CN106047522B - A kind of anhydrous liquid detergent of hyperconcetration type and preparation method thereof and solidifying pearl of doing washing - Google Patents
A kind of anhydrous liquid detergent of hyperconcetration type and preparation method thereof and solidifying pearl of doing washing Download PDFInfo
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- CN106047522B CN106047522B CN201610503126.XA CN201610503126A CN106047522B CN 106047522 B CN106047522 B CN 106047522B CN 201610503126 A CN201610503126 A CN 201610503126A CN 106047522 B CN106047522 B CN 106047522B
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- liquid detergent
- polyoxyethylene ether
- anhydrous liquid
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
- C11D1/8305—Mixtures of non-ionic with anionic compounds containing a combination of non-ionic compounds differently alcoxylised or with different alkylated chains
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
- C11D17/043—Liquid or thixotropic (gel) compositions
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/08—Liquid soap, e.g. for dispensers; capsuled
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/28—Heterocyclic compounds containing nitrogen in the ring
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
- C11D3/42—Brightening agents ; Blueing agents
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups
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Abstract
The invention discloses a kind of anhydrous liquid detergents of hyperconcetration type and preparation method thereof and solidifying pearl of doing washing.According to the mass fraction, which includes: 1 part of cardanol polyoxyethylene ether, 0.2~1.0 part of cocoanut fatty acid diethanolamide, 0.2~1.0 part of AES, 0.2~1.0 part of AEO-10,1.0~2.0 parts of polyethylene glycol.The present invention is using cardanol polyoxyethylene ether, cocoanut fatty acid diethanolamide, AES and AEO-10 as main active, there is good compatibility between each surfactant, simultaneously also using the polyethylene glycol equally with scourability as solvent, the scourability of the anhydrous liquid detergent of hyperconcetration type of the present invention is further increased；Used surfactant is plant base green surfactant or polyethers natural products derivative, and to people and animals' nonhazardous, no pollution to the environment, bio-compatibility is good；It is easy to transport and store, greatly reduces transportation cost.
Description
Technical field
The present invention relates to a kind of daily detergent, and in particular to a kind of anhydrous liquid detergent of hyperconcetration type and preparation method thereof and
It does washing and coagulates pearl.
Background technique
With world economy integration and trade globalization development, culture to strength, technical level and environmental regulation by
Gradually become three large driving forces of articles for washing development of globalization, global articles for washing would tend to diversification, but energy conservation, section
Water, product efficient, mild, easy to use and meeting safety and environmental requirement will be that the current and following cleaning product develops
Main flow direction.
Due to bright containing the largely filler member without any cleaning function in traditional washing powder (including non-phosphide detergent)
Powder, mass fraction >=40% cause great waste in terms of resource and the energy, also will cause powder in process of production
Dustiness dye, is unfavorable for environmental protection.
Liquid detergent is made with resourceful and inexpensive water instead of anhydrous sodium sulphate, and using biodegradable surfactant
For main component and it is aided with phosphorus-free adjuvant and compounds.Due to having, equipment investment is few, production technology is easy, performance is mildly stingless
The features such as sharp, easy to dissolve and easy to use, liquid detergent is gradually accepted by people.
The water content of general liquid detergent is 80~90%, in order to pursue higher clean power, reduction transportation cost, reduce and wash
There is a large amount of concentrated type laundry liquid product in the market in clothing liquid usage amount, while some anhydrous laundry liquid products also occurs.
If the Chinese invention patent application of 104818167 A of Publication No. CN discloses a kind of anhydrous liquid detergent, with weight percent
Meter, the anhydrous liquid detergent include: sodium sulfate of polyethenoxy ether of fatty alcohol 8~12%, nonionic surface active agent 16~24%,
Fatty acid potassium soap 2~6%, enzyme 0.1~0.5%, anhydrous citric acid sodium 0.1~0.3%, essence 0.1~0.5%, preservative
0.02~0.12%, pigment 0.03~0.14%, solvent 57~73%.Wherein, the nonionic surface active agent is fat
At least one of sour methyl ester ethoxylates, aliphatic alcohol polyethenoxy (9) ether and aliphatic alcohol polyethenoxy (7) ether.
