CN106070354A - abamectin insecticide and preparation method thereof - Google Patents

abamectin insecticide and preparation method thereof Download PDF

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Publication number
CN106070354A
CN106070354A CN201610403609.2A CN201610403609A CN106070354A CN 106070354 A CN106070354 A CN 106070354A CN 201610403609 A CN201610403609 A CN 201610403609A CN 106070354 A CN106070354 A CN 106070354A
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consumption
weight portion
insecticide
avilamycin
preparation
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CN201610403609.2A
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Chinese (zh)
Inventor
苏福男
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WUHU FOMAN BIOPHARMA Co Ltd
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WUHU FOMAN BIOPHARMA Co Ltd
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Priority to CN201610403609.2A priority Critical patent/CN106070354A/en
Publication of CN106070354A publication Critical patent/CN106070354A/en
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N29/00Biocides, pest repellants or attractants, or plant growth regulators containing halogenated hydrocarbons
    • A01N29/02Acyclic compounds or compounds containing halogen attached to an aliphatic side-chain of a cycloaliphatic ring system
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N35/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical
    • A01N35/06Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical containing keto or thioketo groups as part of a ring, e.g. cyclohexanone, quinone; Derivatives thereof, e.g. ketals
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N61/00Biocides, pest repellants or attractants, or plant growth regulators containing substances of unknown or undetermined composition, e.g. substances characterised only by the mode of action
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08Magnoliopsida [dicotyledons]
    • A01N65/24Lauraceae [Laurel family], e.g. laurel, avocado, sassafras, cinnamon or camphor
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/30Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • Agronomy & Crop Science (AREA)
  • Environmental Sciences (AREA)
  • Zoology (AREA)
  • Wood Science & Technology (AREA)
  • Plant Pathology (AREA)
  • Pest Control & Pesticides (AREA)
  • Mycology (AREA)
  • Microbiology (AREA)
  • Biotechnology (AREA)
  • Natural Medicines & Medicinal Plants (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a kind of abamectin insecticide and preparation method thereof, wherein, described preparation method includes: by avilamycin, Ketohexamethylene, dichloromethane, chrysanthemum ester, wide cassia oil, rotenone, microemulsion and water mix and blend, obtain described abamectin insecticide, although it is effective to solve general abamectin insecticide deinsectization, but containing some harmful substances in insecticide, the problem easily causing the secondary pollution of environment during parasite killing.

