CN106032314B - Concrete and preparation method thereof - Google Patents

Concrete and preparation method thereof Download PDF

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Publication number
CN106032314B
CN106032314B CN201510126160.5A CN201510126160A CN106032314B CN 106032314 B CN106032314 B CN 106032314B CN 201510126160 A CN201510126160 A CN 201510126160A CN 106032314 B CN106032314 B CN 106032314B
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concrete
aggregate
flyash
weight
mixture
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CN106032314A (en
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张坤
龙波
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Zoomlion Heavy Industry Science and Technology Co Ltd
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Zoomlion Heavy Industry Science and Technology Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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Abstract

The invention relates to the field of building materials, and discloses concrete which comprises a cementing material and a continuous graded mixture bonded with each other through the cementing material, wherein the continuous graded mixture comprises a fine aggregate and a coarse aggregate, and the cementing material comprises the following components in a weight ratio of 1: (0.3-1.5): (0.5-1.5) cement, fly ash and mineral powder, wherein the weight ratio of the fine aggregate to the coarse aggregate is 1: (0.8-1.3), and the particle size of the coarse aggregate is less than or equal to 25 mm. The invention also discloses a preparation method of the concrete, which comprises the step of mixing the cementing material, the continuous grading mixture and water. The invention can prepare the concrete with the self-compacting concrete fluidity effect by adopting the continuous gradation mixture and using the cementing material amount of the common concrete, thereby completely getting rid of the contradiction of high fluidity and high cost, leading the fluidized concrete to be widely popularized and being beneficial to improving various performances of concrete buildings.

