CN106012584A - Alkaline one-bath-process dyeing method for chinlon 56 fiber/cotton blended fabric - Google Patents
Alkaline one-bath-process dyeing method for chinlon 56 fiber/cotton blended fabric Download PDFInfo
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- CN106012584A CN106012584A CN201610437609.4A CN201610437609A CN106012584A CN 106012584 A CN106012584 A CN 106012584A CN 201610437609 A CN201610437609 A CN 201610437609A CN 106012584 A CN106012584 A CN 106012584A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/22—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using vat dyestuffs including indigo
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67333—Salts or hydroxides
- D06P1/6735—Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/003—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated using vat or sulfur dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/028—Material containing basic nitrogen using reactive dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/82—Textiles which contain different kinds of fibres
- D06P3/8204—Textiles which contain different kinds of fibres fibres of different chemical nature
- D06P3/8219—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and amide groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/10—After-treatment with compounds containing metal
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Coloring (AREA)
Abstract
The invention discloses an alkaline one-bath-process dyeing method for a chinlon 56 fiber/cotton blended fabric. The method comprises the following step that vat dyes or reactive dyes are adopted for dyeing the chinlon 56 fiber/cotton blended fabric, wherein the chinlon 56 fiber/ cotton blended fabric is the blended fabric of chinlon 56 and cotton fiber. In the alkaline one-bath-process dyeing method for the chinlon 56 fiber/cotton blended fabric, the reactive dyes and the chinlon 56 are combined through the covalent bond, the fastness is better compared with acid-bath ion bond combination, and the dyeing temperature is lower compared with a conventional dyeing method. Low-temperature dyeing can reduce damage to the fabric. The reactive dyes and the pure cotton fabric are combined through the covalent bond, and the dyeing method is the same as the dyeing method of the chinlon 56 fiber.
Description
Technical field
The present invention relates to the alkali bath method colouring method of a kind of chinlon 56 fibers/cotton blended spinning face fabric.
Background technology
Nylon fabric is the first synthetic fibers occurred in the world, and its kind is a lot, but all contains in molecular structure
One identical amide groups, general conventional kind has nylon-6 for polycaprolactam, and nylon-66 is hexamethylene diamine and oneself
Diacid is polymerized, and chinlon 56 is a kind of novel Fypro, uses petroleum different from chinlon 66, it
The raw material used is biological raw material, is fermented by biological engineering method and prepare penta 2 from each kind of starch and stalk cellulose
Amine, due to high-volume, low cost, therefore can substitute for hexamethylene diamine.Bio-based fiber has green, environmental friendliness, former
Expect the good characteristics such as renewable and biodegradation, contribute to solving that current global economy social development faced is serious
Resource and energy shortage, and the problem such as environmental pollution.
Various fibers, whether natural fiber or staple fibre and synthetic fibers respectively possess some good points, and respectively have weak points.
Natural fiber such as Cotton Gossypii hygroscopicity is relatively good, comfortable and easy to wear, and the general wearability of synthetic fibers is good, and strength is high, but inhales
Moist difference, breathability is bad.Chinlon 56 has many excellent characteristics, and intensity is close to chinlon 66, higher than terylene,
Density is less than terylene；Hygroscopicity is high, and antistatic behaviour is good；Pliability is close to Pilus Caprae seu Ovis；Vitrification point is less than chinlon 66,
Chinlon 56 degree of crystallinity is 46 DEG C relatively lower than nylon-66, chinlon 56 vitrification point, and chinlon 66 is 52 DEG C and is far below
Terylene, it is ensured that lower temperature resistance under cold conditions；Softness, wearability is good.The typically upper dye temperature of chinlon 66 is 40-98 DEG C,
The dyeing fabric temperature of chinlon 56 fiber can be reduced to 40-80 DEG C.
Chinlon 56 and textile blending, it is possible to fully use the feature of various fibers, learn from other's strong points to offset one's weaknesses, reinforced fabric
Wearability.The disclosure of correlation technique is had no with chinlon 56 fiber and textile blended yarn weaved fabric alkali bath method colouring method.
Summary of the invention
It is an object of the invention to provide the alkali bath method colouring method of a kind of chinlon 56 fibers/cotton blended spinning face fabric.
