CN106011976A - Surface treatment technology of high-precision spring - Google Patents
Surface treatment technology of high-precision spring Download PDFInfo
- Publication number
- CN106011976A CN106011976A CN201610530692.XA CN201610530692A CN106011976A CN 106011976 A CN106011976 A CN 106011976A CN 201610530692 A CN201610530692 A CN 201610530692A CN 106011976 A CN106011976 A CN 106011976A
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- CN
- China
- Prior art keywords
- spring
- tap water
- high precision
- clean
- surface treatment
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D13/00—Electrophoretic coating characterised by the process
- C25D13/12—Electrophoretic coating characterised by the process characterised by the article coated
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24B—MACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
- B24B31/00—Machines or devices designed for polishing or abrading surfaces on work by means of tumbling apparatus or other apparatus in which the work and/or the abrasive material is loose; Accessories therefor
- B24B31/02—Machines or devices designed for polishing or abrading surfaces on work by means of tumbling apparatus or other apparatus in which the work and/or the abrasive material is loose; Accessories therefor involving rotary barrels
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/60—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using alkaline aqueous solutions with pH greater than 8
- C23C22/62—Treatment of iron or alloys based thereon
Abstract
The invention provides a surface treatment technology of a high-precision spring, and relates to the field of processing and manufacturing of springs. The surface treatment technology comprises the following steps of (1) performing polishing; (2) performing degreasing and performing descaling; (3) performing washing with water, and performing blow-drying; (4) performing oxidation treatment; (5) performing washing with running water and hot water; (6) performing drying; (7) plating paint; (8) removing oil; and (9) performing drying and performing warehousing. The surface treatment technology disclosed by the invention is simple, the anticorrosion property is good, the technology is high in adaptability, and the service life of the high-precision spring is effectively prolonged.
Description
Technical field
The present invention relates to spring processing and manufacturing field, be specifically related to a kind of high precision spring surface
Process technique.
Background technology
Spring is exposed the most easily to be corroded, and the corrosion of spring can be divided into by its type reacted
Chemical attack and electrochemical corrosion.Chemical attack refers to that spring metal surface is the most simple and surrounding is situated between
Matter generation chemical reaction and cause spring to corrode, as raw in spring oxidation in the air being dried especially
Become oxide-film, and spring is sent out with the impurity in this liquid or this liquid in non-electrolyte liquid
Biochemical changes etc., broadly fall into chemical attack.Electrochemical corrosion refers to spring and electrolyte solution
During contact, make the corrosion that spring occurs due to the effect of micro cell, such as spring and acid or salt
During the electrolyte solution contacts such as class, owing to spring surface existing defects or impurity can form potential difference
Different electrodes, makes spring surface generation electrolysis, causes spring to corrode；And for example at spring
Time in moist atmosphere, vapor in the atmosphere can congeal into moisture film or the globule at spring surface, and
Corrosive gas in air is (in the sulfur dioxide in industrial waste gas and hydrogen sulfide or marine atmosphere
Salt fog etc.) be dissolved in moisture film or the globule and can form electrolyte, add the impurity of spring metal
Or defect forms the electrode that potential difference is different, spring generation electrolytic etching will be made.Spring is in system
Make, deposit, during use etc., often corroded by surrounding medium.Owing to spring exists
Being to play a role by elastic force during work, after spring is corroded, elastic force can change and loss of function,
Therefore prevent spring corrosion from can ensure that spring steady operation, and extend its service life.
A kind of spring table is disclosed in Chinese patent application prospectus CN 104060316 A
Face processing method, comprises the following steps: phosphatization pretreatment-washing-deionization washing from the beginning-
Electrophoretic paint electrophoresis-recovery-ultrafiltrate washes-and deionization washing-be dried-baking-curing-
Cooling.The method processes by spring carries out phosphatization and plating paint, makes spring keep relatively stable
Performance.
The shortcoming that prior art exists is: spring can produce substantial amounts of hydrogen in parkerizing process,
Therefore the spring after phosphatization has Hydrogen Brittleness Phenomena, affects the toughness of spring；And during phosphatization, work
The quality of spring is had an impact by size and the fineness of part, so this surface treatment method is not
It is applicable to the spring of high precision.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of technique simple, and antiseptic property is good,
The high precision spring surface process technique that Technological adaptability is higher.
