CN106046995A - Mildew-proof coating for automobile storage box and preparation method thereof - Google Patents
Mildew-proof coating for automobile storage box and preparation method thereof Download PDFInfo
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- CN106046995A CN106046995A CN201610669106.XA CN201610669106A CN106046995A CN 106046995 A CN106046995 A CN 106046995A CN 201610669106 A CN201610669106 A CN 201610669106A CN 106046995 A CN106046995 A CN 106046995A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Plant Pathology (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a mildew-proof coating for an automobile storage box, wherein the mildew-proof coating is prepared from the following raw materials: hydroxy acrylic acid resin, a vinyl acetate-acrylic emulsion, cellulose resin, alkyd resin, nano-zinc oxide, a preservative, a catalyst, a thickener, super-fine calcium carbonate, diatomite, ethylene glycol monobutyl ether acetate, propylene glycol monomethyl ether, deionized water, and pentaerythritol. A preparation method comprises the following steps successively: (1) uniformly stirring the corresponding raw materials; (2) preparing a mixed solution; (3) preparing a coating mixed solution; and (4) grinding the coating mixed solution, and filtering to obtain the finished product. The product has excellent performance and has good mildew-proof performance, the surface of a coating layer is level, delicate, smooth, and good in gloss retention, and the coating has tensile strength and elongation at break both superior to those of an ordinary coating and can meet corrosion prevention, weather-proof performance and other use requirements of the automobile storage box on box body coating; the preparation method is simple, relatively low in cost, and suitable for industrialized mass production.
Description
Technical field
The present invention relates to coating industry field, particularly relate to a kind of mildew resistant paint for automobile collection box and preparation side thereof
Method.
Background technology
Along with the development of social life level, nowadays increasing people have the private car of oneself, Automobile Products
Motor Maintenance articles for use have the most just become the essential part of vehicle maintenance in other words, as three macroplates in market after automobile
One of, Automobile Products market is also one of industry the most with fastest developing speed, that prospect is best.Blowout along with Domestic Automotive Industry
Formula develops, and Automobile Products industry development speed is at a tremendous pace, and according to statistics, 2011, China's Automobile Products series products gross output value was just
430,000,000,000 yuans are reached, family more than ten thousand more than more than 10 of Automobile Products industry distributing business of current China.Along with Chinese Government
Gradually pay attention to Automobile Products industry, actively push forward the industrialization of Automobile Products, encourage the technological innovation of Automobile Products industry, government
Also in relevant laws and regulations and the standard of gradual perfection Automobile Products industry, for the competition ring that the development offer of Automobile Products enterprise is orderly
Border.Simultaneously Automobile Products enterprise also should constantly autonomous innovation, introduce and cultivate professional, catching the good of Automobile Products industry
Opportunity to develop.
Containing box in Automobile Products is mainly placed in automobile trunk, is used for depositing article.At present, people are for vapour
Article in the interior material of car and automobile are increasingly paid attention to, to the requirement of the aspects such as the coating property of Automobile Products, environmental protection more
Come the highest, but can't be met, in the face of the huge market demand and the ever-increasing application of Automobile Products coating
Prospect, need to develop technically, on cost, more show the coating of powerful competitive advantage in performance so that it is to automobile
Articles for use have well protection and decoration.
Summary of the invention
The invention aims to overcome the deficiencies in the prior art, it is provided that a kind of preventing for automobile collection box
Mould coating and preparation method thereof, this coating products excellent performance, there is good fungicidal properties, and meet environmental requirement.