The alkali bath method colouring method of chinlon 56 fibers/cotton blended spinning face fabric provided by the present invention, comprises the steps:
Use reducing dye or reactive dye that chinlon 56 fibers/cotton blended spinning face fabric is dyeed；
Described chinlon 56 fibers/cotton blended spinning face fabric is the blended yarn weaved fabric of chinlon 56 and cotton fiber.
In above-mentioned colouring method, when using described reactive dye to dye, specifically include following steps:
1) preparation dye liquor, described dye liquor is prepared by K-type reactive dye and sodium sulfate and is obtained；
2) described chinlon 56 fibers/cotton blended spinning face fabric and described dye liquor are sequentially added into staining machine；Heat described dye
Color machine, after temperature rises to 50～60 DEG C, adds alkaline matter regulation pH value to behind 9～10 in described staining machine,
It is continuously heating to 80 DEG C, and is incubated the dye that continuation dyeing i.e. realizes chinlon 56 fibers/cotton blended spinning face fabric for 30～60 minutes
Color.
In described dye liquor, the quality-volumetric concentration of described K-type reactive dye can be 20～80g/L, concretely 20g/L,
Quality-the volumetric concentration of described sodium sulfate can be 30～50g/L, concretely 40g/L.
In above-mentioned colouring method, described alkaline matter can be sodium carbonate.
When using described reactive dye to dye, due to described reactive dye and chinlon 56 fibers/cotton blended fabric
Dyeing in alkalescence is bathed, be combined for covalent bond between dyestuff with fiber, the most every color fastness floats index error except chlorine-resistant
Outer relatively good.
In above-mentioned colouring method, when using described reducing dye to dye, specifically include following steps:
Described chinlon 56 fibers/cotton blended spinning face fabric is padded in reducing dye suspended substance, dries after taking-up；So
After continue to be padded in reducing solution, more successively through decatize, washing, aoxidizing and soaping i.e. realizes chinlon 56 fiber/cotton
The dyeing of blended yarn weaved fabric；
Described reducing dye suspended substance refers to be dispersed in water described reducing dye the dispersion liquid obtained, described reduction
The concentration of reducing dye described in dye suspension can be 10～80g/L.
In above-mentioned colouring method, described reducing solution is the aqueous solution of Caustic soda and sodium dithionite (sodium hydrosulfite), its
Described in the quality-volumetric concentration of Caustic soda be 10～30g/l, concretely 20g/l, the quality of described sodium dithionite-
Volumetric concentration is 20～40g/l, concretely 34g/l.
In above-mentioned colouring method, the temperature of described decatize can be 100 DEG C～110 DEG C, and the time can be 20～150s, specifically
Can under conditions of 102 DEG C decatize 40s；
The oxidant that described oxidation uses can be hydrogen peroxide, and the temperature of described oxidation can be 50 DEG C～60 DEG C, concretely
55℃；
The described temperature soaped can be 90 DEG C～100 DEG C, concretely 95 DEG C, described in soap and can use soap and soda
Aqueous solution is as detergent.
In the present invention, the blending ratio of chinlon 56 described in described chinlon 56 fibers/cotton blended spinning face fabric can be 10～85%,
Such as 50% or 85%.
Fabric bright-colored after the dyeing of described reducing dye, chromatograph is relatively complete, and color fastness is excellent, particularly soap and
Light fastness is excellent.
The alkali bath method colouring method of chinlon 56 fibers/cotton blended spinning face fabric that the present invention provides has the advantage that
Owing to nylon 56 has the most different from common polyamide, the crystal conversion of nylon 56 is irreversible；Brocade
Synthetic fibre 56 is a kind of typical even-odd polyamide, can not produce all possible intermolecular when strand has and is all-trans conformation
Hydrogen bond action.The research of the optical microscope carried out under waiting gentle non-isothermal condition shows the spherocrystal of nylon 56 and often has
Idol-idol the chinlon of rule laminated structure has different optical properties.
Caused by the difference in terms of crystallization, in terms of acid and alkali-resistance, the performance of nylon 56 and common nylon 6, nylon
66 compare, and differ bigger.Under identical treatment conditions, the fibre strength of nylon 56 reduces more, causes research
More nylon 6 and nylon66 fiber dyeing can not fit entirely into the dyeing of nylon 56.And pure cotton fabric is at alkali
Dyeing under the conditions of property is then conventional colouring method, so chinlon 56 fiber and textile blended yarn weaved fabric alkali bath method dye
Color method can realize smoothly.
