CN106064240A - A kind of resistance to grinding column of manganese steel and manufacture method thereof - Google Patents

A kind of resistance to grinding column of manganese steel and manufacture method thereof Download PDF

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Publication number
CN106064240A
CN106064240A CN201610548882.4A CN201610548882A CN106064240A CN 106064240 A CN106064240 A CN 106064240A CN 201610548882 A CN201610548882 A CN 201610548882A CN 106064240 A CN106064240 A CN 106064240A
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resistance
column
manganese steel
grinding column
grinding
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CN201610548882.4A
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Chinese (zh)
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张倩楠
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Individual
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    • B22F1/0003
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/02Compacting only
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/12Both compacting and sintering
    • B22F3/14Both compacting and sintering simultaneously
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F5/00Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/12Both compacting and sintering
    • B22F3/14Both compacting and sintering simultaneously
    • B22F2003/145Both compacting and sintering simultaneously by warm compacting, below debindering temperature

Abstract

The invention belongs to field of powder metallurgy.Disclosing a kind of resistance to grinding column of manganese steel, it is mainly prepared by following raw material: potassium steel powder and weight ratio are the WB of 10.0% the 20.0% of described potassium steel powdern(Me).The invention also discloses the manufacture method of the resistance to grinding column of a kind of manganese steel, including, by raw material: potassium steel powder, liquid paraffin and weight ratio are the WB of 10.0% the 20.0% of described potassium steel powdern(Me) it is sufficiently mixed, in grinding tool, is pressed into column by four-column press, load after dewaxing and composite pyrophyllite uses cubic hinge press increasing temperature and pressure sintering, take out after pressure release.The manganese steel resistance to grinding column manufacturing expense of the present invention is low, and has wearability and toughness concurrently.

