CN106009523A - Joint beautifying agent for ceramic tile joint treatment and decoration - Google Patents
Joint beautifying agent for ceramic tile joint treatment and decoration Download PDFInfo
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- CN106009523A CN106009523A CN201610528137.3A CN201610528137A CN106009523A CN 106009523 A CN106009523 A CN 106009523A CN 201610528137 A CN201610528137 A CN 201610528137A CN 106009523 A CN106009523 A CN 106009523A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/06—Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/346—Clay
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
- C08L63/04—Epoxynovolacs
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
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- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
A joint beautifying agent for ceramic tile joint treatment and decoration contains two components A and B, wherein the components A and B are mixed in accordance with the ratio of 1 to 0.8-1, the component A includes, by weight, 90-100 parts of epoxy resin, 0.5-15 parts of a thickener, 0.5-1.5 parts of a sagging prevention assistant, 1-2 parts of a defoaming agent, 0.2-0.5 part of a flatting agent, 0.2-0.3 part of a dispersant and 5-150 parts of an organic or inorganic pigment, and the component B includes, by weight, 50-100 parts of an epoxy curing agent, 0.5-3 parts of a thickener, 0.2-0.3 part of a dispersant and 0.5-2 parts of a defoaming agent. The joint beautifying agent has excellent flexibility, volume stability, abrasion resistance and contamination resistance.
Description
Technical field:
The present invention relates to a kind of beautiful seam agent, be specifically related to a kind of process for ceramic tile gap and decoration
Beautiful seam agent.
Background technology:
Beautiful seam agent, with epoxy resin as key component, generates after reacting with modified amine curing agent
Having cubical contraction less than 1%, wearability is less than 250mm3, vinegar, soy sauce, black tea,
Machine oil etc. are easy to scrub after soaking, opposing cracking, the smooth performance such as beautiful of apparent condition
New material, 0 grade of mildew-resistant can be reached.At present, volume in ordinary epoxy resin cross-linking process
Contraction, poor flexibility, crisp, it is impossible to be applied to beautiful seam agent material, and epoxy resin gap processes
Material be generally only improve epoxy resin fragility and solidification after volume stability, but to body
The research of later stage decoration performance, contaminated resistance, the opposing cracking etc. of system rarely has report.Such as,
Prior art CN201210127269.7 discloses a kind of bi-component epoxy gap filler and preparation thereof
Method, in this bi-component epoxy gap filler, component A consists of the following composition by weight percentage:
Aqueous epoxy resins 13.5-33.5%, quartz sand 25.5-68.5%, propylene glycol 0.5-2.5%,
Glitter powder 1-5%, organosilicon levelling agent 1-5%, Pulvis Talci 1-31%；B component percentage by weight
Ratio consists of the following composition: aqueous epoxy curing agent 90-95%, phenol 5-10%.Component A
Be 10: 1-4 with the weight ratio of B component, be in harmonious proportion at a given proportion during use uniformly double
Component epoxy gap filler.And containing substantial amounts of quartz sand in component A, and it is functional filling material
Material, it is difficult to produce and vinegar, soy sauce, black tea, the anti-stain characteristic energy of machine oil and later stage are decorated
Performance etc.；In B component, phenol can produce serious harm to environment, and makes water body and air
Become to pollute.
Summary of the invention:
The technical problem to be solved is to provide a kind of has anti-contamination, cracking resistance
Safe efficient, have no side effect processes for ceramic tile gap and the beautiful seam agent of decoration.
The present invention solves its technical problem and the technical scheme is that a kind of at ceramic tile gap
Reason and the beautiful seam agent of decoration, including two components of A, B, A and B mixes according to 1: 0.8～1
Closing, each component forms as follows in parts by weight:
Further, described epoxy resin selected from bisphenol A epoxide resin, bisphenol F epoxy resin and
One or more mixture in novolac epoxy resin.
Further, described thickening agent is aerosil and/or polyamide wax.
Further, described resist sagging auxiliary agent is organobentonite, Oleum Ricini, modified urea, poly-ammonia
One or more mixture in ester association material and acrylates.
Further, the one during described dispersant is unsaturated polycarboxylic acid polymers or or two kinds
Above mixture, such as BYK-104s, HX-4020 or HX-4040.