For realizing object above, the present invention is achieved by the following technical programs:
A kind of high precision stainless steel spring process of surface treatment, step is:
(1) glazing: the spring after quenching is put into the hexagonal plating barrel equipped with brightener and coarse grained abrasive
In, roll 3-5h；
(2) degreasing, descale: taken out in hexagonal plating barrel by spring, put into added with clearly
Cleaning in the ultrasonic equipment of lotion, abluent is 1:25 with the proportioning of tap water, scavenging period
For 15-30min；
(3) washing dries up: is rinsed it with giant, re-uses tap water rinse,
Then dry up with air inducing equipment；
(4) oxidation processes: the spring after drying up put into 600-650g/L sodium hydroxide and
In the sodium nitrite mixed solution of 80～120g/L, solution is heated to 135-140 DEG C, protects
Temperature, 45-60 minute；
(5) double washings: after tap water rinse one time, reusable heat is washed one time, and hot water temperature is
90～100 DEG C, clean 1～2 minute；
(6) dry；
(7) plating paint: spring does negative electrode, applies the voltage of 70-75V, and electrophoresis time is
45-120s, uses electrophoresis method to form enamelled coating at spring surface, uses water soluble coating, paint liquid 4-5h
Circulation primary,；
(8) deoil: carry out soaking 90-150min with gasoline, then deoil with degreaser
Clean, further take out and clean with tap water；
(9) warehouse-in is dried.
Further, described high precision spring surface processes technique, in polishing step, bullet
Spring is 1:3 with the volume ratio of fine grinding material, and the consumption of brightener is the 1%--2% of spring weight.
Further, described high precision spring surface processes in technique oxidation processes, NaOH
With NaNO2Ratio be 7-9:1.
Spring is carried out upper optical processing by described process of surface treatment, just so makes spring surface
Burnishing as nickel plating.Additionally, oxidation processes relatively bonderizing, the quality shadow to spring
Ringing little, the surface being more suitable for the easy winding spring of high precision processes, and Technological adaptability is higher.
Spring aoxidizes in alkaline solution, is about the protectiveness oxygen of 0.5～1.5um at Surface Creation thickness
Change film, the material inside spring can be effectively protected, reach antioxidative effect, from
And extend the service life of high precision spring.
The invention has the beneficial effects as follows the process of surface treatment of further Optimal Spring, be allowed to suitableeer
For the anticorrosion of high precision spring, present invention process is simple, and antiseptic property is good, and technique adapts to
Property strong, can effectively extend the service life of high precision spring.
Detailed description of the invention
For making the purpose of the embodiment of the present invention, technical scheme and advantage clearer, below will knot
Close embodiments of the invention, the technical scheme in the embodiment of the present invention is carried out clearly and completely
Describe.Based on the embodiment in the present invention, those of ordinary skill in the art are not making creation
The every other embodiment obtained under property work premise, broadly falls into the scope of protection of the invention.
Embodiment 1:
A kind of high precision stainless steel spring process of surface treatment, step is:
(1) glazing: the spring after quenching is put into the hexagonal plating barrel equipped with brightener and coarse grained abrasive
In, rolling 3h, spring is 1:3 with the volume ratio of fine grinding material, and the consumption of brightener is spring weight
The 1% of amount；
(2) degreasing, descale: taken out in hexagonal plating barrel by spring, put into added with clearly
Cleaning in the ultrasonic equipment of lotion, abluent is 1:25 with the proportioning of tap water, scavenging period
For 15min；
(3) washing dries up: is rinsed it with giant, re-uses tap water rinse,
Then dry up with air inducing equipment；
(4) oxidation processes: sodium hydroxide and the 80g/L of 600g/L put into by the spring after drying up
Sodium nitrite mixed solution in, solution is heated to 135 DEG C, insulation, 45 minutes NaOH
With NaNO2Ratio be 7:1；
(5) double washings: after tap water rinse one time, reusable heat is washed one time, and hot water temperature is
90 DEG C, clean 1 minute；
(6) dry；
(7) plating paint: spring does negative electrode, applies the voltage of 70V, and electrophoresis time is 45s,
Use electrophoresis method to form enamelled coating at spring surface, use water soluble coating, paint liquid 4h circulation primary,
Voltage is set to；
(8) deoil: carry out soaking 90min with gasoline, then carry out, with degreaser, cleaning of deoiling,
Further take out and clean with tap water；
(9) warehouse-in is dried.
