CN106076650B - A kind of quartz mineral purifying and flotation agent - Google Patents
A kind of quartz mineral purifying and flotation agent Download PDFInfo
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- CN106076650B CN106076650B CN201610419797.8A CN201610419797A CN106076650B CN 106076650 B CN106076650 B CN 106076650B CN 201610419797 A CN201610419797 A CN 201610419797A CN 106076650 B CN106076650 B CN 106076650B
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- flotation agent
- quartz sand
- quartz
- per ton
- purifying
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/012—Organic compounds containing sulfur
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2203/00—Specified materials treated by the flotation agents; specified applications
- B03D2203/02—Ores
- B03D2203/04—Non-sulfide ores
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- Separation Of Suspended Particles By Flocculating Agents (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
The present invention relates to a kind of quartz mineral purifying and flotation agent, the following component by number percentage is contained in composition：Compound amine 20%~30%, petroleum sodium sulfonate 30%~40%, hydroximic acid 5%~10% and industrial alcohol 30%~40%；The flotation agent dosage quartz sand per ton is 0.5kg~1.5kg.Advantages of the present invention：The pharmaceutical mixture property is stablized, selectivity is good, impurity-eliminating effect is substantially better than similar product, good water solubility, environmental adaptability are strong, it can mix and dissolve each other with water arbitrary proportion at ambient temperature, the adaptability of medicament is wider, there is good removal of impurities refining effect, purification efficiency is high, dosage is small, quartz sand purifying flotation agent dosage per ton substantially reduces beneficiation cost, has no irritating odor between 0.5kg~1.5kg, the working environment quality of production operation personnel is obviously improved, the dosing is small.
Description
Technical field
The present invention relates to nonmetallic ores to purify processing technique field, more particularly to a kind of quartz mineral purifying and flotation agent.
Background technology
With the low-carbon environment-friendly economy development requirement of country, using solar energy as the development of clean energy of representative and using
As the current focus of work, the basic material quartz sand utilized as solar energy development is forced increasingly by the weight of people
Depending on.Quartz sand is a kind of quartz particles that processing is crushed by quartz, is a kind of hard, wear-resisting, stable chemical performance
Nonmetallic silicate mineral, main mineral constituent are SiO2, the color of quartz sand is milky or semi-transparent clear shape, not
Family name's hardness is 7, and quartz sand is important industrial mineral raw material, and non-chemical dangerous material are widely used in glass, casting, ceramics and prevent
The fields such as fiery material, smelting duriron, flux for metallurgy, metallurgy, building, chemical industry, plastics, rubber, abrasive material, filtrate.
Natural siliceous sand substantially all containing other impure minerals, these impure minerals generally refer to tourmaline, uhligite,
Feldspar, mica, pyrite, bloodstone, limonite, shale, hornblend, landwaste and pyroxene etc., these contain harmful metal elements
Impure mineral exist directly affect quartz sand industry quality and use value.When most directly performance is production glass, it is harmful to
The light transmittance of the exceeded thermodynamic stability and finished glass that can significantly reduce glass of metal element content, therefore for stone
The purification of sand is just particularly important.Quartz sand purifying generally comprises ore grinding, scouring, gravity treatment, magnetic separation, flotation and chemical treatment
Etc. techniques, usual shale impurity removed by cleaning technique, heavy mineral detached through gravity treatment, and magnetic mineral is then given by magnetic separation
Removal, for feldspar, landwaste, pyrite and pyroxene isodensity are close with quartz, magnetic very weak impure mineral then needs to float simultaneously
Choosing removal, therefore be badly in need of wanting a kind of efficient quartz sand purifying floating agent for using at this stage, by retrieving extensively, not yet
It was found that ideal technical solution.
Invention content
The purpose of the present invention is to solve lack a kind of efficient quartz sand purifying floating agent at this stage to use
The shortcomings that, and a kind of quartz mineral purifying and flotation agent proposed.
To achieve these goals, present invention employs following technical solutions：
A kind of quartz mineral purifying and flotation agent, which is characterized in that it contains the following group by number percentage in forming
Part：Compound amine 20%~30%, petroleum sodium sulfonate 30%~40%, hydroximic acid 5%~10% and industrial alcohol 30%~40%；
The flotation agent dosage quartz sand per ton is 0.5kg~1.5kg.
