CN106045565A - Light high-strength ceramsite and preparation method thereof - Google Patents

Light high-strength ceramsite and preparation method thereof Download PDF

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Publication number
CN106045565A
CN106045565A CN201610387846.4A CN201610387846A CN106045565A CN 106045565 A CN106045565 A CN 106045565A CN 201610387846 A CN201610387846 A CN 201610387846A CN 106045565 A CN106045565 A CN 106045565A
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China
Prior art keywords
light high
parts
strength
preparation
haydite
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Pending
Application number
CN201610387846.4A
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Chinese (zh)
Inventor
陈锋
周敏
林生凤
黄芳
张蔚
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Fujian Academy of Architectural Sciences Co., Ltd.
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Fujian Academy of Building Research
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Priority to CN201610387846.4A priority Critical patent/CN106045565A/en
Publication of CN106045565A publication Critical patent/CN106045565A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/009Porous or hollow ceramic granular materials, e.g. microballoons
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/132Waste materials; Refuse; Residues
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/132Waste materials; Refuse; Residues
    • C04B33/1328Waste materials; Refuse; Residues without additional clay
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/132Waste materials; Refuse; Residues
    • C04B33/138Waste materials; Refuse; Residues from metallurgical processes, e.g. slag, furnace dust, galvanic waste
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/16Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay
    • C04B35/18Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay rich in aluminium oxide
    • C04B35/185Mullite 3Al2O3-2SiO2
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/60Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Treatment Of Sludge (AREA)

Abstract

The invention provides light high-strength ceramsite which is prepared from, by mass, 60-80 parts of iron tailings, 15-35 parts of aluminum factory sludge and 5-15 parts of activated carbon. The invention further discloses a preparation method of the light high-strength ceramsite. The light high-strength ceramsite and the preparation method have the advantages that solid waste is recycled, the aims of waste utilization, energy conservation and environmental friendliness are achieved, social and economic benefits are remarkable, and the light high-strength ceramsite excellent in performance is obtained.

