CN106044911A - Vacuum resolution electrochemical trinity in-series deoxygenation device - Google Patents

Vacuum resolution electrochemical trinity in-series deoxygenation device Download PDF

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Publication number
CN106044911A
CN106044911A CN201610636337.0A CN201610636337A CN106044911A CN 106044911 A CN106044911 A CN 106044911A CN 201610636337 A CN201610636337 A CN 201610636337A CN 106044911 A CN106044911 A CN 106044911A
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CN
China
Prior art keywords
deaeration
container
water
condenser
vacuum
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Pending
Application number
CN201610636337.0A
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Chinese (zh)
Inventor
高谦
张小安
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Horgos Yongxu Energy Saving And Environmental Protection Technology Co ltd
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Individual
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Priority to CN201610636337.0A priority Critical patent/CN106044911A/en
Publication of CN106044911A publication Critical patent/CN106044911A/en
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/20Treatment of water, waste water, or sewage by degassing, i.e. liberation of dissolved gases
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00General aspects of water treatment
    • C02F2301/06Pressure conditions
    • C02F2301/063Underpressure, vacuum

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Air Supply (AREA)

Abstract

The invention discloses a vacuum resolution electrochemical trinity in-series deoxygenation device. The device has a structure composed of multiple in-series vacuum deoxygenation containers with water inlets and water outlets. The device also comprises combustors. The combustor is arranged in each one of the vacuum deoxygenation containers or outside the vacuum deoxygenation container. When the combustors arranged outside the vacuum deoxygenation containers, the combustors are communicated with the inner cavities of the vacuum deoxygenation containers. Between each two adjacent vacuum deoxygenation containers, the water inlet of the rear vacuum deoxygenation container is communicated with the water outlet of the front vacuum deoxygenation container. The device really solves the problems of low temperature deoxygenation so that the national deoxygenation index is satisfied and a deoxygenation index can be randomly adjusted to less than or equal to 0.1mg/L.