Based on the above technical solution, there can be technical solution further below：
It contains the following component by number percentage in forming：Compound amine 25%, petroleum sodium sulfonate 30%, hydroximic acid 5%
With industrial alcohol 40%, the flotation agent dosage quartz sand per ton is 1kg, 0.8kg, 1.5kg or 1.2kg.
It contains the following component by number percentage in forming：Compound amine 20%, petroleum sodium sulfonate 35%, hydroximic acid 8%
With industrial alcohol 37%, the flotation agent dosage quartz sand per ton is 1kg, 0.8kg, 1.5kg or 1.2kg.
It contains the following component by number percentage in forming：Compound amine 22%, petroleum sodium sulfonate 38%, hydroximic acid
10% and industrial alcohol 30%, the flotation agent dosage quartz sand per ton is 1kg, 0.8kg, 1.5kg or 1.2kg.
The advantage of the invention is that：The medicament is made of organic matters such as compounding amine, petroleum sodium sulfonate, hydroximic acid and alcohol
Mixture, the mixture property are stablized, and selectivity is good, and impurity-eliminating effect is substantially better than similar product, good water solubility, environment temperature
It is adaptable, can mix and dissolve each other with water arbitrary proportion at ambient temperature, the adaptability of medicament is wider, for quartzitic ore deposit,
Quartzy sandstone class ore deposit, sea sand class ore deposit, river sand class ore deposit and vein quartz class ore deposit etc. have good removal of impurities refining effect, purification efficiency
Height, dosage are small, and quartz sand purifying flotation agent dosage per ton substantially reduces beneficiation cost between 0.5kg~1.5kg, stingless
Swash property smell, the working environment quality of production operation personnel is obviously improved, the dosing is small.
Specific embodiment
Embodiment one, a kind of quartz mineral purifying and flotation agent provided by the invention contain following by number in forming
The component of percentage：Compounding amine 20%~30%, petroleum sodium sulfonate 30%~40%, hydroximic acid 5%~10% and industrial alcohol 30%~
40%, the flotation agent dosage quartz sand per ton is 0.5kg~1.5kg.
Embodiment two, flotation agent in embodiment one composition in contain the following component by number percentage：Compounding
Amine 25%, petroleum sodium sulfonate 30%, hydroximic acid 5% and industrial alcohol 40% when the flotation agent dosage quartz sand per ton is 1kg, obtain
To washed ore yield 84%, dioxide-containing silica 99.8%, ferric oxide content 0.0068%.
When the flotation agent dosage quartz sand per ton is 0.8kg, washed ore yield 89% is obtained, 99.0 % of dioxide-containing silica,
Ferric oxide content 0.0082%.
When the flotation agent dosage quartz sand per ton is 1.5kg, washed ore yield 92.7%, dioxide-containing silica 99.0 are obtained
%, ferric oxide content 0.015%.
When the flotation agent dosage quartz sand per ton is 1.2kg, washed ore yield 54.3%, dioxide-containing silica 99.2 are obtained
%, ferric oxide content 0.013%.
Embodiment three, flotation agent in embodiment one composition in contain the following component by number percentage：Compounding
Amine 20%, petroleum sodium sulfonate 35%, hydroximic acid 8% and industrial alcohol 37%, the flotation agent dosage quartz sand per ton for 1kg,
0.8kg, 1.5kg or 1.2kg.
Example IV, flotation agent in embodiment one composition in contain the following component by number percentage：Its group
The following component by number percentage is contained in：Compound amine 22%, petroleum sodium sulfonate 38%, hydroximic acid 10% and industrial alcohol
30%, the flotation agent dosage quartz sand per ton is 1kg, 0.8kg, 1.5kg or 1.2kg.
Above example is only that the preferred embodiment of the present invention is described, and the scope of the present invention is not defined,
Without departing from the principle of the present invention, the change of form of ownership should fall into claims of the present invention protection domain
It is interior.
Claims (3)
1. a kind of quartz mineral purifying and flotation agent, which is characterized in that it contains the following component by number percentage in forming：
Compound amine 25%, petroleum sodium sulfonate 30%, hydroximic acid 5% and industrial alcohol 40%, the flotation agent dosage quartz sand per ton is 1kg,
0.8kg, 1.5kg or 1.2kg.
2. a kind of quartz mineral purifying and flotation agent, which is characterized in that it contains the following component by number percentage in forming：
Compound amine 20%, petroleum sodium sulfonate 35%, hydroximic acid 8% and industrial alcohol 37%, the flotation agent dosage quartz sand per ton is 1kg,
0.8kg, 1.5kg or 1.2kg.
