CN106010154A - 一种钢铁行业用耐磨防水涂料 - Google Patents

一种钢铁行业用耐磨防水涂料 Download PDF

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CN106010154A
CN106010154A CN201610496359.1A CN201610496359A CN106010154A CN 106010154 A CN106010154 A CN 106010154A CN 201610496359 A CN201610496359 A CN 201610496359A CN 106010154 A CN106010154 A CN 106010154A
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胡昌悌
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Wuhu Shuangbao Building Material Co Ltd
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Abstract

本发明公开了一种钢铁行业用耐磨防水涂料，其原料按重量份包括：聚酯树脂20‑40份，缩二脲5‑15份，氧化镁1‑2份，丙二醇甲醚15‑35份，锆英粉1‑4份，石英粉4‑8份，黏土1‑3份，改性蒙脱土5‑15份，沉淀硫酸钡2‑4份。本发明耐磨、耐热性好，力学性能优异。

Description

一种钢铁行业用耐磨防水涂料
技术领域
本发明涉及涂料技术领域，尤其涉及一种钢铁行业用耐磨防水涂料。
背景技术
涂料涂覆在基材表面，除具有美观作用以外，还具有防锈、防水、防腐、耐磨和耐热性能，其涂层具有坚韧性、着色性、黏附性、易干性和一定的光泽，可广泛应用于钢铁制造、冶金、石油工业、天然气开采、航空航天等工业领域，目前钢铁制造行业虽已生产出多种涂料仍满足不了需求，如何制备一种耐磨性能好，热稳定性、力学性能优异的涂料成为目前需要解决的技术问题。
发明内容
基于背景技术存在的技术问题，本发明提出了一种钢铁行业用耐磨防水涂料，耐磨、耐热性好，力学性能优异。
本发明提出的一种钢铁行业用耐磨防水涂料，其原料按重量份包括：聚酯树脂20-40份，缩二脲5-15份，氧化镁1-2份，丙二醇甲醚15-35份，锆英粉1-4份，石英粉4-8份，黏土1-3份，改性蒙脱土5-15份，沉淀硫酸钡2-4份。
优选地，改性蒙脱土采用如下工艺制备：将碳酸钠、氯化钠、氯化锌、稀土混合研磨均匀，加入水搅拌均匀，加入蒙脱土、玉米蛋白粉、羧甲基纤维素钠混合研磨均匀，调节体系pH值至9-10，放入水浴振动器中，加入碱性蛋白酶酶解，灭酶，调节体系pH值至中性，加入干酵母发酵，杀菌，喷雾干燥，得到改性蒙脱土。
优选地，改性蒙脱土采用如下工艺制备：按重量份将0.5-1.5份碳酸钠、1-2份氯化钠、1-2份氯化锌、0.5-1份稀土混合研磨均匀，加入20-40份水搅拌均匀，加入12-22份蒙脱土、5-12份玉米蛋白粉、0.5-1.5份羧甲基纤维素钠混合研磨均匀，调节体系pH值至9-10，放入水浴振动器中，加入碱性蛋白酶酶解，灭酶，调节体系pH值至中性，加入干酵母发酵，杀菌，喷雾干燥，得到改性蒙脱土。
优选地，改性蒙脱土采用如下工艺制备：按重量份将0.5-1.5份碳酸钠、1-2份氯化钠、1-2份氯化锌、0.5-1份稀土混合研磨均匀，加入20-40份水搅拌均匀，加入12-22份蒙脱土、5-12份玉米蛋白粉、0.5-1.5份羧甲基纤维素钠混合研磨均匀，调节体系pH值至9-10，放入55-65℃水浴振动器中，加入碱性蛋白酶酶解，灭酶，调节体系pH值至中性，加入干酵母发酵1-4min，杀菌，喷雾干燥，得到改性蒙脱土。
优选地，聚酯树脂、缩二脲、改性蒙脱土的重量比为25-35：8-12：8-12。
优选地，改性蒙脱土和丙二醇甲醚的重量比为8-12：20-30。