Description

A kind of concrete and preparation method thereof
Technical field
The present invention relates to building material fields, and in particular, to a kind of concrete and preparation method thereof.
Background technology
With the development of society, commerical ready-mixed concrete plays significant role, the quality of concrete in the development of the national economy It is merely not only whether intensity meets the requirements, but also need the condition met to be it first to have good workability.Workability Good concrete is not only convenient for constructing, and can be to avoid defects of concrete structure such as similar honeycomb, layerings.The work of concrete Mainly the filling between grading of aggregates, raw material, working volume, additive usage etc. are closely bound up for property.As city is in face of mixed The raising of solidifying soil performance requirement, the following high performance concrete will become market development mainstream, the liquidation under especially low glue Concrete.
For general goods concrete, mix-design mainly uses empirical value, coarse aggregate to mostly use maximum particle diameter greatly For the single aggregate of 31.5mm, grading of aggregates difference and non-adjustable.Workability of concrete mixes additive or water more rely primarily on Ensure, concrete strength ensures mainly by multi-purpose cement, miberal powder, flyash volume mainly determined using empirical value.It needs The slump of pumping needs vibrating head to coordinate in 18 ± 2cm, poor fluidity when pouring.By increase water consumption or Increase admixture dosage to change slump, concrete can be caused collapse damage situation, therefore, the agitated transport vehicle of concrete easily occur After being transported to building site, building site worker would generally add water for ease of construction to concrete, although workability can obtain a degree of change It is kind, but at this time since the ratio of mud increases, the strength reduction of concrete causes concrete component serious security problem easily occur.
For self-compacting concrete (SCC), the total amount for relying primarily on increase cementitious matter (is generally at least 255kg/t bones Total cementitious matter of material), the grain size for reducing coarse aggregate is 5-15mm or 5-25mm, to make concrete obtain more working bodies The characteristics of accumulating, high fluidity reached with this, but its cost is generally higher, and it is mostly only applied to the concrete of high intensity and difficulty With in the concrete structure engineering of cast.
In other words, existing normal concrete is limited to mixing proportion design method, causes aggregate discontinuous, in concrete Portion's filling effect is poor, and workability is poor, and concrete structure the faults of construction such as honeycomb easily occurs after pouring.And self-compacting concrete by Obtain preferable mobility in cementitious matter dosage need to be increased just can make concrete, therefore its cost of raw material is higher, economy compared with Difference.
Invention content
The purpose of the present invention is:Overcome the defect that the workability of concrete in the prior art is not high, cementitious matter dosage is larger, There is provided that a kind of cementitious matter dosage is low, the good liquidation concrete of workability and preparation method thereof.
The present inventor has found under study for action, and specific continuous grading mixture and cementitious matter are mixed with coagulation Soil can be in the lower purpose for realizing improvement liquidation concrete performance of cementing doses.Therefore, above-mentioned in order to realize Purpose, the present invention provides a kind of concrete, which contains cementitious matter and by cementitious matter company bonded to each other Continuous graded mixture, the continuous grading mixture includes fine aggregate and coarse aggregate, wherein the cementitious matter contains weight ratio and is 1:(0.3-1.5):The weight ratio of cement, flyash and the miberal powder of (0.5-1.5), the fine aggregate and coarse aggregate is 1:(0.8- 1.3), grain size≤25mm of the coarse aggregate.
The present invention also provides the preparation method of above-mentioned concrete, this method includes by cementitious matter, continuous grading mixture It is mixed with water.
The present invention uses the glue of normal concrete by using continuous grading mixture (preferably 2 sand, 2 stone of specified particle diameter) Ramming material amount (200-240kg/t aggregates) can make the concrete with self-compacting concrete mobility effect, and (liquidation is mixed Solidifying soil), therefore the high cost of high fluidity (high cementing doses) this contradictory problems have been completely free of, enable liquidation concrete It is widely popularized, contributes to the properties for promoting concrete structure.The concrete of the present invention is the flowing of low cementitious matter Change concrete, for divergence between 55-65cm, intensity can reach C30-C60, be not in that isolation, bleeding and floating ash etc. are existing As having the characteristics that easily construction, good economy performance (workability is good).
Other features and advantages of the present invention will be described in detail in subsequent specific embodiment part.
Specific implementation mode
The specific implementation mode of the present invention is described in detail below.It should be understood that described herein specific Embodiment is merely to illustrate and explain the present invention, and is not intended to restrict the invention.
In the present invention, in the absence of explanation to the contrary, continuous grading refers to the mark with a set of regulations screen size When quasi- sieve carries out mesh analysis to a certain aggregate, obtained grading curve is a smooth curve, has continuous lines, adjacent grade Pellet between have certain proportionate relationship, this descending, each grade particle has, and in mass ratio example collocation composition Aggregate is mixed, referred to as " continuous grading mixture ";Coarse aggregate refers to (also known as " stone ") aggregate that grain size is more than 5mm;Thin bone Material refers to (also known as " sand ") aggregate of the grain size between 0.05-5mm;" doing saturated weight in face " i.e. S.S.D weight indicates bone Material internal void is aqueous to reach saturation and weight when its dry tack free;In the present invention, in the case of not illustrating (as before State S.S.D weight), the weight being related to refers both to the dry weight of material, the i.e. water-free weight of material.
Concrete provided by the invention contains cementitious matter and is mixed by cementitious matter continuous grading bonded to each other Expect (aggregate), the continuous grading mixture includes fine aggregate and coarse aggregate, and it is 1 that the cementitious matter, which contains weight ratio,:(0.3- 1.5):Cement, flyash and the miberal powder (dosage of the flyash and miberal powder is identical or different) of (0.5-1.5), the thin bone The weight ratio of material and coarse aggregate is 1:(0.8-1.3) (preferably 1:(0.9-1)), grain size≤25mm of the coarse aggregate.
Liquidation concrete under low cementitious matter tests the total grade of aggregate by a certain proportion of stone, sand aggregate blending technology It is made into continuous state, and determines that doping quantity of fly ash makes using the filling relationship between inside concrete according to preferred embodiment Inside concrete filling is enough, finally total cementing doses of normal concrete is used to make with self-compacting concrete mobility The concrete of effect, therefore the high cost of high fluidity this contradictory problems have been completely free of, so that liquidation concrete is obtained It is widely popularized, promotes the properties of concrete structure.