Description

A kind of resistance to grinding column of manganese steel and manufacture method thereof
[technical field]
The invention belongs to field of powder metallurgy, particularly relate to a kind of resistance to grinding column of manganese steel and manufacture method thereof.
[background technology]
Within 2015, China's crude steel yield breaches 800,000,000 tons, and abrasion-resistant stee yield also breaches 2,000,000 tons, and production capacity is superfluous. Country has begun to significantly drop production capacity and goes stock, but each trade mark high-quality special steel of extraordinary model but remains a need for import, research The novel strengthened mechanism of special steel is imperative with high reliability long life mechanism.
The method of existing increase abrasion-resistant stee wearability is divided into smelting and casting two kinds, and smelting refers to adjust alloying element Ratio;Casting refers to add alloying element and bonding gold, and original impregnated alloy is mainly diamondite and titanium carbide closes Gold, diamondite and titanium carbide alloy have been sintered by vacuum or inert gas shielding, the prices of raw materials and process program Cause manufacturing expense high, and Wear Resistance can not get both with toughness.
In view of this, it is provided that a kind of wearability grinding column resistance to the manganese steel that toughness can get both and manufacture method thereof are the most necessary.
[summary of the invention]
For solving above-mentioned technical problem, the present invention provides a kind of and has wearability and the resistance to grinding column of manganese steel of toughness and manufacture thereof concurrently Method.
For solving above-mentioned technical problem, embodiment of the present invention offer techniques below scheme:
A kind of resistance to grinding column of manganese steel, it mainly prepares by following raw material: potassium steel powder and weight ratio are described Gao Meng The WB of the 10.0%--20.0% of powdered steeln(Me)。
Preferably, above-mentioned WBn(Me) it is: WB (Me) or WB2(Me)。
Preferably, above-mentioned WBn(Me) particle size range is: 0.5-1.0 micron.
Preferably, above-mentioned WBn(Me) it is WB2(Me), granularity is 1 micron, WB2(Me) percentage of potassium steel powder weight is accounted for Ratio is 10%.
Preferably, above-mentioned WBn(Me) it is WB2(Me), granularity is 0.5 micron, WB2(Me) the hundred of potassium steel powder weight are accounted for Proportion by subtraction is 20%.
Preferably, above-mentioned WBn(Me) being WB (Me), granularity is 0.6 micron, and WB (Me) accounts for the percentage of potassium steel powder weight Ratio is 13%.
Preferably, above-mentioned WBn(Me) being WB (Me), granularity is 0.8 micron, and WB (Me) accounts for the percentage of potassium steel powder weight Ratio is 15%.
Preferably, above-mentioned WBn(Me) being WB (Me), granularity is 1 micron, and WB (Me) accounts for the percentage ratio of potassium steel powder weight It is 18%.
For solving above-mentioned technical problem, the embodiment of the present invention also provides for techniques below scheme:
The manufacture method of the resistance to grinding column of a kind of manganese steel, it is characterised in that it includes raw material: potassium steel powder, liquid stone Wax and weight ratio are the WB of the 10.0%--20.0% of described potassium steel powdern(Me) it is sufficiently mixed, by four-column press at mill Tool is pressed into column, loads after dewaxing and composite pyrophyllite uses cubic hinge press increasing temperature and pressure sintering, take out after pressure release.
Preferably, above-mentioned increasing temperature and pressure sintering includes: within first 2 minutes, boost to 70Mpa, and pressurize began to warm up after 5 seconds, Heater power being raised to 1080 amperes in 10 seconds, again electric current is raised to 1450 amperes for 110 seconds after being incubated 5 minutes, constant temperature stops for 3 minutes Only heat supply, power returns to 0, then pressure release after two minutes, and pressure returns to 0, and sintering overall process is according to the time providing electric current Calculate, totally 10 minutes.
Compared with prior art, the embodiment of the present invention is added in described potassium steel powder and is accounted for its percentage by weight and be The WB of 10.0%--20.0%n(Me) wearability and the toughness of the resistance to grinding column of manganese steel, can be improved simultaneously.The embodiment of the present invention simultaneously The fusing point of the resistance to grinding column of manganese steel only has 1080 degree, and diamondite and titanium carbide alloy melting point are higher than 1600 degree, and the present invention implements The resistance to grinding column of manganese steel of example is easier to combination with molten steel and does not falls off.
[accompanying drawing explanation]
Fig. 1 is the artwork of increasing temperature and pressure sintering in the manganese steel resistance to grinding column manufacture method that the embodiment of the present invention provides.
[detailed description of the invention]
In order to make the purpose of the present invention, method scheme and advantage clearer, below in conjunction with drawings and Examples, right The present invention is further elaborated.Should be appreciated that specific embodiment described herein only in order to explain the present invention, not For limiting the present invention.
The embodiment of the present invention provides a kind of resistance to grinding column of manganese steel, and it is mainly prepared by following raw material: potassium steel powder and Weight ratio is the WB of the 10.0%--20.0% of described potassium steel powdern(Me)。
WBn(Me) being the boron series compound of tungsten, wherein Me is the english abbreviation of metal, and noble metal rhenium Re is therein one Planting optimum selection, also have other optional metal such as titanium, various rare earth elements etc., its microhardness is 50Gpa.
Described WBn(Me) can be WB (Me) or WB2(Me), particle size range is 0.5-1.0 micron.
The embodiment of the present invention is added in described potassium steel powder and is accounted for the WB that its percentage by weight is 10.0%--20.0%n (Me) wearability and the toughness of the resistance to grinding column of manganese steel of the embodiment of the present invention, can be improved simultaneously.
The embodiment of the present invention also provides for the manufacture method of the resistance to grinding column of a kind of manganese steel, including: by potassium steel powder, liquid paraffin And the WB of the 10.0%--20.0% that weight ratio is described potassium steel powdern(Me) it is sufficiently mixed, by four-column press at grinding tool In be pressed into column, load after dewaxing and composite pyrophyllite use cubic hinge press increasing temperature and pressure sintering, take out after pressure release, i.e. obtain Obtain the resistance to grinding column of manganese steel of the embodiment of the present invention.
Described cubic hinge press uses 6 × 3000T press that Shaoguan Saipu Superhard Material Technology Co., Ltd. is self-produced.