Embodiment 2:
A kind of high precision stainless steel spring process of surface treatment, step is:
(1) glazing: the spring after quenching is put into the hexagonal plating barrel equipped with brightener and coarse grained abrasive
In, rolling 3.5h, spring is 1:3 with the volume ratio of fine grinding material, and the consumption of brightener is spring
The 1.5% of weight；
(2) degreasing, descale: taken out in hexagonal plating barrel by spring, put into added with clearly
Cleaning in the ultrasonic equipment of lotion, abluent is 1:25 with the proportioning of tap water, scavenging period
For 20min；
(3) washing dries up: is rinsed it with giant, re-uses tap water rinse,
Then dry up with air inducing equipment；
(4) oxidation processes: sodium hydroxide and the 90g/L of 610g/L put into by the spring after drying up
Sodium nitrite mixed solution in, solution is heated to 135 DEG C, insulation, 50 minutes, NaOH
With NaNO2Ratio be 7.5:1；
(5) double washings: after tap water rinse one time, reusable heat is washed one time, and hot water temperature is
90 DEG C, clean 1 minute；
(6) dry；
(7) plating paint: spring does negative electrode, applies the voltage of 72V, and electrophoresis time is 60s,
Use electrophoresis method to form enamelled coating at spring surface, use water soluble coating, paint liquid 4.5h circulation primary；
(8) deoil: carry out soaking 100min with gasoline, then carry out, with degreaser, cleaning of deoiling,
Further take out and clean with tap water；
(9) warehouse-in is dried.
Embodiment 3:
A kind of high precision stainless steel spring process of surface treatment, it is characterised in that step is:
(1) glazing: the spring after quenching is put into the hexagonal plating barrel equipped with brightener and coarse grained abrasive
In, rolling 4h, spring is 1:3 with the volume ratio of fine grinding material, and the consumption of brightener is spring weight
The 1% of amount；
(2) degreasing, descale: taken out in hexagonal plating barrel by spring, put into added with clearly
Cleaning in the ultrasonic equipment of lotion, abluent is 1:25 with the proportioning of tap water, scavenging period
For 25min；
(3) washing dries up: is rinsed it with giant, re-uses tap water rinse,
Then dry up with air inducing equipment；
(4) oxidation processes: sodium hydroxide and the 100g/L of 620g/L put into by the spring after drying up
Sodium nitrite mixed solution in, solution is heated to 140 DEG C, insulation, 50 minutes, NaOH
With NaNO2Ratio be 8:1；
(5) double washings: after tap water rinse one time, reusable heat is washed one time, and hot water temperature is
100 DEG C, clean 2 minutes；
(6) dry；
(7) plating paint: spring does negative electrode, applies the voltage of 75V, and electrophoresis time is 80s,
Use electrophoresis method to form enamelled coating at spring surface, use water soluble coating, paint liquid 5h circulation primary；
(8) deoil: carry out soaking 110min with gasoline, then carry out, with degreaser, cleaning of deoiling,
Further take out and clean with tap water；
(9) warehouse-in is dried.
