CN106011881A - Water-based steel brightening and rust removing agent and preparation method thereof - Google Patents

Water-based steel brightening and rust removing agent and preparation method thereof Download PDF

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Publication number
CN106011881A
CN106011881A CN201610496372.7A CN201610496372A CN106011881A CN 106011881 A CN106011881 A CN 106011881A CN 201610496372 A CN201610496372 A CN 201610496372A CN 106011881 A CN106011881 A CN 106011881A
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CN
China
Prior art keywords
parts
rust removing
removing agent
brightening
steel
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Pending
Application number
CN201610496372.7A
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Chinese (zh)
Inventor
灏や负
尤为
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Wuxi Epic Technology Co Ltd
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Wuxi Epic Technology Co Ltd
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Publication date
Application filed by Wuxi Epic Technology Co Ltd filed Critical Wuxi Epic Technology Co Ltd
Priority to CN201610496372.7A priority Critical patent/CN106011881A/en
Publication of CN106011881A publication Critical patent/CN106011881A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/02Cleaning or pickling metallic material with solutions or molten salts with acid solutions
    • C23G1/08Iron or steel
    • C23G1/088Iron or steel solutions containing organic acids
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/02Cleaning or pickling metallic material with solutions or molten salts with acid solutions
    • C23G1/04Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors
    • C23G1/06Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors organic inhibitors
    • C23G1/063Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors organic inhibitors heterocyclic compounds

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)

Abstract

The invention discloses a water-based steel brightening and rust removing agent and a preparation method thereof. The water-based steel brightening and rust removing agent is prepared by the following raw materials in parts by weight: 22-26 parts of polyvinyl alcohol, 5-8 parts of sodium tripolyphosphate, 1-8 parts of phenol, 13-16 parts of zinc dialkyl dithiophosphate, 3-10 parts of benzophenone, 5-8 parts of konjac glucomannan, 10-14 parts of sodium alginate, 3-6 parts of methyl methylphosphate, 6-9 parts of methyl siloxane, 3-6 parts of tannic acid, 2-6 parts of potassium oxalate, 22-25 parts of glycol, and 50-60 parts of water. The prepared water-based steel brightening and rust removing agent is reasonable in formula, simple in used formula process, environment-friendly, free of pollution and excellent in rust removing and preventing effect, and can increase the metal surface gloss; all the components in the rust removing liquid are environment-friendly and non-toxic; and the preparation method is simple and low in cost.