In the alkali bath method colouring method of chinlon 56 fibers/cotton blended spinning face fabric of the present invention, reactive dye and chinlon 56 with
Covalent bond combines, and fastness is better than what acid bath combined with ionic bond, and dyeing temperature is less than common staining method.Low temperature
Dyeing can reduce the damage to fabric.Reactive dye are also to be combined with covalent bond with pure cotton fabric, contaminate with chinlon 56 fiber
Color method is consistent.
Detailed description of the invention
Experimental technique used in following embodiment if no special instructions, is conventional method.
Material used in following embodiment, reagent etc., if no special instructions, the most commercially obtain.
K-type reactive dye: reactive brilliant red 3B, purchased from Hensel Man.
Reducing dye: the black FBL of wheat siron, purchased from Hensel Man.
Embodiment 1, K-type reactive dyeing
The dyeing of chinlon 56 fibers/cotton blended spinning face fabric be suitable for high temperature modification K reactive dye.
20D × 20D × 350T chinlon 56 fibers/cotton blended spinning face fabric (chinlon 56 fiber blend ratio is 50%) is loaded and overflows
In stream staining machine, in adjusting staining machine, coolant-temperature gage is 40 DEG C of start circulations, by reactive brilliant red 3B reactive dye during dyeing
(20g/L) dye liquor being made into sodium sulfate (40g/L) slowly heats up 1 DEG C/1 minute to 60 DEG C in adding staining machine and adds
Enter sodium carbonate (20g/l) regulation pH value to after 10, continue to heat up 80 DEG C and be incubated continuation dyeing 60 by 1 DEG C/min
Minute.Check colors qualified after carry out post processing.
Every color fastness index of the fabric after the present embodiment dyes is as shown in table 1.
By data in table 1 it can be seen that after Ran Se every fastness reach requirement.
Embodiment 2, the dyeing of reducing dye
45 × 45/130 × 70 chinlon 56 fibers/cotton blended spinning face fabric (chinlon 56 fiber blend ratio is 85%), uses reducing dye
Dye chinlon 56 dyes on continuous pad-dyeing range.
Two leaching two roll reducing dye suspended substance liquid → infrared ray 90 DEG C dryings → room temperature one immersing and rolling reducing solution (Caustic soda and
The aqueous solution of sodium hydrosulfite (sodium dithionite), wherein quality-the volumetric concentration of Caustic soda is 20g/l, the matter of sodium hydrosulfite
Amount-volumetric concentration is 34g/l) → 102 DEG C of decatizes → 55 DEG C of oxidations of 40 seconds → washing, hydrogen peroxide (30wt%) 1g/l → 95 DEG C
Soap, the 3g/l → post processing of soap 5g/l, soda.
Every color fastness index of the fabric after the present embodiment dyes is as shown in table 1.
By data in table 1 it can be seen that after Ran Se every fastness reach requirement.
Table 1 dyes chinlon 56 fabric every color fastness index
| Name of an article project | Embodiment 1 | Embodiment 2 |
| Dry friction color fastness | 4.5 | 4.5 |
| Wet friction color fastness | 4.5 | 4.5 |
| Color fastness to water | 4.5 | 4.5 |
| Color fastness to chlorine | 4.5 | 4.5 |
| Color fastness to sea water | 5 | 5 |
| Alkaline-resisting PERSPIRATION COLOR FASTNESS | 5 | 5 |
| Colour fasteness to sunlight | 6.5 | 7.5 |
| Fastness to soaping | 4.5 | 5 |
In table 1, the method for testing of each index is as follows:
1, fastness to soaping is tested by GB GB/T3921.4-1997.
2, dry/wet friction color fastness presses GB/3920 execution.
3, resistance to (alkali) PERSPIRATION COLOR FASTNESS presses ISO105-E04:2008 execution.
4, chlorine-resistant drift color fastness presses ISO105E03:2010 execution.
5, color fastness to sea water presses AATCC106-2002 execution.
6, color fastness to water presses JIS (37 ± 2) DEG C × 4h.
7, colour fasteness to sunlight presses ISO105B02-1994.