The embodiment of the present invention uses cubic hinge press hot pressed sintering manufacture to obtain the resistance to grinding column of manganese steel of the embodiment of the present invention, its Wearability gets both with toughness, and diamondite and titanium carbide that the ratio of performance to price sinters higher than vacuum or inert gas shielding close Gold.Simultaneously because the fusing point of the resistance to grinding column of the manganese steel of the embodiment of the present invention only has 1080 degree, and diamondite and titanium carbide alloy Fusing point is higher than 1600 degree, and the resistance to grinding column of manganese steel of the embodiment of the present invention is easily combined with molten steel and does not falls off.
Embodiment 1
Weigh the Fe70Mn30 powder of 10 kilogram of 200 mesh, the WB of 1 kilogram 1 micron2(Me) powder, and 100 grams of liquid stones Wax, and three is sufficiently mixed, in grinding tool, it is pressed into column by four-column press, loads after 650 degree of dewaxings in composite pyrophyllite, Sintering process line the most as shown in Figure 1 uses cubic hinge press to be sintered, and in figure, abscissa is time shaft, and vertical coordinate is pressure Power, power qualitative representation.First pressure line boosts to 70Mpa for 2 minutes, and pressurize began to warm up after 5 seconds, and 10 seconds by heater Power be raised to 1080 amperes, again electric current is raised at a slow speed 1450 amperes for 110 seconds after being incubated 5 minutes, constant temperature 3 minutes stops supplying Heat, power line returns to 0, then pressure release after two minutes, and pressure line returns to 0, and sintering overall process is according to the time providing electric current Calculate, totally 10 minutes.Take out the resistance to grinding column of manganese steel after pressure release, measure the resistance to grinding column of manganese steel and silicon carbide grinding wheel with Standard erosion than emery wheel Relative wear ratio be 7-7.5:1.And under same testing standard: 45 steel (hardness HRC40) and silicon carbide grinding wheel relative wear ratio It is 0.3:1;GT20 hard alloy is 6:1 with silicon carbide grinding wheel relative wear ratio.Meanwhile, manganese steel resistance to grinding column toughness is manganese steel powder 2 times of sintering post.
Embodiment 2
Weigh the Fe70Mn30 powder of 10 kilogram of 200 mesh, the WB of 2 kilograms 0.5 micron2(Me) powder, and 150 grams of liquid stones Wax, is then sufficiently mixed three, is pressed into column by four-column press, loads composite pyrophyllite after 650 degree of dewaxings in grinding tool Middle use cubic hinge press is sintered, and flow process, with embodiment 1, is taken out the resistance to grinding column of manganese steel, compared emery wheel with Standard erosion after pressure release The mensuration resistance to grinding column of manganese steel is 9.8-10:1 with the relative wear ratio of silicon carbide grinding wheel.And under same testing standard: 45 steel (hardness HRC40) the relative wear ratio with silicon carbide grinding wheel is 0.3:1;GT20 hard alloy with the relative wear ratio of silicon carbide grinding wheel is 6:1.Meanwhile, manganese steel resistance to grinding column toughness is 2 times of the powder sintered post of manganese steel.
Embodiment 3
Weigh the Fe70Mn30 powder of 10 kilogram of-200 mesh, WB (Me) powder of 1.3 kilograms 0.6 micron, and 150 grams of liquid Paraffin, is then sufficiently mixed three, is pressed into column by four-column press in grinding tool, loads compound leaf cured after 650 degree of dewaxings Using cubic hinge press to be sintered in stone, flow process, with embodiment 1, is taken out the resistance to grinding column of manganese steel, is compared sand with Standard erosion after pressure release The wheel mensuration resistance to grinding column of manganese steel is 7.5-8:1 with the relative wear ratio of silicon carbide grinding wheel.And under same testing standard: 45 steel (hardness HRC40) the relative wear ratio with silicon carbide grinding wheel is 0.3:1;GT20 hard alloy with the relative wear ratio of silicon carbide grinding wheel is 6:1.Meanwhile, manganese steel resistance to grinding column toughness is 2 times of the powder sintered post of manganese steel.
Embodiment 4
Weigh the Fe70Mn30 powder of 10 kilogram of-200 mesh, WB (Me) powder of 1.5 kilograms 0.8 micron, and 150 grams of liquid Paraffin, is then sufficiently mixed three, is pressed into column by four-column press in grinding tool, loads compound leaf cured after 650 degree of dewaxings Using cubic hinge press to be sintered in stone, flow process, with embodiment 1, is taken out the resistance to grinding column of manganese steel, is compared sand with Standard erosion after pressure release Wheel measure the resistance to grinding column of manganese steel and silicon carbide grinding wheel relative wear ratio be 8.5-9:1.And under same testing standard: 45 steel are (hard Degree HRC40) it is 0.3:1 with the relative wear ratio of silicon carbide grinding wheel;The relative wear ratio of GT20 hard alloy and silicon carbide grinding wheel It is 6:1.Meanwhile, manganese steel resistance to grinding column toughness is 2 times of the powder sintered post of manganese steel.
Embodiment 5
Weigh the Fe70Mn30 powder of 10 kilogram of-200 mesh, WB (Me) powder of 1.8 kilograms 1 micron, and 150 grams of liquid stones Wax, is then sufficiently mixed three, is pressed into column by four-column press, loads composite pyrophyllite after 650 degree of dewaxings in grinding tool Middle use cubic hinge press is sintered, and flow process, with embodiment 1, is taken out the resistance to grinding column of high abrasion manganese steel, used Standard erosion after pressure release It is 9.2-9.6:1 than the relative wear ratio of the emery wheel mensuration resistance to grinding column of manganese steel with silicon carbide grinding wheel.And under same testing standard: 45 steel (hardness HRC40) is 0.3:1 with the relative wear ratio of silicon carbide grinding wheel;GT20 hard alloy and the relative wear of silicon carbide grinding wheel Ratio is 6:1.Meanwhile, manganese steel resistance to grinding column toughness is 2 times of the powder sintered post of manganese steel.
In the present invention in embodiment, smelting the resistance to grinding column of the manganese steel and have wearability and toughness concurrently, the ratio of performance to price is higher than Vacuum or inert gas shielding sintering diamondite and titanium carbide alloy.Simultaneously because the manganese steel of the embodiment of the present invention is wear-resisting The fusing point of post only has 1080 degree, and diamondite and titanium carbide alloy melting point are higher than 1600 degree, the manganese steel of the embodiment of the present invention Resistance to grinding column and molten steel are easier to combination and do not fall off.
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all essences in the present invention Any amendment, equivalent and the improvement etc. made within god and principle, should be included within the scope of the present invention.

