CN106077025A - Process the system and method for house refuse - Google Patents

Process the system and method for house refuse Download PDF

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Publication number
CN106077025A
CN106077025A CN201610431683.5A CN201610431683A CN106077025A CN 106077025 A CN106077025 A CN 106077025A CN 201610431683 A CN201610431683 A CN 201610431683A CN 106077025 A CN106077025 A CN 106077025A
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CN
China
Prior art keywords
outlet
gas
pyrolysis
house refuse
entrance
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Pending
Application number
CN201610431683.5A
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Chinese (zh)
Inventor
贾懿曼
包欣欣
肖磊
陶进峰
吴道洪
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Beijing Shenwu Environmental and Energy Technology Co Ltd
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Beijing Shenwu Environmental and Energy Technology Co Ltd
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Priority to CN201610431683.5A priority Critical patent/CN106077025A/en
Publication of CN106077025A publication Critical patent/CN106077025A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • B09B3/40Destroying solid waste or transforming solid waste into something useful or harmless involving thermal treatment, e.g. evaporation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B5/00Operations not covered by a single other subclass or by a single other group in this subclass
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B21/00Heating of coke ovens with combustible gases
    • C10B21/08Heating of coke ovens with combustible gases by applying special heating gases
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B47/00Destructive distillation of solid carbonaceous materials with indirect heating, e.g. by external combustion
    • C10B47/18Destructive distillation of solid carbonaceous materials with indirect heating, e.g. by external combustion with moving charge
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/58Production of combustible gases containing carbon monoxide from solid carbonaceous fuels combined with pre-distillation of the fuel
    • C10J3/60Processes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10Feedstock materials
    • C10G2300/1003Waste materials
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913Carbonaceous raw material
    • C10J2300/0946Waste, e.g. MSW, tires, glass, tar sand, peat, paper, lignite, oil shale
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • Y02P20/129Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Processing Of Solid Wastes (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention discloses the system and method processing house refuse, this system includes: pretreatment unit, and described pretreatment unit has house refuse entrance, foul smell outlet, organic waste outlet, inorganic refuse outlet and the first outlet of sewer;Heat accumulation type radiant tube revolving bed, described heat accumulation type radiant tube revolving bed has the first combustible gas entrance, combustion air inlet, organic waste entrance, pyrolysis oil gas vent and pyrolytic carbon outlet, described combustion air inlet is connected with the outlet of described foul smell, and described organic waste entrance is connected with the outlet of described organic waste;Cement kiln synergetic unit, described cement kiln synergetic unit has feed(raw material)inlet, fuel inlet, waste gas outlet and cement exit, and described fuel inlet is connected with the outlet of described pyrolytic carbon.This system is possible not only to effectively reduce manufacture of cement cost, and can realize the innoxious of house refuse and recycling treatment, has huge economic benefit and social benefit.

Description

Process the system and method for house refuse
Technical field
The invention belongs to chemical technology field, specifically, the present invention relates to a kind of system processing house refuse and side Method.
Background technology
At present, the process problem of domestic waste becomes whole people's focus of attention already.Existing landfill, compost, burning Etc. technology due to himself intrinsic shortcoming so that it is development is limited to.China many urban construction consumer waste incineration is sent out Power plant, but burn the two English pollution problems brought and cause people's dispute to waste incineration mode.Two English environmental toxicities Greatly, the most degradable, cause great threat to resident is healthy.The method using cement kiln synergic processing rubbish, existing skill Art have rubbish is directly burned after or directly garbage raw material is thrown away in cement kiln.Directly burn away the refuse and can produce two English etc. Pollute environment, produce the device of some corrosive gas meeting corrosive water stall, breaking plant;And directly house refuse is thrown away into water Reacting in stall, the complicated component of rubbish, water content high can affect the quality of cement products, affects whole cement kiln Technique.
Therefore, the technology of existing process house refuse is further improved.
Summary of the invention
It is contemplated that one of technical problem solved the most to a certain extent in correlation technique.To this end, the present invention One purpose is to propose a kind of system and method processing house refuse, and this system is by by the process of house refuse and cement Kiln is worked in coordination with treatment technology and is combined, and is possible not only to effectively reduce manufacture of cement cost, and can realize house refuse Innoxious and recycling treatment, there is huge economic benefit and social benefit.
In the first aspect of the invention, this present invention proposes a kind of system processing house refuse.According to the present invention Embodiment, this system includes:
Pretreatment unit, described pretreatment unit have house refuse entrance, foul smell outlet, organic waste outlet, inorganic Garbage outlet and the first outlet of sewer;
Heat accumulation type radiant tube revolving bed, described heat accumulation type radiant tube revolving bed has the first combustible gas entrance, combustion air Entrance, organic waste entrance, pyrolysis oil gas vent and pyrolytic carbon outlet, described combustion air inlet exports phase with described foul smell Even, described organic waste entrance is connected with the outlet of described organic waste;
Cement kiln synergetic unit, described cement kiln synergetic unit has feed(raw material)inlet, fuel inlet, waste gas go out Mouth and cement exit, described fuel inlet is connected with the outlet of described pyrolytic carbon.