The anhydrous liquid detergent is disadvantageous in that: (1) its active constituent (sodium sulfate of polyethenoxy ether of fatty alcohol, it is non-from
Subtype surfactant, fatty acid potassium soap) content is between 26~42%, and the content of active constituent is still not counting high, solvent content
Higher, transportation cost is still higher；
(2) contain fatty acid methyl ester ethoxylate in the nonionic surface active agent that it is used, and fatty acid methyl ester
One of raw material of ethoxylate fatty acid methyl ester does not contain active hydrogen, it is difficult to ethoxylation occur, in fatty acid methyl ester
In the production process of ethoxylate, the production technology that most of manufacturer uses is to use water as raising ethoxylation yield
Solvent, therefore the product of technical grade contains more moisture, is unable to get the fatty acid methyl ester ethoxylate of high-content,
High purity product can only be obtained by low-pressure distillation, if reagent grade (medicine analysis is pure) can accomplish 99% or more content,
This not only substantially increases the production cost of fatty acid methyl ester ethoxylate, also substantially increases the production of the anhydrous liquid detergent
Cost；
(3) fatty acid methyl ester ethoxylate returns back out existing muddy, opaque phenomenon at low ambient temperatures, to influence anhydrous
The detergency ability of liquid detergent at low ambient temperatures.
Summary of the invention
The present invention provides a kind of anhydrous liquid detergents of hyperconcetration type, solve active constituent in the anhydrous liquid detergent of the prior art
The problem of low, high production cost.
A kind of anhydrous liquid detergent of hyperconcetration type, according to the mass fraction, comprising:
The present invention is with cardanol polyoxyethylene ether, cocoanut fatty acid diethanolamide, fatty alcohol polyoxyethylene ether sulfuric acid
Sodium and fatty alcohol polyoxyethylene ether also use polyethylene glycol conduct equally with scourability as main active
Solvent, in the case where only regarding polyethylene glycol as solvent, the content of active component minimum 44%, up to 80% or more,
Active component content is high, has good compatibility between each component, and polyethylene glycol had not only been used as solvent but also had been used as active component, into
One step improves the scourability of the anhydrous liquid detergent of hyperconcetration type of the present invention, so that the anhydrous liquid detergent of hyperconcetration type of the present invention is easy to transport
Defeated and storage, greatly reduces transportation cost.
The present invention is using cardanol polyoxyethylene ether and cocoanut fatty acid diethanolamide as main non-ionic table
Face activating agent, both nonionic surface active agent are all plant base green surfactants, not only have excellent chemistry
Property, and it is nontoxic to human body, livestock, the environmental nonpollution in existence, the bio-compatibility of emission are relied to the mankind
It is good, it can be biodegradable quickly.
Wherein, cardanol polyoxyethylene ether is the straight chained alkyl phenol polyethenoxy ether produced using anacardol as raw material, not only
Production cost is low, yield is high, and anacardol is a kind of natural phenol of reproducible environment-friendly type, can substitute or part substitutes benzene
Phenol；One of raw material of cocoanut fatty acid diethanolamide is also natural coconut oil, can substitute alkyl quaternaries sun from
Sub- surfactant；So as to avoid using produced by conventional petroleum based raw material under the premise of guaranteeing heavy duty wash performance
Environmental pollution, human body irritation problem.
Also, sodium sulfate of polyethenoxy ether of fatty alcohol and fatty alcohol polyoxyethylene ether are that polyethers natural products is derivative
Object, the advantages of being likewise supplied with easily biological-degradable and non-environmental-pollution.
Since cardanol polyoxyethylene ether, fatty alcohol polyoxyethylene ether and fatty alcohol polyoxyethylene ether are non-ionic
Surfactant, and sodium sulfate of polyethenoxy ether of fatty alcohol is anionic surfactant, two class surfactants are in water
Dissolubility differ greatly.In order to guarantee uniform anhydrous liquid detergent system of the invention, balance, stablize, preferably, the waist
The hydrophilic lipophilic balance (HLB value) of fruit phenol polyethenoxy ether is 9~25；Preferably, the fatty alcohol polyoxyethylene ether is
Fatty alcohol polyoxyethylene ether AEO-7, AEO-9, AEO-10, AEO-15 or AEO-20；Preferably, the coco-nut oil fatty acid two
Glycollic amide is cocoanut fatty acid diethanolamide 6501,6502 or 6503.