Further, during described defoamer is silicone defoamer, mineral oil defoaming agent
Kind or two or more mixture.
Further, described levelling agent is modified polyorganosiloxane class and modified acroleic acid esters levelling agent
In one or more mixture.
Further, described organic or inorganic pigment is the one in titanium dioxide, mill base and glitter powder
Or two or more mixture.
Further, the one during described epoxy hardener is fat polyamine, polyamide and aliphatic cyclic amine
Or two or more mixture.
Preferably, the preparation method of the beautiful seam agent of the present invention, comprise the following steps:
(1) by epoxy resin, thickening agent, resist sagging auxiliary agent, levelling agent, defoamer, dispersant,
Organic or inorganic color stuffing is thoroughly mixed uniformly, obtains component A；
(2) epoxy hardener, thickening agent, dispersant, defoamer are thoroughly mixed uniformly,
Obtain B component.
During use, by A, B component proportionally (component A gross score: B component gross score)
A: B=1: (0.8-1), mixing and stirring is filled in ceramic tile gap.When packaging and use
Can use and but be not limited to domestic and international injecting glue glue bucket packaging, glue bucket can be that up-down structure also may be used
Thinking concentric structure, the most any packaged form is all within the scope of this patent.
The present invention by use component A epoxy resin, each analog assistant, organic or inorganic pigment,
B component epoxy hardener, each analog assistant is prepared from, wherein, epoxy resin and curable epoxide
Agent is reacted, and forms that fine and close, hardness is high also has a flexible bulk composition, various helps
Agent is played and is made organic or inorganic pigment obtain good peptizaiton, and organic or inorganic pigment plays
The various decorative color of product is provided.
It is high and right that the beautiful seam agent of the present invention has superior pliable and tough crack resistance, volume stability
The superior toleration of pollutant, the superior dicorations such as vinegar, soy sauce, tea, machine oil, not only color
Color further flexibility, and gloss can debug formula according to actual application environment, also has excellence anti-
Mould performance, wearability etc., thus more effectively it is applied to gap decoration.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1
By 90 parts of bisphenol-A liquid-state epoxy resin E44,2 parts of aerosils, 0.3 part point
Powder BYK-104s, 1 part of silicone defoamer BYK-A530,0.3 part of silicone levelling
Agent BYK310,1 part of organobentonite, 50 parts of phthalocyanine blues, 3 parts of glitter powder mix homogeneously obtain
To component A.
By 50 parts of fat polyamine firming agent, 3 parts of aerosils, 0.2 part of dispersant
BYK-104s, 1 part of silicone defoamer BYK-A530, mix homogeneously obtains B component.
In use, by A, B component in gross score ratio A: B=1: 1 mix homogeneously spreads upon
Ceramic tile gap.
Embodiment 2
By 95 parts of bisphenol-A liquid-state epoxy resin F51,10 parts of aerosils, 0.2 part
Dispersant B YK-104s, 1.5 parts of defoamer (wherein 1 part of modified organic silicon BYK-A530 with
The mixture of 0.5 part of DEFOM6500), 0.5 part of silicone levelling agent LEVASLIP810,
0.5 part of organobentonite, 150 parts of color stuffings comprise 50 parts of barium sulfate, titanium dioxide 50 parts,
Pulvis Talci 50 parts, mix homogeneously obtains component A.
By 90 parts of fat polyamine firming agent, 2 polyamide waxes, 0.1 part of dispersant B YK-104s,
0.8 part of silicone defoamer DEFOM6500, mix homogeneously obtains B component.
In use, by A, B component in total number ratio A: fill out after B=1: 0.8 mix homogeneously
Fill in ceramic tile gap.
Embodiment 3
By 95 parts of bisphenol F epoxy resin F652,10 parts of aerosils, 0.2 part of dispersion
Agent HX-4020,1 part of defoamer DEFOM6500, the esters of acrylic acid levelling of 0.1 part of fluorine richness
Agent LEVASLIP839,0.3 part of 1484 levelling agent, 20 parts of glitter powders, 30 parts of titanium dioxides, 1
Part resist sagging auxiliary agent B YK-410, mix homogeneously obtains component A.