Thus, the system of process house refuse according to embodiments of the present invention is by obtaining after house refuse pretreatment Organic waste and foul smell supply carry out pyrolysis processing to heat accumulation type radiant tube revolving bed, can obtain being pyrolyzed oil gas and pyrolysis Charcoal, such that it is able to avoid the wasting of resources that garbage loading embeading or burning cause, and can effectively solve to burn by pyrolysis processing The problem that two English that rubbish is brought pollute, supplies gained pyrolytic carbon to cement kiln synergetic unit as combustion simultaneously Material uses, such that it is able to garbage disposal combined with cement kiln synergetic unit, relative to existing cement kiln Cooperative disposal method, in this application, once cement kiln production line stops production, and house refuse can also be pyrolyzed in advance, will not bank up Smelly, produce the problem that rubbish can be put nowhere, thus realize the innoxious of house refuse and recycling treatment.
It addition, the system of process house refuse according to the above embodiment of the present invention can also have following additional technology Feature:
In some embodiments of the invention, the system of described process house refuse farther includes: Oil-gas Separation purifies Device, described Oil-gas Separation purifier has pyrolysis oil gas entrance, pyrolysis gas outlet, pyrolysis oil outlet and the second sewage and goes out Mouthful, described pyrolysis oil gas entrance is connected with described pyrolysis oil gas vent;Combustible gas storage tank, described combustible gas storage tank has second can Fuel gas inlet and the outlet of the second combustible gas, described second combustible gas entrance is connected with described pyrolysis gas outlet, described second flammable Gas outlet is connected with described first combustible gas entrance;Sewage-treatment plant, described sewage-treatment plant has sewage inlet and place Reason liquid outlet, described sewage inlet is connected with described first outlet of sewer and described second outlet of sewer respectively.Thus, it is possible to it is aobvious Write the environmental benefit improving this system.
In some embodiments of the invention, the outlet of described inorganic refuse is connected with described feed(raw material)inlet.Thus, it is possible to it is aobvious Write and reduce manufacture of cement cost.
In some embodiments of the invention, the outlet of described pyrolytic carbon and the preheating in described cement kiln synergetic unit Device, dore furnace are connected with the fuel inlet at least one in rotary kiln.Become thus, it is possible to reduce manufacture of cement further This.
In some embodiments of the invention, the system of described process house refuse farther includes: TRT, described TRT has exhaust gas entrance and the outlet of boiler residual air, and described exhaust gas entrance is connected with described waste gas outlet, described boiler residual Gas outlet is connected with the raw material grinding mill in described cement kiln synergetic unit.Thus, it is possible to significantly reduce system energy consumption.
In another aspect of the invention, the present invention proposes a kind of method processing house refuse.According to the present invention's Embodiment, the method is that the system using process house refuse described above is carried out.According to a particular embodiment of the invention, The method includes:
(1) will house refuse supply to described pretreatment unit carries out pretreatment, in order to obtain foul smell, organic waste, Inorganic refuse and the first sewage;
(2) described organic waste and described foul smell are supplied to described heat accumulation type radiant tube revolving bed, in order to have described Machine rubbish carries out pyrolysis processing, obtains being pyrolyzed oil gas and pyrolytic carbon;
(3) as fuel, cement slurry is assisted to described cement kiln synergetic unit the supply of described pyrolytic carbon With processing, in order to obtain waste gas and cement.
Thus, the method for process house refuse according to embodiments of the present invention is by obtaining after house refuse pretreatment Organic waste and foul smell supply carry out pyrolysis processing to heat accumulation type radiant tube revolving bed, can obtain being pyrolyzed oil gas and pyrolysis Charcoal, such that it is able to avoid the wasting of resources that garbage loading embeading or burning cause, and can effectively solve to burn by pyrolysis processing The problem that two English that rubbish is brought pollute, supplies gained pyrolytic carbon to cement kiln synergetic unit as combustion simultaneously Material uses, such that it is able to garbage disposal combined with cement kiln synergetic unit, relative to existing cement kiln Cooperative disposal method, in this application, once cement kiln production line stops production, and house refuse can also be pyrolyzed in advance, will not bank up Smelly, produce the problem that rubbish can be put nowhere, thus realize the innoxious of house refuse and recycling treatment.
It addition, the method for process house refuse according to the above embodiment of the present invention can also have following additional technology Feature:
In some embodiments of the invention, the method for described process house refuse farther includes: (4) are by described pyrolysis Oil gas supply carries out isolation of purified process to described Oil-gas Separation purifier, in order to obtain pyrolysis gas, pyrolysis oil and second dirty Water, and the supply of described pyrolysis gas is used to described heat accumulation type radiant tube revolving bed as combustion gas;(5) step (1) is obtained Described second sewage that described first sewage and step (4) obtain supplies to sewage-treatment plant, in order to obtain treatment fluid.By This, can significantly improve the environmental benefit of this system.
In some embodiments of the invention, the method for described process house refuse farther includes: (6) are by step (1) The described inorganic refuse supply obtained carries out described collaborative process to described cement kiln synergetic unit.Thus, it is possible to it is aobvious Write and reduce manufacture of cement cost.
In some embodiments of the invention, the method for described process house refuse farther includes: step (2) obtained The supply of described pyrolytic carbon at least one in preheater, dore furnace and the rotary kiln in described cement kiln synergetic unit Use as fuel.Thus, it is possible to reduce manufacture of cement cost further.
In some embodiments of the invention, the method for described process house refuse farther includes: (7) are by step (3) The described waste gas supply obtained carries out UTILIZATION OF VESIDUAL HEAT IN to described TRT, in order to obtain boiler residual air, and by described boiler residual Gas supply uses to the raw material grinding mill in described cement kiln synergetic unit as dry medium.Thus, it is possible to significantly reduce it is System energy consumption.