Description

Vacuum analysis electrochemistry Trinity series connection deaeration plant
Technical field
The present invention relates to a kind of vacuum analysis electrochemistry Trinity series connection deaeration plant.
Background technology
Conventional oxygen-eliminating device technology all uses a kind of method to solve, and for low temperature deoxygenation, water temperature more low oxygen content is the highest, low Temperature deoxygenation is more difficult to remove.
Summary of the invention
Goal of the invention: the present invention provides a kind of vacuum analysis electrochemistry Trinity series connection deaeration plant, its objective is to solve The most existing problem.
Technical scheme: invention is achieved through the following technical solutions:
A kind of vacuum analysis electrochemistry Trinity series connection deaeration plant, it is characterised in that: this equipment is with water inlet by multiple The structure that mouth is in series with the deaeration in condenser container of outlet, this equipment also includes burner, and burner is arranged on vacuum and removes Oxygen container is interior or is arranged on outside deaeration in condenser container, when outside burner is arranged on deaeration in condenser container, and itself and deaeration in condenser Container intracavity connects;Between two adjacent deaeration in condenser containers, the water inlet of later deaeration in condenser container with previous very The outlet connection of empty oxygen scavenging container.
It is additionally provided with in the most one or more or whole deaeration in condenser containers and water is sprayed at uniformly deaeration in condenser The spray thrower connected with water inlet in container.
When burner is arranged on deaeration in condenser outside of containers, each deaeration in condenser container all connects a burner.
When burner is arranged on deaeration in condenser outside of containers, each two deaeration in condenser container connects a burner jointly (2) the deaeration in condenser container of more than or three connects a burner jointly.
It is provided with filler in one of which or multiple or whole deaeration in condenser containers;Filler for making all or Part water flows to the structure of outlet again after flowing through filler.
Burner is charcoal burning device, and charcoal burning device is the device by electric heating device heating wood carbon.
It is additionally provided with electrolyzer in the deaeration in condenser container that one of which is multiple or whole;Electrolyzer is complete for making The structure that portion or part water move to outlet after electrolyzer again.
Go out at outlet and be provided with the water pump drawn by water.
Water pump is immersible pump, and it is interior or outside that immersible pump is arranged on deaeration in condenser container so that previous deaeration in condenser holds The water of device outlet guides the water inlet of later deaeration in condenser container into through immersible pump, and last deaeration in condenser container The water of outlet is directly led out by immersible pump.
Electrolyzer external direct current power supply, anode uses iron plate, steel plate or uses form steel, iron material as victim;Cloudy Pole uses iron plate, steel plate or the conductive material taken other form.
Advantageous effect:
The present invention provides a kind of vacuum analysis electrochemistry Trinity series connection deaeration plant, and it can really solve low temperature deoxygenation and ask Topic, makes up to country's deoxygenation index, and deoxygenation index can arbitrarily regulate≤0.1mg/L.
Owing to being provided with electrolyzer in deaeration plant, cell operation size of current is the most arbitrarily arranged, dissolved oxygen index Can arbitrarily regulate, so when water entrance deaeration plant is after vacuum analysis, spray dispersion reduce major part dissolved oxygen, then through electricity Chemical treatment, residue dissolved oxygen index can arbitrarily be reconciled to less than 0.01 milligram/every liter.
When water temperature 7 degree, when content of oxygen dissolved in water is 9 milligrams/every liter, the content of oxygen dissolved in water after being processed is less than 0.01 milligram/every liter.
Accompanying drawing illustrates:
Fig. 1 is the structural representation of the present invention;
Fig. 2 is the structural representation of the one form of which of the present invention;
Fig. 3 be one of them single deaeration in condenser container and structural scheme of mechanism.
Detailed description of the invention:
As it can be seen, the present invention provides a kind of vacuum analysis electrochemistry Trinity series connection deaeration plant, this equipment is by multiple With the structure that the deaeration in condenser container 1 of water inlet 8 and outlet 9 is in series, this equipment also includes burner 2, burner 2 In being arranged on deaeration in condenser container 1 or be arranged on outside deaeration in condenser container 1, outside burner 2 is arranged on deaeration in condenser container 1 Time, itself and deaeration in condenser container 1 inner space;Between two adjacent deaeration in condenser containers 1, later deaeration in condenser container 1 Water inlet connect with the outlet of previous deaeration in condenser container 1.
Be additionally provided with in deaeration in condenser container 1 water is sprayed in deaeration in condenser container 1 uniformly with water inlet 8 even Logical spray thrower 7.
When burner 2 is arranged on outside deaeration in condenser container 1, each deaeration in condenser container 1 all connects a burner 2。
When burner 2 is arranged on outside deaeration in condenser container 1, each two deaeration in condenser container 1 connects a combustion jointly The deaeration in condenser container 1 of burner 2 or more than three connects a burner 2 jointly.Burner 2 is charcoal burning device, and Linesless charcoal fires Burner is the device by electric heating device heating wood carbon.
