CN106070295A - A kind of brominated cyanogen insect amide and the Synergistic insecticidal compositions of imidacloprid and application thereof - Google Patents
A kind of brominated cyanogen insect amide and the Synergistic insecticidal compositions of imidacloprid and application thereof Download PDFInfo
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- CN106070295A CN106070295A CN201610455678.8A CN201610455678A CN106070295A CN 106070295 A CN106070295 A CN 106070295A CN 201610455678 A CN201610455678 A CN 201610455678A CN 106070295 A CN106070295 A CN 106070295A
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- Prior art keywords
- imidacloprid
- insect amide
- cyanogen insect
- insecticidal compositions
- synergistic insecticidal
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
Abstract
The invention discloses Synergistic insecticidal compositions of a kind of brominated cyanogen insect amide and imidacloprid and application thereof, this Pesticidal combination with bromine cyanogen insect amide with imidacloprid as principle active component, wherein, the weight ratio of bromine cyanogen insect amide and imidacloprid is 1～60:1～60.This Pesticidal combination has expanding prevention spectrum and the effect of potentiation, and drug cost can be reduced, cream, wettable powder, microemulsion, aqueous emulsion, suspending agent, water dispersible granules can be configured to, be used for preventing and treating the various pests such as Lepidoptera, Semiptera, Hymenoptera, coleoptera.
Description
Technical field
The invention belongs to pesticide field, be specifically related to a kind of with bromine cyanogen insect amide and imidacloprid killing as principle active component
Worm compositions and application thereof.
Background technology
Bromine cyanogen insect amide (cyantraniliprole), is E.I.Du Pont Company's second filial generation that success is developed after chlorantraniliprole
Ryanodine receptor inhibitor insecticides, cyanogen insect amide is to be formed by the various polar groups on change phenyl ring, has higher
Effect, applicable crops is more extensive, can effectively prevent and treat Lepidoptera, Semiptera and coleopteran pest.
Imidacloprid (Imidacloprid), chemical name: 1-(6-chloropyridine-3-pyridylmethyl)-N-nitro
Sub-imidazolidine-2-base amine, molecular formula: C9H10ClN5O2, chemical structural formula:
Imidacloprid is nitro-methylene-type systemic insecticide, is the acting body of nicotinic acetylcholine esterase receptor, interference evil
Worm kinetic system makes chemical signal transmission malfunctioning, no interactions resistance problem.For preventing and treating sucking pest and resisting
Property strain.Imidacloprid is a new generation's chloro nicotine insecticide, has wide spectrum, efficient, low toxicity, low-residual, and insect is not likely to produce
Resistance, to features such as people, animal, plant and natural enemies securities, and have tag, stomach toxicity and the multiple drug effect of interior suction.After contacting pests medicament,
Nervus centralis normal conduction is obstructed so that it is paralysis death.Quick-acting is good, within after medicine 1 day, i.e. has higher preventive effect, and residual period is up to 25
About it.Drug effect and temperature are proportionate, and temperature is high, good disinsection effect.It is mainly used in preventing and treating sucking pest.Main use
Sucking pest on the crops such as preventing and treating Oryza sativa L., Semen Tritici aestivi, Cotton Gossypii, such as aphid, leafhopper, thrips, trialeurodes vaporariorum and Rhizoma Solani tuber osi
Beetle and frit fly etc..
Insecticide variety containing single component often existing defects in pesticide Pest control: use continuously easily produce anti-
The property of medicine, insecticidal spectrum is narrow, it is impossible to providing comprehensively protection for crop, peasant's drug cost is high.
Summary of the invention
It is an object of the invention to provide a kind of brominated cyanogen insect amide and the Synergistic insecticidal compositions of imidacloprid, said composition can
For preventing and treating various agricultural insect, such as preventing and treating vegetable diamondback moth, Pieris rapae, it is also possible to be used for preventing and treating cotton boll worm, sweet
Dish noctuid and Brown Planthopper etc., can reach a drug and prevent and treat the effect of dissimilar insect.