The additional aspect of the present invention and advantage will part be given in the following description, and part will become from the following description Obtain substantially, or recognized by the practice of the present invention.
Accompanying drawing explanation
Above-mentioned and/or the additional aspect of the present invention and advantage are from combining the accompanying drawings below description to embodiment and will become Substantially with easy to understand, wherein:
Fig. 1 is the system structure schematic diagram processing house refuse according to an embodiment of the invention;
Fig. 2 is the system structure schematic diagram of the process house refuse according to further embodiment of the present invention;
Fig. 3 is the system structure schematic diagram of the process house refuse according to another embodiment of the present invention;
Fig. 4 is the system structure schematic diagram of the process house refuse according to another embodiment of the present invention;
Fig. 5 is the system structure schematic diagram of the process house refuse according to another embodiment of the present invention;
Fig. 6 is the method flow schematic diagram processing house refuse according to an embodiment of the invention;
Fig. 7 is the method flow schematic diagram of the process house refuse according to further embodiment of the present invention;
Fig. 8 is the method flow schematic diagram of the process house refuse according to another embodiment of the present invention;
Fig. 9 is the method flow schematic diagram of the process house refuse according to another embodiment of the present invention;
Figure 10 is the system structure schematic diagram of the process house refuse according to another embodiment of the present invention.
Detailed description of the invention
Embodiments of the invention are described below in detail, and the example of described embodiment is shown in the drawings, the most from start to finish Same or similar label represents same or similar element or has the element of same or like function.Below with reference to attached The embodiment that figure describes is exemplary, it is intended to is used for explaining the present invention, and is not considered as limiting the invention.
In describing the invention, it is to be understood that term " " center ", " longitudinally ", " laterally ", " length ", " width ", " thickness ", " on ", D score, "front", "rear", "left", "right", " vertically ", " level ", " top ", " end ", " interior ", " outward ", " up time Pin ", " counterclockwise ", " axially ", " radially ", the orientation of the instruction such as " circumferential " or position relationship be based on orientation shown in the drawings or Position relationship, is for only for ease of the description present invention and simplifies description rather than instruction or imply that the device of indication or element must Must have specific orientation, with specific azimuth configuration and operation, be therefore not considered as limiting the invention.
Additionally, term " first ", " second " are only used for describing purpose, and it is not intended that instruction or hint relative importance Or the implicit quantity indicating indicated technical characteristic.Thus, define " first ", the feature of " second " can express or Implicitly include at least one this feature.In describing the invention, " multiple " are meant that at least two, such as two, three Individual etc., unless otherwise expressly limited specifically.
In the present invention, unless otherwise clearly defined and limited, term " install ", " being connected ", " connection ", " fixing " etc. Term should be interpreted broadly, and connects for example, it may be fixing, it is also possible to be to removably connect, or integral;Can be that machinery connects Connect, it is also possible to be electrical connection;Can be to be joined directly together, it is also possible to be indirectly connected to by intermediary, in can being two elements The connection in portion or the interaction relationship of two elements, unless otherwise clear and definite restriction.For those of ordinary skill in the art For, above-mentioned term concrete meaning in the present invention can be understood as the case may be.
In the present invention, unless otherwise clearly defined and limited, fisrt feature second feature " on " or D score permissible It is that the first and second features directly contact, or the first and second features are by intermediary mediate contact.And, fisrt feature exists Second feature " on ", " top " and " above " but fisrt feature directly over second feature or oblique upper, or be merely representative of Fisrt feature level height is higher than second feature.Fisrt feature second feature " under ", " lower section " and " below " can be One feature is immediately below second feature or obliquely downward, or is merely representative of fisrt feature level height less than second feature.
In one aspect of the invention, the present invention proposes a kind of system processing house refuse.Reality according to the present invention Executing example, with reference to Fig. 1, this system includes: pretreatment unit 100, heat accumulation type radiant tube revolving bed 200 and cement kiln are collaborative processes list Unit 300.
According to embodiments of the invention, pretreatment unit 100 have house refuse entrance 101, foul smell outlet 102, organic Garbage outlet 103, inorganic refuse outlet 104 and the first outlet of sewer 105, and be suitable to house refuse is carried out pretreatment, thus Foul smell, organic waste, inorganic refuse and the first sewage can be obtained.Concrete, after house refuse is weighed by weighbridge office, through unloading Material platform is poured refuse pit into and is carried out heap filter, obtains foul smell (being mainly composed of methane) and contaminant water, then will by garbage grab bucket Rubbish after heap filter is sent in apron feeder, and uniform and stable for material is transported to belt with uniform distribution machine by apron feeder On machine, rubbish is transported to manual sorting room by belt feeder, is sorted by the chaff interference such as inorganic refuse such as glass, brick and tile, branch, nettle Out, then sieving through rotary screen, the organic waste obtained supplies after roll crushing crusher machine to subsequent process again and carries out Process.