By 80 parts of alicyclic ring polyamines, 2 parts of aerosils, 0.2 part of dispersant B YK-104s,
1 part of silicone defoamer BYK-A530, mix homogeneously obtains B component.
In use, by A, B component in total number ratio A: B=1: 0.9 mix homogeneously is filled
In ceramic tile gap.
Embodiment 4
By 100 parts of liquefied phenol formaldehyde epoxy resin F51,15 parts of aerosils, 0.25 part
Wetting dispersing agent HX-4040,1 part of defoamer DEFOM6500,0.4 part of levelling agent acrylate
SKR-1153,0.8 part of organobentonite, 11 parts of titanium dioxides, 5 parts of white carbon blacks, mix homogeneously obtains
To component A.
By 90 parts of fat polyamine mixture, 3 parts of aerosils, 10 parts of titanium dioxide mixing
0.2 part of dispersant B YK-104s, 1 part of silicone defoamer DEFOM6500, mix homogeneously
Obtain B component.
In use, by A, B component in total number ratio A: B=1: 1 mix homogeneously is filled in
Ceramic tile gap.
Embodiment 5
By 95 parts of liquefied phenol formaldehyde epoxy resin F51 (10 parts) and bisphenol A epoxide resin F51
The mixture of (85 parts), 14 parts of aerosils, 0.3 part of dispersant HX-4040 (0.1
Part) and the mixture of BYK104s (0.2 part), 1 part of silicone defoamer DEFOM6500,
0.3 part of levelling agent be (0.1 part of acrylate levelling agent SKR-1153's and 0.2 part of BYK310
Mixture), 0.5 part of resist sagging auxiliary agent B YK-410,120 parts of barium sulfate, mix homogeneously obtains
To component A.
By 80 parts of polyamide, 3 parts of aerosils, 10 parts of titanium dioxides mix, 0.2 part
Dispersant B YK-104s, 1 part of silicone defoamer DEFOM6500, mix homogeneously obtains B
Component.
In use, by A, B component in total number ratio A: B=1: 0.8 mix homogeneously is filled
In ceramic tile gap.
Beautiful seam agent prepared by embodiment 1～5 is carried out performance test, and the performance test results is shown in Table
Shown in 1.
The performance test results of the beautiful seam agent of table 1-embodiment 1～5 preparation
As shown in Table 1, the beautiful seam agent cubical contraction of embodiment 1～5 preparation is 0.1～0.5%
Between, wearability is less than 31～61mm3, after vinegar, soy sauce, black tea, machine oil etc. soak
Being easy to scrub, opposing cracking, apparent condition is smooth beautiful, can reach various amplitude
Gloss, be deployed into shades of colour, 0 grade of mildew-resistant can be reached.
Claims (9)
1. one kind processes and the beautiful seam agent of decoration for ceramic tile gap, it is characterised in that include A, B
Two components, wherein, A and B is according to 1: 0.8～1 mixing, and component A includes following weight
The raw material of number: epoxy resin 90～100 parts, thickening agent 0.5～15 parts, resist sagging auxiliary agent
0.5～1.5 part, defoamer 1～2 parts, levelling agent 0.2～0.5 part, dispersant 0.2～0.3
Part, organic or inorganic pigment 5～150 parts；B component includes the raw material of following parts by weight:
Epoxy hardener 50～100 parts, thickening agent 0.5～3 parts, dispersant 0.1～0.3 part, disappear
Infusion 1～2 parts.
The beautiful seam agent processing for ceramic tile gap and decorating the most according to claim 1, it is special
Levying and be, described epoxy resin is selected from bisphenol A epoxide resin, bisphenol F epoxy resin and phenolic aldehyde
One or more mixture in epoxy resin.
The beautiful seam agent processing for ceramic tile gap and decorating the most according to claim 1, it is special
Levying and be, described thickening agent is selected from aerosil and/or polyamide wax.
The beautiful seam agent processing for ceramic tile gap and decorating the most according to claim 1, it is special
Levying and be, described resist sagging auxiliary agent is that organobentonite, Oleum Ricini, modified urea, polyurethane are formed
One or more mixture in condensation material and acrylates.