Description

Aqueous steel brightening rust removing agent and preparation method thereof
Technical field
The present invention relates to a kind of aqueous steel brightening rust removing agent and preparation method thereof.
Background technology
Iron and steel is to use most metals in human history, grows with each passing day the demand of iron and steel especially into the mankind after industrialization.Now, the storage level of verifying of iron and steel is very limited, and the yield of the mankind remains high, and this conflict can not get alleviating, and largely will restrict the further development of the mankind.And the iron and steel caused because of corrosion every year loses the most surprising, cause the waste of ample resources.Iron and steel, during production process or finished product use, runs into that there was dampness in the air and during the rainy day, and easily oxidation and rusting affects product appearance quality.And preventing iron and steel simplest method of getting rusty is to make iron and steel and water, air exclusion, often keep being dried and clean of steel surface.The measure being usually taken is: is coated with mineral oils and fats on the surface of steel product, paints or cover enamel, plastics etc..Can also be coated with, at steel surface, the metal that last layer is difficult to be corroded by methods such as plating, hot dip, spraying platings.If conventional galvanized iron sheet is exactly at one layer of zinc of steel-sheet plated surface, the tinplate making canned food is exactly at steel-sheet plated surface last layer stannum.The steel ring of bicycle is exactly the chromium corrosion-resistant, wear-resisting with electric plating method plating last layer and nickel.But said method only just uses when a small amount of ferrous materials, cannot use in a large number during stock's steel substantial amounts of to steel production enterprise and marketer;Using antirust oil and steel surface plating, need to consume substantial amounts of oil plant raw material and anti-rust metal, energy resource consumption aggravates, and increases cost.And along with the progress of technology, increasing employing antirust agent prevents iron and steel from getting rusty, antirust agent is the most antirust depends on the protection to metal surface, thus stops or postponing moisture, oxygen and the invasion of other impurity.Antirust agent selects high-quality anticorrosion raw material and multiple auxiliary agent to process, and surface can be protected not encroached on by moisture, chemicals, air and other corrosives.Can be widely used for iron and steel, rustless steel, steel alloy article assembly and the rust prevention during manufacture of material in many industries.The material such as steel, ferrum can be effectively protected, prevent from getting rusty.According to the difference of rust-proof life requirement, and water is used in mixed way by a definite proportion, and the antirust time limit can reach several days to several months, if having certain damp-proof outer package condition or leaving dry environment condition in, antirust time was up to more than 1 year.And having easy and simple to handle, technique is simple, postorder easy cleaning, processes postorder without features such as impacts, low price simultaneously, and rust-proof effect is preferable, is increasingly favored by numerous clients.And current Deruster for metal operation is many, efficiency is low, process the time long, and the course of processing easily to metal surface produce corrosion, cause metal surface coarse low and deep, do not work, the therefore outward appearance of metallic article.To this end, we set about from formula and the technique of product, it is provided that a kind of aqueous steel brightening rust removing agent and preparation method thereof.
Summary of the invention
It is an object of the invention to provide a kind of aqueous steel brightening rust removing agent and preparation method thereof.
To achieve these goals, the invention provides a kind of aqueous steel brightening rust removing agent, raw material includes following component by weight: prepared by the raw material of following weight portion: polyvinyl alcohol 22-26 part, sodium tripolyphosphate 5-8 part, phenol 1-8 part, zinc dialkyl dithiophosphate 13-16 part, benzophenone 3-10 part, Konjac glucomannan 5-8 part, sodium alginate 10-14 part, methyl-phosphoric acid dimethyl ester 3-6 part, methyl cyclosiloxane 6-9 part, tannic acid 3-6 part, potassium oxalate 2-6 part, ethylene glycol 22-25 part, water 50-60 part.
It is possibly together with phenylpropyl alcohol triazole 4-8 part.
It is possibly together with butyl titanate 6-8 part.
It is possibly together with sulfide isobutene 4-7 part.
The preparation method of a kind of aqueous steel brightening rust removing agent, comprises the following steps: weighs each component, then mix and blend according to above-mentioned weight fraction ratio, stirs and make each component be completely dissolved, and obtains described aqueous steel brightening rust removing agent.
The method have the advantages that the aqueous steel brightening rust removing agent formula that the present invention prepares is reasonable, Recipe used is simple, environment friendly and pollution-free, derusting rust-proofing is effective, and can be at blast metal surface gloss, and each component environmental protection in this antirust solution, nontoxic, and preparation method is simple, low cost.
Detailed description of the invention
Embodiment 1
The aqueous steel brightening rust removing agent of the present embodiment, is prepared by the component of following weight portion: polyvinyl alcohol 22 parts, sodium tripolyphosphate 5 parts, phenol 1 part, zinc dialkyl dithiophosphate 13 parts, benzophenone 3 parts, Konjac glucomannan 5 parts, sodium alginate 10 parts, methyl-phosphoric acid dimethyl ester 3 parts, methyl cyclosiloxane 6 parts, 3 parts of tannic acid, potassium oxalate 2 parts, ethylene glycol 22 parts, 50 parts of water.
Weigh each component, then mix and blend according to above-mentioned weight fraction ratio, stir and make each component be completely dissolved, obtain described aqueous steel brightening rust removing agent.
The aqueous steel brightening rust removing agent of the present embodiment can use directly immersion, the method for spraying that surface of the work is carried out processing of rust removing.
Embodiment 2
The aqueous steel brightening rust removing agent of the present embodiment, is prepared by the component of following weight portion: polyvinyl alcohol 26 parts, sodium tripolyphosphate 8 parts, phenol 8 parts, zinc dialkyl dithiophosphate 16 parts, benzophenone 10 parts, Konjac glucomannan 8 parts, sodium alginate 14 parts, methyl-phosphoric acid dimethyl ester 6 parts, methyl cyclosiloxane 9 parts, 6 parts of tannic acid, potassium oxalate 6 parts, ethylene glycol 25 parts, phenylpropyl alcohol triazole 8 parts, 60 parts of water.
Weigh each component, then mix and blend according to above-mentioned weight fraction ratio, stir and make each component be completely dissolved, obtain described aqueous steel brightening rust removing agent.
The aqueous steel brightening rust removing agent of the present embodiment can use directly immersion, the method for spraying that surface of the work is carried out processing of rust removing.
Embodiment 3
The aqueous steel brightening rust removing agent of the present embodiment, is prepared by the component of following weight portion: polyvinyl alcohol 22 parts, sodium tripolyphosphate 5 parts, phenol 1 part, zinc dialkyl dithiophosphate 13 parts, benzophenone 3 parts, Konjac glucomannan 5 parts, sodium alginate 10 parts, methyl-phosphoric acid dimethyl ester 3 parts, methyl cyclosiloxane 6 parts, 3 parts of tannic acid, potassium oxalate 2 parts, ethylene glycol 22 parts, phenylpropyl alcohol triazole 4 parts, butyl titanate 6 parts, 50 parts of water.
Weigh each component, then mix and blend according to above-mentioned weight fraction ratio, stir and make each component be completely dissolved, obtain described aqueous steel brightening rust removing agent.
The aqueous steel brightening rust removing agent of the present embodiment can use directly immersion, the method for spraying that surface of the work is carried out processing of rust removing.
Embodiment 4
The aqueous steel brightening rust removing agent of the present embodiment, is prepared by the component of following weight portion: polyvinyl alcohol 26 parts, sodium tripolyphosphate 8 parts, phenol 8 parts, zinc dialkyl dithiophosphate 16 parts, benzophenone 10 parts, Konjac glucomannan 8 parts, sodium alginate 14 parts, methyl-phosphoric acid dimethyl ester 6 parts, methyl cyclosiloxane 9 parts, 6 parts of tannic acid, potassium oxalate 6 parts, ethylene glycol 25 parts, phenylpropyl alcohol triazole 8 parts, butyl titanate 8 parts, sulfide isobutene 7 parts, 60 parts of water.
Weigh each component, then mix and blend according to above-mentioned weight fraction ratio, stir and make each component be completely dissolved, obtain described aqueous steel brightening rust removing agent.
The aqueous steel brightening rust removing agent of the present embodiment can use directly immersion, the method for spraying that surface of the work is carried out processing of rust removing.
Embodiment 5
The rust remover of above-described embodiment 1-4 gained is used for workpiece rust cleaning, and rust cleaning efficiency is high, and a few minutes can complete the metal works invariant color after the descaling process of general workpiece, and rust cleaning, without dust, without hydrogen embrittlement.
The above is only the optimal way of the present invention, it is noted that to those skilled in the art, without departing from the concept of the premise of the invention, it is also possible to make some similar deformation and improvement, within these also should be regarded as protection scope of the present invention.