According to embodiments of the invention, heat accumulation type radiant tube revolving bed 200 has the first combustible gas entrance 201, combustion-supporting sky Gas entrance 202, organic waste entrance 203, pyrolysis oil gas vent 204 and pyrolytic carbon outlet 205, combustion air inlet 202 is with smelly Gas outlet 102 is connected, and organic waste entrance 203 is connected with organic waste outlet 103, and is suitable to supply to heat accumulating type spoke foul smell Penetrate pipe revolving bed to use as the combustion air of heat accumulation type radiant tube, and fire in heat accumulation type radiant tube together with the first combustible gas Burn for providing heat in revolving bed, organic waste supply is carried out pyrolysis processing, such that it is able to obtain pyrolysis oil to revolving bed Gas and pyrolytic carbon.Concrete, the organic waste from rubbish pretreatment unit is pyrolyzed at revolving bed under conditions of isolation air Being heated to about 600~900 DEG C in stove, its contained Organic substance and the volatile matter overwhelming majority separate out, and obtain pyrolysis oil after pyrolysis Gas and two kinds of products of pyrolytic carbon.Ringwise, furnace bottom can rotate the burner hearth of the heat accumulation type radiant tube revolving bed that pyrolysis uses continuously, warp The organic waste obtained after crossing pretreatment, is loaded in heat accumulation type radiant tube revolving bed by feeding device, is laid in furnace bottom equably On, layer thickness about 40~800mm, furnace bottom machine drives furnace bottom to rotate continuously, and the bed of material being layered on furnace bottom rotates with furnace bottom, depends on The secondary preheating section through stove, a conversion zone, two conversion zones and three conversion zones, be finally heated to about 600~900 DEG C and complete Become pyrolytic reaction, outside the pyrolytic carbon after pyrolysis is unloaded come out of the stove by pyrolytic carbon outlet, and immediately enter cooling chamber cooling, pyrolysis oil gas from Multiple pyrolysis oil gas vents of burner hearth are discharged.Inventor finds, by the organic waste that will obtain after house refuse pretreatment and Foul smell supply carries out pyrolysis processing to heat accumulation type radiant tube revolving bed, can obtain being pyrolyzed oil gas and pyrolytic carbon, thus can With the wasting of resources avoiding garbage loading embeading or burning to cause, and can effectively solve to burn away the refuse brought by pyrolysis processing Two English pollute problem.
According to embodiments of the invention, cement kiln synergetic unit 300 have feed(raw material)inlet 301, fuel inlet 302, Waste gas outlet 303 and cement exit 304, fuel inlet 302 is connected with pyrolytic carbon 205 outlet, and is suitable to heat accumulation type radiant tube The pyrolytic carbon that revolving bed obtains makes cement slurry carry out collaborative process as the fuel of cement kiln synergetic unit, thus can To obtain waste gas and cement.Inventor finds, is supplied to cement kiln by the pyrolytic carbon obtained by heat accumulation type radiant tube revolving bed Synergetic unit uses as fuel so that limestone, clay matter etc. as between cement slurry occur synergism, from And garbage disposal and cement kiln synergetic unit can be combined, relative to existing cement kiln synergic processing side Method, in this application, once cement kiln production line stops production, and house refuse can also be pyrolyzed in advance, will not bank up smelly, produces rubbish The problem that rubbish can be put nowhere, and then realize the innoxious of organic waste and recycling treatment.
Concrete, with reference to Fig. 2, cement kiln synergetic unit 300 includes raw material grinding mill 31, homogenizing storehouse 32, preheater 33, divides Solve stove 34, rotary kiln 35, clinker warehouse 36 and fine coal deployment device 37 etc., according to a particular embodiment of the invention, with reference to Fig. 2, can So that at least one in pyrolytic carbon supply to preheater 33, dore furnace 34, rotary kiln 35 is used as fuel, cement slurry warp Raw material grinding mill 31 carries out pulverizing and dried, supplies successively to homogenizing storehouse 32, preheater 33, dore furnace 34, rotary kiln 35, clinker warehouse 36 and fine coal deployment device 37 process, obtain waste gas and cement products.Can increase at raw material grinding mill for controlling material composition fluctuation Add in-line analyzer, such that it is able to save the input of cement raw material.
The system of process house refuse according to embodiments of the present invention is by organic by obtain after house refuse pretreatment Rubbish and foul smell supply carry out pyrolysis processing to heat accumulation type radiant tube revolving bed, can obtain being pyrolyzed oil gas and pyrolytic carbon, Such that it is able to avoid the wasting of resources that garbage loading embeading or burning cause, and can effectively solve to burn away the refuse by pyrolysis processing The problem that two English brought pollute, makes the supply of gained pyrolytic carbon as fuel to cement kiln synergetic unit simultaneously With, such that it is able to garbage disposal is combined with cement kiln synergetic unit, work in coordination with relative to existing cement kiln Method of disposal, in this application, once cement kiln production line stops production, and house refuse can also be pyrolyzed in advance, will not bank up smelly, Produce the problem that rubbish can be put nowhere, thus realize the innoxious of house refuse and recycling treatment.
With reference to Fig. 3, according to embodiments of the invention, the system of described process house refuse farther includes: Oil-gas Separation Purifier 400, combustible gas storage tank 500 and sewage-treatment plant 600.
According to embodiments of the invention, Oil-gas Separation purifier 400 has pyrolysis oil gas entrance 401, pyrolysis gas outlet 402, pyrolysis oil outlet 403 and the second outlet of sewer 404, pyrolysis oil gas entrance 401 is connected with pyrolysis oil gas vent 204, and suitable In the pyrolysis oil gas that will obtain in heat accumulation type radiant tube revolving bed for carrying out isolation of purified process, such that it is able to isolated pyrolysis Air and heat solution oil and the second sewage.Concrete, from the pyrolysis oil gas of heat accumulation type radiant tube revolving bed through wet dedusting tower, will After the dust carried in pyrolysis oil gas is removed, enter the transverse pipe initial cooler of two parallel operations, enter back into two parallel connections and grasp simultaneously The electrical tar precipitator made, completes to remove the tar work carried secretly in pyrolysis gas, then is delivered to by pyrolysis gas by coal gas Roots blower Dry desulfurization operation, the gas-liquid separator separates pyrolysis oil got off and circulation pyrolysis water enter mechanization oil-water separation tank, This is circulated pyrolysis water, pyrolysis oil separating, i.e. isolated pyrolysis oil and sewage.It should be noted that art technology Actual conditions during this can be selected by personnel according to actual needs.