优选地，改性蒙脱土、石英粉、锆英粉、黏土、沉淀硫酸钡的重量比为8-12：5-7：2-3：1.5-2.5：3-3.5。
优选地，其原料按重量份包括：聚酯树脂25-35份，缩二脲8-12份，氧化镁1.2-1.8份，丙二醇甲醚20-30份，锆英粉2-3份，石英粉5-7份，黏土1.5-2.5份，改性蒙脱土8-12份，沉淀硫酸钡3-3.5份。
本发明采用聚酯树脂、缩二脲与改性蒙脱土相互配合，制品固含量高，耐热性好；而采用一定工艺制备的改性蒙脱土粘结强度极高，透气性能好，传热速度加快，热稳定性能优异，力学性能好，其中的玉米蛋白粉经过碱性蛋白酶酶解、干酵母发酵后，溶解度好，乳化性能优异，且无不良气味；改性蒙脱土与丙二醇甲醚的相容性极好，与缩二脲、聚酯树脂合理配比，涂刷时涂膜均匀，且粘附强度极高；改性蒙脱土与石英粉、锆英粉、黏土、沉淀硫酸钡协同作用，耐磨强度极高，力学性能极好。
具体实施方式
下面，通过具体实施例对本发明的技术方案进行详细说明。
实施例1
本发明提出的一种钢铁行业用耐磨防水涂料，其原料按重量份包括：聚酯树脂20份，缩二脲15份，氧化镁1份，丙二醇甲醚35份，锆英粉1份，石英粉8份，黏土1份，改性蒙脱土15份，沉淀硫酸钡2份。
实施例2
本发明提出的一种钢铁行业用耐磨防水涂料，其原料按重量份包括：聚酯树脂40份，缩二脲5份，氧化镁2份，丙二醇甲醚15份，锆英粉4份，石英粉4份，黏土3份，改性蒙脱土5份，沉淀硫酸钡4份。
改性蒙脱土采用如下工艺制备：将碳酸钠、氯化钠、氯化锌、稀土混合研磨均匀，加入水搅拌均匀，加入蒙脱土、玉米蛋白粉、羧甲基纤维素钠混合研磨均匀，调节体系pH值至9-10，放入水浴振动器中，加入碱性蛋白酶酶解，灭酶，调节体系pH值至中性，加入干酵母发酵，杀菌，喷雾干燥，得到改性蒙脱土。
实施例3
本发明提出的一种钢铁行业用耐磨防水涂料，其原料按重量份包括：聚酯树脂25份，缩二脲12份，氧化镁1.2份，丙二醇甲醚30份，锆英粉2份，石英粉7份，黏土1.5份，改性蒙脱土12份，沉淀硫酸钡3份。
改性蒙脱土采用如下工艺制备：按重量份将1.5份碳酸钠、1份氯化钠、2份氯化锌、0.5份稀土混合研磨均匀，加入40份水搅拌均匀，加入12份蒙脱土、12份玉米蛋白粉、0.5份羧甲基纤维素钠混合研磨均匀，调节体系pH值至9-10，放入65℃水浴振动器中，加入碱性蛋白酶酶解，灭酶，调节体系pH值至中性，加入干酵母发酵1min，杀菌，喷雾干燥，得到改性蒙脱土。
实施例4
本发明提出的一种钢铁行业用耐磨防水涂料，其原料按重量份包括：聚酯树脂35份，缩二脲8份，氧化镁1.8份，丙二醇甲醚20份，锆英粉3份，石英粉5份，黏土2.5份，改性蒙脱土8份，沉淀硫酸钡3.5份。
改性蒙脱土采用如下工艺制备：按重量份将0.5份碳酸钠、2份氯化钠、1份氯化锌、1份稀土混合研磨均匀，加入20份水搅拌均匀，加入22份蒙脱土、5份玉米蛋白粉、1.5份羧甲基纤维素钠混合研磨均匀，调节体系pH值至9-10，放入55℃水浴振动器中，加入碱性蛋白酶酶解，灭酶，调节体系pH值至中性，加入干酵母发酵4min，杀菌，喷雾干燥，得到改性蒙脱土。
实施例5
本发明提出的一种钢铁行业用耐磨防水涂料，其原料按重量份包括：聚酯树脂30份，缩二脲10份，氧化镁1.5份，丙二醇甲醚25份，锆英粉2.5份，石英粉6份，黏土2份，改性蒙脱土10份，沉淀硫酸钡3.2份。
改性蒙脱土采用如下工艺制备：按重量份将1份碳酸钠、1.5份氯化钠、1.6份氯化锌、0.8份稀土混合研磨均匀，加入30份水搅拌均匀，加入17份蒙脱土、8份玉米蛋白粉、1份羧甲基纤维素钠混合研磨均匀，调节体系pH值至9-10，放入60℃水浴振动器中，加入碱性蛋白酶酶解，灭酶，调节体系pH值至中性，加入干酵母发酵2.5min，杀菌，喷雾干燥，得到改性蒙脱土。
以上所述，仅为本发明较佳的具体实施方式，但本发明的保护范围并不局限于此，任何熟悉本技术领域的技术人员在本发明揭露的技术范围内，根据本发明的技术方案及其发明构思加以等同替换或改变，都应涵盖在本发明的保护范围之内。

