CN106011324A - Tanning process for kid lamb skin and Hu sheep skin - Google Patents
Tanning process for kid lamb skin and Hu sheep skin Download PDFInfo
- Publication number
- CN106011324A CN106011324A CN201610409557.XA CN201610409557A CN106011324A CN 106011324 A CN106011324 A CN 106011324A CN 201610409557 A CN201610409557 A CN 201610409557A CN 106011324 A CN106011324 A CN 106011324A
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- Prior art keywords
- skin
- agent
- water
- tanning
- waste water
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C1/00—Chemical treatment prior to tanning
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14B—MECHANICAL TREATMENT OR PROCESSING OF SKINS, HIDES OR LEATHER IN GENERAL; PELT-SHEARING MACHINES; INTESTINE-SPLITTING MACHINES
- C14B1/00—Manufacture of leather; Machines or devices therefor
- C14B1/02—Fleshing, unhairing, samming, stretching-out, setting-out, shaving, splitting, or skiving skins, hides, or leather
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C1/00—Chemical treatment prior to tanning
- C14C1/04—Soaking
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C1/00—Chemical treatment prior to tanning
- C14C1/08—Deliming; Bating; Pickling; Degreasing
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C3/00—Tanning; Compositions for tanning
- C14C3/02—Chemical tanning
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C9/00—Impregnating leather for preserving, waterproofing, making resistant to heat or similar purposes
- C14C9/02—Impregnating leather for preserving, waterproofing, making resistant to heat or similar purposes using fatty or oily materials, e.g. fat liquoring
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14B—MECHANICAL TREATMENT OR PROCESSING OF SKINS, HIDES OR LEATHER IN GENERAL; PELT-SHEARING MACHINES; INTESTINE-SPLITTING MACHINES
- C14B2700/00—Mechanical treatment or processing of skins, hides or leather in general; Pelt-shearing machines; Making driving belts; Machines for splitting intestines
- C14B2700/01—Machines or devices for treating skins, hides or leather in general, e.g. fleshing, unhairing, samming, stretching-out, setting-out
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
- Detergent Compositions (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
The invention discloses a tanning process for kid lamb skin and Hu sheep skin. The tanning process comprises the following steps that size measuring, skin cleaning, fleshing, first degreasing, first cleaning, acid maceration, depickling and secondary degreasing are sequentially conducted; the piece of the kid lamb skin and the piece of the Hu sheep skin are soaked into clear water and heated to 36-38 DEG C; a degreasing agent is added into the clear water for rotating the pieces of skin; two hours after the stop of rotating, the pieces of skin are taken out, and waste water is discharged into a skin cleaning water collecting tank; cleaning, acid maceration and tanning are conducted again, and then the pieces of skin are soaked into tanning collected water which has been recycled for less than a week to be heated to 33 DEG C; a grease dispersing agent, a fatting agent, an aluminum tanning agent, a chrome tanning agent, a synthetic tanning agent, an auxiliary tanning agent, sodium bicarbonate and a mildew preventive are complementally added, so that the PH value of the tanning collected water is 3.8-3.9, the pieces of skin are stored overnight and taken out, and waste water is discharged into a tanning water collecting tank; and wet grinding, rinsing, neutralizing, fat liquoring, drying and tidying are conducted. The tanning process for the kid lamb skin and the Hu sheep skin saves energy, protects the environment and lowers the manufacturing cost.
Description
Technical field:
The present invention relates to leather and fur and make field, be especially a kind of little sheep, cunning sub-Mirabilitum technique.
Background technology:
In prior art, little sheep, the cunning sub-skin Treated sewage reusing when taw process is the most thorough, it is impossible to meet joint
The requirement that can reduce discharging, needs to carry out separately water process, not only adds cost but also waste water resource.
Summary of the invention:
The technical problem to be solved is to provide the little sheep of a kind of energy-conserving and environment-protective, cunning sub-Mirabilitum work
Skill.