A preferred embodiment of the invention, on the basis of the total weight of the fine aggregate, in the fine aggregate The content that grain size is more than aggregates of the 0.075mm less than or equal to 3mm is 65-75wt.% (weight percent), and it is small that grain size is more than 3mm In the aggregate equal to 5mm content be 25-35wt.%.
In order to obtain more preferably working volume, the ratio between the S.S.D weight and the weight of flyash of the fine aggregate For 9-16.
A preferred embodiment of the invention, on the basis of the total weight of the coarse aggregate, in the coarse aggregate The content that grain size is more than aggregates of the 5mm less than or equal to 12.5mm is 25-35wt.%, and grain size is more than 12.5mm and is less than or equal to 25mm Aggregate content be 65-75wt.%.
The content for regulating and controlling different-grain diameter aggregate in coarse aggregate and fine aggregate using above-mentioned preferred embodiment can be further Make grading of aggregates that continuous grading state be presented, obtained grading curve is more close with ideal Fu Leshi curves, to make concrete Performance more preferably.
In the present invention, the cement, flyash and miberal powder can be the conventional selection of this field.But the cement is excellent It is selected as the Portland cement of PO42.5.
Flyash is preferably (steam power plant generates) flyash (such as second class powered coal ash or first level flour of grade more than two level Coal ash).Flyash is the particle matter that coal-burning power plant obtains, mainly by calcium aluminium silicate (calcium Aluminosilicates it) forms, bulk density is usually 0.5-1.5g/cm3
Miberal powder is preferably granulated blast-furnace slag of the grade at S95 grades or more.
In the present invention, by being used cooperatively specific cementitious matter and aggregate, can largely it reduce described cementing The dosage of material.Therefore, in a preferred embodiment of the invention, relative to continuous grading mixture per ton, the cementitious matter Dosage be 200-240kg.
In the present invention, the concrete can also contain water-reducing agent.The dosage of the water-reducing agent is not required particularly, Under preferable case, relative to continuous grading mixture per ton, the dosage of the water-reducing agent is 3.5-4kg.The water-reducing agent can Think polycarboxylate water-reducer commonly used in the art (solution that solid content is 10-30wt.% is typically formulated as when use), and Can be commercially available, this will not be detailed here.
The content of water can be customary amount in the concrete of the present invention, for example, being mixed relative to continuous grading per ton Material, the dosage of water are generally 90-100kg.
The method provided by the invention for preparing the concrete includes mixing cementitious matter, continuous grading mixture and water. Wherein, the type and dosage of cementitious matter and continuous grading mixture are as previously mentioned, details are not described herein.
Conventional mode may be used and carry out the mixing, for example, can be by blender.Preferred reality according to the present invention Mode is applied, is by the mode that cementitious matter, continuous grading mixture and water mix:(1) first cementitious matter, fine aggregate and water are mixed, (2) mixture of acquisition is mixed with coarse aggregate again.If using water-reducing agent, water-reducing agent is preferably mixed in step (1).
The particle of flyash is in ball-type, and addition is helpful to the liquidation of concrete.The glue of common flyash Knot property is very low, and only has an impact to the later strength of concrete.The present inventor has found under study for action, flyash and thin The Unit Weight (tight packing density) of aggregate is bigger, and the mobility of concrete is better.It, can in order to obtain more preferably working volume To determine the dosage of flyash according to fine aggregate.Therefore, in a preferred embodiment of the invention, flyash is mixed with fine aggregate Unit Weight afterwards indicates that the weight of flyash is indicated with F with U, and the S.S.D weight of fine aggregate indicates that flyash adds with Wa Rate is added to be indicated with F% and F%=F/ (F+Wa), this method further includes determining relationship between U and F% using unit weight experiment, And conic section regression equation is established, so that it is determined that the adding rate of best flyash.Wherein, the unit weight experiment is specific Operation can be found in GB/T14685-2001.
In the present invention, the dosage of water is not particularly limited, can be conventional amount used.For example, relative to company per ton Continuous graded mixture, the dosage of water can be 90-100kg.
The present invention will be described in more detail by the following examples, but the present invention is not limited to these embodiments.
In following embodiment, the addition method for determination of amount of flyash is following (by taking embodiment 1 as an example):
Flyash indicates that the weight of flyash is indicated with F, fine aggregate with U with the mixed Unit Weight of fine aggregate S.S.D weight indicates that the adding rate of flyash is indicated with F% and F%=F/ (F+Wa) with Wa.According to unit weight experiment (referring to Standard GB/T14685-2001) determine relationship between U (y) and F% (x), and establish conic section regression equation " y=- 5843.2x2+ 946.78x+4760.9, R2=0.9251 ", so as to be calculated, when x=8%, y will be maximized, thus The dosage (F) of flyash can be further determined according to the S.S.D weight of fine aggregate.
Embodiment 1-4
Cement is the Portland cement of PO42.5, and technical parameter meets GB175-2007;Flyash is two level;Mine Powder is S95 grades, 7 days activity >=75%, 28 days activity >=95%;The selection of aggregate is as shown in table 1 below.
Preparation process is:First fine aggregate (fine sand and coarse sand), cement, miberal powder, flyash, water, polycarboxylate water-reducer (are subtracted Water rate is 25%, is purchased from Shanghai Sanrui Chemistry Co., Ltd, and when use is configured to the solution that solid content is 12wt.%) input stirs Stirring 45 seconds in machine are mixed, mortar is formed, coarse aggregate (gravelstone and great Shi) is then cast to discharging after stirring 15 seconds again, obtains coagulation Soil.
Reference standard GB/T50080-2002 measures the divergence of concrete with slump bucket.
Concrete test block is made using die trial, and is conserved 28 days in fog room, conjunction should just be calculated in 46MPa or more by surveying its intensity Lattice.Concrete strength is tested according to GB/T 50081-2002 standard for test methods of mechanical properties of ordinary concretes.
Table 1
As can be seen from the above embodiments, for concrete divergence of the invention between 55-65cm, intensity can reach C30- Phenomena such as C60 is not in isolation, bleeding and floating ash.
The preferred embodiment of the present invention has been described above in detail, still, during present invention is not limited to the embodiments described above Detail can carry out a variety of simple variants to technical scheme of the present invention within the scope of the technical concept of the present invention, this A little simple variants all belong to the scope of protection of the present invention.
It is further to note that specific technical features described in the above specific embodiments, in not lance In the case of shield, can be combined by any suitable means, in order to avoid unnecessary repetition, the present invention to it is various can The combination of energy no longer separately illustrates.
In addition, various embodiments of the present invention can be combined randomly, as long as it is without prejudice to originally The thought of invention, it should also be regarded as the disclosure of the present invention.