According to embodiments of the invention, combustible gas storage tank 500 has the second combustible gas entrance 501 and the outlet of the second combustible gas 502, the second combustible gas entrance 501 is connected with pyrolysis gas outlet 402, the second combustible gas outlet 502 and the first combustible gas entrance 201 It is connected, and is suitable to store the combustible gas of Oil-gas Separation purifier isolated, and the supply of this combustible gas is radiated to heat accumulating type Pipe revolving bed uses as the fuel of radial canal.Thus, it is possible to significantly reduce processing cost.
According to embodiments of the invention, sewage-treatment plant 600 has sewage inlet 601 and treatment fluid outlet 602, sewage Entrance 601 is connected with the first outlet of sewer 105 and the second outlet of sewer 404 respectively, and is suitable to obtained by pretreatment unit The second sewage that one sewage and Oil-gas Separation purifier obtain carries out purified treatment, such that it is able to obtain treatment fluid.Need Bright, the actual conditions employed in this process can be selected by those skilled in the art according to actual needs.
With reference to Fig. 4, according to embodiments of the invention, inorganic refuse outlet 104 is connected with feed(raw material)inlet 301, and be suitable to by The inorganic refuse containing glass, brick and tile and branch etc. of pretreatment unit isolated supplies to cement kiln synergetic unit Substitute For Partial clayey raw material uses, such that it is able to significantly reduce manufacture of cement cost.Concrete, on the one hand inorganic refuse can replace For part clay raw material, saving cement raw material and put into, on the other hand the poisonous and harmful substance in inorganic refuse is solid through cement Change effect achieves harmless treatment, and wherein, inorganic refuse is of low quality in the 15% of cement entirety raw material.
With reference to Fig. 5, the system of process house refuse according to embodiments of the present invention farther includes: TRT 700.
According to embodiments of the invention, TRT 700 has exhaust gas entrance 701 and boiler residual air outlet 702, and waste gas enters Mouth 701 is connected with waste gas outlet 303, and boiler residual air outlet 702 is connected with the raw material grinding mill 31 in cement kiln synergetic unit, and The kiln tail gas supply being suitable to obtain quality coal in cement kiln systems processing unit carries out waste heat recovery to TRT, and by obtained Boiler residual air use as dry medium to the raw material grinding mill on quality coal in cement kiln systems processing unit as thermal source supply.Thus, may be used To significantly reduce system energy consumption.
As it has been described above, the system of process house refuse according to embodiments of the present invention can have selected from following advantage at least One of:
The system of process house refuse according to embodiments of the present invention uses heat accumulation type radiant tube revolving bed to house refuse It is pyrolyzed, it is to avoid burn the problem that two English brought pollute;
The system of process house refuse according to embodiments of the present invention is by being combined refuse pyrolysis with cement kiln production line Get up, take full advantage of the oil of refuse pyrolysis generation, gas, charcoal, the product after refuse pyrolysis is directly utilized, need not sell outward, save Remove sales section;
Product after the refuse pyrolysis of the system of process house refuse according to embodiments of the present invention can be by cement kiln Utilize, save the raw material required for cement kiln produces;
The system of process house refuse according to embodiments of the present invention combines with cement kiln skill relative to original rubbish Art, this technology does not interferes with the production line of cement kiln itself, does not interferes with the quality of its product, and once cement kiln stops production, House refuse can also process;
The system of process house refuse according to embodiments of the present invention improves the macroeconomic of refuse pyrolysis gasifying process Property, it is easy to industrialization promotion.
In another aspect of the invention, the present invention proposes a kind of method processing house refuse.According to the present invention's Embodiment, the method is that the system using above-mentioned process house refuse is carried out.According to a particular embodiment of the invention, with reference to figure 6, the method for described process house refuse includes:
S100: house refuse supply is carried out pretreatment to pretreatment unit
According to embodiments of the invention, house refuse supply is carried out pretreatment to pretreatment unit, such that it is able to To foul smell, organic waste, inorganic refuse and the first sewage.Concrete, after house refuse is weighed by weighbridge office, through discharging platform Pour refuse pit into and carry out heap filter, obtain foul smell (being mainly composed of methane) and contaminant water, after then being filtered by heap by garbage grab bucket Rubbish send in apron feeder, uniform and stable for material is transported on belt feeder by apron feeder with uniform distribution machine, Rubbish is transported to manual sorting room by belt feeder, is sorted out by the chaff interference such as inorganic refuse such as glass, brick and tile, branch, nettle, Sieving through rotary screen, the organic waste obtained supplies after roll crushing crusher machine to subsequent process again and processes again.