Description

Abamectin insecticide and preparation method thereof
Technical field
The present invention relates to field of pesticides, in particular it relates to abamectin insecticide and preparation method thereof.
Background technology
Avilamycin is a kind of common insecticide raw material, and it is widely used in sterilization agricultural or for animals, parasite killing, kills The preparation of demodicid mite agent, although general abamectin insecticide deinsectization is effective, but containing some harmful substances in insecticide, holds During parasite killing, easily cause the secondary pollution of environment.
Therefore it provides a kind of environmental protection, during parasite killing, environment will not be caused the abamectin pest killing of secondary pollution Agent and preparation method thereof is the problem that the present invention needs solution badly.
Summary of the invention
It is an object of the invention to provide a kind of abamectin insecticide and preparation method thereof, solve general avilamycin Although insecticide deinsectization is effective, but containing some harmful substances in insecticide, during parasite killing, easily cause environment The problem of secondary pollution.
To achieve these goals, the invention provides a kind of abamectin insecticide, wherein, described abamectin pest killing The raw material of agent includes: avilamycin, Ketohexamethylene, dichloromethane, chrysanthemum ester, wide cassia oil, rotenone, microemulsion and water;Wherein,
Relative to the water of 100 weight portions, the consumption of described avilamycin is 20-30 weight portion, the consumption of described Ketohexamethylene For 10-20, the consumption of described dichloromethane is 5-10 weight portion, and the consumption of described chrysanthemum ester is 2-8 weight portion, described wide cassia oil Consumption is 1-10 weight portion, and the consumption of described rotenone is 2-8 weight portion, and the consumption of described microemulsion is 0.5-3 weight portion.
Present invention also offers the preparation method of a kind of abamectin insecticide, wherein, described preparation method includes: by Ah Dimension rhzomorph, Ketohexamethylene, dichloromethane, chrysanthemum ester, wide cassia oil, rotenone, microemulsion and water mix and blend, obtain described avilamycin Insecticide;Wherein,
Relative to the water of 100 weight portions, the consumption of described avilamycin is 20-30 weight portion, the consumption of described Ketohexamethylene For 10-20, the consumption of described dichloromethane is 5-10 weight portion, and the consumption of described chrysanthemum ester is 2-8 weight portion, described wide cassia oil Consumption is 1-10 weight portion, and the consumption of described rotenone is 2-8 weight portion, and the consumption of described microemulsion is 0.5-3 weight portion.
According to technique scheme, the invention provides a kind of abamectin insecticide and preparation method thereof, wherein, described Preparation method includes: the mixing of avilamycin, Ketohexamethylene, dichloromethane, chrysanthemum ester, wide cassia oil, rotenone, microemulsion and water stirred Mix, obtain described abamectin insecticide, by the synergism between each raw material so that prepared abamectin insecticide tool Standby excellent sterilizing ability, abamectin insecticide all uses free of contamination plant extract, will not cause environment after using Secondary pollution, meanwhile, for preparing, the method for this insecticide is simple, raw material is easy to get.
Other features and advantages of the present invention will be described in detail in detailed description of the invention part subsequently.
Detailed description of the invention
Hereinafter the detailed description of the invention of the present invention is described in detail.It should be appreciated that described herein specifically Embodiment is merely to illustrate and explains the present invention, is not limited to the present invention.
The invention provides a kind of abamectin insecticide, wherein, the raw material of described abamectin insecticide includes: A Wei Rhzomorph, Ketohexamethylene, dichloromethane, chrysanthemum ester, wide cassia oil, rotenone, microemulsion and water;Wherein, relative to the water of 100 weight portions, The consumption of described avilamycin is 20-30 weight portion, and the consumption of described Ketohexamethylene is 10-20, and the consumption of described dichloromethane is 5-10 weight portion, the consumption of described chrysanthemum ester is 2-8 weight portion, and the consumption of described wide cassia oil is 1-10 weight portion, described rotenone Consumption be 2-8 weight portion, the consumption of described microemulsion is 0.5-3 weight portion.
The present invention one preferred embodiment in, in order to further increase the insecticidal effect of insecticide, relatively In the water of 100 weight portions, the consumption of described avilamycin is 20-30 weight portion, and the consumption of described Ketohexamethylene is 10-20, described The consumption of dichloromethane is 5-10 weight portion, and the consumption of described chrysanthemum ester is 2-8 weight portion, and the consumption of described wide cassia oil is 1-10 weight Amount part, the consumption of described rotenone is 2-8 weight portion, and the consumption of described microemulsion is 0.5-3 weight portion.
The present invention one preferred embodiment in so that can preferably dissolve each other between raw material, improve former The dispersibility of material, described microemulsion is one or more in Celastrus angulatus, Flos Caryophylli and Cinnamomum burmanii oil.
