CN106010193A - Environment-friendly anti-freezing slippery road surface coating and preparation method thereof - Google Patents
Environment-friendly anti-freezing slippery road surface coating and preparation method thereof Download PDFInfo
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- CN106010193A CN106010193A CN201610522121.1A CN201610522121A CN106010193A CN 106010193 A CN106010193 A CN 106010193A CN 201610522121 A CN201610522121 A CN 201610522121A CN 106010193 A CN106010193 A CN 106010193A
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- coating
- anticoagulant ice
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
- C08K9/06—Ingredients treated with organic substances with silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01C—CONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
- E01C11/00—Details of pavings
- E01C11/24—Methods or arrangements for preventing slipperiness or protecting against influences of the weather
-
- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01C—CONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
- E01C11/00—Details of pavings
- E01C11/24—Methods or arrangements for preventing slipperiness or protecting against influences of the weather
- E01C11/245—Methods or arrangements for preventing slipperiness or protecting against influences of the weather for preventing ice formation or for loosening ice, e.g. special additives to the paving material, resilient coatings
-
- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01C—CONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
- E01C7/00—Coherent pavings made in situ
- E01C7/08—Coherent pavings made in situ made of road-metal and binders
- E01C7/35—Toppings or surface dressings; Methods of mixing, impregnating, or spreading them
- E01C7/356—Toppings or surface dressings; Methods of mixing, impregnating, or spreading them with exclusively synthetic resin as a binder; Aggregate, fillers or other additives for application on or in the surface of toppings having exclusively synthetic resin as binder
Abstract
The invention discloses an environment-friendly anti-freezing slippery road surface coating and a preparation method thereof. The coating is prepared from anti-freezing filler, a polyurethane coating composition and antiskid ceramic beads. The anti-freezing filler is formed by mixing potassium formate and hydrophobic modification kieselguhr powder in a ball-milling mode. The coating is obtained after the anti-freezing filler and the polyurethane coating composition are mixed to be uniform. When the coating is in use, the coating coats the surface of a test piece, then, ceramic beads are evenly spread, the surplus ceramic beads are removed after solidification is performed, and construction of the environment-friendly anti-freezing slippery road surface coating is completed. The environment-friendly anti-freezing slippery road surface coating is small in environmental hazard, low in corrosion, and capable of being used for preventing or relieving frozen ice on road surfaces of airport pavements, culvert entrances, up hills, down hills, sharp turns and the like when it is cold, rainy and snowy, and therefore the road driving safety is improved.
Description
Technical field
The present invention relates to a kind of anticoagulant ice anti-skid road surface paint and preparation method thereof, particularly relate to the anticoagulant of a kind of environment-friendly type
Ice anti-skid road surface paint and preparation method thereof.
Background technology
Pavement antiskid paint typically has gorgeous color, has and prevents vehicle slip, the function such as beautify the environment, and has attached
Put forth effort the features such as strong, wear-proof sliding-proof, it is adaptable to the sections such as gateway, tunnel, zig zag, climb and fall, ETC dedicated Lanes.Road surface is prevented
Sliding coating has easy construction, good antiskid effect specific.But, current pavement antiskid paint does not generally the most have anti-condensation ice
Function.When winter sleet microthermal climate cause icy on road after, owing to the coefficient of friction of ice is the lowest, cause road vehicles controllability
Decline, easily produce vehicle accident.The most conventional road surface deicing method is to use ice-melt salt, and it is mainly composed of Nacl chlorine
Change sodium.Although sodium chloride has significant deicing or snow melting ability, but iron structure is corroded more greatly and easily in environmental hazard by it.This
Outward, sodium chloride the most all uses after icy on road, needs controlled traffic in use, runs the high speed of highway system not
Profit.To this end, traffic department is badly in need of developing a kind of environment-friendly type and can preventing new-type antiskid material icy on road in time.
Summary of the invention
Anticoagulant ice anti-skid road surface paint that it is an object of the invention to provide a kind of environment-friendly type and preparation method thereof.