Preferably, the polyethylene glycol is polyethylene glycol 100, polyethylene glycol 200, polyethylene glycol 400, polyethylene glycol
600 or polyethylene glycol-800；More preferably polyethylene glycol 400.
Preferably, according to the mass fraction, the anhydrous liquid detergent of hyperconcetration type includes:
Under the proportion, the active constituent of the anhydrous liquid detergent of hyperconcetration type is high, the compatibility between each component more preferably, system
Stablize, more preferably, shelf life of products is longer for scourability.
Preferably, according to the mass fraction, the anhydrous liquid detergent of hyperconcetration type further include:
As further preferred, according to the mass fraction, the anhydrous liquid detergent of hyperconcetration type further include:
Wherein, the addition of antistatic agent is conducive to that the clothing after washing is made to keep fluffy, is not likely to produce electrostatic.Hard water resistance dose
Addition be conducive to chelate water in calcium ions and magnesium ions, prevent calcium ions and magnesium ions influence liquid detergent scourability.Alkali protease
Addition is conducive to improve the anhydrous liquid detergent of hyperconcetration type of the invention to the washing effect of protein stain on clothing.
Preferably, according to the mass fraction, the anhydrous liquid detergent of hyperconcetration type of the present invention includes:
Under the formula, the active component content of the anhydrous liquid detergent of hyperconcetration type of the present invention is up to 88%, washing performance
It can reach best.
Preferably, the antistatic agent is at least one of oleic acid, palm oil and lauric acid.It is used in the present invention
Antistatic agent is natural products ingredient, and bio-compatibility is good, to the non-stimulated injury of human body.
As further preferred, the antistatic agent is oleic acid.Oleic acid is also equipped with certain other than as antistatic agent
Scourability can be improved the washing effect of liquid detergent.
Preferably, described hard water resistance dose in anhydrous citric acid sodium, citric acid and disodium ethylene diamine tetraacetate at least
It is a kind of.
As further preferred, described hard water resistance dose is anhydrous citric acid sodium.Anhydrous citric acid sodium is not only had excellent performance, and
And as a kind of natural products ingredient, there is excellent bio-compatibility.
Preferably, the preservative is at least one of Kathon CG, Jie Ma and matrine.
As further preferred, the preservative is matrine.
The present invention also provides a kind of preparation method of anhydrous liquid detergent of hyperconcetration type, which includes:
(1) at room temperature, by preset mass fraction, by cardanol polyoxyethylene ether, cocoanut fatty acid diethanolamide,
Sodium sulfate of polyethenoxy ether of fatty alcohol, fatty alcohol polyoxyethylene ether and antistatic agent are dissolved in polyethylene glycol, are stirred to completely molten
It is slowly heated to 25~80 DEG C after solution, obtains sticky clear solution I；
Be heated to 25~80 DEG C and be in order to improve hard water resistance dose of subsequent addition (anhydrous citric acid sodium), alkali protease,
The solution rate of preservative and pigment, between 0~100 DEG C, not heating theoretically can also delay the solution temperature of these substances
Slow dissolution.Preferably, optimal solution temperature is 60 DEG C.At such a temperature, each substance can quickly dissolve, and can also prevent alkalinity
Protease is denaturalized at relatively high temperatures.
(2) preset mass fraction is pressed, hard water resistance dose, preservative, basic protein is added into the sticky clear solution I
Enzyme and pigment are stirred to after being completely dissolved at 25~80 DEG C and are cooled to room temperature, and essence is added, and stirring to solution is clarified, and are obtained
Clear solution II；
(3) deicer is added in Xiang Suoshu clear solution II, is filtered after dry, obtains the hyperconcetration type without water washing
Liquid.
The addition of deicer is beneficial to prevent a small amount of moisture carried in raw material or a small amount of water brought into during the preparation process
Dry about 1h can completely remove the moisture in product after dividing the performance for influencing final products, deicer to be added, after the completion of dry
It filters and removes deicer.
Preferably, the deicer is anhydrous sodium sulfate, anhydrous magnesium sulfate, molecular sieve or silica gel.More preferably molecule
Sieve.
Preferably, according to the mass fraction, the additional amount of the deicer is 0.05~0.5 part, more preferably 0.1~
0.3 part, most preferably 0.2 part.