Claims (6)
1. an alkali bath method colouring method for chinlon 56 fibers/cotton blended spinning face fabric, comprises the steps:
Use reducing dye or reactive dye that chinlon 56 fibers/cotton blended spinning face fabric is dyeed；
Described chinlon 56 fibers/cotton blended spinning face fabric is the blended yarn weaved fabric of chinlon 56 and cotton fiber.
Colouring method the most according to claim 1, it is characterised in that: when using described reactive dye to dye,
Specifically include following steps:
1) preparation dye liquor, described dye liquor is prepared by K-type reactive dye and sodium sulfate and is obtained；
2) described chinlon 56 fibers/cotton blended spinning face fabric and described dye liquor are sequentially added into staining machine；Heat described dye
Color machine, after temperature rises to 50～60 DEG C, adds alkaline matter regulation pH value to behind 9～10 in described staining machine,
It is continuously heating to 80 DEG C, and is incubated the dye that continuation dyeing i.e. realizes chinlon 56 fibers/cotton blended spinning face fabric for 30～60 minutes
Color.
Colouring method the most according to claim 2, it is characterised in that: in described dye liquor, described K-type activity
Quality-the volumetric concentration of dyestuff is 20～80g/L, and the quality-volumetric concentration of described sodium sulfate is 30～50g/L；
Described alkaline matter is sodium carbonate.
Colouring method the most according to claim 1, it is characterised in that: when using described reducing dye to dye,
Specifically include following steps:
Described chinlon 56 fabric lining is padded in reducing dye suspended substance, dries after taking-up；Then proceed to leaching
Roll in reducing solution, more successively through decatize, the dyeing i.e. realized chinlon 56 fiber of washing, aoxidize and soap；
Described reducing dye suspended substance refers to described reducing dye is dispersed in water the dispersion liquid obtained.
Colouring method the most according to claim 4, it is characterised in that: described reducing solution is Caustic soda and even two sulfurous
The aqueous solution of acid sodium, the quality-volumetric concentration of wherein said Caustic soda is 10～30g/l, the quality of described sodium dithionite
-volumetric concentration is 20～40g/l.
6. according to the colouring method described in claim 4 or 5, it is characterised in that: the temperature of described decatize is
100 DEG C～110 DEG C, the time is 20～150s；
The oxidant that described oxidation uses is hydrogen peroxide, and the temperature of described oxidation is 50 DEG C～60 DEG C；
The described temperature soaped is 90 DEG C～100 DEG C.
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| CN201610437609.4A CN106012584B (en) | 2016-06-17 | 2016-06-17 | A kind of alkali bath method colouring method of 56 fibers of polyamide fibre/cotton blended spinning face fabric |
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| CN201610437609.4A CN106012584B (en) | 2016-06-17 | 2016-06-17 | A kind of alkali bath method colouring method of 56 fibers of polyamide fibre/cotton blended spinning face fabric |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108060588A (en) * | 2017-12-11 | 2018-05-22 | 佛山市顺德金纺集团有限公司 | A kind of brocade cotton woven active amide dyestuff one-bath dyeing method |
| CN109183448A (en) * | 2018-09-30 | 2019-01-11 | 绍兴文理学院 | A kind of dyeing of nylon-cotton fabric |
| CN109554939A (en) * | 2017-09-27 | 2019-04-02 | 上海凯赛生物技术研发中心有限公司 | A kind of 56 fiber of polyamide or the indigo dyeing method of 56/ cotton blended spinning face fabric of polyamide and products thereof |
| CN110284315A (en) * | 2019-06-26 | 2019-09-27 | 华纺股份有限公司 | A kind of dyeing method of graphene brocade cotton woven fabric |
