel Degree, simultaneously as the existence of pre-enhancement layer, the strength and stability that tack coat is combined with aerogel blanket is greatly enhanced, and coordinates not Same protective layer, can meet the stability and persistency being combined with different materials.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is further illustrated.
Embodiment 1
Utilize the nano silicon aerogel blanket after hydrophobic treatment, lay the thick loose glass fibers of one layer of 0.1mm on surface in advance Wei Bu, is then strengthened with nanometer titanium dioxide silica aerogel by needle-punching method, the most pre-hot pressing 0.15mmPO hot melt adhesive film in advance, then At one layer of aluminium foil of surface hot pressing, prepared product in an outdoor environment can be steady in a long-term.
Embodiment 2
Utilize the nano silicon aerogel blanket after hydrophobic treatment, lay the thick glass fabric of one layer of 0.1mm on surface in advance, Then strengthened in advance with nanometer titanium dioxide silica aerogel by needle-punching method, the most pre-hot pressing 0.25mmTPU hot melt adhesive film, then at table Fever sensation of the face one layer of polyamide fibre cloth of pressure, can be steady in a long-term after preparing product external application mortar.
Embodiment 3
Utilize the nano silicon aerogel blanket after hydrophobic treatment, lay the thick glass fibre of one layer of 0.5mm in advance on surface, so Strengthened in advance with nanometer titanium dioxide silica aerogel by needle-punching method afterwards, the most pre-quick glue of hot pressing 0.35mm, then in surface hot pressing one Layer woven dacron, can be steady in a long-term after preparing product external application mortar.
In the present invention: protective layer and the existence of tack coat, completely cut off aerogel blanket and contacted with the direct of empty gas and water, subtracted The weak efflorescence speed of aeroge surface gel, meanwhile, selects the form of protective layer, can meet strong with the combination of different materials Degree demand.For ensureing preferable product stability, nano silicon aerogel blanket is preferred with the product after hydrophobic treatment.Bonding Layer can be pressure sensitive adhesive, PUR etc., is preferred with hot melt adhesive film, does not has solvent, the most do not produce low point in the course of processing Sub-compound, will not damage the structure of nanometer titanium dioxide silica aerogel and affect the heat conductivility of product.
For strengthening intensity and the persistency that tack coat is combined with nanometer titanium dioxide silica aerogel, in advance at nano silicon A thin layer bonding enhancement layer such as glass fibre thin layer etc. is laid on aerogel blanket surface, and pre-with aerogel blanket by methods such as acupunctures Strengthen, the strength and stability of combination can be obviously improved.
Above the detailed description of the invention of the present invention is described, but the present invention is not limited to above description.For this For the technical staff in field, any equal amendment to the technical program and replacement are all within the scope of the invention.Cause This, the impartial conversion made without departing from the spirit and scope of the invention and amendment, all should contain in the scope of the present invention.

Claims (6)

1. the aerosil felt of a strong weatherability, it is characterised in that: include nano silicon aerogel blanket body, Pre-enhancement layer, tack coat and protective layer, described tack coat is located at the surface of nano silicon aerogel blanket body, described Protective layer sets the top of tack coat, described pre-enhancement layer between nano silicon aerogel blanket body and tack coat, Described protective layer is that polyamide fibre cloth, woven dacron, macromolecule membrane or aluminum foil material are constituted, and described pre-enhancement layer is glass fibre Material is constituted, and described tack coat is pressure sensitive adhesive or hot melt adhesive material composition.
2. according to the aerosil felt of a kind of strong weatherability described in claim 1, it is characterised in that: described protective layer Thickness is 0.1 1.5mm.
3. according to a kind of low temperature nano silicon aerogel blanket described in claim 1, it is characterised in that: described pre-enhancement layer Thickness be 0.1 0.5mm.
4. according to a kind of low temperature nano silicon aerogel blanket described in claim 1, it is characterised in that: described tack coat It is 0.15 0.35mm.
5. the method for the aerosil felt preparing weatherability as strong in claim 1, it is characterised in that: include as follows Step:
(1), after nano silicon aerogel blanket body completes, before hydrophobic treatment or pre-on its surface after hydrophobic treatment Lay one layer of pre-enhancement layer being made up of glass fiber material, then by needle-punching method with nano silicon aerogel blanket originally Body strengthens in advance;
(2), on pre-enhancement layer, one layer of tack coat being made up of pressure sensitive adhesive or hot melt adhesive material is laid;
(3), by pre-thermo-compression bonding layer, then its surface hot pressing one layer by polyamide fibre cloth, woven dacron, macromolecule membrane or aluminium foil The protective layer that material is constituted.
6. the aerosil felt prepared by the preparation method described in claim 5, it is characterised in that: described Aerosil felt external application mortar, can be steady in a long-term after preparing aerosil felt external application mortar.
CN201610410115.7A 2016-06-13 2016-06-13 A kind of aerosil felt of strong weatherability and preparation method thereof Pending CN106079690A (en)

