CN106035367B - A kind of composition pesticide containing azacyclotin and propargite - Google Patents
A kind of composition pesticide containing azacyclotin and propargite Download PDFInfo
- Publication number
- CN106035367B CN106035367B CN201610426360.7A CN201610426360A CN106035367B CN 106035367 B CN106035367 B CN 106035367B CN 201610426360 A CN201610426360 A CN 201610426360A CN 106035367 B CN106035367 B CN 106035367B
- Authority
- CN
- China
- Prior art keywords
- azacyclotin
- propargite
- composition
- composition pesticide
- mite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- ZYHMJXZULPZUED-UHFFFAOYSA-N propargite Chemical compound C1=CC(C(C)(C)C)=CC=C1OC1C(OS(=O)OCC#C)CCCC1 ZYHMJXZULPZUED-UHFFFAOYSA-N 0.000 title claims abstract description 31
- 239000000203 mixture Substances 0.000 title claims abstract description 26
- 239000000575 pesticide Substances 0.000 title claims abstract description 16
- 239000003814 drug Substances 0.000 claims abstract description 6
- 239000004480 active ingredient Substances 0.000 claims abstract description 5
- 229940079593 drug Drugs 0.000 claims abstract description 3
- 239000000839 emulsion Substances 0.000 claims description 5
- 239000000375 suspending agent Substances 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 239000004562 water dispersible granule Substances 0.000 claims description 3
- 239000002552 dosage form Substances 0.000 claims description 2
- 239000004530 micro-emulsion Substances 0.000 claims description 2
- 239000003094 microcapsule Substances 0.000 claims description 2
- 239000000725 suspension Substances 0.000 claims description 2
- 150000001345 alkine derivatives Chemical class 0.000 claims 1
- 239000002245 particle Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 10
- 230000002195 synergetic effect Effects 0.000 abstract description 8
- 239000000642 acaricide Substances 0.000 abstract description 7
- 238000013329 compounding Methods 0.000 abstract description 6
- 241000488581 Panonychus citri Species 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 206010059866 Drug resistance Diseases 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 230000003449 preventive effect Effects 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 244000141359 Malus pumila Species 0.000 description 3
- 235000011430 Malus pumila Nutrition 0.000 description 3
- 235000015103 Malus silvestris Nutrition 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 241000607479 Yersinia pestis Species 0.000 description 3
- 230000002045 lasting effect Effects 0.000 description 3
- 230000002265 prevention Effects 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 2
- 241000238631 Hexapoda Species 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- 235000009754 Vitis X bourquina Nutrition 0.000 description 2
- 235000012333 Vitis X labruscana Nutrition 0.000 description 2
- 240000006365 Vitis vinifera Species 0.000 description 2
- 235000014787 Vitis vinifera Nutrition 0.000 description 2
- 230000000895 acaricidal effect Effects 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 239000002390 adhesive tape Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 210000004027 cell Anatomy 0.000 description 2
- 235000020971 citrus fruits Nutrition 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 230000001934 delay Effects 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 230000000749 insecticidal effect Effects 0.000 description 2
- 239000002917 insecticide Substances 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 238000000386 microscopy Methods 0.000 description 2
- 239000002574 poison Substances 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- 125000003626 1,2,4-triazol-1-yl group Chemical group [*]N1N=C([H])N=C1[H] 0.000 description 1
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 description 1
- 241000238876 Acari Species 0.000 description 1
- 241000207199 Citrus Species 0.000 description 1
- 241001672694 Citrus reticulata Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 240000008067 Cucumis sativus Species 0.000 description 1
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 1
- -1 Cyclohexyl propine Chemical compound 0.000 description 1
- 241000219146 Gossypium Species 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 241000497192 Phyllocoptruta oleivora Species 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 241000344246 Tetranychus cinnabarinus Species 0.000 description 1
- 241001454293 Tetranychus urticae Species 0.000 description 1
- 241000488533 Tetranychus viennensis Species 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- ONHBDDJJTDTLIR-UHFFFAOYSA-N azocyclotin Chemical compound C1CCCCC1[Sn](N1N=CN=C1)(C1CCCCC1)C1CCCCC1 ONHBDDJJTDTLIR-UHFFFAOYSA-N 0.000 description 1
- 150000003851 azoles Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- RRTCFFFUTAGOSG-UHFFFAOYSA-N benzene;phenol Chemical compound C1=CC=CC=C1.OC1=CC=CC=C1 RRTCFFFUTAGOSG-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 239000007884 disintegrant Substances 0.000 description 1