It is provided with filler 6 in one of which or multiple or whole deaeration in condenser containers 1.
Filler 6 is the structure making all or part of water flow to outlet after flowing through filler 6 again.
It is additionally provided with electrolyzer 4 in the deaeration in condenser container 1 that one of which is multiple or whole;Electrolyzer 4 is for making Obtain the structure that all or part of water moves after electrolyzer 4 again to outlet.
Go out at outlet 9 and be provided with the water pump drawn by water.
Water pump is immersible pump 5, and it is interior or outside that immersible pump 5 is arranged on deaeration in condenser container 1 so that previous deaeration in condenser The water of container 1 outlet 9 guides the water inlet 8 of later deaeration in condenser container 1 into through immersible pump 5, and last vacuum is removed The water of the outlet of oxygen container 1 is directly led out by immersible pump 5.
Spray, baffling, filler etc. can be used when water flows through this container to increase the dispersion of water;
Immersible pump 3 uses full-closed structure when being placed in oxygen-eliminating device 1 outside.
Reducing substances in burner 2 uses Linesless charcoal, coke or anthracite.
Every oxygen-eliminating device 1 works all under negative pressure of vacuum;Every oxygen-eliminating device can individually use vacuum pump also and can to connect group Close and use vacuum pump.
Spray equipment can use the nozzle type of various pattern, and shower nozzle also can be upward, it is possible to down, or towards side all can, As shown in Figure 2.
Spray in 7 devices are placed in each oxygen-eliminating device or be placed in certain oxygen-eliminating device.
Filler is arranged in the bottom of spray, as shown in Figure 2.
Electrolyzer 4 external direct current power supply, anode can use iron plate, steel plate or use other any form steel, iron material Material is as victim;Negative electrode also can use iron plate, steel plate or use the conductive material of other any form.In electrolysis Under the effect in pond
Anode: iron plate betatopic produces ferrous ion
Fe0→Fe+2+2e
Negative electrode: oxygen obtains electronics at negative electrode and is eliminated generation hydroxyl
O2+4e+2H2O→4OH
In water: electrochemical products is:
Fe+2+2OH→Fe(OH)2
Fe(OH)2Generation Fe (OH) is reacted continuously with oxygen in water3
4Fe(OH)2+O2+2H2O →4Fe(OH)3
Processed water can enter from the top of electrolyzer and also can intake from the bottom of electrolyzer, carries out electrochemical deoxidization;Work as water When entering from top, outlet is in the bottom of electrolyzer;When water enters from below, outlet is on the top of electrolyzer, such as Fig. 3 institute Show.
Burner 2 is placed in inside oxygen-eliminating device being also placed in the outside total enclosing of oxygen-eliminating device and connects with oxygen-eliminating device and be also at vacuum Work under negative pressure.
Burner 2 is to be burnt by electrical heating 10;Reducing substances in burner uses Linesless charcoal, and coke or anthracite will remove The oxygen burning parsed in oxygen device generates oxide so that in oxygen-eliminating device, the dividing potential drop of oxygen goes to zero.
As long as vacuum deaerator i.e. deaeration in condenser container 1 can use any shape can bear negative pressure meets requirement of strength i.e. Can.
Electrolyzer is combined by pole plate assembly.In figure, A is pole plate.5 is vacuum pump.
When being arranged on by electrolyzer in last oxygen-eliminating device, finally complete the removing to residual dissolved oxygen.
The shower nozzle disposed in deaeration in condenser container 1 and filler are used for increasing the dispersion of water.And filler also slow down simultaneously The speed that current move, in order to increase the deoxygenation time.
The water processed through electrolyzer can from top to bottom flow through electrolyzer process outlet in the lower section of electrolyzer.Also can be by Flowing through electrolyzer on down to process, outlet is above electrolyzer.
Deaeration in condenser container 1 is placed in the negative pressure system of deaeration in condenser by this equipment;I.e. burner is placed in oxygen-eliminating device 2 In, it is possible to being placed in the outer total enclosing of oxygen-eliminating device and be connected by connecting tube with oxygen-eliminating device, but be all under negative pressure of vacuum and work, entrance removes It is to parse dissolved oxygen when zero that water in oxygen device increases dispersion dividing potential drop of oxygen in container through spray, say, that When the dividing potential drop of oxygen in water after deaeration in condenser container 1 that enters of processed water separates out more than the dividing potential drop of oxygen in container, dissolved oxygen, The oxygen and the wood carbon burning that separate out make the dividing potential drop of oxygen in gas in container go to zero all the time.Water immersible pump removes under negative pressure afterwards Water in oxygen device is extracted out in entering next deaeration in condenser container 1 and is carried out further deoxygenation.And shower nozzle and filler and electrolyzer It is all to strengthen deaerating effect further.
Conventional parsing deoxygenation is that this deoxidation method is by noble gas deoxygenation after strongly being mixed by the water of deoxygenation Burner is placed in deaerating type of cycles, allows oxygen combustion, make the dividing potential drop of oxygen in oxygen-eliminating device go to zero, and then by the dissolved oxygen in water Parse in oxygen-eliminating device, and elimination of burning.This deoxidation method floor space is little, saves combustion medium, power saving, deaerating effect Good.
And the present invention is operated through the most multistage oxygen scavenging step, it can preferably realize oxygen removal process, with Time, three kinds of deoxidation methods are combined together by it, it is thus possible to thoroughly solve low temperature deoxygenation problem.