S200: organic waste and foul smell are supplied to heat accumulation type radiant tube revolving bed
According to embodiments of the invention, foul smell is supplied to heat accumulation type radiant tube revolving bed helping as heat accumulation type radiant tube Combustion air uses, and provides heat in burning for revolving bed in heat accumulation type radiant tube together with the first combustible gas, by organic rubbish Rubbish supply carries out pyrolysis processing to revolving bed, such that it is able to obtain being pyrolyzed oil gas and pyrolytic carbon.Concrete, locate in advance from rubbish The organic waste of reason device is heated to about 600~900 DEG C, contained by it under conditions of isolation air in revolving bed pyrolysis oven Organic substance and the volatile matter overwhelming majority separate out, obtain after pyrolysis being pyrolyzed oil gas and two kinds of products of pyrolytic carbon.The storage that pyrolysis uses Ringwise, furnace bottom can rotate the burner hearth of hot type radial canal revolving bed continuously, and the organic waste obtained after pretreatment, by feeding Device loads in heat accumulation type radiant tube revolving bed, is laid in equably on furnace bottom, layer thickness about 40~800mm, furnace bottom machine Drive furnace bottom rotate continuously, the bed of material being layered on furnace bottom with furnace bottom rotate, sequentially pass through the preheating section of stove, a conversion zone, two Conversion zone and three conversion zones, be finally heated to about 600~900 DEG C and complete pyrolytic reaction, and the pyrolytic carbon after pyrolysis is by warm Solution charcoal outlet is unloaded outside coming out of the stove, and immediately enters cooling chamber cooling, and pyrolysis oil gas is discharged from multiple pyrolysis oil gas vents of burner hearth.Send out A person of good sense finds, is supplied to heat accumulation type radiant tube revolving bed by the organic waste that will obtain after house refuse pretreatment and foul smell Carry out pyrolysis processing, can obtain being pyrolyzed oil gas and pyrolytic carbon, such that it is able to avoid the resource that garbage loading embeading or burning cause Waste, and can effectively be solved to burn away the refuse the problem that two brought English pollute by pyrolysis processing.
S300: make cement slurry carry out collaborative process as fuel pyrolytic carbon supply to cement kiln synergetic unit
According to embodiments of the invention, the pyrolytic carbon obtained by heat accumulation type radiant tube revolving bed processes as cement kiln is collaborative The fuel of unit makes cement slurry carry out collaborative process, such that it is able to obtain waste gas and cement.Inventor finds, by storing The pyrolytic carbon supply that hot type radial canal revolving bed obtains uses as fuel to cement kiln synergetic unit so that Calx Stone, clay matter etc. are as synergism occurs between cement slurry, such that it is able to process list by collaborative to garbage disposal and cement kiln Unit combines, and relative to existing cement kiln synergic processing method, in this application, once cement kiln production line stops Producing, house refuse can also be pyrolyzed in advance, will not bank up smelly, produces the problem that rubbish can be put nowhere, and then realizes organic rubbish Innoxious and the recycling treatment of rubbish.According to a particular embodiment of the invention, list is processed by collaborative for pyrolytic carbon supply to cement kiln At least one in preheater, dore furnace and rotary kiln in unit uses as fuel.
The method of process house refuse according to embodiments of the present invention is by organic by obtain after house refuse pretreatment Rubbish and foul smell supply carry out pyrolysis processing to heat accumulation type radiant tube revolving bed, can obtain being pyrolyzed oil gas and pyrolytic carbon, Such that it is able to avoid the wasting of resources that garbage loading embeading or burning cause, and can effectively solve to burn away the refuse by pyrolysis processing The problem that two English brought pollute, makes the supply of gained pyrolytic carbon as fuel to cement kiln synergetic unit simultaneously With, such that it is able to garbage disposal is combined with cement kiln synergetic unit, work in coordination with relative to existing cement kiln Method of disposal, in this application, once cement kiln production line stops production, and house refuse can also be pyrolyzed in advance, will not bank up smelly, Produce the problem that rubbish can be put nowhere, thus realize the innoxious of house refuse and recycling treatment.
With reference to Fig. 7, according to embodiments of the invention, the method for described process house refuse farther includes:
S400: the supply of pyrolysis oil gas is carried out isolation of purified process to Oil-gas Separation purifier, and by gained pyrolysis gas Supply to heat accumulation type radiant tube revolving bed uses as combustion gas
According to embodiments of the invention, by the pyrolysis oil gas obtained in heat accumulation type radiant tube revolving bed for carrying out isolation of purified Process, such that it is able to isolated pyrolysis gas, pyrolysis oil and the second sewage, and gained pyrolysis gas is supplied to heat accumulation type radiant tube Revolving bed uses as combustion gas.Concrete, from the pyrolysis oil gas of heat accumulation type radiant tube revolving bed through wet dedusting tower, by heat After the dust carried in solution oil gas is removed, enter the transverse pipe initial coolers of two parallel operations, enter back into two parallel connections and operate simultaneously Electrical tar precipitator, complete to remove the tar work carried secretly in pyrolysis gas, then delivered to do by pyrolysis gas by coal gas Roots blower Method desulfurization process, the gas-liquid separator separates pyrolysis oil got off and circulation pyrolysis water enter mechanization oil-water separation tank, at this It is circulated pyrolysis water, pyrolysis oil separating, i.e. isolated pyrolysis oil and sewage.It should be noted that people in the art Actual conditions during this can be selected by member according to actual needs.
The second sewage that S500: the first sewage obtained by S100 and S400 obtain supplies to sewage-treatment plant
According to embodiments of the invention, the first sewage obtained by pretreatment unit and Oil-gas Separation purifier obtain Second sewage carries out purified treatment, such that it is able to obtain treatment fluid.It should be noted that those skilled in the art can be according to reality Border needs to select the actual conditions employed in this process.