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 231100001231 less toxic Toxicity 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000003129 miticidal effect Effects 0.000 description 1
- 210000002569 neuron Anatomy 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 230000003151 ovacidal effect Effects 0.000 description 1
- 230000010627 oxidative phosphorylation Effects 0.000 description 1
- 239000003090 pesticide formulation Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 229940051841 polyoxyethylene ether Drugs 0.000 description 1
- 229920000056 polyoxyethylene ether Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
- 230000009885 systemic effect Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 230000002110 toxicologic effect Effects 0.000 description 1
- 231100000027 toxicology Toxicity 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N55/00—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur
- A01N55/02—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur containing metal atoms
- A01N55/04—Tin
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of miticide compositions containing azacyclotin and propargite.The miticide composition includes the first active ingredient azacyclotin and the second active ingredient propargite and common auxiliary element, and the wherein weight ratio of azacyclotin and propargite is 1:20‑10:1.There is apparent synergistic effect after miticide composition compounding, there is outstanding control effect to the evil mite on crop.The application of miticide composition of the present invention can effectively reduce the usage amount of pesticide, so as to reduce drug cost and reduce the pollution to environment.
Description
Technical field
The invention belongs to pesticide fields, and in particular to be a kind of composition pesticide containing azacyclotin and propargite and its should
With.
Background technology
Azacyclotin, Chinese name：Three（Cyclohexyl）(1,2,4_ triazol-1-yl）Tin, English name：Azocyclotin.Three
Azoles tin is the stronger broad spectrum activity acaricide of action of contace poison, can kill deutonymph, into mite and summer egg, invalid to winter egg, the longevity of residure is reachable
30 days or more, there is good control effect to sensibility and with drug resistance mite class.Its toxicological mechanism may be with inhibition
The oxidative phosphorylation process of nerve cell is related.Suitable for the full pawl of apple on the crops such as prevention apple, citrus, grape, vegetables
Mite, tetranychus viennensis, panonychus citri, phyllocoptruta oleivora, Tetranychus urticae, Tetranychus cinnabarinus, Mite etc..
Propargite, Chinese name：2-（4- tert-butyl benzene oxies）Cyclohexyl propine -2- base sulfites, English name:
Propargite.Belong to efficiently, less toxic acaricide, have and tag and stomach poison function, no infiltration and systemic action.To children mite and into
Mite effect is good, and ovicidal effect is poor.It can effectively preventing and treating apple-tree, cotton, cucumber, tetranychid class pest on grape and vegetables.
Insecticide variety containing single active ingredient existing defects in pesticide control of insect, for example, continuous use is a kind of
Insecticide easily generates resistance, and insecticidal spectrum is narrow, it is impossible to provide comprehensive protection, peasant's drug cost height etc. for crop.And pass through
The composition of two kinds of active components can overcome drawbacks described above to a certain extent.Agriculture chemical compounding uses, and not only facilitates and delays
The generation of drug resistance, and the service life of pesticide species can be extended, lower usage amount, it is cost-effective, it reduces to environment
Pollution.
The present inventor has found to compound azacyclotin and propargite by the further investigation to azacyclotin and propargite,
In the range of certain mixed ratio have synergistic function, in practical applications, have synergistic effect two kinds of activity into
Point compounding, can improve preventive effect, reduce effective ingredient consumption, cost-effective, slow down pest resistance, play that more worms are simultaneous to be controlled, and reduce
The use cost of peasant.
Invention content
The purpose of the present invention is to provide a kind of miticide composition containing azacyclotin and propargite, the composition compounding has
Apparent synergistic effect, applied to the evil mite on prevention crop.
In order to achieve the above objectives, the present invention adopts the following technical scheme that：A kind of Insecticidal combinations containing azacyclotin and propargite
Object, it is characterised in that：The weight ratio of azacyclotin and propargite is 1:20-10:1, azacyclotin and propargite weight summation are in pesticide
Weight percent in composition is 1-60%, remaining is auxiliary element conventional in Pesticide formulation.
Composition pesticide of the present invention is prepared into any one dosage form agriculturally used by known method, including wettable
Pulvis, granule, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent.