Claims (10)

1. the resistance to grinding column of manganese steel, it is characterised in that it is mainly prepared by following raw material: potassium steel powder and weight ratio are The WB of the 10.0%--20.0% of described potassium steel powdern(Me)。
The resistance to grinding column of manganese steel the most according to claim 1, it is characterised in that: above-mentioned WBn(Me) it is: WB (Me) or WB2 (Me)。
The resistance to grinding column of manganese steel the most according to claim 2, it is characterised in that: above-mentioned WBn(Me) particle size range is: 0.5-1.0 Micron.
The resistance to grinding column of manganese steel the most according to claim 1, it is characterised in that: above-mentioned WBn(Me) it is WB2(Me), granularity is 1 micro- Rice, WB2(Me) percentage ratio accounting for potassium steel powder weight is 10%.
The resistance to grinding column of manganese steel the most according to claim 1, it is characterised in that: above-mentioned WBn(Me) it is WB2(Me), granularity is 0.5 Micron, WB2(Me) percentage ratio accounting for potassium steel powder weight is 20%.
The resistance to grinding column of manganese steel the most according to claim 1, it is characterised in that: above-mentioned WBn(Me) being WB (Me), granularity is 0.6 micro- Rice, it is 13% that WB (Me) accounts for the percentage ratio of potassium steel powder weight.
The resistance to grinding column of manganese steel the most according to claim 1, it is characterised in that: above-mentioned WBn(Me) being WB (Me), granularity is 0.8 micro- Rice, it is 15% that WB (Me) accounts for the percentage ratio of potassium steel powder weight.
The resistance to grinding column of manganese steel the most according to claim 1, it is characterised in that: above-mentioned WBn(Me) being WB (Me), granularity is 1 micro- Rice, it is 18% that WB (Me) accounts for the percentage ratio of potassium steel powder weight.
9. the manufacture method of the resistance to grinding column of manganese steel, it is characterised in that it includes raw material: potassium steel powder, liquid paraffin And the WB of the 10.0%--20.0% that weight ratio is described potassium steel powdern(Me) it is sufficiently mixed, by four-column press at grinding tool In be pressed into column, load after dewaxing and composite pyrophyllite use cubic hinge press increasing temperature and pressure sintering, take out after pressure release.
Manufacture method the most according to claim 9, it is characterised in that described increasing temperature and pressure sintering includes: first 2 minutes Boosting to 70Mpa, pressurize begins to warm up after 5 seconds, heater power was raised to 1080 amperes in 10 seconds, will after being incubated 5 minutes again Electric current is raised to 1450 amperes for 110 seconds, and constant temperature stops heat supply in 3 minutes, and power returns to 0, then pressure release after two minutes, and pressure recovers To 0, sintering overall process was calculated according to the time providing electric current, was 10 minutes.
CN201610548882.4A 2016-07-12 2016-07-12 A kind of resistance to grinding column of manganese steel and manufacture method thereof Pending CN106064240A (en)

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