The technical solution of the present invention is to provide a kind of little sheep, cunning sub-Mirabilitum technique, it include with
Lower step:
The first step, gage, manually chop unnecessary head, lower limb, length with ruler amount root of the tail to head and shoulder portion with cutter
Degree, then it is multiplied by the width of middle mesothelium, draw the size of skin, be then watered 2.2-2.8kg by the skin of every 2 square chi;
Second step, washes skin, skin is steeped the reuse skin of washing less than two days and collects in water, control water temperature 20-27 DEG C,
Addition degreasing agent, penetrating agent, antibacterial rotate, and then stand more than 4 hours, go out skin, by waste water
Enter in treatment tank;
3rd step, fleshing, manually operating equipped with on the fleshing equipment of return pipe water, accomplishing the clean nothing of flesh noodles
Scratch, oil-free lack, and return pipe water emptied to treatment tank the same day;
4th step, first defat, steep skin in the reuse middle water less than two days, heat 38-40 DEG C, add
Enter soda, degreasing agent, antibacterial carry out rotating, standing combination, repeated multiple times after go out skin, get rid of with dewaterer
Water 12-18 minute, waste water enters treatment tank;
5th step, cleans first, and skin is steeped in clear water, and heating 30-35 DEG C carries out rotating, stands and combine 30
More than minute, waste water enters washes skin collecting pit;
6th step, pickling softens, and skin is steeped the reuse pickling less than a week and softens in collection water, heat
30-35 DEG C, salt adding, formic acid, lactic acid, acidicenzym, oils and fats separating medium, fatting agent, it is adjusted to pH value 2.7-2.8,
Overnight, secondary sunrise skin, control water, waste water enter pickling and soften collecting pit;
7th step, goes acid, skin is steeped the reuse acid of going less than one week and collects in water, be warmed to 33 DEG C,
Add sodium bicarbonate, soda, to pH value 6.5-7, overnight, go out skin, waste water enter acid collecting pit in;
8th step, secondary degreasing, steeps skin in clear water, heats 36-38 DEG C, add degreasing agent, turn, stop 2
As a child going out skin, waste water enters washes severe edema due to hypofunction of the spleen collecting pit;
9th step, cleans, skin is steeped in clear water, heats 30-35 DEG C, turns, stops 30 minutes, and waste water is arranged
Enter the pond of defat wastewater collection first;
Tenth step, multiple pickling softens, and skin is steeped the reuse pickling less than a week and softens in collection water, supplement
Addition salt, formic acid, lactic acid, acidicenzym, oils and fats dispersant, fatting agent, to pH value 2.7-2.8, overnight,
Secondary sunrise skin draining, waste water enters pickling and softens pond;
11st step, tanning, skin is steeped the reuse tanning less than a week and collects in water, be warmed to 33 DEG C,
Supplement add oils and fats dispersant, fatting agent, aluminium tanningagent, chrome tanning agent, syntans, auxiliary tanning agent, sodium bicarbonate,
Antifungus agent, to pH value 3.8-3.9, overnight, go out skin, waste water enters tanning water collecting pit;
12nd step, wet grinding, rinses, neutralizes, stuffing, is dried, and arranges.
As preferably, degreasing agent 1g/L in step 2, penetrating agent 0.5-1g/L, antibacterial 0.5g/L.
As preferably, soda 1g/L degreasing agent 2.5g/L, antibacterial 0.3g/L in step 4.
As preferably, salt 5-10g/L in step 6, formic acid 2-4g/L, lactic acid 1-2g/L, acidicenzym 1.5-2
G/L, fatting agent 1-2g/L, oils and fats dispersant 0.1-0.3g/L.
As preferably, sodium bicarbonate 1.5-2g/L in step 7, soda 0.5-1g/L.
Further, in step 11, supplement the oils and fats dispersant 0.3-0.5g/L, fatting agent 1-2 added
G/L, aluminium tanningagent 2-4g/L, chrome tanning agent 8-10g/L, syntans 1-2g/L, auxiliary tanning agent 1-2g/L,
Sodium bicarbonate 1-2g/L, antifungus agent 0.3-0.5g/L.
Compared with prior art, the present invention has techniques below effect, by using in backwater, it is possible to reduce water
Consumption, and, Reusability backwater in some step, it is possible to reduce the use of additive, reduce cost,
Energy-conserving and environment-protective.