Description

Light high-strength haydite and preparation method thereof
[technical field]
The invention belongs to building material field, be specifically related to a kind of light high-strength haydite and preparation method thereof.
[background technology]
Haydite is a kind of artificial lightweight coarse aggregate, it is common that processes under uniform temperature (usually high temperature), makes raw material send out Biochemical reaction release gas, produces pore and expansion, formed after cooling light porous, have some strength spherical or oval Silicate spheroid.The inner structural features of haydite is fine and closely woven cellular micropore.These micropores are all case type rather than connection Type, this is the main cause of haydite light weight.
And two kinds of solid industrial garbages that iron tailings, the aluminum manufacturer sludge current discharge capacity that is China is bigger.Wherein, iron tailings For iron mine mine tailing of discharge after machinery washing, there is higher SiO2、Fe2O3Content, SiO2Content value about 45%~ 80%, Fe2O3Content value about 12%~18%;Aluminum manufacturer sludge is that aluminium manufacturer processes mine tailing, its Al2O3Content is up to more than 90%, CaO、MgO、K2O、Na2O equal size about 5~10%;Existing iron tailings is with aluminum manufacturer sludge is as the main process side of solid waste Formula is long-term stacking, does not only take up a large amount of soil, and atmospheric environment and groundwater resources are caused extremely ill effect. Utilization to iron tailings, aluminum manufacturer sludge the most both at home and abroad has carried out correlational study, and majority is applied to roadbed landfill, brickmaking, coagulation The application of the aspects such as soil admixture, but there is not yet both integrated applications in the research report of haydite aspect production application.
[summary of the invention]
The technical problem to be solved is to provide a kind of light high-strength haydite and preparation method thereof, it is achieved that Gu The recycling of body garbage, reaches useless, the energy-conservation and purpose of environmental protection of profit, has significant Social and economic benef@, and obtain The light high-strength haydite of excellent performance.
The present invention is to solve above-mentioned technical problem by the following technical programs: a kind of light high-strength haydite and preparation side thereof Method, this light high-strength haydite is made up of the component of following proportion by weight:
Iron tailings 60~80 parts;
Aluminum manufacturer sludge 15~35 parts;
Activated carbon 5~15 parts.
Further, the preparation method of this light high-strength haydite includes following concrete operations:
By iron tailings, aluminum manufacturer sludge each grinding, and cross 0.08mm sieve;Each group is prepared afterwards by following proportion by weight Point: iron tailings 60~80 parts, aluminum manufacturer sludge 15~35 parts, activated carbon 5~15 parts, ready each component is mixed and stirred for all Even formation compound, speed of agitator is 80 ± 4r/min, mixing time >=10min;100 are added then according to every 500g compound The water of ± 30ml carries out mixing, and ball shape is i.e. made in molding, is then dried 24h at 100-105 DEG C;Finally burn till, Firing temperature is 1150~1300 DEG C, burns till and lasts 10-20min, i.e. obtains described light high-strength haydite after burning till end.
The present invention has the beneficial effects that:
Providing a kind of light high-strength haydite with solid waste as primary raw material, this light high-strength haydite has preferably Intensity, relatively low water absorption rate and bulk density, and based on mullite and the network structure of glass, i.e. there is excellence Performance;Disclosing the preparation method of this light high-strength haydite, whole preparation process is the most easily operated and stability is good simultaneously Good;Therefore, present invention achieves the recycling of solid waste, reach useless, the energy-conservation and purpose of environmental protection of profit, there is significant society Meeting and economic benefit, and obtain the light high-strength haydite of excellent performance.
[accompanying drawing explanation]
The invention will be further described the most in conjunction with the embodiments.
Fig. 1 is the XRD figure in the embodiment of the present invention 1.
Fig. 2 is the SEM figure in the embodiment of the present invention 1.
Fig. 3 is the XRD figure in the embodiment of the present invention 2.
Fig. 4 is the SEM figure in the embodiment of the present invention 2.
Fig. 5 is the XRD figure in the embodiment of the present invention 3.
Fig. 6 is the SEM figure in the embodiment of the present invention 3.
[detailed description of the invention]
Light high-strength haydite of the present invention is made up of the component of following proportion by weight: iron tailings 60~80 parts;Aluminum manufacturer sludge 15~35 parts;Activated carbon 5~15 parts.Wherein, iron tailings, as getting angry and flux composition, can be effectively increased product hole and again may be used Reduce firing temperature;Aluminum manufacturer sludge has the effect reducing firing temperature, and it contains CaO, MgO, K2O、Na2O etc. fluxes into Point;Activated carbon is primarily to introduce composition of effectively getting angry.
The concrete operations of the preparation method of described light high-strength haydite are as follows:
By iron tailings, aluminum manufacturer sludge each grinding, and cross 0.08mm sieve;Each group is prepared afterwards by following proportion by weight Point: iron tailings 60~80 parts, aluminum manufacturer sludge 15~35 parts, activated carbon 5~15 parts, ready each component is mixed and stirred for all Even formation compound, speed of agitator is 80 ± 4r/min, mixing time >=10min;100 are added then according to every 500g compound The water of ± 30ml carries out mixing, and ball shape is i.e. made in molding, is then dried 24h at 100-105 DEG C;Finally burn till, Firing temperature is 1150~1300 DEG C, burns till and lasts 10-20min, i.e. obtains described light high-strength haydite after burning till end.