Claims (10)

1. a vacuum analysis electrochemistry Trinity series connection deaeration plant, it is characterised in that: this equipment is with entering by multiple The structure that the deaeration in condenser container (1) of the mouth of a river (8) and outlet (9) is in series, this equipment also includes burner (2), burning Device (2) is arranged in deaeration in condenser container (1) or is arranged on deaeration in condenser container (1) outward, when burner (2) is arranged on vacuum When oxygen scavenging container (1) is outer, itself and deaeration in condenser container (1) inner space;Between two adjacent deaeration in condenser containers (1), after The water inlet of one deaeration in condenser container (1) connects with the outlet of previous deaeration in condenser container (1).
The vacuum analysis electrochemistry Trinity the most according to claim 1 series connection deaeration plant, it is characterised in that: wherein It is additionally provided with in one or more or whole deaeration in condenser containers (1) and water is sprayed at uniformly in deaeration in condenser container (1) The spray thrower (7) connected with water inlet (8).
The vacuum analysis electrochemistry Trinity the most according to claim 1 series connection deaeration plant, it is characterised in that: work as burning When device (2) is arranged on deaeration in condenser container (1) outside, each deaeration in condenser container (1) all connects a burner (2).
The vacuum analysis electrochemistry Trinity the most according to claim 1 series connection deaeration plant, it is characterised in that: work as burning When device (2) is arranged on deaeration in condenser container (1) outside, each two deaeration in condenser container (1) jointly one burner (2) of connection or The deaeration in condenser container (1) of more than three one burner (2) of connection jointly.
The vacuum analysis electrochemistry Trinity the most according to claim 1 series connection deaeration plant, it is characterised in that: wherein One or more or whole deaeration in condenser containers (1) in be provided with filler (6);Filler (6) is all or part of for making Water flows to the structure of outlet again after flowing through filler (6).
The vacuum analysis electrochemistry Trinity the most as claimed in any of claims 1 to 4 series connection deaeration plant, it is special Levying and be: burner (2) is charcoal burning device, charcoal burning device is the device by electric heating device heating wood carbon.
Vacuum analysis electrochemistry Trinity series connection deaeration plant the most according to claim 1 or 5, it is characterised in that: It is additionally provided with electrolyzer (4) in one or more or whole deaeration in condenser container (1);Electrolyzer (4) is complete for making The structure that portion or part water move to outlet after electrolyzer (4) again.
The vacuum analysis electrochemistry Trinity the most according to claim 1 series connection deaeration plant, it is characterised in that: in water outlet Mouth (9) goes out to be provided with the water pump drawn by water.
The vacuum analysis electrochemistry Trinity the most according to claim 8 series connection deaeration plant, it is characterised in that: water pump is Immersible pump (5), it is interior or outside that immersible pump (5) is arranged on deaeration in condenser container (1) so that previous deaeration in condenser container (1) The water of outlet (9) guides the water inlet (8) of later deaeration in condenser container (1) into through immersible pump (5), and last vacuum The water of the outlet of oxygen scavenging container (1) is directly led out by immersible pump (5).
The vacuum analysis electrochemistry Trinity the most according to claim 7 series connection deaeration plant, it is characterised in that: electrolysis Pond (4) external direct current power supply, anode uses iron plate, steel plate or uses form steel, iron material as victim;Negative electrode uses ferrum Plate, steel plate or the conductive material taken other form.
CN201610636337.0A 2016-08-05 2016-08-05 Vacuum resolution electrochemical trinity in-series deoxygenation device Pending CN106044911A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610636337.0A CN106044911A (en) 2016-08-05 2016-08-05 Vacuum resolution electrochemical trinity in-series deoxygenation device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610636337.0A CN106044911A (en) 2016-08-05 2016-08-05 Vacuum resolution electrochemical trinity in-series deoxygenation device