The pesticide auxiliary element includes dispersant, wetting agent, emulsifier, antifreezing agent, antifoaming agent, thickener, stabilization
Agent, disintegrant, film forming agent, colorant, filler and solvent.
The frequency of administration and usage amount of the present composition are with crops, pest, weather condition changes and small variations,
It can achieve the purpose that effectively to prevent by using appropriate dosage.
Compared with prior art, the beneficial effects of the present invention are：
1st, composition compounding has synergistic function, and the prevention to evil mite significantly improved compared with single dose exclusive use is imitated
Fruit.
2nd, double action mechanism delays the generation of evil mite drug resistance.
3rd, composition pesticide of the invention is to crop safety, and preventive effect is good, and the lasting period is long.
Specific embodiment
In order to make the purpose of the present invention, technical solution and advantage definitely, with reference to embodiment to the present invention into
Row is described in detail.
First, example of formulations
Embodiment 1:50% azacyclotin propargite aqueous emulsion（Azacyclotin：Propargite=1:9）
Azacyclotin 5%
Propargite 45%
Phenethyl phenol polyethenoxy ether 4%
Thermally coupled distillation columns 3%
Triphenoethyl benzene phenol polyethenoxy ether phosphate 2%
Organosilicon 1%
Polyvinyl alcohol 3%
Dimethylbenzene 8%
Deionized water surplus
Embodiment 2：30% azacyclotin propargite suspending agent（Azacyclotin：Propargite=1:2）
Azacyclotin 10%
Propargite 20%
Nonylphenol polyoxyethylene ether 5%
Sodium lignin sulfonate 8%
Polyvinyl alcohol 1%
Propylene glycol 4%
Deionized water surplus
Embodiment 3：40% azacyclotin propargite water dispersible granules（Azacyclotin：Propargite=7:1）
Azacyclotin 35%
Propargite 5%
Neopelex 3%
Alkylnaphthalene sulfonate formaldehyde condensation products 6%
Xanthans 4%
Diatomite surplus
2nd, indoor biological determination of activity and field control effectiveness test
1st, azacyclotin and propargite are to the Toxicity Determination of panonychus citri
Test method refers to《People's Republic of China (PRC) agricultural industry criteria NY/T1154. 7-2006》With《The Chinese people are total to
With state agricultural industry criteria NY/T1154. 12-2008》.Using slide proofing method, i.e., double faced adhesive tape is cut into IcmX2cm and be attached to
The female back side into mite of panonychus citri is sticked on adhesive tape by one end of glass slide, and each 40 mites of slide, if 4 repetitions, 4 is small
When after microscopy.After choosing dead mite, benefit adds living into mite, takes out, uses after 5 seconds being stained with the female slide into mite and being placed in proofing in liquid
Filter paper absorbs extra liquid around glass slide and mite body, is cultivated under the conditions of 25 °C of immigration, relative humidity 90%, microscopy after 24 hours,
Record death toll and survival number（The motionless person of mite body is touched with writing brush point and is considered as death), blank control is handled with clear water.It calculates each
The death rate or corrected mortality of processing, and co-toxicity coefficient is calculated according to the abundant methods of Sun Yun.Result of the test is as shown in table 1
Azacyclotin is can be seen that by the data of table 1：Propargite is 1:20-10:Co-toxicity coefficient is above 120 when 1, table
Reveal good synergistic function.Wherein, azacyclotin：Propargite is 1:When 10, synergistic function is best.
2nd, azacyclotin and propargite are to the field control effectiveness test of panonychus citri
In order to preferably verify the present invention practical application effect, below embodiment using the present invention preparation, do mandarin orange
Citrus red mite control effect field control effectiveness test investigates insect population before dispenser, 14d, 30d investigate residual mite living respectively after medicine
Number looks into 2 plants during investigation per cell, and every plant is looked into 5 blades respectively by the orientation of the four corners of the world 4, looks into 40 blades altogether per cell, remembers
Mite number living is carried, calculates control effect.
As can be seen from Table 2, the preparation described in embodiment dilution 5000 times after, after medicine 14 days and 30 days preventive effects it is preferable,
Control effect when diluting 2000 times better than single dose, illustrates azacyclotin and propargite compounding compared with two kinds of single doses are used alone,
The preventive effect to panonychus citri can be improved, while reduces the dosage of active ingredient, there is good lasting effect, and do not send out
Now the medicament produces poisoning to citrus fruit tree.