In order to realize this purpose, the present invention uses environment-friendly type potassium formate as anticoagulant ice additive, uses following technology
Scheme:
A kind of environment-friendly type anticoagulant ice anti-skid road surface paint, this coating is by anticoagulant ice filler, polyurethane coating composition and anti-skidding
Grain composition;Wherein the mass fraction of each composition is:
Anticoagulant ice filler 10 ~ 30 parts;
Polyurethane coating composition 40 ~ 60 parts;
Antiskid particles 30 parts;
Wherein, polyurethane coating composition is no-solvent type double-component polyurethane coating, and by Shenzhen, Cai Tian Chemical Co., Ltd. carries
Confession, polyurethane coating and firming agent are used in mixed way by proportioning 3 to 1;Antiskid particles is entire body redness Tao Zhu, Guangdong city Land Rover hand over
Logical facility company limited provides, and particle diameter is 3 ~ 5 mm.
The preparation method of described a kind of environment-friendly type anticoagulant ice anti-skid road surface paint:
1) anticoagulant ice filler is prepared
By (commercially available at 200 mL normal hexane for 25 g diatomite powders (Jinan Ying Chu Chemical Industry Science Co., Ltd, particle diameter is 450 mesh)
Analytical pure) in mechanical agitation obtain dispersion liquid, be subsequently adding 10 mL MTESs (lark prestige science and technology, purity >
98%) mechanical agitation is continued 30 minutes;Solidliquid mixture is stood after terminating by stirring, goes the supernatant;Lower floor's powder body is 60
It is vacuum dried 2 hours at DEG C, obtains the diatomite powder of hydrophobically modified;By 100 g potassium formate powder (analytical pure, traditional Chinese medicines group)
It is dry mixed in ball mill 2 hours with 25 g diatomite powders, then i.e. obtains anticoagulant ice filler by 100 mesh sub-sieves, dry
Dry device stores for future use.
2) anticoagulant ice coating is prepared
Proportionally mixing according to mass fraction polyurethane coating and firming agent, the anticoagulant ice being subsequently adding required mass fraction is filled out
Material, mechanical agitation mixes 10 minutes, obtains anticoagulant ice coating.
The construction method of described a kind of environment-friendly type anticoagulant ice anti-skid road surface paint:
1) preparation of sample
Mud green grass or young crops road surface sample, cement pavement sample are provided by Jiangxi Gan-Yue Expressway Co., Ltd, from rebuilt pavement
Cutting obtains, and rinses through dehydrated alcohol before using, and uses after natural drying.
2) coating anticoagulant ice coating
Anticoagulant ice coating is poured over specimen surface, and coating thickness is 2 ~ 3 mm.
3) surface dispenses Tao Zhu
By mass parts, Tao Zhu is spread in uniform in the coating surface of coating, by clear for unnecessary Tao Zhu after at room temperature solidifying 2 ~ 5 hours
Remove, i.e. complete construction.
The invention have the advantage that this coating is made up of anticoagulant ice filler, polyurethane coating composition and anti-skidding Tao Zhu.Anticoagulant
Ice filler is mixed by the diatomite powder ball milling of potassium formate and hydrophobically modified.By anticoagulant ice filler and polyurethane coating composition
Coating is obtained after thing mix homogeneously.During use, coating is coated in surface of test piece, subsequently uniform broadcasting Tao Zhu, by unnecessary after solidification
Tao Zhu removes the construction i.e. completing environment-friendly type anticoagulant ice anti-skid road surface paint.The environment-friendly type anticoagulant ice anti-skid road surface paint of the present invention
Environmental hazard is little, and corrosivity is low, can be used for preventing or alleviating under winter low temperature sleety weather airfield runway, culvert gateway,
The icing of the pavement of road such as climb and fall and zig zag, thus improve the driving safety of road.
Detailed description of the invention
The present invention is described in further detail for example below.
Embodiment 1
The preparation of anticoagulant ice filler: 25 g diatomite powders mechanical agitation in 200 mL normal hexane is obtained dispersion liquid, then
Add 10 mL MTESs and continue mechanical agitation 30 minutes;Solidliquid mixture is stood after terminating by stirring, goes
Layer clear liquid;Lower floor's powder body is vacuum dried 2 hours at 60 DEG C, obtains the diatomite powder of hydrophobically modified;By 100 g potassium formates
Powder and 25 g diatomite powders are dry mixed 2 hours in ball mill, then i.e. obtain anticoagulant ice filler by 100 mesh sub-sieves,
Exsiccator stores for future use.
Preparation anticoagulant ice coating: be 40 urethane compositions proportionally (polyurethane coating and firming agent by mass fraction
Ratio is 3 to 1) mixing, it is subsequently adding the anticoagulant ice filler that mass fraction is 30, mechanical agitation mixes 10 minutes, obtains anticoagulant
Ice coating.