Present invention also offers the preparation method of a kind of abamectin insecticide, wherein, described preparation method includes: by Ah Dimension rhzomorph, Ketohexamethylene, dichloromethane, chrysanthemum ester, wide cassia oil, rotenone, microemulsion and water mix and blend, obtain described avilamycin Insecticide;Wherein, relative to the water of 100 weight portions, the consumption of described avilamycin is 20-30 weight portion, described Ketohexamethylene Consumption is 10-20, and the consumption of described dichloromethane is 5-10 weight portion, and the consumption of described chrysanthemum ester is 2-8 weight portion, described wide osmanthus The consumption of oil is 1-10 weight portion, and the consumption of described rotenone is 2-8 weight portion, and the consumption of described microemulsion is 0.5-3 weight Part.
The present invention one preferred embodiment in, in order to further increase the insecticidal effect of insecticide, relatively In the water of 100 weight portions, the consumption of described avilamycin is 20-30 weight portion, and the consumption of described Ketohexamethylene is 10-20, described The consumption of dichloromethane is 5-10 weight portion, and the consumption of described chrysanthemum ester is 2-8 weight portion, and the consumption of described wide cassia oil is 1-10 weight Amount part, the consumption of described rotenone is 2-8 weight portion, and the consumption of described microemulsion is 0.5-3 weight portion.
The present invention one preferred embodiment in so that can preferably dissolve each other between raw material, improve former The dispersibility of material, described microemulsion is one or more in Celastrus angulatus, Flos Caryophylli and Cinnamomum burmanii oil.
The present invention one preferred embodiment in so that can preferably dissolve each other between raw material, described system Preparation Method heats when being additionally included in mix and blend, it is preferred that described heating-up temperature is 45-55 DEG C.
Hereinafter will be described the present invention by embodiment.
Embodiment 1
By 24g avilamycin, 14g Ketohexamethylene, 6g dichloromethane, 4g chrysanthemum ester, the wide cassia oil of 4g, 4g rotenone, 1g Celastrus angulatus Element and 100g water heat (heating-up temperature is 45 DEG C) mix and blend, obtain abamectin insecticide A1.
Embodiment 2
By 26g avilamycin, 16g Ketohexamethylene, 8g dichloromethane, 6g chrysanthemum ester, the wide cassia oil of 6g, 6g rotenone, 2g Flos Caryophylli and 100g water heating (heating-up temperature is 55 DEG C) mix and blend, obtains abamectin insecticide A2.
Embodiment 3
By 25g avilamycin, 15g Ketohexamethylene, 7g dichloromethane, 5g chrysanthemum ester, the wide cassia oil of 5g, 5g rotenone, 1.5g the moon perfume Oil and water heat (heating-up temperature is 50 DEG C) mix and blend, obtain abamectin insecticide A3.
Embodiment 4
By 20g avilamycin, 10g Ketohexamethylene, 5g dichloromethane, 2g chrysanthemum ester, the wide cassia oil of 1g, 2g rotenone, 0.5g hardship skin Rattan element and 100g water heat (heating-up temperature is 45 DEG C) mix and blend, obtain abamectin insecticide A4.
Embodiment 5
By 30g avilamycin, 20g Ketohexamethylene, 10g dichloromethane, 8g chrysanthemum ester, the wide cassia oil of 10g, 8g rotenone, 3g hardship skin Rattan element and 100g water heat (heating-up temperature is 45 DEG C) mix and blend, obtain abamectin insecticide A5.
Comparative example 1
By 15g avilamycin, 5g Ketohexamethylene, 3g dichloromethane, 1g chrysanthemum ester, the wide cassia oil of 0.5g, 1g rotenone, 0.2g hardship skin Rattan element and 100g water heat (heating-up temperature is 45 DEG C) mix and blend, obtain abamectin insecticide D1.
Comparative example 2
By 35g avilamycin, 25g Ketohexamethylene, 12g dichloromethane, 10g chrysanthemum ester, the wide cassia oil of 12g, 10g rotenone, 5g hardship Skin rattan element and 100g water heat (heating-up temperature is 45 DEG C) mix and blend, obtain abamectin insecticide D2.
Table 1
Embodiment is numbered Killing rate
A1 90%
A2 92%
A3 90%
A4 75%
A5 75%
D1 65%
D2 60%
By above table data it can be seen that the insecticide A1-A5 prepared within the scope of the present invention, its killing rate is relatively Height, and insecticide D1 and D2 prepared outside the scope of the invention, its killing rate is relatively low, makes in currently preferred scope The insecticide A1-A3 obtained possesses the most outstanding sterilizing ability.
The preferred embodiment of the present invention described in detail above, but, the present invention is not limited in above-mentioned embodiment Detail, in the technology concept of the present invention, technical scheme can be carried out multiple simple variant, this A little simple variant belong to protection scope of the present invention.
It is further to note that each the concrete technical characteristic described in above-mentioned detailed description of the invention, at not lance In the case of shield, can be combined by any suitable means, in order to avoid unnecessary repetition, the present invention to various can The compound mode of energy illustrates the most separately.
Additionally, combination in any can also be carried out between the various different embodiment of the present invention, as long as it is without prejudice to this The thought of invention, it should be considered as content disclosed in this invention equally.