The present invention also provides a kind of solidifying pearl of doing washing, which coagulates pearl and includes water-soluble film layer and sealed by the water-soluble film layer
The liquid detergent of package, the liquid detergent are the anhydrous liquid detergent of hyperconcetration type of the present invention.
Compared with prior art, the invention has the benefit that
(1) present invention is with cardanol polyoxyethylene ether, cocoanut fatty acid diethanolamide, fatty alcohol polyoxyethylene ether sulphur
Sour sodium and fatty alcohol polyoxyethylene ether are as main active, wherein cardanol polyoxyethylene ether and coco-nut oil fatty acid two
Glycollic amide is all plant base green surfactant, not only has excellent chemical property, but also to human body, the nontoxic nothing of livestock
The mankind are relied the environmental nonpollution in existence, the bio-compatibility of emission is good, can be biodegradable quickly, fatty alcohol by evil
Polyethenoxy ether sodium sulfate and fatty alcohol polyoxyethylene ether are polyethers natural products derivative, are likewise supplied with easily biological-degradable
And the advantages of non-environmental-pollution；
(2) there is good compatibility, while also use equally has between each surfactant used in the present invention
The polyethylene glycol of scourability further increases the scourability of the anhydrous liquid detergent of hyperconcetration type of the present invention as solvent, so that
The anhydrous liquid detergent of hyperconcetration type of the present invention is easy to transport and storage, greatly reduces transportation cost；
(3) according to national standard QB/T1224-2012 " dress material washes agent by liquid " to hyperconcetration type of the invention without water washing
Liquid carries out quality testing, and indices meet the requirements, wherein gross activity object accounting 88%, pH6.8, total phosphorus pentoxide account for
Than less than 0.1%, in high temperature ((40 ± 2) DEG C restore afterwards for 24 hours to room temperature), low temperature ((- 5 ± 2) DEG C restore afterwards for 24 hours to room temperature)
Good stability is all had under environment, standard liquid detergent test concentrations be 0,2%, sample test concentration be 0.1% before
It puts and carries out detergency detection, the detergency of the anhydrous liquid detergent of hyperconcetration type of the invention is all larger than standard liquid detergent, detergency
Up to 1.7 times of standard liquid detergent.
Specific embodiment
Technical solution of the present invention is described in further detail using specific embodiment below.
Embodiment 1
A kind of anhydrous liquid detergent of hyperconcetration type of the present embodiment, preparation method include:
(1) at room temperature, by 100.0g cardanol polyoxyethylene ether (HLB 18), 30.0g coco-nut oil fatty acid diethanol acyl
Amine (6501), 30.0g sodium sulfate of polyethenoxy ether of fatty alcohol (AES), 45.0g fatty alcohol polyoxyethylene ether (AEO-10) and 5.0g
Oleic acid is dissolved in 150mL polyethylene glycol 400, is stirred to being completely dissolved, is heated slowly to 60 DEG C, obtains sticky clear solution I；
(2) anhydrous citric acid sodium 15.0g, alkali protease 20.0g, matrine are added into the sticky clear solution I of gained
2.5g and pigment brilliant blue 0.36g, solution temperature are maintained at 60 DEG C, and after stirring to solid dissolution, stirring is cooled to room temperature, and Cape jasmine is added
Sub- extrait 20.0g, stirring to liquid are clarified, and clear solution II is obtained；
(3) molecular sieve 20.0g is added into gained clear solution II, dry 1.0h filters, obtains the hyperconcetration of the present embodiment
The anhydrous liquid detergent 401.2g of type.
Embodiment 2
A kind of anhydrous liquid detergent of hyperconcetration type of the present embodiment, preparation method include:
(1) at room temperature, by 100.0g cardanol polyoxyethylene ether (HLB 20), 20.0g coco-nut oil fatty acid diethanol acyl
Amine (6501), 100.0g sodium sulfate of polyethenoxy ether of fatty alcohol (AES), 20.0g fatty alcohol polyoxyethylene ether (AEO-20) and
2.0g palm oil is dissolved in 100mL polyethylene glycol 100, is stirred to being completely dissolved, is heated slowly to 60 DEG C, obtains sticky clear solution
Ⅰ；
(2) citric acid 10.0g, alkali protease 30.0g, Kathon CG 1.0g and color are added into the sticky clear solution I of gained
Plain brilliant blue 0.1g, solution temperature are maintained at 60 DEG C, and after stirring to solid dissolution, stirring is cooled to room temperature, and jasmine flower essence is added
8.0g, stirring to liquid are clarified, and clear solution II is obtained；
(3) anhydrous sodium sulfate 10.0g is added into gained clear solution II, dry 1.0h is filtered, and obtains the super of the present embodiment
The anhydrous liquid detergent 386.1g of concentrated type.