The construction of environment-friendly type anticoagulant ice anti-skid road surface paint: mud green grass or young crops road surface sample is rinsed through dehydrated alcohol, natural drying
Rear use;Anticoagulant ice coating is poured over specimen surface, and with double faced adhesive tape around preventing spilling around sample, coating thickness is 2 mm;
The Tao Zhu that mass parts is 30 is spread in uniform in the coating surface of coating, and when room temperature is 20 ± 5 DEG C, at room temperature solidification 2 is little
Time after, unnecessary Tao Zhu is removed, i.e. complete construction.
The preparation process of blank sample is identical with construction method said process, but does not use anticoagulant ice filler, and polyurethane
Composition levels rises to 70 mass fractions, and Tao Zhu consumption is constant.
Performance evaluation:
1) anticoagulant ice performance
Testing in cryogenic refrigerator, when refrigerator temperature is set as-10 DEG C, be placed in cryogenic refrigerator by sample, surface is dripped
Add water droplet, observe it and freeze time delay.After tested, anticoagulant ice non-skid coating sample surfaces water droplet freezes after 2 hours not yet;Right
Freeze than in blank sample 3 minutes.
2) coating and substrate adhesion
Using tensile testing machine to test, test value is 0.56 MPa.
3) coating surface coefficient of friction
Use BM-3 type pendulum friction coefficient determinator, measure according to testing standard and average for 5 times, be at room temperature
9.02, it is 7.02 at-5 DEG C.
Embodiment 2
The preparation of anticoagulant ice filler: prepared by the method using embodiment 1 identical.
Preparation anticoagulant ice coating: be 50 urethane compositions proportionally (polyurethane coating and firming agent by mass fraction
Ratio is 3 to 1) mixing, it is subsequently adding the anticoagulant ice filler that mass fraction is 20, mechanical agitation mixes 10 minutes, obtains anticoagulant
Ice coating.
The construction of environment-friendly type anticoagulant ice anti-skid road surface paint: mud green grass or young crops road surface sample is rinsed through dehydrated alcohol, natural drying
Rear use;Being poured over around specimen surface, sample by anticoagulant ice coating with double faced adhesive tape around preventing spilling, coating thickness is 3
mm;The Tao Zhu that mass parts is 30 is spread in uniform in the coating surface of coating, when room temperature is 15 ± 5 DEG C, at room temperature solidifies
After 3 hours, unnecessary Tao Zhu is removed, i.e. complete construction.
The preparation process of blank sample is same as in Example 1 with construction method.
Performance evaluation:
1) anticoagulant ice performance
Testing in cryogenic refrigerator, when refrigerator temperature is set as-10 DEG C, be placed in cryogenic refrigerator by sample, surface is dripped
Add water droplet, observe it and freeze time delay.After tested, anticoagulant ice non-skid coating sample surfaces water droplet froze after 27 minutes;Contrast
Blank sample froze in 3 minutes.
2) coating and substrate adhesion
Using tensile testing machine to test, test value is 0.51 MPa.
3) coating surface coefficient of friction
Use BM-3 type pendulum friction coefficient determinator, measure according to testing standard and average for 5 times, be at room temperature
9.05, it is 7.01 at-5 DEG C.
Embodiment 3
The preparation of anticoagulant ice filler: prepared by the method using embodiment 1 identical.
Preparation anticoagulant ice coating: be 60 urethane compositions proportionally (polyurethane coating and firming agent by mass fraction
Ratio is 3 to 1) mixing, it is subsequently adding the anticoagulant ice filler that mass fraction is 10, mechanical agitation mixes 10 minutes, obtains anticoagulant
Ice coating.
The construction of environment-friendly type anticoagulant ice anti-skid road surface paint: mud green grass or young crops road surface sample is rinsed through dehydrated alcohol, natural drying
Rear use;Anticoagulant ice coating is poured over specimen surface, and with double faced adhesive tape around preventing spilling around sample, coating thickness is 3 mm;
The Tao Zhu that mass parts is 30 is spread in uniform in the coating surface of coating, and when room temperature is 20 ± 5 DEG C, at room temperature solidification 2 is little
Time after, unnecessary Tao Zhu is removed, i.e. complete construction.