Detailed description of the invention:
Below in conjunction with detailed description of the invention, the invention will be further described:
Embodiment
A kind of little sheep, cunning sub-Mirabilitum technique, it comprises the following steps:
The first step, gage, manually chop unnecessary head, lower limb, length with ruler amount root of the tail to head and shoulder portion with cutter
Degree, then it is multiplied by the width of middle mesothelium, draw the size of skin, be then watered 2.5kg by the skin of every 2 square chi;
Second step, washes skin, skin is steeped the reuse skin of washing less than two days and collects in water, control water temperature 25 DEG C,
Addition degreasing agent, penetrating agent, antibacterial rotate, and then stand more than 4 hours, go out skin, by waste water
Enter in treatment tank;
3rd step, fleshing, manually operating equipped with on the fleshing equipment of return pipe water, accomplishing the clean nothing of flesh noodles
Scratch, oil-free lack, and return pipe water emptied to treatment tank the same day;
4th step, first defat, steep skin in the reuse middle water less than two days, heat 38-40 DEG C, add
Enter soda, degreasing agent, antibacterial carry out rotating, standing combination, repeated multiple times after go out skin, get rid of with dewaterer
Water 12-18 minute, waste water enters treatment tank;
5th step, cleans first, and skin is steeped in clear water, and heating 30-35 DEG C carries out rotating, stands and combine 30
More than minute, waste water enters washes skin collecting pit;
6th step, pickling softens, and skin is steeped the reuse pickling less than a week and softens in collection water, heat
30-35 DEG C, salt adding, formic acid, lactic acid, acidicenzym, oils and fats separating medium, fatting agent, it is adjusted to pH value 2.7-2.8,
Overnight, secondary sunrise skin, control water, waste water enter pickling and soften collecting pit;
7th step, goes acid, skin is steeped the reuse acid of going less than one week and collects in water, be warmed to 33 DEG C,
Add sodium bicarbonate, soda, to pH value 6.5-7, overnight, go out skin, waste water enter acid collecting pit in;
8th step, secondary degreasing, steeps skin in clear water, heats 36-38 DEG C, add degreasing agent, turn, stop 2
As a child going out skin, waste water enters washes severe edema due to hypofunction of the spleen collecting pit;
9th step, cleans, skin is steeped in clear water, heats 30-35 DEG C, turns, stops 30 minutes, and waste water is arranged
Enter the pond of defat wastewater collection first;
Tenth step, multiple pickling softens, and skin is steeped the reuse pickling less than a week and softens in collection water, supplement
Addition salt, formic acid, lactic acid, acidicenzym, oils and fats dispersant, fatting agent, to pH value 2.7-2.8, overnight,
Secondary sunrise skin draining, waste water enters pickling and softens pond;
11st step, tanning, skin is steeped the reuse tanning less than a week and collects in water, be warmed to 33 DEG C,
Supplement add oils and fats dispersant, fatting agent, aluminium tanningagent, chrome tanning agent, syntans, auxiliary tanning agent, sodium bicarbonate,
Antifungus agent, to pH value 3.8-3.9, overnight, go out skin, waste water enters tanning water collecting pit;
12nd step, wet grinding, rinses, neutralizes, stuffing, is dried, and arranges.
Wherein, degreasing agent 1g/L in step 2, penetrating agent 0.5-1g/L, antibacterial 0.5g/L.
Soda 1g/L degreasing agent 2.5g/L in step 4, antibacterial 0.3g/L.
Salt 5-10g/L in step 6, formic acid 2-4g/L, lactic acid 1-2g/L, acidicenzym 1.5-2g/L,
Fatting agent 1-2g/L, oils and fats dispersant 0.1-0.3g/L.
Sodium bicarbonate 1.5-2g/L in step 7, soda 0.5-1g/L.
In step 11, supplement the oils and fats dispersant 0.3-0.5g/L added, fatting agent 1-2g/L, aluminum tanning
Agent 2-4g/L, chrome tanning agent 8-10g/L, syntans 1-2g/L, auxiliary tanning agent 1-2g/L, sodium bicarbonate 1-2
G/L, antifungus agent 0.3-0.5g/L.
Claims (6)
1. a little sheep, cunning sub-Mirabilitum technique, it is characterised in that: it comprises the following steps:
The first step, gage, manually chop unnecessary head, lower limb, length with ruler amount root of the tail to head and shoulder portion with cutter
Degree, then it is multiplied by the width of middle mesothelium, draw the size of skin, be then watered 2.2-2.8kg by the skin of every 2 square chi;
Second step, washes skin, skin is steeped the reuse skin of washing less than two days and collects in water, control water temperature 20-27 DEG C,
Addition degreasing agent, penetrating agent, antibacterial rotate, and then stand more than 4 hours, go out skin, by waste water
Enter in treatment tank;
3rd step, fleshing, manually operating equipped with on the fleshing equipment of return pipe water, accomplishing the clean nothing of flesh noodles
Scratch, oil-free lack, and return pipe water emptied to treatment tank the same day;
4th step, first defat, steep skin in the reuse middle water less than two days, heat 38-40 DEG C, add