Embodiment 3
A kind of anhydrous liquid detergent of hyperconcetration type of the present embodiment, preparation method include:
(1) at room temperature, by 100.0g cardanol polyoxyethylene ether (HLB 9), 80.0g coco-nut oil fatty acid diethanol acyl
Amine (6502), 30.0g sodium sulfate of polyethenoxy ether of fatty alcohol (AES), 50.0g fatty alcohol polyoxyethylene ether (AEO-9) and 6.0g
Lauric acid is dissolved in 180mL polyethylene glycol 200, is stirred to being completely dissolved, is heated slowly to 60 DEG C, obtains sticky clear solution I；
(2) EDTA 18.0g, alkali protease 10.0g, outstanding person horse 2.5g and pigment are added into the sticky clear solution I of gained
Brilliant blue 0.5g, solution temperature are maintained at 60 DEG C, and after stirring to solid dissolution, stirring is cooled to room temperature, and rose essence is added
30.0g, stirring to liquid are clarified, and clear solution II is obtained；
(3) anhydrous magnesium sulfate 30.0g is added into gained clear solution II, dry 1.0h is filtered, and obtains the super of the present embodiment
The anhydrous liquid detergent 500.3g of concentrated type.
Embodiment 4
A kind of anhydrous liquid detergent of hyperconcetration type of the present embodiment, preparation method include:
(1) at room temperature, by 100.0g cardanol polyoxyethylene ether (HLB 25), 30.0g coco-nut oil fatty acid diethanol acyl
Amine (6501), 60.0g sodium sulfate of polyethenoxy ether of fatty alcohol (AES), 30.0g fatty alcohol polyoxyethylene ether (AEO-7) and 4.0g
Oleic acid is dissolved in 120mL Macrogol 600, is stirred to being completely dissolved, is obtained sticky clear solution I；
(2) anhydrous citric acid sodium 25.0g, alkali protease 15.0g, matrine are added into the sticky clear solution I of gained
1.5g and pigment brilliant blue 0.2g, after stirring to solid dissolution, stirring is cooled to room temperature, lavender oil 10.0g is added, stirring is extremely
Liquid clarification, obtains clear solution II；
(3) silica gel 20.0g is added into gained clear solution II, dry 1.0h filters, obtains the hyperconcetration type of the present embodiment
Anhydrous liquid detergent 388.1g.
Embodiment 5
A kind of anhydrous liquid detergent of hyperconcetration type of the present embodiment, preparation method include:
(1) at room temperature, by 100.0g cardanol polyoxyethylene ether (HLB 15), 100.0g coco-nut oil fatty acid diethanol
Amide (6503), 20.0g sodium sulfate of polyethenoxy ether of fatty alcohol (AES), 100.0g fatty alcohol polyoxyethylene ether (AEO-15) and
10.0g oleic acid is dissolved in 200mL polyethylene glycol-800, is stirred to being completely dissolved, is heated slowly to 80 DEG C, obtains sticky clear solution
Ⅰ；
(2) anhydrous citric acid sodium 12.0g, alkali protease 50.0g, matrine are added into the sticky clear solution I of gained
3.0g and pigment brilliant blue 1.0g, solution temperature are maintained at 80 DEG C, and after stirring to solid dissolution, stirring is cooled to room temperature, is added thin
Lotus essence 50.0g, stirring to liquid are clarified, and clear solution II is obtained；
(3) anhydrous sodium sulfate 50.0g is added into gained clear solution II, dry 1.0h is filtered, and obtains the super of the present embodiment
The anhydrous liquid detergent 625.1g of concentrated type.