Performance evaluation:
1) anticoagulant ice performance
Testing in cryogenic refrigerator, when refrigerator temperature is set as-10 DEG C, be placed in cryogenic refrigerator by sample, surface is dripped
Add water droplet, observe it and freeze time delay.After tested, anticoagulant ice non-skid coating sample surfaces water droplet froze after 8 minutes;Contrast sky
White sample froze in 3 minutes.
2) coating and substrate adhesion
Using tensile testing machine to test, test value is 0.55 MPa.
3) coating surface coefficient of friction
Use BM-3 type pendulum friction coefficient determinator, measure according to testing standard and average for 5 times, be at room temperature
9.02, it is 7.01 at-5 DEG C.
Embodiment 4
The preparation of anticoagulant ice filler: prepared by the method using embodiment 1 identical.
Preparation anticoagulant ice coating: be 40 urethane compositions proportionally (polyurethane coating and firming agent by mass fraction
Ratio is 3 to 1) mixing, it is subsequently adding the anticoagulant ice filler that mass fraction is 30, mechanical agitation mixes 10 minutes, obtains anticoagulant
Ice coating.
The construction of environment-friendly type anticoagulant ice anti-skid road surface paint: cement pavement sample is rinsed through dehydrated alcohol, natural drying
Rear use;Being poured over around specimen surface, sample by anticoagulant ice coating with double faced adhesive tape around preventing spilling, coating thickness is 3
mm;The Tao Zhu that mass parts is 30 is spread in uniform in the coating surface of coating, when room temperature is 10 ± 5 DEG C, at room temperature solidifies
After 12 hours, unnecessary Tao Zhu is removed, i.e. complete construction.
Performance evaluation:
1) anticoagulant ice performance
Testing in cryogenic refrigerator, when refrigerator temperature is set as-10 DEG C, be placed in cryogenic refrigerator by sample, surface is dripped
Add water droplet, observe it and freeze time delay.After tested, anticoagulant ice non-skid coating sample surfaces water droplet did not froze in 2 hours;Contrast
Blank sample froze in 3 minutes.
2) coating and substrate adhesion
Using tensile testing machine to test, test value is 0.57 MPa.
3) coating surface coefficient of friction
Use BM-3 type pendulum friction coefficient determinator, measure according to testing standard and average for 5 times, be at room temperature
9.05, it is 7.00 at-5 DEG C.
Embodiment 5
The preparation of anticoagulant ice filler: prepared by the method using embodiment 1 identical.
Preparation anticoagulant ice coating: be 40 urethane compositions proportionally (polyurethane coating and firming agent by mass fraction
Ratio is 3 to 1) mixing, it is subsequently adding the anticoagulant ice filler that mass fraction is 30, mechanical agitation mixes 10 minutes, obtains anticoagulant
Ice coating.
The construction of environment-friendly type anticoagulant ice anti-skid road surface paint: cement pavement sample is rinsed through dehydrated alcohol, natural drying
Rear use;Being poured over around specimen surface, sample by anticoagulant ice coating with double faced adhesive tape around preventing spilling, coating thickness is 2
mm;The Tao Zhu that mass parts is 30 is spread in uniform in the coating surface of coating, when room temperature is 5 ± 5 DEG C, at room temperature solidifies
After 24 hours, unnecessary Tao Zhu is removed, i.e. complete construction.
Performance evaluation:
1) anticoagulant ice performance
Testing in cryogenic refrigerator, when refrigerator temperature is set as-10 DEG C, be placed in cryogenic refrigerator by sample, surface is dripped
Add water droplet, observe it and freeze time delay.After tested, anticoagulant ice non-skid coating sample surfaces water droplet did not froze in 2 hours;Contrast
Blank sample froze in 3 minutes.
2) coating and substrate adhesion
Using tensile testing machine to test, test value is 0.57 MPa.
3) coating surface coefficient of friction
Use BM-3 type pendulum friction coefficient determinator, measure according to testing standard and average for 5 times, be at room temperature
9.01, it is 7.03 at-5 DEG C.
Claims (3)
1. an environment-friendly type anticoagulant ice anti-skid road surface paint, it is characterised in that: by anticoagulant ice filler, polyurethane coating composition and
Antiskid particles forms;Wherein the mass fraction of each composition is:
Anticoagulant ice filler 10 ~ 30 parts;
Polyurethane coating composition 40 ~ 60 parts;
Antiskid particles 30 parts;
Wherein, polyurethane coating composition is that no-solvent type double-component polyurethane coating, polyurethane coating and firming agent are by proportioning 3
It is used in mixed way than 1;Antiskid particles is entire body redness Tao Zhu, and particle diameter is 3 ~ 5 mm.