Enter soda, degreasing agent, antibacterial carry out rotating, standing combination, repeated multiple times after go out skin, get rid of with dewaterer
Water 12-18 minute, waste water enters treatment tank;
5th step, cleans first, and skin is steeped in clear water, and heating 30-35 DEG C carries out rotating, stands and combine 30
More than minute, waste water enters washes skin collecting pit;
6th step, pickling softens, and skin is steeped the reuse pickling less than a week and softens in collection water, heat
30-35 DEG C, salt adding, formic acid, lactic acid, acidicenzym, oils and fats separating medium, fatting agent, it is adjusted to pH value 2.7-2.8,
Overnight, secondary sunrise skin, control water, waste water enter pickling and soften collecting pit;
7th step, goes acid, skin is steeped the reuse acid of going less than one week and collects in water, be warmed to 33 DEG C,
Add sodium bicarbonate, soda, to pH value 6.5-7, overnight, go out skin, waste water enter acid collecting pit in;
8th step, secondary degreasing, steeps skin in clear water, heats 36-38 DEG C, add degreasing agent, turn, stop 2
As a child going out skin, waste water enters washes severe edema due to hypofunction of the spleen collecting pit;
9th step, cleans, skin is steeped in clear water, heats 30-35 DEG C, turns, stops 30 minutes, and waste water is arranged
Enter the pond of defat wastewater collection first;
Tenth step, multiple pickling softens, and skin is steeped the reuse pickling less than a week and softens in collection water, supplement
Addition salt, formic acid, lactic acid, acidicenzym, oils and fats dispersant, fatting agent, to pH value 2.7-2.8, overnight,
Secondary sunrise skin draining, waste water enters pickling and softens pond;
11st step, tanning, skin is steeped the reuse tanning less than a week and collects in water, be warmed to 33 DEG C,
Supplement add oils and fats dispersant, fatting agent, aluminium tanningagent, chrome tanning agent, syntans, auxiliary tanning agent, sodium bicarbonate,
Antifungus agent, to pH value 3.8-3.9, overnight, go out skin, waste water enters tanning water collecting pit;
12nd step, wet grinding, rinses, neutralizes, stuffing, is dried, and arranges.
Little sheep the most according to claim 1, cunning sub-Mirabilitum technique, it is characterised in that: step 2
Middle degreasing agent 1g/L, penetrating agent 0.5-1g/L, antibacterial 0.5g/L.
Little sheep the most according to claim 1, cunning sub-Mirabilitum technique, it is characterised in that: step 4
Middle soda 1g/L degreasing agent 2.5g/L, antibacterial 0.3g/L.
Little sheep the most according to claim 1, cunning sub-Mirabilitum technique, it is characterised in that: step 6
Middle salt 5-10g/L, formic acid 2-4g/L, lactic acid 1-2g/L, acidicenzym 1.5-2g/L, fatting agent 1-2g/L,
Oils and fats dispersant 0.1-0.3g/L.
Little sheep the most according to claim 1, cunning sub-Mirabilitum technique, it is characterised in that: step 7
Middle sodium bicarbonate 1.5-2g/L, soda 0.5-1g/L.
Little sheep the most according to claim 1, cunning sub-Mirabilitum technique, it is characterised in that: step 10
In one, supplement oils and fats dispersant 0.3-0.5g/L, fatting agent 1-2g/L, the aluminium tanningagent 2-4g/L added,
Chrome tanning agent 8-10g/L, syntans 1-2g/L, auxiliary tanning agent 1-2g/L, sodium bicarbonate 1-2g/L, mildew-resistant
Agent 0.3-0.5g/L.
Priority Applications (1)
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CN201610409557.XA CN106011324B (en) | 2016-06-12 | 2016-06-12 | A kind of small sheep, cunning sub- mirabilite technique |
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CN201610409557.XA CN106011324B (en) | 2016-06-12 | 2016-06-12 | A kind of small sheep, cunning sub- mirabilite technique |
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CN106011324A true CN106011324A (en) | 2016-10-12 |
CN106011324B CN106011324B (en) | 2017-11-28 |
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5868798A (en) * | 1994-08-23 | 1999-02-09 | Tanning Technologies Pty Ltd | Treatment of hides |
CN102534056A (en) * | 2010-12-14 | 2012-07-04 | 张壮斗 | Tanning production process capable of recycling waste water repeatedly from soaking to dyeing |
CN104673943A (en) * | 2013-11-30 | 2015-06-03 | 孟州市光宇皮业有限公司 | Method for manufacturing environment-friendly ecological tanned lamb skin |
CN104843807A (en) * | 2014-02-15 | 2015-08-19 | 张壮斗 | Cycle engineering for realization of tanning waste water near-zero emission |
-
2016
- 2016-06-12 CN CN201610409557.XA patent/CN106011324B/en active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5868798A (en) * | 1994-08-23 | 1999-02-09 | Tanning Technologies Pty Ltd | Treatment of hides |
CN102534056A (en) * | 2010-12-14 | 2012-07-04 | 张壮斗 | Tanning production process capable of recycling waste water repeatedly from soaking to dyeing |
CN104673943A (en) * | 2013-11-30 | 2015-06-03 | 孟州市光宇皮业有限公司 | Method for manufacturing environment-friendly ecological tanned lamb skin |
CN104843807A (en) * | 2014-02-15 | 2015-08-19 | 张壮斗 | Cycle engineering for realization of tanning waste water near-zero emission |
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