For solve above-mentioned technical problem, the present invention by the following technical solutions:
A kind of mildew resistant paint for automobile collection box, it is characterised in that be prepared by the raw materials in: hydroxyl third
Olefin(e) acid resin 15～35 parts, acrylate and vinyl acetate emulsion 5～20 parts, celluosic resin 5～20 parts, alkyd resin 2～10 parts, nano zine oxide
1～5 part, preservative 0.2～1 part, catalyst 1～5 parts, thickening agent 0.2～1.5 parts, calcium carbonate superfine powder 1～5 parts, kieselguhr 1
～5 parts, 2-Butoxyethyl acetate 0.2～1 part, propylene glycol monomethyl ether 0.3～2 parts, deionized water 20～50 parts, tetramethylolmethane 2
～10 parts；
Its preparation method in turn includes the following steps:
(1) by Hydroxylated acrylic resin, acrylate and vinyl acetate emulsion, celluosic resin, alkyd resin, nano zine oxide and deionized water
Putting in reaction vessel, controlling temperature is 50～60 DEG C, stirs and makes mixture dispersed in 15～30 minutes；
(2) again calcium carbonate superfine powder, kieselguhr, 2-Butoxyethyl acetate and propylene glycol monomethyl ether are joined reaction vessel
In, it is stirred continuously until mix homogeneously, temperature is risen to 70～75 DEG C and carries out being heated at reflux 1～1.5 hour, be finally slowly added to
Tetramethylolmethane, and stirring and dissolving 0.5～1 hour, obtain mixed solution；
(3) mixed solution that step (2) prepares is cooled to 20～30 DEG C, then is separately added into preservative, catalyst and increasing
Thick dose, it is kept stirring for 20～50 minutes, obtains coating mixed liquor；
(4) the coating mixed liquor that step (3) prepares is entered sand mill to grind 4～6 times, filter to obtain finished product.
Preferably, described preservative is isothiazolinone derivatives.
Preferably, described catalyst is sodium sulfonate.
Preferably, described thickening agent is carboxymethyl cellulose.
The present invention is had advantageous effect in that compared with prior art:
The present invention mostly is plastic material in view of automobile collection box, and its lower hardness, the feature of surface not scratch resistance, by adopting
With combination property preferably high-molecular organic material and carry out optimum organization, improve the fungicidal properties of compositions, use this
The bright coating surface obtained is smooth, fine and smooth, smooth, and gloss retention is good, and hot strength and elongation at break are superior to common coating, energy
Meet automobile collection box and the anticorrosion of casing application, weather-proof etc. is used requirement；Present invention achieves the abundant profit of resource and the energy
With, production process is environment friendly and pollution-free, and its preparation method is simple, and cost is relatively low, with short production cycle, has convenient transportation, it is easy to storage
Deposit, the feature such as easy to use, be suitable to industrialized mass production.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1:
A kind of mildew resistant paint for automobile collection box, it is characterised in that be prepared by the raw materials in: hydroxyl third
Olefin(e) acid resin 15 parts, acrylate and vinyl acetate emulsion 5 parts, celluosic resin 5 parts, alkyd resin 2 parts, nano zine oxide 1 part, preservative 0.2 part,
Catalyst 1 part, thickening agent 0.2 part, calcium carbonate superfine powder 1 part, 1 part of kieselguhr, 2-Butoxyethyl acetate 0.2 part, propylene glycol first
0.3 part of ether, deionized water 20 parts, tetramethylolmethane 2 parts；
Its preparation method in turn includes the following steps:
(1) by Hydroxylated acrylic resin, acrylate and vinyl acetate emulsion, celluosic resin, alkyd resin, nano zine oxide and deionized water
Putting in reaction vessel, controlling temperature is 50～60 DEG C, stirs and makes mixture dispersed in 15 minutes；
(2) again calcium carbonate superfine powder, kieselguhr, 2-Butoxyethyl acetate and propylene glycol monomethyl ether are joined reaction vessel
In, it is stirred continuously until mix homogeneously, temperature is risen to 70～75 DEG C and carries out being heated at reflux 1 hour, be finally slowly added to season penta
Tetrol, and stirring and dissolving 0.5 hour, obtain mixed solution；
(3) mixed solution that step (2) prepares is cooled to 20～30 DEG C, then is separately added into preservative, catalyst and increasing
Thick dose, it is kept stirring for 20 minutes, obtains coating mixed liquor；
(4) the coating mixed liquor that step (3) prepares is entered sand mill to grind 4 times, filter to obtain finished product.