Embodiment 4:
A kind of high precision stainless steel spring process of surface treatment, it is characterised in that step is:
(1) glazing: the spring after quenching is put into the hexagonal plating barrel equipped with brightener and coarse grained abrasive
In, rolling 4.5h, spring is 1:3 with the volume ratio of fine grinding material, and the consumption of brightener is spring
The 2% of weight；
(2) degreasing, descale: taken out in hexagonal plating barrel by spring, put into added with clearly
Cleaning in the ultrasonic equipment of lotion, abluent is 1:25 with the proportioning of tap water, scavenging period
For 30min；
(3) washing dries up: is rinsed it with giant, re-uses tap water rinse,
Then dry up with air inducing equipment；
(4) oxidation processes: sodium hydroxide and the 110g/L of 630g/L put into by the spring after drying up
Sodium nitrite mixed solution in, solution is heated to 135 DEG C, is incubated 55 minutes, NaOH
With NaNO2Ratio be 9:1；
(5) double washings: after tap water rinse one time, reusable heat is washed one time, and hot water temperature is
100 DEG C, clean 2 minutes；
(6) dry；
(7) plating paint: spring does negative electrode, applies the voltage of 70V, and electrophoresis time is 90s,
Use electrophoresis method to form enamelled coating at spring surface, use water soluble coating, paint liquid 5h circulation primary；
(8) deoil: carry out soaking 120min with gasoline, then carry out, with degreaser, cleaning of deoiling,
Further take out and clean with tap water；
(9) warehouse-in is dried.
Embodiment 5:
A kind of high precision spring surface processes technique, it is characterised in that step is:
(1) glazing: the spring after quenching is put into the hexagonal plating barrel equipped with brightener and coarse grained abrasive
In, rolling 5h, spring is 1:3 with the volume ratio of fine grinding material, and the consumption of brightener is spring weight
The 2% of amount；
(2) degreasing, descale: taken out in hexagonal plating barrel by spring, put into added with clearly
Cleaning in the ultrasonic equipment of lotion, abluent is 1:25 with the proportioning of tap water, scavenging period
For 30min；
(3) washing dries up: is rinsed it with giant, re-uses tap water rinse,
Then dry up with air inducing equipment；
(4) oxidation processes: sodium hydroxide and the 120g/L of 650g/L put into by the spring after drying up
Sodium nitrite mixed solution in, solution is heated to 140 DEG C, insulation, 60 minutes, NaOH
With NaNO2Ratio be 9:1；
(5) double washings: after tap water rinse one time, reusable heat is washed one time, and hot water temperature is
100 DEG C, clean 2 minutes；
(6) dry；
(7) plating paint: spring does negative electrode, applies the voltage of 75V, and electrophoresis time is 120s,
Use electrophoresis method to form enamelled coating at spring surface, use water soluble coating, paint liquid 5h circulation primary；
(8) deoil: carry out soaking 150min with gasoline, then carry out, with degreaser, cleaning of deoiling,
Further take out and clean with tap water；
(9) warehouse-in is dried.
Above example only in order to technical scheme to be described, is not intended to limit；Although
With reference to previous embodiment, the present invention is described in detail, those of ordinary skill in the art
It is understood that the technical scheme described in foregoing embodiments still can be modified by it,
Or wherein portion of techniques feature is carried out equivalent；And these amendments or replacement, not
The essence making appropriate technical solution departs from the spirit and scope of various embodiments of the present invention technical scheme.
Claims (3)
1. a high precision spring surface processes technique, it is characterised in that step is:
(1) glazing: the spring after quenching is put into the hexagonal plating barrel equipped with brightener and coarse grained abrasive
In, roll 3-5h；
(2) degreasing, descale: taken out in hexagonal plating barrel by spring, put into added with clearly
Cleaning in the ultrasonic equipment of lotion, abluent is 1:25 with the proportioning of tap water, scavenging period
For 15-30min；
(3) washing dries up: is rinsed it with giant, re-uses tap water rinse,
Then dry up with air inducing equipment；
(4) oxidation processes: the spring after drying up put into 600-650g/L sodium hydroxide and
In the sodium nitrite mixed solution of 80～120g/L, solution is heated to 135-140 DEG C, protects
Temperature, 45-60 minute；
(5) double washings: after tap water rinse one time, reusable heat is washed one time, and hot water temperature is
90～100 DEG C, clean 1～2 minute；
(6) dry；
(7) plating paint: spring does negative electrode, applies the voltage of 70-75V, and electrophoresis time is
45-120s, uses electrophoresis method to form enamelled coating at spring surface, uses water soluble coating, paint liquid 4-5h
Circulation primary；
(8) deoil: carry out soaking 90-150min with gasoline, then deoil with degreaser
Clean, further take out and clean with tap water；
(9) warehouse-in is dried.