It is a further object of the present invention to provide the Synergistic insecticidal compositions of brominated cyanogen insect amide and imidacloprid in preparation preventing and treating
Application in the insecticidal materials of one or more insects in resistance Lepidoptera, Semiptera, Hymenoptera or coleoptera.
The present invention adopts the following technical scheme that
A kind of brominated cyanogen insect amide and the Synergistic insecticidal compositions of imidacloprid, it is main with bromine cyanogen insect amide and imidacloprid
Effective ingredient, wherein, the weight ratio of bromine cyanogen insect amide and imidacloprid is 1～60:1～60.Preferably bromine cyanogen insect amide and imidacloprid
Weight ratio be 1～40:1～40, the weight ratio of further preferred bromine cyanogen insect amide and imidacloprid is 1～30:1～30.
In some preferred technical schemes: bromine cyanogen insect amide and imidacloprid can 1:30,1:29,1:28,1:27,1:
26、1:25、1:24、1:24、1:22、1:21、1:20、1:19、1:18、1:17、1:16、1:15、1:14、1:13、1:12、1:
11、1:10、1:9、1:8、1:7、1:6、1:5、1:4、1:3、1:2、1:1、2:1、3:1、4:1、5:1、6:1、7:1、8:1、9:1、
10:1、11:1、12:1、13:1、14:1、15:1、16:1、17:1、18:1、19:1、20:1、21:1、22:1、23:1、24:1、
25:1、26:1、27:1、28:1、29:1、30:1、2:3、3:2、2:5、5:2、3:4、4:3、5:2、2:5、5:3、3:5、5:4、4:5
These ratios select.
At brominated cyanogen insect amide and the Synergistic insecticidal compositions of imidacloprid of the present invention, bromine cyanogen insect amide and both imidacloprids
Weight percentage in this Synergistic insecticidal compositions is 2%～80%, preferably 8%～60%, optimum be 20%～
40%.
The Synergistic insecticidal compositions of above-mentioned brominated cyanogen insect amide and imidacloprid with bromine cyanogen insect amide with imidacloprid for mainly having
Effect composition (active component) and insecticides adjuvant, excipient are configured on pesticide any one dosage form allowed.The preferred powder of dosage form,
Wettable powder, suspending agent, cream and water dispersion granule.
Described auxiliary agent can use calcium dodecyl benzene sulfonate, alkylphenol polyoxyethylene, polyoxyethylene polyoxy propylene embedding
Section compound is (such as agriculture breast 33#), NPE etc., excipient comprises Ketohexamethylene, dimethylbenzene, solvent naphtha, water, antifreeze
Agent (such as propylene glycol), deionized water etc..Above auxiliary agent, excipient and other agriculturally known adjuvant can be alone or and use.
Above-mentioned brominated cyanogen insect amide and the Synergistic insecticidal compositions of imidacloprid are at preparation preventing and treating Lepidoptera, Semiptera, film
Application in the insecticidal materials of one or more insects in wing mesh or coleoptera.Especially preparation preventing and treating planthopper or snout moths larva
Application effect in insecticidal materials is notable.
The Synergistic insecticidal compositions antagonism lepidoptera pest of the present invention has significant preventive effect, particularly with cotton boll
Worm, beet armyworm, diamondback moth etc. easily produce the various pests of resistance and have good preventive effect；And suppress insect to single
The Drug resistance of preparation (bromine cyanogen insect amide or imidacloprid) produces and can prevent and treat Hemipteran pest such as Brown Planthopper etc. simultaneously.
The insecticidal materials prepared by the Synergistic insecticidal compositions of described brominated cyanogen insect amide and imidacloprid is preventing and treating resistance
While Lepidoptera, Hymenoptera or coleopteran pest, Hemipteran pest can be prevented and treated again, especially to cotton boll worm, diamondback moth and
Beet armyworm has good preventive effect, reaches the effect that a medicine is controlled more.