Publications (1)

Publication Number Publication Date
CN106044911A true CN106044911A (en) 2016-10-26

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113104922A (en) * 2021-04-25 2021-07-13 连云港正航电力节能技术有限公司 Electrochemical trinity deaerator

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN86207235U (en) * 1986-10-17 1987-12-23 田伟 Food-preservatory using combustion oxide-removing method
CN2327896Y (en) * 1997-06-04 1999-07-07 黄河清 Vacuum multi-stage degasifying and deoxidising device
RU2153471C1 (en) * 1999-10-05 2000-07-27 Ульяновский государственный технический университет Water vacuum deaeration method
CN2389882Y (en) * 1999-09-29 2000-08-02 张小安 Water treatment device
JP2007106612A (en) * 2005-10-11 2007-04-26 Mitsubishi Heavy Ind Ltd Fuel reforming apparatus and fuel cell power generation system using the same
CA2594988A1 (en) * 2006-07-27 2008-01-27 Lg Chem, Ltd. Electrochemical device with high safety at over-voltage and high temperature
CN101531404A (en) * 2009-04-03 2009-09-16 上海晟煜科贸有限公司 Method for producing analysis gas in vacuum analysis deaerator with boiler flue gas
CN101857312A (en) * 2010-06-13 2010-10-13 刘利华 Method and device for preventing and removing scales, removing oxygen, cleaning, sterilizing and removing algal by using ultrasonic waves
CN201770145U (en) * 2010-07-14 2011-03-23 蔡文高 Deoxidizing storage cabinet
CN202829641U (en) * 2012-09-07 2013-03-27 孙宏庆 Secondary vacuum electrochemistry deoxidizing device
CN104445483A (en) * 2014-11-11 2015-03-25 常州市品鑫除尘设备有限公司 Vacuum deaerator structure

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN86207235U (en) * 1986-10-17 1987-12-23 田伟 Food-preservatory using combustion oxide-removing method
CN2327896Y (en) * 1997-06-04 1999-07-07 黄河清 Vacuum multi-stage degasifying and deoxidising device
CN2389882Y (en) * 1999-09-29 2000-08-02 张小安 Water treatment device
RU2153471C1 (en) * 1999-10-05 2000-07-27 Ульяновский государственный технический университет Water vacuum deaeration method
JP2007106612A (en) * 2005-10-11 2007-04-26 Mitsubishi Heavy Ind Ltd Fuel reforming apparatus and fuel cell power generation system using the same
CA2594988A1 (en) * 2006-07-27 2008-01-27 Lg Chem, Ltd. Electrochemical device with high safety at over-voltage and high temperature
CN101531404A (en) * 2009-04-03 2009-09-16 上海晟煜科贸有限公司 Method for producing analysis gas in vacuum analysis deaerator with boiler flue gas
CN101857312A (en) * 2010-06-13 2010-10-13 刘利华 Method and device for preventing and removing scales, removing oxygen, cleaning, sterilizing and removing algal by using ultrasonic waves
CN201770145U (en) * 2010-07-14 2011-03-23 蔡文高 Deoxidizing storage cabinet
CN202829641U (en) * 2012-09-07 2013-03-27 孙宏庆 Secondary vacuum electrochemistry deoxidizing device
CN104445483A (en) * 2014-11-11 2015-03-25 常州市品鑫除尘设备有限公司 Vacuum deaerator structure

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113104922A (en) * 2021-04-25 2021-07-13 连云港正航电力节能技术有限公司 Electrochemical trinity deaerator

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Address after: 835221 room 425, 4th floor, affordable housing project (bid section I), textile industrial park, Qingshuihe supporting area, Horgos Economic Development Zone, Ili Kazakh Autonomous Prefecture, Xinjiang Uygur Autonomous Region

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