Claims (7)

1. an abamectin insecticide, it is characterised in that the raw material of described abamectin insecticide includes: avilamycin, ring Hexanone, dichloromethane, chrysanthemum ester, wide cassia oil, rotenone, microemulsion and water;Wherein,
Relative to the water of 100 weight portions, the consumption of described avilamycin is 20-30 weight portion, and the consumption of described Ketohexamethylene is 10- 20, the consumption of described dichloromethane is 5-10 weight portion, and the consumption of described chrysanthemum ester is 2-8 weight portion, the consumption of described wide cassia oil For 1-10 weight portion, the consumption of described rotenone is 2-8 weight portion, and the consumption of described microemulsion is 0.5-3 weight portion.
Abamectin insecticide the most according to claim 1, wherein, relative to the water of 100 weight portions, described avilamycin Consumption be 24-26 weight portion, the consumption of described Ketohexamethylene is 14-16, and the consumption of described dichloromethane is 6-8 weight portion, institute The consumption stating chrysanthemum ester is 4-6 weight portion, and the consumption of described wide cassia oil is 4-6 weight portion, and the consumption of described rotenone is 4-6 weight Part, the consumption of described microemulsion is 1-2 weight portion.
Abamectin insecticide the most according to claim 1 and 2, wherein, described microemulsion is Celastrus angulatus, Flos Caryophylli and the moon One or more in Oleum sesami.
4. the preparation method of an abamectin insecticide, it is characterised in that described preparation method includes: by avilamycin, ring Hexanone, dichloromethane, chrysanthemum ester, wide cassia oil, rotenone, microemulsion and water mix and blend, obtain described abamectin insecticide;Its In,
Relative to the water of 100 weight portions, the consumption of described avilamycin is 20-30 weight portion, and the consumption of described Ketohexamethylene is 10- 20, the consumption of described dichloromethane is 5-10 weight portion, and the consumption of described chrysanthemum ester is 2-8 weight portion, the consumption of described wide cassia oil For 1-10 weight portion, the consumption of described rotenone is 2-8 weight portion, and the consumption of described microemulsion is 0.5-3 weight portion.
Preparation method the most according to claim 4, wherein, relative to the water of 100 weight portions, the consumption of described avilamycin For 24-26 weight portion, the consumption of described Ketohexamethylene is 14-16, and the consumption of described dichloromethane is 6-8 weight portion, described chrysanthemum ester Consumption be 4-6 weight portion, the consumption of described wide cassia oil is 4-6 weight portion, and the consumption of described rotenone is 4-6 weight portion, institute The consumption stating microemulsion is 1-2 weight portion.
Preparation method the most according to claim 4, wherein, described preparation method adds when being additionally included in mix and blend Heat.
Preparation method the most according to claim 6, wherein, described heating-up temperature is 45-55 DEG C.
CN201610403609.2A 2016-06-08 2016-06-08 abamectin insecticide and preparation method thereof Pending CN106070354A (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1360836A (en) * 2000-12-25 2002-07-31 上海宝田科技发展有限公司 Mixed sanitary insecticide liquid
CN100998331A (en) * 2006-01-10 2007-07-18 潘贞德 Series microemulsion insecticide using Pyrethrum as raw material
CN102106345A (en) * 2009-12-28 2011-06-29 ***南通农药剂型开发中心 Avermectin microcapsule suspending agent and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1360836A (en) * 2000-12-25 2002-07-31 上海宝田科技发展有限公司 Mixed sanitary insecticide liquid
CN100998331A (en) * 2006-01-10 2007-07-18 潘贞德 Series microemulsion insecticide using Pyrethrum as raw material
CN102106345A (en) * 2009-12-28 2011-06-29 ***南通农药剂型开发中心 Avermectin microcapsule suspending agent and preparation method thereof

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
孔祥海: "植物源杀虫剂的研究进展", 《龙岩师专学报》 *
林锦明等: "《化学实验室工作手册》", 31 January 2016, 第二军医大学出版社 *
许定发等: "《中国经济植物 上卷》", 30 September 2015, 江苏凤凰科学技术出版社 *

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