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Cited By (7)

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Publication number Priority date Publication date Assignee Title
CN106697593A (en) * 2016-12-23 2017-05-24 顺丰速运有限公司 Thermal-insulation packing material and preparation method thereof and thermal insulation bag
CN108673997A (en) * 2018-05-29 2018-10-19 安徽中航名坤新材料科技有限公司 It is a kind of to prepare large scale, the preparation method of high thickness aerogel plate
CN109437661A (en) * 2018-12-27 2019-03-08 深圳市通泰盈电子科技有限公司 A kind of heat-insulating, fire-preventing composite material and its preparation, application method
CN109715384A (en) * 2016-11-30 2019-05-03 松下知识产权经营株式会社 Heat shield and its manufacturing method
CN111730926A (en) * 2020-07-13 2020-10-02 巩义市泛锐熠辉复合材料有限公司 Heat-insulating flame-retardant plate and preparation method thereof
CN111873574A (en) * 2020-07-29 2020-11-03 南京拉思德新材料科技有限公司 Nanoscale aerogel heat insulation felt
CN112038513A (en) * 2019-06-03 2020-12-04 江苏泛亚微透科技股份有限公司 Silica aerogel felt product coated with high silica glass fiber cloth and used for lithium ion power battery of electric vehicle and manufacturing method of silica aerogel felt product

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US20060182943A1 (en) * 2003-02-27 2006-08-17 Wacker-Chemie Gmbh Thermal insulation for underwater components for oil and gas production
CN201599533U (en) * 2009-06-02 2010-10-06 成都思摩纳米技术有限公司 High temperature heat-perseveration thermal-insulation composite material
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CN104496403A (en) * 2014-12-23 2015-04-08 南京唯才新能源科技有限公司 Reinforced aerogel composite material and preparation method thereof
CN105500780A (en) * 2015-12-04 2016-04-20 卓达新材料科技集团有限公司 Aerogel vacuum insulated panel and preparation method thereof

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CN104496403A (en) * 2014-12-23 2015-04-08 南京唯才新能源科技有限公司 Reinforced aerogel composite material and preparation method thereof
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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109715384A (en) * 2016-11-30 2019-05-03 松下知识产权经营株式会社 Heat shield and its manufacturing method
CN106697593A (en) * 2016-12-23 2017-05-24 顺丰速运有限公司 Thermal-insulation packing material and preparation method thereof and thermal insulation bag
CN108673997A (en) * 2018-05-29 2018-10-19 安徽中航名坤新材料科技有限公司 It is a kind of to prepare large scale, the preparation method of high thickness aerogel plate
CN109437661A (en) * 2018-12-27 2019-03-08 深圳市通泰盈电子科技有限公司 A kind of heat-insulating, fire-preventing composite material and its preparation, application method
CN109437661B (en) * 2018-12-27 2021-04-06 深圳市通泰盈科技股份有限公司 Heat-insulating fireproof composite material and preparation and application methods thereof
CN112038513A (en) * 2019-06-03 2020-12-04 江苏泛亚微透科技股份有限公司 Silica aerogel felt product coated with high silica glass fiber cloth and used for lithium ion power battery of electric vehicle and manufacturing method of silica aerogel felt product
CN111730926A (en) * 2020-07-13 2020-10-02 巩义市泛锐熠辉复合材料有限公司 Heat-insulating flame-retardant plate and preparation method thereof
CN111730926B (en) * 2020-07-13 2021-11-26 巩义市泛锐熠辉复合材料有限公司 Heat-insulating flame-retardant plate and preparation method thereof
CN111873574A (en) * 2020-07-29 2020-11-03 南京拉思德新材料科技有限公司 Nanoscale aerogel heat insulation felt

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Application publication date: 20161109