The Pesticidal combination of the present invention compared with prior art, produces following beneficial effect: (1) compared with single dose, this group
Compound insect has notable synergistic, hence it is evident that improve prevention effect；(2) one medicines are controlled more, and a dispenser can prevent and treat various pests simultaneously,
Reduce preventing and treating recruitment cost；(3) alternative high-toxic pesticide, and field dosage is greatly reduced, effectively reduce environmental pollution and
Pesticide residues；(4) have concurrently quick-acting and long-acting；(5) compared with bromine cyanogen insect amide single dose, produce and use cost reduces；(6) suppression
The resistance of pesticide is strengthened by insect.
Detailed description of the invention
Embodiments of the invention are the methods using indoor bioassay and field test to combine.First pass through indoor biological
Measure, the co-toxicity coefficient after clear and definite two kinds of medicaments are compounding by a certain percentage；On this basis, then carry out field test.
Embodiment 1:
Weigh 80g bromine cyanogen insect amide, 2g imidacloprid, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g, two
Toluene puts into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, forms principle active component weight
Amount percentage composition is the bromine cyanogen insect amide imidacloprid cream of 82%.
Embodiment 2:
Weigh 2g bromine cyanogen insect amide, 80g imidacloprid, lignin 10g, Negel 2g, add to 100g with Kaolin,
Above raw material is mixed in super micron mill, forms the bromine cyanogen insect amide that principle active component weight percentage is 82%
Imidacloprid wettable powder.
Embodiment 3:
Weigh 60g bromine cyanogen insect amide, 2g imidacloprid, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 6g, two
Toluene adds to 100g, and the method that above raw material is prepared cream routinely puts into mixing in mixing kettle, forms principle active component
Weight percentage is the bromine cyanogen insect amide imidacloprid cream of 62%.
Embodiment 4:
Weigh 2g bromine cyanogen insect amide, 60g imidacloprid, nonyl phenol phosphate 5g, alkylphenol polyoxyethylene 4g, n-butyl alcohol
The dimethylbenzene of 3g, 10g and the ketopyrrolidine of 10g, the xanthan gum of 0.1g, remaining supplies 100g, n-butyl alcohol and water dissolution shape with water
Becoming aqueous phase, remaining component mix and blend forms oil phase, slowly aqueous phase is added in oil phase, and continue to cut under cutter effect
Cut 10～30 minutes, form the bromine cyanogen insect amide imidacloprid aqueous emulsion that principle active component weight percentage is 62%.
Embodiment 5:
Weigh 40g bromine cyanogen insect amide, 2g imidacloprid, calcium dodecyl benzene sulfonate 5g, alkylphenol polyoxyethylene 4g, 30g
Solvent xylene and the ketopyrrolidine of 15g, remaining complements to 100g with water, and the mixing of former medicine, solvent, emulsifying agent, cosolvent is stirred
Mix formation homogeneous phase transparent solution, be then slowly added into water and stir formation clear solution, being principle active component weight percent
Content is the bromine cyanogen insect amide imidacloprid emulsion of 42%.
Embodiment 6:
Weigh 2g bromine cyanogen insect amide, 40g imidacloprid, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 3g, two
Toluene is to 100g.The method that above raw material is prepared cream routinely puts into mixing in mixing kettle, forms principle active component weight
Amount percentage composition is the bromine cyanogen insect amide imidacloprid cream of 42%.
Embodiment 7:
Weigh 20g bromine cyanogen insect amide, 2g imidacloprid, sodium lignin sulfonate 3g, polyoxyethylene poly-oxygen propylene aether and sulphuric acid thereof
Salt 4g, xanthan gum 0.2g, ethylene glycol 10g, silica ethane 0.1g, aluminium-magnesium silicate 0.5g, supply 100g with water, at the work of sand mill
With the bromine cyanogen insect amide imidacloprid suspending agent that lower formation principle active component weight percentage is 22%.