It should be noted that sinter three-phase diagram, SiO according to light high-strength haydite2Content preferably exists
53~79%, Al2O3Content is preferably 12~26%, and composition of fluxing is preferably 3~22%, and composition of effectively getting angry is preferably 5 ~10%, therefore, present invention applicant is studied by formula design and firing process, forms according to the chemical composition of each raw material, Carry out scientific and effective preparation, reach at utmost to utilize the purpose of Industrial Solid Waste, make each component carry out best of breed simultaneously, make SiO2And Al2O3In conjunction with generating mullite crystalline phase and the amorphous glass phase with strength support effect, make Fe2O3Increase with activated carbon Add amount of air entrainment, form more fine pores, make Fe2O3、CaO、MgO、K2O、Na2The fluxs such as O reduce firing temperature, burn out There is the haydite of high-strength light physical property.
In order to preferably be described the present invention, applicant illustrates below embodiment.
Embodiment 1
By iron tailings, aluminum manufacturer sludge each grinding, and cross 0.08mm sieve;Take activated carbon 1.5Kg afterwards, sieve after ferrum tail Ore deposit 6Kg, aluminum manufacturer sludge 2.5Kg also mix, and are placed in agitator the formation compound 10Kg that stirs, and speed of agitator is 80 ± 4r/min, mixing time is 10min;Enter then according to every 500g compound amount of water 120ml (i.e. adding total Water is 2.4L) Row mixing, and make spherical, at 100 DEG C, then it is dried 24h;Finally burning till, firing temperature is 1200 DEG C, burns till and lasts 20min, i.e. obtains light high-strength haydite after burning till end.
The light high-strength haydite of the present embodiment gained is used X-ray diffraction, then gained diffracting spectrum i.e. XRD figure such as Fig. 1 Shown in;Light high-strength haydite is placed under scanning electron microscope observation detection simultaneously, then gained SEM schemes as shown in Figure 2;In conjunction with Fig. 1 Yu Fig. 2 understands, and, has certain hole in the present embodiment gained light high-strength haydite based on mullite with glass mutually Gap, it is 5.1% that physical property characterizes its water absorption rate, cylindrical compress strength 6.2MPa, bulk density 656kg/m3
Embodiment 2
By iron tailings, aluminum manufacturer sludge each grinding, and cross 0.08mm sieve;Take activated carbon 1Kg afterwards, sieve after iron tailings 7Kg, aluminum manufacturer sludge 2Kg also mix, and are placed in agitator the formation compound 10Kg that stirs, and speed of agitator is 80 ± 4r/ Min, mixing time is 15min;Mix then according to every 500g compound amount of water 120ml (i.e. adding total Water is 2.4L) System, and make spherical, at 105 DEG C, then it is dried 24h;Finally burning till, firing temperature is 1250 DEG C, burns till and lasts 20min, i.e. obtains light high-strength haydite after burning till end.
The light high-strength haydite of the present embodiment gained is used X-ray diffraction, then gained diffracting spectrum i.e. XRD figure such as Fig. 3 Shown in;Light high-strength haydite is placed under scanning electron microscope observation detection simultaneously, then gained SEM schemes as shown in Figure 4;In conjunction with Fig. 3 Yu Fig. 4 understands, and, has certain hole in the present embodiment gained light high-strength haydite based on mullite with glass mutually Gap, it is 2.6% that physical property characterizes its water absorption rate, cylindrical compress strength 8.8MPa, bulk density 773kg/m3
Embodiment 3
By iron tailings, aluminum manufacturer sludge each grinding, and cross 0.08mm sieve;Take activated carbon 0.5Kg afterwards, sieve after ferrum tail Ore deposit 8Kg, aluminum manufacturer sludge 1.5Kg also mix, and are placed in agitator the formation compound 10Kg that stirs, and speed of agitator is 80 ± 4r/min, mixing time is 12min;Enter then according to every 500g compound amount of water 130ml (i.e. adding total Water is 2.6L) Row mixing, and make spherical, at 102 DEG C, then it is dried 24h;Finally burning till, firing temperature is 1300 DEG C, burns till and lasts 18min, i.e. obtains light high-strength haydite after burning till end.
The light high-strength haydite of the present embodiment gained is used X-ray diffraction, then gained diffracting spectrum i.e. XRD figure such as Fig. 5 Shown in;Light high-strength haydite is placed under scanning electron microscope observation detection simultaneously, then gained SEM schemes as shown in Figure 6;In conjunction with Fig. 5 Yu Fig. 6 understands, and, has certain hole in the present embodiment gained light high-strength haydite based on mullite with glass mutually Gap, it is 3.6% that physical property characterizes its water absorption rate, cylindrical compress strength 7.8MPa, bulk density 857kg/m3
In summary, light high-strength haydite of the present invention has preferable intensity, relatively low water absorption rate and bulk density, and Based on mullite and the network structure of glass;And preparation process primary raw material be simple, be easy to get, cheap discarded Thing, whole preparation process is the most easily operated and has good stability;In other words, present invention achieves solid waste again Utilize, reach useless, the energy-conservation and purpose of environmental protection of profit, there is significant Social and economic benef@, obtain excellent performance simultaneously Light high-strength haydite.