With reference to Fig. 8, according to embodiments of the invention, the method for described process house refuse farther includes:
S600: carry out collaborative process in the inorganic refuse supply obtained by S100 to cement kiln synergetic unit
According to embodiments of the invention, by inorganic containing glass, brick and tile and branch etc. of pretreatment unit isolated Rubbish supply uses, such that it is able to significantly reduce manufacture of cement to Substitute For Partial clayey raw material in cement kiln synergetic unit Cost.Concrete, inorganic refuse on the one hand alternative part clay raw material, save cement raw material and put into, the most inorganic Poisonous and harmful substance in rubbish achieves harmless treatment through cement solidification effect, wherein, inorganic refuse of low quality in The 15% of cement entirety raw material.
With reference to Fig. 9, according to embodiments of the invention, the method for described process house refuse farther includes:
S700: waste gas supply to the TRT obtained by S300 carries out UTILIZATION OF VESIDUAL HEAT IN, and supplies boiler residual air to water Raw material grinding mill in stall synergetic unit
According to embodiments of the invention, waste gas step S300 obtained supply carries out UTILIZATION OF VESIDUAL HEAT IN to TRT, from And boiler residual air can be obtained, and using the raw material grinding mill in boiler residual air supply to cement kiln synergetic unit as dry medium Use.Thus, it is possible to significantly reduce energy consumption.
Below with reference to specific embodiment, present invention is described, it should be noted that these embodiments are only to describe Property, and limit the present invention never in any form.
Embodiment
Certain city's house refuse is processed by the system using the process house refuse shown in Figure 10, and house refuse becomes packet Become as shown in table 1:
Table 1 house refuse becomes to be grouped into (wt%)
A, pretreatment unit carry out pretreatment: after house refuse is weighed by weighbridge office, pour rubbish into through discharging platform Storage hole carries out heap filter, obtains foul smell (being mainly composed of methane) and contaminant water, and the rubbish after then being filtered by heap by garbage grab bucket send Entering in apron feeder, uniform and stable for material is transported on belt feeder by apron feeder with uniform distribution machine, and belt feeder will Rubbish is transported to manual sorting room, is sorted out by the chaff interference such as inorganic refuse such as glass, brick and tile, branch, nettle, then through cylinder Sieving, the organic waste obtained supplies to heat accumulation type radiant tube revolving bed after roll crushing crusher machine again;
B, heat accumulation type radiant tube revolving bed are pyrolyzed: foul smell and organic waste from rubbish pretreatment unit supply to accumulation of heat Formula radial canal revolving bed is heated to about 800 DEG C under conditions of isolation air in revolving bed pyrolysis oven, its contained having Machine thing and the volatile matter overwhelming majority separate out, and obtain being pyrolyzed oil gas and two kinds of products of pyrolytic carbon after pyrolysis.The heat accumulating type that pyrolysis uses Ringwise, furnace bottom can rotate the burner hearth of radial canal revolving bed continuously, and the organic waste obtained after pretreatment, by feeding device Loading in heat accumulation type radiant tube revolving bed, be laid in equably on furnace bottom, layer thickness about 700mm, furnace bottom machine drives furnace bottom Rotating continuously, the bed of material being layered on furnace bottom rotates with furnace bottom, sequentially pass through the preheating section of stove, a conversion zone, two conversion zones and Three conversion zones, are finally heated to about 800 DEG C and complete pyrolytic reaction, and the pyrolytic carbon after pyrolysis is unloaded by pyrolytic carbon outlet and comes out of the stove Outward, and immediately entering cooling chamber cooling, pyrolysis oil gas is discharged from multiple pyrolysis oil gas vents of burner hearth.
C, cement kiln synergetic unit carry out collaborative process: the pyrolytic carbon obtained by heat accumulation type radiant tube revolving bed supplies Preheater, dore furnace and rotary kiln to cement kiln synergetic unit use as fuel, fill from house refuse pretreatment Inorganic matter warehouse in the cement plant that the inorganic refuse put send, delivers on the feed belt of raw material grinding mill after grab bucket feeding, metering, After dispensing, enter raw material grinding mill with raw material carry out pulverizing and be dried, can increase in raw material grinding mill system for controlling material composition fluctuation Line analysis instrument.Inorganic refuse on the one hand alternative part clay raw material, saves cement raw material and puts into, on the other hand inorganic refuse In poisonous and harmful substance achieve harmless treatment through cement solidification effect, and inorganic refuse gross mass is not higher than cement The 5% of overall proportion scale, kiln tail gas supply cement kiln synergetic unit obtained carries out waste heat to TRT and returns Receive, and the raw material grinding mill that obtained boiler residual air supply is worked in coordination with in processing means to cement kiln is used as dry medium.
D, Oil-gas Separation purifier carry out being pyrolyzed oil gas purification separation: from the pyrolysis oil of heat accumulation type radiant tube revolving bed Gas is through wet dedusting tower, after being removed by the dust carried, enters the transverse pipe initial cooler of two parallel operations in pyrolysis oil gas, then Enter the electrical tar precipitator that two parallel connections operate simultaneously, complete to remove the tar work carried secretly in pyrolysis gas, then by coal gas Roots Pyrolysis gas is delivered to dry desulfurization operation, the gas-liquid separator separates pyrolysis oil got off and circulation pyrolysis water and is entered machine by aerator Tool oil-water separation tank, is circulated pyrolysis water, pyrolysis oil separating, i.e. isolated pyrolysis oil and sewage, and will divide at this It is stored in combustible gas storage tank from the pyrolysis gas obtained, and supplies to heat accumulation type radiant tube revolving bed as spoke through combustible gas storage tank Penetrate pipe combustion gas to use, gained sewage supply in Oil-gas Separation purifier gained sewage and pretreatment unit is filled to sewage disposal Put and process.