Embodiment 8:
Weigh 2g bromine cyanogen insect amide, 20g imidacloprid, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether 15g,
Dimethylbenzene puts into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, forms principle active component
Weight percentage is the bromine cyanogen insect amide imidacloprid cream of 22%.
Embodiment 9:
Weigh 2g bromine cyanogen insect amide, 10g imidacloprid, sodium lignin sulfonate 8g, sodium lauryl sulphate 2g, ammonium sulfate 5g,
Polyvinyl alcohol 5g, Borax 2g, Kaolin 28g, the method that above raw material is pressed water dispersion granule forms principle active component weight
Amount percentage composition is the bromine cyanogen insect amide imidacloprid water dispersible granule of 12%.
Embodiment 10:
Weigh 5g bromine cyanogen insect amide, 10g imidacloprid, alkylphenol polyoxyethylene 14g, phenethyl phenol polyethenoxy ether 15g,
Dimethylbenzene puts into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, forms principle active component
Weight percentage is the bromine cyanogen insect amide imidacloprid cream of 15%.
Embodiment 11:
Weigh 10g bromine cyanogen insect amide, 10g imidacloprid, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 3g,
Dimethylbenzene puts into mixing in mixing kettle to 100g, the method that above raw material is prepared cream routinely, forms principle active component
Weight percentage is the bromine cyanogen insect amide imidacloprid cream of 20%.
Drug effect checking test
1, indoor virulence determination of activity
Weigh bromine cyanogen insect amide, imidacloprid uses conventional formulation method to be configured to principle active component weight by different proportion
Percentage composition is the bromine cyanogen insect amide imidacloprid cream of 30%.Concrete ratio is shown in Table 1.
Use feedstuff to add poison method and measure bromine cyanogen insect amide and imidacloprid and the compounding sample virulence to cotton boll worm thereof, often
Process is repeated 3 times, and every concentration processes 30, uses LC50It is worth and presses Sun Yun abundant method calculating co-toxicity coefficient:
Table 1 bromine cyanogen insect amide, imidacloprid and compounding sample thereof are to the toxicity test of cotton boll worm and co-toxicity coefficient
In table, data show, after bromine cyanogen insect amide and imidacloprid mixture, cotton boll worm are had potentiation, institute in table
The proportioning co-toxicity coefficient of row is both greater than 120, and therefore bromine cyanogen insect amide and imidacloprid mixture have significant synergies.
Weigh bromine cyanogen insect amide, imidacloprid uses conventional formulation method to be configured to principle active component weight by different proportion
Percentage composition is the bromine cyanogen insect amide imidacloprid cream of 30%.Concrete ratio is shown in Table 2.
Rice-stem dipping method is used to measure bromine cyanogen insect amide and imidacloprid and the compounding sample virulence to Brown Planthopper thereof, often
Process is repeated 3 times, and uses LC50It is worth and presses Sun Yun abundant method calculating co-toxicity coefficient:
Table 2 bromine cyanogen insect amide, imidacloprid and compounding sample thereof are to the toxicity test of Brown Planthopper and co-toxicity coefficient
In table, data show, have potentiation, institute in table after bromine cyanogen insect amide and imidacloprid mixture to Brown Planthopper
The proportioning co-toxicity coefficient of row is all much larger than 120, and therefore bromine cyanogen insect amide and imidacloprid mixture have significant synergies.
2, field control effectiveness test
Using embodiment institute sample product to carry out the field test of control in field cotton boll worm, comparison medicament is 5% bromine cyanogen
Insect amide EC and 10% imidacloprid WDG, concrete consumption is shown in Table 3, and every mu of use water, amount are 30kg, looks into 3 days, 7 days, within 14 days, tie after medicine
Really, result of the test is shown in Table 3:
Table 3 sample field test results to cotton boll worm
Example has fabulous quick-acting to cotton boll worm as can be seen from Table 3, and the lasting period is long, at field table
Now good, it is the outstanding medicament of preventing and treating cotton boll worm.