Preferably, described preservative is isothiazolinone derivatives.
Preferably, described catalyst is sodium sulfonate.
Preferably, described thickening agent is carboxymethyl cellulose.
Embodiment 2:
A kind of mildew resistant paint for automobile collection box, it is characterised in that be prepared by the raw materials in: hydroxyl third
Olefin(e) acid resin 35 parts, acrylate and vinyl acetate emulsion 20 parts, celluosic resin 20 parts, alkyd resin 10 parts, nano zine oxide 5 parts, preservative 1
Part, catalyst 5 parts, thickening agent 1.5 parts, calcium carbonate superfine powder 5 parts, 5 parts of kieselguhr, 2-Butoxyethyl acetate 1 part, propylene glycol first
2 parts of ether, deionized water 50 parts, tetramethylolmethane 10 parts；
Its preparation method in turn includes the following steps:
(1) by Hydroxylated acrylic resin, acrylate and vinyl acetate emulsion, celluosic resin, alkyd resin, nano zine oxide and deionized water
Putting in reaction vessel, controlling temperature is 50～60 DEG C, stirs and makes mixture dispersed in 30 minutes；
(2) again calcium carbonate superfine powder, kieselguhr, 2-Butoxyethyl acetate and propylene glycol monomethyl ether are joined reaction vessel
In, it is stirred continuously until mix homogeneously, temperature is risen to 70～75 DEG C and carries out being heated at reflux 1.5 hours, be finally slowly added to season
Penta tetrol, and stirring and dissolving 1 hour, obtain mixed solution；
(3) mixed solution that step (2) prepares is cooled to 20～30 DEG C, then is separately added into preservative, catalyst and increasing
Thick dose, it is kept stirring for 50 minutes, obtains coating mixed liquor；
(4) the coating mixed liquor that step (3) prepares is entered sand mill to grind 6 times, filter to obtain finished product.
In the above embodiment of the present invention:
Described preservative is isothiazolinone derivatives；
Described catalyst is sodium sulfonate；
Described thickening agent is carboxymethyl cellulose.
The present invention mostly is plastic material in view of automobile collection box, and its lower hardness, the feature of surface not scratch resistance, by adopting
With combination property preferably high-molecular organic material and carry out optimum organization, improve the fungicidal properties of compositions, use this
The bright coating surface obtained is smooth, fine and smooth, smooth, and gloss retention is good, and hot strength and elongation at break are superior to common coating, energy
Meet automobile collection box and the anticorrosion of casing application, weather-proof etc. is used requirement；Present invention achieves the abundant profit of resource and the energy
With, production process is environment friendly and pollution-free, and its preparation method is simple, and cost is relatively low, with short production cycle, has convenient transportation, it is easy to storage
Deposit, the feature such as easy to use, be suitable to industrialized mass production.
Finally it should be noted that above example only in order to illustrative not limiting technical scheme, although reference
The present invention has been described in detail by above-described embodiment, it will be appreciated by those skilled in the art that and still can carry out the present invention
Amendment or equivalent, any modification or partial replacement without departing from the spirit and scope of the present invention, it all should be contained
In scope of the presently claimed invention.