In conclusion azacyclotin and the complex composition of propargite that the present invention uses, have synergistic function.With showing
Some single formulations are compared, and miticidal effect significantly improves, and the lasting period is long, to crop safety, can slow down the production of evil mite drug resistance
It is raw, it is worth promoting and applying in agricultural production.
Claims (4)
1. a kind of composition pesticide, which is characterized in that active ingredient includes azacyclotin and propargite, wherein, azacyclotin and alkynes mite
Special weight ratio is 1:20-10:1.
2. composition pesticide according to claim 1, which is characterized in that the gross weight of azacyclotin and propargite in the composition
Amount percentage composition is 1-80%.
3. composition pesticide according to claim 1 or 2, which is characterized in that the dosage form of the composition pesticide is particle
One kind in agent, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent.
4. the application of the composition pesticide according to any one of claim 1-3 claims, which is characterized in that the agriculture
Drug composition is used to prevent the evil mite on crop.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610426360.7A CN106035367B (en) | 2016-06-16 | 2016-06-16 | A kind of composition pesticide containing azacyclotin and propargite |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610426360.7A CN106035367B (en) | 2016-06-16 | 2016-06-16 | A kind of composition pesticide containing azacyclotin and propargite |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106035367A CN106035367A (en) | 2016-10-26 |
| CN106035367B true CN106035367B (en) | 2018-06-08 |
Family
ID=57168276
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610426360.7A Active CN106035367B (en) | 2016-06-16 | 2016-06-16 | A kind of composition pesticide containing azacyclotin and propargite |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106035367B (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101138340A (en) * | 2006-09-07 | 2008-03-12 | 葛尧伦 | Compounded miticide composition containing fenbutatin oxide |
| CN102484990A (en) * | 2010-12-01 | 2012-06-06 | 联保作物科技有限公司 | Composite miticide for farmland and fruit trees |
-
2016
- 2016-06-16 CN CN201610426360.7A patent/CN106035367B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101138340A (en) * | 2006-09-07 | 2008-03-12 | 葛尧伦 | Compounded miticide composition containing fenbutatin oxide |
| CN102484990A (en) * | 2010-12-01 | 2012-06-06 | 联保作物科技有限公司 | Composite miticide for farmland and fruit trees |
Non-Patent Citations (1)
| Title |
|---|
| ***锡与不同药剂混配施用对柑桔的药害试验;姚廷山等;《中国南方果树》;20111231;第40卷(第4期);第57-59页 * |
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| Publication number | Publication date |
|---|---|
| CN106035367A (en) | 2016-10-26 |
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Effective date of registration: 20180504 Address after: 362000 the research and development center of biological pharmaceutical industry incubation platform (Yongchun youth Pioneer Park) A011, de Feng Village, Peach Town, Yongchun, Quanzhou, Fujian Applicant after: YONGCHUN RUITUO INFORMATION TECHNOLOGY CENTER Address before: 528000 2 Chancheng Zhi Bo Li Hai garden, Ji Hua three road, Chancheng District, Foshan, Guangdong Applicant before: Li Xiangying |
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Effective date of registration: 20201229 Address after: 250100, 4 story 415, office building, 2 sang Yuan Road, Licheng District, Ji'nan, Shandong. Patentee after: Zhongxin konong (Shandong) Ecological Agriculture Co.,Ltd. Address before: 362000 the research and development center of biological pharmaceutical industry incubation platform (Yongchun youth Pioneer Park) A011, de Feng Village, Peach Town, Yongchun, Quanzhou, Fujian Patentee before: YONGCHUN RUITUO INFORMATION TECHNOLOGY CENTER |
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Address after: Room 304, Building 4, South District, Agricultural Academy of Sciences, No. 28 Sangyuan Road, Quanfu Street, Licheng District, Jinan City, Shandong Province, 250000 Patentee after: Shandong Zhongxin Kenong Life Technology Co.,Ltd. Address before: 250100, 4 story 415, office building, 2 sang Yuan Road, Licheng District, Ji'nan, Shandong. Patentee before: Zhongxin konong (Shandong) Ecological Agriculture Co.,Ltd. |