CN106046700B - 利用petg塑料和植物纤维制备3d打印材料的方法 - Google Patents
利用petg塑料和植物纤维制备3d打印材料的方法 Download PDFInfo
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- CN106046700B CN106046700B CN201610255705.7A CN201610255705A CN106046700B CN 106046700 B CN106046700 B CN 106046700B CN 201610255705 A CN201610255705 A CN 201610255705A CN 106046700 B CN106046700 B CN 106046700B
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- Prior art keywords
- plant fiber
- petg
- powder
- compatilizer
- spare
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- 239000000835 fiber Substances 0.000 title claims abstract description 78
- 229920003023 plastic Polymers 0.000 title claims abstract description 41
- 239000004033 plastic Substances 0.000 title claims abstract description 41
- 229920005644 polyethylene terephthalate glycol copolymer Polymers 0.000 title claims abstract description 41
- 238000000034 method Methods 0.000 title claims abstract description 37
- 239000000463 material Substances 0.000 title claims abstract description 36
- 238000010146 3D printing Methods 0.000 title claims abstract description 31
- 239000000843 powder Substances 0.000 claims abstract description 50
- 239000000203 mixture Substances 0.000 claims abstract description 22
- 239000003513 alkali Substances 0.000 claims abstract description 12
- 241000196324 Embryophyta Species 0.000 claims description 72
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 45
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- 238000007605 air drying Methods 0.000 claims description 12
- 239000002994 raw material Substances 0.000 claims description 10
- 230000008569 process Effects 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 7
- 240000003183 Manihot esculenta Species 0.000 claims description 6
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 claims description 6
- 239000008367 deionised water Substances 0.000 claims description 6
- 229910021641 deionized water Inorganic materials 0.000 claims description 6
- 239000012153 distilled water Substances 0.000 claims description 6
- 238000001914 filtration Methods 0.000 claims description 6
- 230000035484 reaction time Effects 0.000 claims description 6
- 239000002699 waste material Substances 0.000 claims description 6
- 238000007654 immersion Methods 0.000 claims description 4
- 239000000123 paper Substances 0.000 claims description 4
- 241000274582 Pycnanthus angolensis Species 0.000 claims description 3
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical group O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 3
- 239000011087 paperboard Substances 0.000 claims description 3
- 239000002893 slag Substances 0.000 claims description 3
- 239000002131 composite material Substances 0.000 abstract description 3
- -1 polyethylene Polymers 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 5
- 238000002386 leaching Methods 0.000 description 4
- 238000007493 shaping process Methods 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000011017 operating method Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229920001634 Copolyester Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920001587 Wood-plastic composite Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 230000035800 maturation Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 239000012783 reinforcing fiber Substances 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 239000011155 wood-plastic composite Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/08—Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
Abstract
Description
Claims (3)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610255705.7A CN106046700B (zh) | 2016-04-22 | 2016-04-22 | 利用petg塑料和植物纤维制备3d打印材料的方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610255705.7A CN106046700B (zh) | 2016-04-22 | 2016-04-22 | 利用petg塑料和植物纤维制备3d打印材料的方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN106046700A CN106046700A (zh) | 2016-10-26 |
CN106046700B true CN106046700B (zh) | 2018-05-08 |
Family
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Family Applications (1)
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CN201610255705.7A Active CN106046700B (zh) | 2016-04-22 | 2016-04-22 | 利用petg塑料和植物纤维制备3d打印材料的方法 |
Country Status (1)
Country | Link |
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CN (1) | CN106046700B (zh) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106566273A (zh) * | 2016-11-11 | 2017-04-19 | 南宁梦幻三体环保科技有限公司 | 一种3d打印用塑料材料 |
US11718830B1 (en) | 2022-06-13 | 2023-08-08 | Caromeats Inc. | Silicone-based membrane surface chemistry and topography control for making self-assembled cell sheets with cell alignment and positioning |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104312119A (zh) * | 2014-11-06 | 2015-01-28 | 芜湖瀚博电子科技有限公司 | 一种秸秆3d打印耗材及其制备方法 |
CN104559088A (zh) * | 2015-01-28 | 2015-04-29 | 上海材料研究所 | 一种适用于3d打印的改性复合材料及其制备方法 |
-
2016
- 2016-04-22 CN CN201610255705.7A patent/CN106046700B/zh active Active
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Publication number | Publication date |
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CN106046700A (zh) | 2016-10-26 |
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Effective date of registration: 20180409 Address after: 530000 the Guangxi Zhuang Autonomous Region Zhenhua Road Nanning hi tech science park building 3, room 404, dormitory workers Applicant after: GUANGXI CHUNJING ENVIRONMENTAL PROTECTION TECHNOLOGY CO.,LTD. Address before: 530004 the Guangxi Zhuang Autonomous Region XiXiangTang Nanning University Road No. 100 Applicant before: Guangxi University |
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Address after: Room 1207, Internet Building, Dongtai Hi tech Industrial Development Zone, Dongtai City, Yancheng City, Jiangsu Province, 224200 Patentee after: Yancheng Zuanmeng Environmental Protection Technology Co.,Ltd. Country or region after: China Address before: Room 404, youth workers dormitory building, Kaide science and Technology Park, No.3 Zhenhua Road, Nanning, Guangxi 530000 Patentee before: GUANGXI CHUNJING ENVIRONMENTAL PROTECTION TECHNOLOGY CO.,LTD. Country or region before: China |