Claims (2)

1. a light high-strength haydite, it is characterised in that: this light high-strength haydite is made up of the component of following proportion by weight:
Iron tailings 60~80 parts;
Aluminum manufacturer sludge 15~35 parts;
Activated carbon 5~15 parts.
2. the preparation method of the light high-strength haydite described in claim 1, it is characterised in that: include following concrete operations:
By iron tailings, aluminum manufacturer sludge each grinding, and cross 0.08mm sieve;Afterwards by the following proportion by weight each component of preparation: ferrum Mine tailing 60~80 parts, aluminum manufacturer sludge 15~35 parts, activated carbon 5~15 parts, be mixed and stirred for uniform shape by ready each component Becoming compound, speed of agitator is 80 ± 4r/min, mixing time >=10min;Then according to every 500g compound add 100 ± The water of 30ml carries out mixing, and ball shape is i.e. made in molding, is then dried 24h at 100-105 DEG C;Finally burn till, burn Becoming temperature is 1150~1300 DEG C, burns till and lasts 10-20min, i.e. obtains described light high-strength haydite after burning till end.
CN201610387846.4A 2016-06-02 2016-06-02 Light high-strength ceramsite and preparation method thereof Pending CN106045565A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107915471A (en) * 2017-12-01 2018-04-17 武汉钢铁有限公司 A kind of light thermal-insulation aggregate and method that iron-stone tailing is prepared using large-sized rotary kiln
CN108516857A (en) * 2018-06-24 2018-09-11 大连地拓环境科技有限公司 A kind of cyanidation tailings high-strength ceramic granule and preparation method thereof
CN110917724A (en) * 2019-12-13 2020-03-27 陕西速源节能科技有限公司 Preparation method of filter material for sewage treatment
CN111087185A (en) * 2019-12-19 2020-05-01 广东清大同科环保技术有限公司 Foamed lightweight aggregate prepared from iron tailings and preparation method thereof
CN114315315A (en) * 2021-12-30 2022-04-12 大连地拓环境科技有限公司 Boric sludge light high-strength ceramsite and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101486563A (en) * 2009-02-25 2009-07-22 刘阳生 Biological haydite burned from mine tailings, and preparation and use method thereof
CN101618971A (en) * 2009-07-31 2010-01-06 西安墙体材料研究设计院 Municipal sludge expanded ceramsite and preparation method thereof
CN104876625A (en) * 2015-05-27 2015-09-02 中钢集团马鞍山矿山研究院有限公司 Method for preparing ultralight ceramsites from clay iron-containing tailings
CN104892019A (en) * 2015-05-27 2015-09-09 中钢集团马鞍山矿山研究院有限公司 Ultralight ceramsite prepared by totally taking solid waste as raw material

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101486563A (en) * 2009-02-25 2009-07-22 刘阳生 Biological haydite burned from mine tailings, and preparation and use method thereof
CN101618971A (en) * 2009-07-31 2010-01-06 西安墙体材料研究设计院 Municipal sludge expanded ceramsite and preparation method thereof
CN104876625A (en) * 2015-05-27 2015-09-02 中钢集团马鞍山矿山研究院有限公司 Method for preparing ultralight ceramsites from clay iron-containing tailings
CN104892019A (en) * 2015-05-27 2015-09-09 中钢集团马鞍山矿山研究院有限公司 Ultralight ceramsite prepared by totally taking solid waste as raw material

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杜芳等: "铁尾矿烧制陶粒及其性能的研究", 《环境工程》 *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107915471A (en) * 2017-12-01 2018-04-17 武汉钢铁有限公司 A kind of light thermal-insulation aggregate and method that iron-stone tailing is prepared using large-sized rotary kiln
CN108516857A (en) * 2018-06-24 2018-09-11 大连地拓环境科技有限公司 A kind of cyanidation tailings high-strength ceramic granule and preparation method thereof
CN110917724A (en) * 2019-12-13 2020-03-27 陕西速源节能科技有限公司 Preparation method of filter material for sewage treatment
CN111087185A (en) * 2019-12-19 2020-05-01 广东清大同科环保技术有限公司 Foamed lightweight aggregate prepared from iron tailings and preparation method thereof
CN114315315A (en) * 2021-12-30 2022-04-12 大连地拓环境科技有限公司 Boric sludge light high-strength ceramsite and preparation method thereof

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Application publication date: 20161026