Comparative example 1
A kind of anhydrous liquid detergent of hyperconcetration type of this comparative example, preparation method include:
(1) at room temperature, by 100.0g cardanol polyoxyethylene ether (HLB 18), 30.0g coco-nut oil fatty acid diethanol acyl
Amine (6501), 30.0g sodium sulfate of polyethenoxy ether of fatty alcohol (AES), 45.0g fatty alcohol polyoxyethylene ether (AEO-10) and 5.0g
Oleic acid is dissolved in 150mL D-pantothenyl aleohol, is stirred to being completely dissolved, is heated slowly to 60 DEG C, obtains sticky clear solution I；
(2) anhydrous citric acid sodium 15.0g, alkali protease 20.0g, matrine are added into the sticky clear solution I of gained
2.5g and pigment brilliant blue 0.36g, solution temperature are maintained at 60 DEG C, and after stirring to solid dissolution, stirring is cooled to room temperature, and osmanthus is added
Extrait 20.0g, stirring to liquid are clarified, and clear solution II is obtained；
(3) molecular sieve 20.0g is added into gained clear solution II, dry 1.0h filters, obtains the hyperconcetration of the present embodiment
The anhydrous liquid detergent 401.5g of type.
Comparative example 2
A kind of anhydrous liquid detergent of hyperconcetration type of this comparative example, preparation method include:
(1) at room temperature, by 110.0g cardanol polyoxyethylene ether (HLB 18), 40.0g fatty alcohol polyoxyethylene ether sulfuric acid
Sodium (AES), 55.0g fatty alcohol polyoxyethylene ether (AEO-10) and 5.0g oleic acid are dissolved in 150mL polyethylene glycol 400, and stirring is extremely
It is completely dissolved, is heated slowly to 60 DEG C, obtain sticky clear solution I；
(2) anhydrous citric acid sodium 15.0g, alkali protease 20.0g, matrine are added into the sticky clear solution I of gained
2.5g and pigment brilliant blue 0.36g, solution temperature are maintained at 60 DEG C, and after stirring to solid dissolution, stirring is cooled to room temperature, and Cape jasmine is added
Sub- extrait 20.0g, stirring to liquid are clarified, and clear solution II is obtained；
(3) molecular sieve 20.0g is added into gained clear solution II, dry 1.0h filters, obtains the hyperconcetration of the present embodiment
The anhydrous liquid detergent 402.2g of type.
Comparative example 3
A kind of anhydrous liquid detergent of hyperconcetration type of this comparative example, preparation method include:
(1) at room temperature, by 110.0g cardanol polyoxyethylene ether (HLB 18), 40.0g coco-nut oil fatty acid diethanol acyl
Amine (6501), 55.0g fatty alcohol polyoxyethylene ether (AEO-10) and 5.0g oleic acid are dissolved in 150mL polyethylene glycol 400, and stirring is extremely
It is completely dissolved, is heated slowly to 60 DEG C, obtain sticky clear solution I；
(2) anhydrous citric acid sodium 15.0g, alkali protease 20.0g, matrine are added into the sticky clear solution I of gained
2.5g and pigment brilliant blue 0.36g, solution temperature are maintained at 60 DEG C, and after stirring to solid dissolution, stirring is cooled to room temperature, and water is added
Honey peach essence 20.0g, stirring to liquid are clarified, and clear solution II is obtained；
(3) molecular sieve 20.0g is added into gained clear solution II, dry 1.0h filters, obtains the hyperconcetration of the present embodiment
The anhydrous liquid detergent 401.8g of type.
Comparative example 4
A kind of anhydrous liquid detergent of hyperconcetration type of this comparative example, preparation method include:
(1) at room temperature, by 110.0g cocoanut fatty acid diethanolamide (6501), 40.0g fatty alcohol polyoxyethylene ether
Sodium sulphate (AES), 55.0g fatty alcohol polyoxyethylene ether (AEO-10) and 5.0g oleic acid are dissolved in 150mL polyethylene glycol 400, are stirred
It mixes to being completely dissolved, is heated slowly to 60 DEG C, obtain sticky clear solution I；
(2) anhydrous citric acid sodium 15.0g, alkali protease 20.0g, matrine are added into the sticky clear solution I of gained
2.5g and pigment brilliant blue 0.36g, solution temperature are maintained at 60 DEG C, and after stirring to solid dissolution, stirring is cooled to room temperature, and lemon is added
Lemon orange essence 20.0g, stirring to liquid are clarified, and clear solution II is obtained；
(3) molecular sieve 20.0g is added into gained clear solution II, dry 1.0h filters, obtains the hyperconcetration of the present embodiment
The anhydrous liquid detergent 402.4g of type.