2. a kind of high precision spring surface as claimed in claim 1 processes technique, and its feature exists
In, in step (1), spring is 1:3 with the volume ratio of fine grinding material, and the consumption of brightener is spring
The 1%-2% of weight.
3. a kind of high precision spring surface as claimed in claim 1 processes technique, and its feature exists
In, in step (4), NaOH and NaNO2Ratio be 7-9:1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610530692.XA CN106011976B (en) | 2016-07-06 | 2016-07-06 | A kind of high precision spring surface handling process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610530692.XA CN106011976B (en) | 2016-07-06 | 2016-07-06 | A kind of high precision spring surface handling process |
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| CN106011976A true CN106011976A (en) | 2016-10-12 |
| CN106011976B CN106011976B (en) | 2018-01-05 |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106736302A (en) * | 2017-01-19 | 2017-05-31 | 浙江金昌弹簧有限公司 | A kind of spring production process |
| CN108392016A (en) * | 2018-03-02 | 2018-08-14 | 南京林业大学 | Adjustable health sofa cushion of hardness and preparation method thereof |
| CN108754476A (en) * | 2018-08-06 | 2018-11-06 | 苏州捷捷威自动化装备有限公司 | A kind of numerical control cutting machine height-regulating device spring surface treatment process |
| CN109732457A (en) * | 2018-12-28 | 2019-05-10 | 华讯方舟科技有限公司 | Plastics color mixing machine method for cleaning |
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| CN101831684A (en) * | 2010-05-28 | 2010-09-15 | 河海大学常州校区 | Microarc-oxidation electrophoretic-coating composite processing method of surface of Q 235 steel part |
| CN103243372A (en) * | 2013-04-24 | 2013-08-14 | 常熟市长发铝业有限公司 | Electrophoresis film-painting method |
| CN104060316A (en) * | 2014-05-26 | 2014-09-24 | 安徽红桥金属制造有限公司 | Surface treatment method for spring |
| CN104278306A (en) * | 2014-09-26 | 2015-01-14 | 无锡市天力五金弹簧厂 | Surface treatment process for spring |
| WO2015089827A1 (en) * | 2013-12-20 | 2015-06-25 | 邓志刚 | Method and system for lacquering outer tube of rod core of gas spring |
| CN103352217B (en) * | 2013-06-21 | 2016-01-20 | 安徽省六安市朝晖机械制造有限公司 | Turn blue anti-corrosion treatment process for a kind of surface of workpiece |
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| CN101831684A (en) * | 2010-05-28 | 2010-09-15 | 河海大学常州校区 | Microarc-oxidation electrophoretic-coating composite processing method of surface of Q 235 steel part |
| CN103243372A (en) * | 2013-04-24 | 2013-08-14 | 常熟市长发铝业有限公司 | Electrophoresis film-painting method |
| CN103352217B (en) * | 2013-06-21 | 2016-01-20 | 安徽省六安市朝晖机械制造有限公司 | Turn blue anti-corrosion treatment process for a kind of surface of workpiece |
| WO2015089827A1 (en) * | 2013-12-20 | 2015-06-25 | 邓志刚 | Method and system for lacquering outer tube of rod core of gas spring |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106736302A (en) * | 2017-01-19 | 2017-05-31 | 浙江金昌弹簧有限公司 | A kind of spring production process |
| CN108392016A (en) * | 2018-03-02 | 2018-08-14 | 南京林业大学 | Adjustable health sofa cushion of hardness and preparation method thereof |
| CN108754476A (en) * | 2018-08-06 | 2018-11-06 | 苏州捷捷威自动化装备有限公司 | A kind of numerical control cutting machine height-regulating device spring surface treatment process |
| CN109732457A (en) * | 2018-12-28 | 2019-05-10 | 华讯方舟科技有限公司 | Plastics color mixing machine method for cleaning |
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| Publication number | Publication date |
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| CN106011976B (en) | 2018-01-05 |
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Denomination of invention: A high-precision spring surface treatment process Effective date of registration: 20220825 Granted publication date: 20180105 Pledgee: China Postal Savings Bank Limited by Share Ltd. Ningguo branch Pledgor: ANHUI HONGQIAO METAL MANUFACTURING Co.,Ltd. Registration number: Y2022980013601 |
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