Claims (8)

1.一种钢铁行业用耐磨防水涂料，其特征在于，其原料按重量份包括：聚酯树脂20-40份，缩二脲5-15份，氧化镁1-2份，丙二醇甲醚15-35份，锆英粉1-4份，石英粉4-8份，黏土1-3份，改性蒙脱土5-15份，沉淀硫酸钡2-4份。
2.根据权利要求1所述的钢铁行业用耐磨防水涂料，其特征在于，改性蒙脱土采用如下工艺制备：将碳酸钠、氯化钠、氯化锌、稀土混合研磨均匀，加入水搅拌均匀，加入蒙脱土、玉米蛋白粉、羧甲基纤维素钠混合研磨均匀，调节体系pH值至9-10，放入水浴振动器中，加入碱性蛋白酶酶解，灭酶，调节体系pH值至中性，加入干酵母发酵，杀菌，喷雾干燥，得到改性蒙脱土。
3.根据权利要求1或2所述的钢铁行业用耐磨防水涂料，其特征在于，改性蒙脱土采用如下工艺制备：按重量份将0.5-1.5份碳酸钠、1-2份氯化钠、1-2份氯化锌、0.5-1份稀土混合研磨均匀，加入20-40份水搅拌均匀，加入12-22份蒙脱土、5-12份玉米蛋白粉、0.5-1.5份羧甲基纤维素钠混合研磨均匀，调节体系pH值至9-10，放入水浴振动器中，加入碱性蛋白酶酶解，灭酶，调节体系pH值至中性，加入干酵母发酵，杀菌，喷雾干燥，得到改性蒙脱土。
4.根据权利要求1-3任一项所述的钢铁行业用耐磨防水涂料，其特征在于，改性蒙脱土采用如下工艺制备：按重量份将0.5-1.5份碳酸钠、1-2份氯化钠、1-2份氯化锌、0.5-1份稀土混合研磨均匀，加入20-40份水搅拌均匀，加入12-22份蒙脱土、5-12份玉米蛋白粉、0.5-1.5份羧甲基纤维素钠混合研磨均匀，调节体系pH值至9-10，放入55-65℃水浴振动器中，加入碱性蛋白酶酶解，灭酶，调节体系pH值至中性，加入干酵母发酵1-4min，杀菌，喷雾干燥，得到改性蒙脱土。
5.根据权利要求1-4任一项所述的钢铁行业用耐磨防水涂料，其特征在于，聚酯树脂、缩二脲、改性蒙脱土的重量比为25-35：8-12：8-12。
6.根据权利要求1-5任一项所述的钢铁行业用耐磨防水涂料，其特征在于，改性蒙脱土和丙二醇甲醚的重量比为8-12：20-30。
7.根据权利要求1-6任一项所述的钢铁行业用耐磨防水涂料，其特征在于，改性蒙脱土、石英粉、锆英粉、黏土、沉淀硫酸钡的重量比为8-12：5-7：2-3：1.5-2.5：3-3.5。
8.根据权利要求1-7任一项所述的钢铁行业用耐磨防水涂料，其特征在于，其原料按重量份包括：聚酯树脂25-35份，缩二脲8-12份，氧化镁1.2-1.8份，丙二醇甲醚20-30份，锆英粉2-3份，石英粉5-7份，黏土1.5-2.5份，改性蒙脱土8-12份，沉淀硫酸钡3-3.5份。
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