2. the preparation method of the environment-friendly type anticoagulant ice anti-skid road surface paint described in a claim 1, it is characterised in that:
1) anticoagulant ice filler is prepared:
25 g diatomite powders mechanical agitation in 200 mL normal hexane is obtained dispersion liquid, is subsequently adding 10 mL methyl three second
TMOS continues mechanical agitation 30 minutes;Solidliquid mixture is stood after terminating by stirring, goes the supernatant;Lower floor's powder body exists
It is vacuum dried 2 hours at 60 DEG C, obtains the diatomite powder of hydrophobically modified;By 100 g potassium formate powder and 25 g diatomites in powder
End is dry mixed 2 hours in ball mill, then i.e. obtains anticoagulant ice filler by 100 mesh sub-sieves, stores for future use in exsiccator;
2) anticoagulant ice coating is prepared:
Proportionally mixing according to mass fraction polyurethane coating and firming agent, the anticoagulant ice being subsequently adding required mass fraction is filled out
Material, mechanical agitation mixes 10 minutes, obtains anticoagulant ice coating.
3. the construction method of a kind of environment-friendly type anticoagulant ice anti-skid road surface paint described in claim 2, it is characterised in that:
1) preparation of sample;
By mud green grass or young crops road surface sample, cement pavement sample, obtain from rebuilt pavement cutting, rinse through dehydrated alcohol alcohol before using, from
The most dried use;
2) coating anticoagulant ice coating;
Being poured at specimen surface by anticoagulant ice coating, coating thickness is 2 ~ 3 mm;
3) surface dispenses Tao Zhu;
By mass parts, Tao Zhu is spread in uniform in the coating surface of coating, by clear for unnecessary Tao Zhu after at room temperature solidifying 2 ~ 5 hours
Remove, i.e. complete construction.
Priority Applications (1)
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CN201610522121.1A CN106010193A (en) | 2016-07-05 | 2016-07-05 | Environment-friendly anti-freezing slippery road surface coating and preparation method thereof |
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CN201610522121.1A CN106010193A (en) | 2016-07-05 | 2016-07-05 | Environment-friendly anti-freezing slippery road surface coating and preparation method thereof |
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Family
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CN201610522121.1A Pending CN106010193A (en) | 2016-07-05 | 2016-07-05 | Environment-friendly anti-freezing slippery road surface coating and preparation method thereof |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110044813A (en) * | 2019-04-11 | 2019-07-23 | 东南大学 | A kind of detection method of frost region bituminous pavement wide temperature field coefficient of friction |
CN114031343A (en) * | 2021-10-12 | 2022-02-11 | 山西交科桥梁隧道加固维护工程有限公司 | Environment-friendly slow-release type anti-freezing fine surface material and preparation method thereof |
CN114045746A (en) * | 2021-11-11 | 2022-02-15 | 重庆海聚道路材料有限公司 | Anti-freezing ultrathin wearing layer for preventive maintenance of bridge |
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WO2008066319A1 (en) * | 2006-11-28 | 2008-06-05 | Woo-Jae Lee | Inorganic pigments composition having high hardness |
CN103834290A (en) * | 2012-11-27 | 2014-06-04 | 上海东大化学有限公司 | Environmental-friendly two-component polyurethane waterproof coating and preparation method thereof |
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Title |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110044813A (en) * | 2019-04-11 | 2019-07-23 | 东南大学 | A kind of detection method of frost region bituminous pavement wide temperature field coefficient of friction |
CN114031343A (en) * | 2021-10-12 | 2022-02-11 | 山西交科桥梁隧道加固维护工程有限公司 | Environment-friendly slow-release type anti-freezing fine surface material and preparation method thereof |
CN114045746A (en) * | 2021-11-11 | 2022-02-15 | 重庆海聚道路材料有限公司 | Anti-freezing ultrathin wearing layer for preventive maintenance of bridge |
CN114045746B (en) * | 2021-11-11 | 2024-02-06 | 重庆海聚道路材料有限公司 | Anti-freezing ultra-thin wearing layer for bridge preventive maintenance |
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