Composition and the calorific value of pyrolytic carbon are as shown in table 2:
Table 2 pyrolytic carbon composition and calorific value
In the description of this specification, reference term " embodiment ", " some embodiments ", " example ", " specifically show Example " or the description of " some examples " etc. means to combine this embodiment or example describes specific features, structure, material or spy Point is contained at least one embodiment or the example of the present invention.In this manual, to the schematic representation of above-mentioned term not Identical embodiment or example must be directed to.And, the specific features of description, structure, material or feature can be in office One or more embodiments or example combine in an appropriate manner.Additionally, in the case of the most conflicting, the skill of this area The feature of the different embodiments described in this specification or example and different embodiment or example can be tied by art personnel Close and combination.
Although above it has been shown and described that embodiments of the invention, it is to be understood that above-described embodiment is example Property, it is impossible to being interpreted as limitation of the present invention, those of ordinary skill in the art within the scope of the invention can be to above-mentioned Embodiment is changed, revises, replaces and modification.

Claims (10)

1. the system processing house refuse, it is characterised in that including:
Pretreatment unit, described pretreatment unit has house refuse entrance, foul smell outlet, organic waste outlet, inorganic refuse Outlet and the first outlet of sewer;
Heat accumulation type radiant tube revolving bed, described heat accumulation type radiant tube revolving bed have the first combustible gas entrance, combustion air inlet, Organic waste entrance, pyrolysis oil gas vent and pyrolytic carbon outlet, described combustion air inlet is connected with the outlet of described foul smell, described Organic waste entrance is connected with the outlet of described organic waste;
Cement kiln synergetic unit, described cement kiln synergetic unit have feed(raw material)inlet, fuel inlet, waste gas outlet and Cement exit, described fuel inlet is connected with the outlet of described pyrolytic carbon.
System the most according to claim 1, it is characterised in that farther include:
Oil-gas Separation purifier, described Oil-gas Separation purifier has pyrolysis oil gas entrance, pyrolysis gas outlet, pyrolysis oil go out Mouth and the second outlet of sewer, described pyrolysis oil gas entrance is connected with described pyrolysis oil gas vent;
Combustible gas storage tank, described combustible gas storage tank has the second combustible gas entrance and the outlet of the second combustible gas, described second flammable Gas entrance is connected with described pyrolysis gas outlet, and described second combustible gas outlet is connected with described first combustible gas entrance;
Sewage-treatment plant, described sewage-treatment plant have sewage inlet and treatment fluid outlet, described sewage inlet respectively with Described first outlet of sewer is connected with described second outlet of sewer.
System the most according to claim 1 and 2, it is characterised in that the outlet of described inorganic refuse and described feed(raw material)inlet phase Even.
4. according to the system described in any one of claim 1-3, it is characterised in that the outlet of described pyrolytic carbon is assisted with described cement kiln It is connected with the fuel inlet at least one in rotary kiln with the preheater on processing unit, dore furnace.
5. according to the system described in any one of claim 1-4, it is characterised in that farther include:
TRT, described TRT has exhaust gas entrance and the outlet of boiler residual air, and described exhaust gas entrance goes out with described waste gas Mouth is connected, and the outlet of described boiler residual air is connected with the raw material grinding mill in described cement kiln synergetic unit.
6. use the method that the system of the process house refuse according to any one of Claims 1 to 5 processes house refuse, It is characterized in that, including:
(1) will house refuse supply to described pretreatment unit carries out pretreatment, in order to obtain foul smell, organic waste, inorganic Rubbish and the first sewage;
(2) described organic waste and described foul smell are supplied to described heat accumulation type radiant tube revolving bed, in order to described organic rubbish Rubbish carries out pyrolysis processing, obtains being pyrolyzed oil gas and pyrolytic carbon;
(3) cement slurry is made to carry out collaborative place as fuel described pyrolytic carbon supply to described cement kiln synergetic unit Reason, in order to obtain waste gas and cement.
Method the most according to claim 6, it is characterised in that farther include:
(4) supply of described pyrolysis oil gas is carried out isolation of purified process to described Oil-gas Separation purifier, in order to be pyrolyzed Air and heat solution oil and the second sewage, and the supply of described pyrolysis gas is used to described heat accumulation type radiant tube revolving bed as combustion gas;
(5) the described second sewage supply that described first sewage step (1) obtained and step (4) obtain fills to sewage disposal Put, in order to obtain treatment fluid.
8. according to the method described in claim 6 or 7, it is characterised in that farther include:
(6) described inorganic refuse supply step (1) obtained carries out described working in coordination with to described cement kiln synergetic unit Process.
9. according to the method according to any one of claim 6-8, it is characterised in that the described pyrolytic carbon that step (2) is obtained At least one in preheater, dore furnace and rotary kiln in supply extremely described cement kiln synergetic unit makes as fuel With.
10. according to the method according to any one of claim 6-9, it is characterised in that farther include:
(7) described waste gas supply step (3) obtained carries out UTILIZATION OF VESIDUAL HEAT IN to described TRT, in order to obtain boiler residual Gas, and the supply of described boiler residual air is used to the raw material grinding mill in described cement kiln synergetic unit as dry medium.
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