| CN110344266A (en) * | 2018-04-08 | 2019-10-18 | 上海凯赛生物技术研发中心有限公司 | 56 fiber blended fabric reactive dye of cotton/polyamide and acid or neutral dye are the same as one step decoration method of bath |
| CN111058316A (en) * | 2019-12-31 | 2020-04-24 | 军事科学院***工程研究院军需工程技术研究所 | Alkaline pad dyeing method for chinlon 56 and cellulose fiber blended fabric |
| CN111058317A (en) * | 2019-12-31 | 2020-04-24 | 军事科学院***工程研究院军需工程技术研究所 | Alkaline one-bath dip-dyeing method for chinlon 56 and cellulose fiber blended fabric |
| CN111270533A (en) * | 2020-02-10 | 2020-06-12 | 军事科学院***工程研究院军需工程技术研究所 | Alkaline pad dyeing method for chinlon 56 fiber and fabric |
| CN111809412A (en) * | 2020-01-09 | 2020-10-23 | 军事科学院***工程研究院军需工程技术研究所 | Low-temperature one-bath one-step dyeing method for chinlon 56 and protein fiber blended fabric |
| CN112011868A (en) * | 2019-05-28 | 2020-12-01 | 上海凯赛生物技术股份有限公司 | Polyamide fiber and cotton blended yarn and preparation method and application thereof |
| WO2021147942A1 (en) * | 2020-01-22 | 2021-07-29 | 军事科学院***工程研究院军需工程技术研究所 | Alkaline dip-dyeing method for polyamide 56 fiber and fabric |
| CN116005470A (en) * | 2023-01-10 | 2023-04-25 | 浙江三元纺织有限公司 | Chinlon reactive dyeing method |
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Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109554939B (en) * | 2017-09-27 | 2021-03-16 | 上海凯赛生物技术股份有限公司 | Indigo dyeing method of polyamide 56 fiber or polyamide 56/cotton blended fabric and product thereof |
| CN109554939A (en) * | 2017-09-27 | 2019-04-02 | 上海凯赛生物技术研发中心有限公司 | A kind of 56 fiber of polyamide or the indigo dyeing method of 56/ cotton blended spinning face fabric of polyamide and products thereof |
| CN108060588A (en) * | 2017-12-11 | 2018-05-22 | 佛山市顺德金纺集团有限公司 | A kind of brocade cotton woven active amide dyestuff one-bath dyeing method |
| CN110344266B (en) * | 2018-04-08 | 2021-05-14 | 上海凯赛生物技术股份有限公司 | One-step dyeing method for cotton/polyamide 56 fiber blended fabric by using reactive dye and acid or neutral dye in one bath |
| CN110344266A (en) * | 2018-04-08 | 2019-10-18 | 上海凯赛生物技术研发中心有限公司 | 56 fiber blended fabric reactive dye of cotton/polyamide and acid or neutral dye are the same as one step decoration method of bath |
| CN109183448B (en) * | 2018-09-30 | 2020-12-01 | 绍兴文理学院 | Dyeing process of nylon-cotton fabric |
| CN109183448A (en) * | 2018-09-30 | 2019-01-11 | 绍兴文理学院 | A kind of dyeing of nylon-cotton fabric |
| CN112011868A (en) * | 2019-05-28 | 2020-12-01 | 上海凯赛生物技术股份有限公司 | Polyamide fiber and cotton blended yarn and preparation method and application thereof |
| CN110284315A (en) * | 2019-06-26 | 2019-09-27 | 华纺股份有限公司 | A kind of dyeing method of graphene brocade cotton woven fabric |
| CN111058316A (en) * | 2019-12-31 | 2020-04-24 | 军事科学院***工程研究院军需工程技术研究所 | Alkaline pad dyeing method for chinlon 56 and cellulose fiber blended fabric |
| CN111058317A (en) * | 2019-12-31 | 2020-04-24 | 军事科学院***工程研究院军需工程技术研究所 | Alkaline one-bath dip-dyeing method for chinlon 56 and cellulose fiber blended fabric |
| WO2021136412A1 (en) * | 2019-12-31 | 2021-07-08 | 军事科学院***工程研究院军需工程技术研究所 | Alkaline pad dyeing method for nylon 56 and cellulose fiber blended fabric |
| CN111809412A (en) * | 2020-01-09 | 2020-10-23 | 军事科学院***工程研究院军需工程技术研究所 | Low-temperature one-bath one-step dyeing method for chinlon 56 and protein fiber blended fabric |
| WO2021147942A1 (en) * | 2020-01-22 | 2021-07-29 | 军事科学院***工程研究院军需工程技术研究所 | Alkaline dip-dyeing method for polyamide 56 fiber and fabric |
| CN111270533A (en) * | 2020-02-10 | 2020-06-12 | 军事科学院***工程研究院军需工程技术研究所 | Alkaline pad dyeing method for chinlon 56 fiber and fabric |
| CN116005470A (en) * | 2023-01-10 | 2023-04-25 | 浙江三元纺织有限公司 | Chinlon reactive dyeing method |
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