Claims (4)
1. the mildew resistant paint for automobile collection box, it is characterised in that be prepared by the raw materials in: hydroxy
Acid resin 15～35 parts, acrylate and vinyl acetate emulsion 5～20 parts, celluosic resin 5～20 parts, alkyd resin 2～10 parts, nano zine oxide 1
～5 parts, preservative 0.2～1 part, catalyst 1～5 parts, thickening agent 0.2～1.5 parts, calcium carbonate superfine powder 1～5 parts, kieselguhr 1～
5 parts, 2-Butoxyethyl acetate 0.2～1 part, propylene glycol monomethyl ether 0.3～2 parts, deionized water 20～50 parts, tetramethylolmethane 2～
10 parts；
Its preparation method in turn includes the following steps:
(1) Hydroxylated acrylic resin, acrylate and vinyl acetate emulsion, celluosic resin, alkyd resin, nano zine oxide and deionized water are put into
In reaction vessel, controlling temperature is 50～60 DEG C, stirs and makes mixture dispersed in 15～30 minutes；
(2) again calcium carbonate superfine powder, kieselguhr, 2-Butoxyethyl acetate and propylene glycol monomethyl ether are joined in reaction vessel, no
Temperature, until mix homogeneously, is risen to 70～75 DEG C and carries out being heated at reflux 1～1.5 hour, be finally slowly added to season penta by disconnected stirring
Tetrol, and stirring and dissolving 0.5～1 hour, obtain mixed solution；
(3) mixed solution that step (2) prepares is cooled to 20～30 DEG C, then is separately added into preservative, catalyst and thickening agent,
It is kept stirring for 20～50 minutes, obtains coating mixed liquor；
(4) the coating mixed liquor that step (3) prepares is entered sand mill to grind 4～6 times, filter to obtain finished product.
Mildew resistant paint for automobile collection box the most according to claim 1, it is characterised in that described preservative is different thiophene
Oxazoline ketone derivatives.
Mildew resistant paint for automobile collection box the most according to claim 1, it is characterised in that described catalyst is sulfonic acid
Sodium.
Mildew resistant paint for automobile collection box the most according to claim 1, it is characterised in that described thickening agent is carboxylic first
Base cellulose.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610669106.XA CN106046995A (en) | 2016-08-13 | 2016-08-13 | Mildew-proof coating for automobile storage box and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610669106.XA CN106046995A (en) | 2016-08-13 | 2016-08-13 | Mildew-proof coating for automobile storage box and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106046995A true CN106046995A (en) | 2016-10-26 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610669106.XA Pending CN106046995A (en) | 2016-08-13 | 2016-08-13 | Mildew-proof coating for automobile storage box and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106519839A (en) * | 2016-10-31 | 2017-03-22 | 程志鹏 | Mechanical anti-aging coating and preparation method thereof |
| CN107177253A (en) * | 2017-05-25 | 2017-09-19 | 曹平 | A kind of water-based anticorrosive paint and preparation method thereof |
| CN107629601A (en) * | 2017-10-07 | 2018-01-26 | 梁荣铿 | A kind of anti-corrosion automobile coating |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101486863A (en) * | 2008-01-18 | 2009-07-22 | 深圳市海川实业股份有限公司 | Environment friendly waterborne paint and preparation thereof |
| CN105567037A (en) * | 2014-10-08 | 2016-05-11 | 江苏瑞丰科技实业有限公司 | Efficient antibacterial formaldehyde-removing environmental protection coating material |
-
2016
- 2016-08-13 CN CN201610669106.XA patent/CN106046995A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101486863A (en) * | 2008-01-18 | 2009-07-22 | 深圳市海川实业股份有限公司 | Environment friendly waterborne paint and preparation thereof |
| CN105567037A (en) * | 2014-10-08 | 2016-05-11 | 江苏瑞丰科技实业有限公司 | Efficient antibacterial formaldehyde-removing environmental protection coating material |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106519839A (en) * | 2016-10-31 | 2017-03-22 | 程志鹏 | Mechanical anti-aging coating and preparation method thereof |
| CN107177253A (en) * | 2017-05-25 | 2017-09-19 | 曹平 | A kind of water-based anticorrosive paint and preparation method thereof |
| CN107629601A (en) * | 2017-10-07 | 2018-01-26 | 梁荣铿 | A kind of anti-corrosion automobile coating |
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Application publication date: 20161026 |