3. a kind of quartz mineral purifying and flotation agent, which is characterized in that it contains the following component by number percentage in forming：
Compound amine 22%, petroleum sodium sulfonate 38%, hydroximic acid 10% and industrial alcohol 30%, the flotation agent dosage quartz sand per ton is 1kg,
0.8kg, 1.5kg or 1.2kg.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610419797.8A CN106076650B (en) | 2016-06-14 | 2016-06-14 | A kind of quartz mineral purifying and flotation agent |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610419797.8A CN106076650B (en) | 2016-06-14 | 2016-06-14 | A kind of quartz mineral purifying and flotation agent |
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| Publication Number | Publication Date |
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| CN106076650A CN106076650A (en) | 2016-11-09 |
| CN106076650B true CN106076650B (en) | 2018-07-10 |
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Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108176518A (en) * | 2017-12-29 | 2018-06-19 | 中建材蚌埠玻璃工业设计研究院有限公司 | A kind of preparation method of neutral flotation agent for quartz mineral purification |
| CN110976103A (en) * | 2019-12-25 | 2020-04-10 | 中建材蚌埠玻璃工业设计研究院有限公司 | Flotation combination method for purifying iron oxide dip-dyed quartz |
| CN113441283B (en) * | 2021-07-14 | 2022-10-11 | 中国科学院合肥物质科学研究院 | Method for direct flotation of quartz from quartz and feldspar mixed ore under neutral pH condition |
| CN113926590B (en) * | 2021-11-01 | 2024-05-24 | 武汉理工大学 | Flotation reagent and flotation method for separating feldspar from quartz |
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| CN1322592A (en) * | 2001-06-06 | 2001-11-21 | 山东蓝星玻璃(集团)有限公司 | Floating method and floating agent for floating feldspar and quartz from silica sand |
| CN1586728A (en) * | 2004-09-16 | 2005-03-02 | 中国凯盛国际工程有限公司 | Flotation process for quartz tail sand and its special floatation collecting agent |
| CN101628258A (en) * | 2009-08-18 | 2010-01-20 | 广宝来特种石英（凤阳）科技有限公司 | Floatation process of quartz sand |
| CN102600982A (en) * | 2012-03-26 | 2012-07-25 | 武汉理工大学 | Fluoride-free low-acid zwitterion quartz sand reverse flotation process |
| CN102824961A (en) * | 2012-07-07 | 2012-12-19 | 蚌埠玻璃工业设计研究院 | Beneficiation method for producing quartz and feldspar by using river and lake sands |
| CN105057088A (en) * | 2015-08-10 | 2015-11-18 | 山东华晟投资有限公司 | Method for recycling quartz and feldspar mixtures from gold flotation tailings |
| CN105327785A (en) * | 2015-11-16 | 2016-02-17 | 合肥万泉非金属矿科技有限公司 | Flotation technology of PPM level low-iron high-purity quartz sand |
-
2016
- 2016-06-14 CN CN201610419797.8A patent/CN106076650B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1322592A (en) * | 2001-06-06 | 2001-11-21 | 山东蓝星玻璃(集团)有限公司 | Floating method and floating agent for floating feldspar and quartz from silica sand |
| CN1586728A (en) * | 2004-09-16 | 2005-03-02 | 中国凯盛国际工程有限公司 | Flotation process for quartz tail sand and its special floatation collecting agent |
| CN101628258A (en) * | 2009-08-18 | 2010-01-20 | 广宝来特种石英（凤阳）科技有限公司 | Floatation process of quartz sand |
| CN102600982A (en) * | 2012-03-26 | 2012-07-25 | 武汉理工大学 | Fluoride-free low-acid zwitterion quartz sand reverse flotation process |
| CN102824961A (en) * | 2012-07-07 | 2012-12-19 | 蚌埠玻璃工业设计研究院 | Beneficiation method for producing quartz and feldspar by using river and lake sands |
| CN105057088A (en) * | 2015-08-10 | 2015-11-18 | 山东华晟投资有限公司 | Method for recycling quartz and feldspar mixtures from gold flotation tailings |
| CN105327785A (en) * | 2015-11-16 | 2016-02-17 | 合肥万泉非金属矿科技有限公司 | Flotation technology of PPM level low-iron high-purity quartz sand |
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| CN106076650A (en) | 2016-11-09 |
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