Measure through indoor synergism test and show: by bromine cyanogen insect amide with imidacloprid built agent to cotton boll worm and Rice Brown
Plant hopper has significant synergistic insecticidal action；Field control effectiveness test also indicates that all of built agent of the present invention is to cotton boll worm equally
Insecticidal effect is all remarkably higher than the effect of corresponding single dose pesticide.
Claims (9)
1. brominated cyanogen insect amide and a Synergistic insecticidal compositions for imidacloprid, is characterized in that this Synergistic insecticidal compositions is with bromine cyanogen
Insect amide and imidacloprid are principle active component, and wherein, the weight ratio of bromine cyanogen insect amide and imidacloprid is 1～60:1～60.
Brominated cyanogen insect amide the most according to claim 1 and the Synergistic insecticidal compositions of imidacloprid, is characterized in that this parasite killing
The active ingredient bromine cyanogen insect amide of compositions and the weight ratio of imidacloprid are 1～40:1～40.
Brominated cyanogen insect amide the most according to claim 2 and the Synergistic insecticidal compositions of imidacloprid, is characterized in that this parasite killing
The active ingredient bromine cyanogen insect amide of compositions and the weight ratio of imidacloprid are 1～30:1～30.
Brominated cyanogen insect amide the most according to claim 1 and the Synergistic insecticidal compositions of imidacloprid, is characterized in that bromine cyanogen worm
Amide and both imidacloprids weight percentage in this Synergistic insecticidal compositions are 2%～80%.
Brominated cyanogen insect amide the most according to claim 4 and the Synergistic insecticidal compositions of imidacloprid, is characterized in that bromine cyanogen worm
Amide and both imidacloprids weight percentage in this Synergistic insecticidal compositions are 8%～60%.
Brominated cyanogen insect amide the most according to claim 1 and the Synergistic insecticidal compositions of imidacloprid, is characterized in that this potentiation
With bromine cyanogen insect amide, as principle active component and insecticides adjuvant is configured on pesticide any of permission to Pesticidal combination with imidacloprid
A kind of dosage form.
Brominated cyanogen insect amide the most according to claim 6 and the Synergistic insecticidal compositions of imidacloprid, is characterized in that described dose
Type is cream, wettable powder, microemulsion, aqueous emulsion, suspending agent or water dispersion granule.
8. the Synergistic insecticidal compositions of brominated cyanogen insect amide described in claim 1 and imidacloprid preparation preventing and treating Lepidoptera, half
Application in the insecticidal materials of one or more insects in wing mesh, Hymenoptera or coleoptera.
Application the most according to claim 8, is characterized in that the Synergistic insecticidal compositions of brominated cyanogen insect amide and imidacloprid exists
Application in the insecticidal materials of preparation preventing and treating cotton boll worm, beet armyworm and Brown Planthopper.
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| CN104798805A (en) * | 2015-03-26 | 2015-07-29 | 河北博嘉农业有限公司 | Insecticide composition for corn |
| JP2015214554A (en) * | 2015-06-11 | 2015-12-03 | 住友化学株式会社 | Plant disease and harmful arthropod control composition and plant disease and harmful arthropod control method |
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- 2016-06-21 CN CN201610455678.8A patent/CN106070295A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102283205A (en) * | 2004-07-26 | 2011-12-21 | 杜邦公司 | Mixtures of anthranilamide invertebrate pest control agents |
| CN103283764A (en) * | 2012-02-24 | 2013-09-11 | 陕西韦尔奇作物保护有限公司 | Cyantraniliprole containing insecticidal composition |
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| CN103229780A (en) * | 2013-04-23 | 2013-08-07 | 中国农业科学院蔬菜花卉研究所 | Cyantraniliprole-imidacloprid pesticide composition |
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