Test case
Above-described embodiment 1~5, comparative example 1~4 are made according to national standard QB/T1224-2012 " dress material washes agent by liquid "
The anhydrous liquid detergent of the hyperconcetration type obtained carries out quality testing, and testing result is shown in Tables 1 and 2.
The quality measurements of 1 embodiment of table, the 1 anhydrous liquid detergent of hyperconcetration type
Note: (a) standard liquid detergent test concentrations are 0.2%, and sample test concentration is 0.1%, similarly hereinafter.
The quality measurements of 2 embodiment 2~5 of table, 1~4 anhydrous liquid detergent of hyperconcetration type of comparative example
Note: (b) is identical as each detection project in table 1, identical detection project serial number having the same；S2~S5 indicates real
Example 2~5 is applied, D1~D4 indicates comparative example 1~4.
By Tables 1 and 2 as it can be seen that the indices of the anhydrous liquid detergent of hyperconcetration type of Examples 1 to 5 meet the requirements,
In, for gross activity object accounting in 80% or more, pH6.8, total phosphorus pentoxide accounting is respectively less than 0.1%, high temperature (40 ± 2 DEG C,
Restore afterwards for 24 hours to room temperature), all have good stability under low temperature (- 5 ± 2 DEG C, restore afterwards for 24 hours to room temperature) environment, in standard
Liquid detergent test concentrations be 0,2%, sample test concentration be 0.1% under the premise of carry out detergency detection, Examples 1 to 5
The detergency of the anhydrous liquid detergent of hyperconcetration type is all larger than standard liquid detergent, wherein the anhydrous liquid detergent of hyperconcetration type of embodiment 1
The detection of JB-03 detergency is 1.7 times of standard liquid detergent.
As can be seen from Table 2, the appearance of comparative example 1~4, smell, stability, gross activity object content, pH and total five oxidation two
Phosphorus content meets the requirements, but standard liquid detergent test concentrations be 0,2%, sample test concentration be 0.1% under the premise of, comparison
The detergency index of each anhydrous liquid detergent of hyperconcetration type of example 1~4 is slightly inferior to standard liquid detergent.
Claims (6)
1. a kind of anhydrous liquid detergent of hyperconcetration type, which is characterized in that according to the mass fraction, comprising:
1 part of cardanol polyoxyethylene ether；
0.3 part of cocoanut fatty acid diethanolamide；
0.3 part of sodium sulfate of polyethenoxy ether of fatty alcohol；
0.45 part of fatty alcohol polyoxyethylene ether；
1.5 parts of polyethylene glycol；
0.15 part of anhydrous citric acid sodium；
0.2 part of alkali protease；
0.05 part of oleic acid；
0.025 part of matrine；
0.0036 part of pigment brilliant blue；
0.2 part of cape jasmine extrait；
The polyethylene glycol is polyethylene glycol 400.
2. the anhydrous liquid detergent of hyperconcetration type as described in claim 1, which is characterized in that the parent of the cardanol polyoxyethylene ether
Hydrophile-lipophile balance value is 9~25.
3. the anhydrous liquid detergent of hyperconcetration type as described in claim 1, which is characterized in that the fatty alcohol polyoxyethylene ether is rouge
Fat alcohol polyoxyethylene ether AEO-7, AEO-9, AEO-10, AEO-15 or AEO-20.
4. the anhydrous liquid detergent of hyperconcetration type as described in claim 1, which is characterized in that the coco-nut oil fatty acid diethanol acyl
Amine is cocoanut fatty acid diethanolamide 6501,6502 or 6503.