Claims (5)

1. an aqueous steel brightening rust removing agent, it is characterised in that prepared by the raw material of following weight portion: polyvinyl alcohol 22-26 part, sodium tripolyphosphate 5-8 part, phenol 1-8 part, zinc dialkyl dithiophosphate 13-16 part, benzophenone 3-10 part, Konjac glucomannan 5-8 part, sodium alginate 10-14 part, methyl-phosphoric acid dimethyl ester 3-6 part, methyl cyclosiloxane 6-9 part, tannic acid 3-6 part, potassium oxalate 2-6 part, ethylene glycol 22-25 part, water 50-60 part.
2. according to the aqueous steel brightening rust removing agent described in claim 1, it is characterised in that: it is possibly together with phenylpropyl alcohol triazole 4-8 part.
3. according to the aqueous steel brightening rust removing agent described in claim 2, it is characterised in that: it is possibly together with butyl titanate 6-8 part.
4. according to the aqueous steel brightening rust removing agent described in claim 3, it is characterised in that: it is possibly together with sulfide isobutene 4-7 part.
5. according to the preparation method of the aqueous steel brightening rust removing agent according to any one of claim 1-4, it is characterized in that comprising the following steps: weigh each component according to above-mentioned weight fraction ratio, then mix and blend, stirs and makes each component be completely dissolved, and obtains described aqueous steel brightening rust removing agent.
CN201610496372.7A 2016-06-30 2016-06-30 Water-based steel brightening and rust removing agent and preparation method thereof Pending CN106011881A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610496372.7A CN106011881A (en) 2016-06-30 2016-06-30 Water-based steel brightening and rust removing agent and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610496372.7A CN106011881A (en) 2016-06-30 2016-06-30 Water-based steel brightening and rust removing agent and preparation method thereof

Publications (1)

Publication Number Publication Date
CN106011881A true CN106011881A (en) 2016-10-12

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101412948A (en) * 2007-10-19 2009-04-22 安集微电子(上海)有限公司 Cleaning agent for plasma etching residue
WO2012035156A1 (en) * 2010-09-17 2012-03-22 Bbt Bergedorfer Biotechnik Gmbh Cleaning agent having a urea content
CN103757648A (en) * 2014-01-16 2014-04-30 段云豪 Agent for removing aerugo on surfaces of mobile phones and protecting surfaces of mobile phones
CN104195579A (en) * 2014-07-01 2014-12-10 国家电网公司 Surface-tolerant rust treatment fluid

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101412948A (en) * 2007-10-19 2009-04-22 安集微电子(上海)有限公司 Cleaning agent for plasma etching residue
WO2012035156A1 (en) * 2010-09-17 2012-03-22 Bbt Bergedorfer Biotechnik Gmbh Cleaning agent having a urea content
CN103757648A (en) * 2014-01-16 2014-04-30 段云豪 Agent for removing aerugo on surfaces of mobile phones and protecting surfaces of mobile phones
CN104195579A (en) * 2014-07-01 2014-12-10 国家电网公司 Surface-tolerant rust treatment fluid

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Application publication date: 20161012

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