The beautiful seam agent processing for ceramic tile gap and decorating the most according to claim 1, it is special
Levy and be, described defoamer one in silicone defoamer, mineral oil defoaming agent
Or two or more mixture.
The beautiful seam agent processing for ceramic tile gap and decorating the most according to claim 1, it is special
Levying and be, described levelling agent is in modified polyorganosiloxane class and modified acroleic acid esters levelling agent
One or more mixture.
The beautiful seam agent processing for ceramic tile gap and decorating the most according to claim 1, it is special
Levying and be, described dispersant is one or more in unsaturated polycarboxylic acid polymers
Mixture.
The beautiful seam agent processing for ceramic tile gap and decorating the most according to claim 1, it is special
Levy and be, described organic or inorganic pigment one in titanium dioxide, mill base and glitter powder or
Two or more mixture.
The beautiful seam agent processing for ceramic tile gap and decorating the most according to claim 1, it is special
Levy and be, described epoxy hardener one in fat polyamine, polyamide and aliphatic cyclic amine or
Two or more mixture.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610528137.3A CN106009523A (en) | 2016-07-05 | 2016-07-05 | Joint beautifying agent for ceramic tile joint treatment and decoration |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610528137.3A CN106009523A (en) | 2016-07-05 | 2016-07-05 | Joint beautifying agent for ceramic tile joint treatment and decoration |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106009523A true CN106009523A (en) | 2016-10-12 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610528137.3A Pending CN106009523A (en) | 2016-07-05 | 2016-07-05 | Joint beautifying agent for ceramic tile joint treatment and decoration |
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| Country | Link |
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| CN (1) | CN106009523A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109679554A (en) * | 2019-01-04 | 2019-04-26 | 福建惠安县惠兴工贸有限公司 | A kind of bicomponent epoxy resin base gap filler |
| CN110628301A (en) * | 2019-09-06 | 2019-12-31 | 广州市五羊油漆(翁源)有限公司 | Special water-based paint for ceramic tiles and application method thereof |
| CN112841220A (en) * | 2021-01-11 | 2021-05-28 | 同曦集团有限公司 | Silver-zinc nano composite antibacterial agent and preparation method and application thereof |
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| CN103409090A (en) * | 2013-06-05 | 2013-11-27 | 武汉市科达云石护理材料有限公司 | Epoxy caulk compound used in humid environment |
| CN105084814A (en) * | 2015-08-17 | 2015-11-25 | 北京东方雨虹防水技术股份有限公司 | Self-expansion sand-free ceramic tile gap filling treatment material and preparation method thereof |
| CN105349079A (en) * | 2015-12-01 | 2016-02-24 | 上海域金澜优电子商务有限公司 | Production formula of negative ion seam beautifying agent capable of purifying air |
-
2016
- 2016-07-05 CN CN201610528137.3A patent/CN106009523A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103409090A (en) * | 2013-06-05 | 2013-11-27 | 武汉市科达云石护理材料有限公司 | Epoxy caulk compound used in humid environment |
| CN105084814A (en) * | 2015-08-17 | 2015-11-25 | 北京东方雨虹防水技术股份有限公司 | Self-expansion sand-free ceramic tile gap filling treatment material and preparation method thereof |
| CN105349079A (en) * | 2015-12-01 | 2016-02-24 | 上海域金澜优电子商务有限公司 | Production formula of negative ion seam beautifying agent capable of purifying air |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109679554A (en) * | 2019-01-04 | 2019-04-26 | 福建惠安县惠兴工贸有限公司 | A kind of bicomponent epoxy resin base gap filler |
| CN109679554B (en) * | 2019-01-04 | 2021-12-03 | 福建惠安县惠兴工贸有限公司 | Two-component epoxy resin-based joint mixture |
| CN110628301A (en) * | 2019-09-06 | 2019-12-31 | 广州市五羊油漆(翁源)有限公司 | Special water-based paint for ceramic tiles and application method thereof |
| CN112841220A (en) * | 2021-01-11 | 2021-05-28 | 同曦集团有限公司 | Silver-zinc nano composite antibacterial agent and preparation method and application thereof |
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