5. the preparation method of the anhydrous liquid detergent of hyperconcetration type as described in Claims 1 to 4 is any characterized by comprising
(1) at room temperature, by preset mass fraction, by cardanol polyoxyethylene ether, cocoanut fatty acid diethanolamide, fat
Alcohol polyethenoxy ether sodium sulfate, fatty alcohol polyoxyethylene ether and oleic acid are dissolved in polyethylene glycol 400, and stirring is delayed to after being completely dissolved
Slowly 60 DEG C are heated to, obtain sticky clear solution I；
(2) preset mass fraction is pressed, anhydrous citric acid sodium, alkali protease, hardship are added into the sticky clear solution I
Join alkali and pigment brilliant blue, stir to after being completely dissolved and be cooled to room temperature at 60 DEG C, cape jasmine extrait is added, stirs clear to solution
Clearly, clear solution II is obtained；
(3) deicer is added in Xiang Suoshu clear solution II, the deicer is molecular sieve, is filtered after dry, is obtained described super
The anhydrous liquid detergent of concentrated type.
6. a kind of solidifying pearl of doing washing, including water-soluble film layer and by the liquid detergent of the water-soluble film layer sealed envelope, which is characterized in that institute
Stating liquid detergent is the anhydrous liquid detergent of hyperconcetration type as described in Claims 1 to 4 is any.
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| CN107955152A (en) * | 2017-11-27 | 2018-04-24 | 山东诺威新材料有限公司 | Cardanol polyoxyethylene ether, its preparation method and its preparation method of the without phosphorus laundry sheet of preparation and without phosphorus laundry sheet |
| CN108559678A (en) * | 2018-06-19 | 2018-09-21 | 福建省金鹿日化股份有限公司 | Four times of concentration liquid detergents of a kind of microcapsules perfume sweet smell and preparation method thereof |
| CN108795588B (en) * | 2018-07-31 | 2021-01-26 | 福建植嘉生物科技有限公司 | Enzyme-containing laundry gel ball and preparation method thereof |
| CN109679778B (en) * | 2018-12-03 | 2021-05-04 | 常熟耐素生物材料科技有限公司 | Low-foam low-viscosity laundry detergent and preparation method thereof |
| CN109868191A (en) * | 2019-03-21 | 2019-06-11 | 福建省纯杰绿色科技有限公司 | A kind of plant cleaning agent for human secretion cleaning |
| CN111117795A (en) * | 2019-12-31 | 2020-05-08 | 长沙如洋环保科技有限公司 | Environment-friendly concentrated laundry detergent with sterilization and mite removal functions and preparation method thereof |
| CN111690475B (en) * | 2020-05-15 | 2021-08-31 | 泉后(广州)生物科技研究院有限公司 | Hard water-resistant high-efficiency active matter composition and application thereof |
| CN114085718B (en) * | 2021-11-12 | 2024-05-24 | 东莞市建文洗涤用品有限公司 | Concentrated laundry detergent and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101463294A (en) * | 2008-08-28 | 2009-06-24 | 王先军 | Hyperconcentration oil stain rapid cleaning agent and production method thereof |
| CN103343065A (en) * | 2013-07-08 | 2013-10-09 | 山东丽波日化股份有限公司 | Non-water-based high-active-substance-content clothing detergent, preparation method thereof and packaging bag therefor |
| CN103666822A (en) * | 2012-09-12 | 2014-03-26 | 上海得高实业有限公司 | Anacardol polyoxyethylene ether laundry detergent |
| CN103695197A (en) * | 2013-12-04 | 2014-04-02 | 佛山市新战略知识产权文化有限公司 | High-concentration laundry detergent |
| CN105062703A (en) * | 2015-07-27 | 2015-11-18 | 东莞市香与化工有限公司 | Protease super-concentrated laundry detergent and preparation method thereof |
-
2016
- 2016-06-27 CN CN201610503126.XA patent/CN106047522B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101463294A (en) * | 2008-08-28 | 2009-06-24 | 王先军 | Hyperconcentration oil stain rapid cleaning agent and production method thereof |
| CN103666822A (en) * | 2012-09-12 | 2014-03-26 | 上海得高实业有限公司 | Anacardol polyoxyethylene ether laundry detergent |
| CN103343065A (en) * | 2013-07-08 | 2013-10-09 | 山东丽波日化股份有限公司 | Non-water-based high-active-substance-content clothing detergent, preparation method thereof and packaging bag therefor |
| CN103695197A (en) * | 2013-12-04 | 2014-04-02 | 佛山市新战略知识产权文化有限公司 | High-concentration laundry detergent |
| CN105062703A (en) * | 2015-07-27 | 2015-11-18 | 东莞市香与化工有限公司 | Protease super-concentrated laundry detergent and preparation method thereof |
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