Claims (7)

1. a kind of concrete, which contains cementitious matter and is mixed by cementitious matter continuous grading bonded to each other Material, the continuous grading mixture includes fine aggregate and coarse aggregate, which is characterized in that it is 1 that the cementitious matter, which contains weight ratio,: 0.3-1.5:The weight ratio of cement, flyash and the miberal powder of 0.5-1.5, the fine aggregate and coarse aggregate is 1:0.8-1.3, it is described Grain size≤25mm of coarse aggregate;Wherein, on the basis of the total weight of the fine aggregate, grain size is more than in the fine aggregate The content of aggregates of the 0.075mm less than or equal to 3mm is 65-75wt.%, and grain size is more than the content of aggregates of the 3mm less than or equal to 5mm For 25-35wt.%;On the basis of the total weight of the coarse aggregate, grain size is more than 5mm and is less than or equal to 12.5mm in the coarse aggregate Aggregate content be 25-35wt.%, grain size be more than 12.5mm less than or equal to 25mm aggregate content be 65-75wt.%;
Wherein, relative to continuous grading mixture per ton, the dosage of the cementitious matter is 200-240kg.
2. concrete according to claim 1, wherein the face of the fine aggregate do saturated weight and flyash weight it Between ratio be 9-16.
3. concrete according to claim 1 or 2, wherein the cement is the Portland cement of PO42.5;Fine coal Ash is second class powered coal ash or level-one flyash;The granulated blast-furnace slag that miberal powder is S95 grades or more.
4. concrete according to claim 1, wherein the concrete also contains water-reducing agent;Relative to per ton continuous The dosage of graded mixture, the water-reducing agent is 3.5-4kg.
5. the method for preparing the concrete described in any one of claim 1-4, this method includes by cementitious matter, continuous grading Mixture and water mixing.
6. according to the method described in claim 5, wherein, being by the mode that cementitious matter, continuous grading mixture and water mix:First Cementitious matter, fine aggregate and water are mixed, then the mixture of acquisition is mixed with coarse aggregate.
7. method according to claim 5 or 6, wherein flyash indicates with the mixed Unit Weight of fine aggregate with U, The weight of flyash indicates that the face of fine aggregate does saturated weight and indicates that the adding rate of flyash is indicated with F% and F% with Wa with F =F/ (F+Wa), this method further include using unit weight experiment to determine the relationship between U and F%, and establish conic section recurrence Equation, so that it is determined that the adding rate of best flyash.
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