CN106007806B - A kind of preparation method of ink-jet marble ceramic tile - Google Patents
A kind of preparation method of ink-jet marble ceramic tile Download PDFInfo
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- CN106007806B CN106007806B CN201610346688.8A CN201610346688A CN106007806B CN 106007806 B CN106007806 B CN 106007806B CN 201610346688 A CN201610346688 A CN 201610346688A CN 106007806 B CN106007806 B CN 106007806B
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- 239000000919 ceramic Substances 0.000 title claims abstract description 60
- 239000004579 marble Substances 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 28
- 239000003086 colorant Substances 0.000 claims abstract description 18
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 38
- 239000000203 mixture Substances 0.000 claims description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
- 239000000843 powder Substances 0.000 claims description 16
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 10
- 239000004368 Modified starch Substances 0.000 claims description 10
- 229920000881 Modified starch Polymers 0.000 claims description 10
- 235000019426 modified starch Nutrition 0.000 claims description 10
- 239000007767 bonding agent Substances 0.000 claims description 9
- 239000003381 stabilizer Substances 0.000 claims description 9
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 8
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 8
- 239000000908 ammonium hydroxide Substances 0.000 claims description 8
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 8
- 238000007641 inkjet printing Methods 0.000 claims description 6
- 239000005995 Aluminium silicate Substances 0.000 claims description 5
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 5
- 235000012211 aluminium silicate Nutrition 0.000 claims description 5
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 5
- 239000008367 deionised water Substances 0.000 claims description 5
- 229910021641 deionized water Inorganic materials 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 239000010433 feldspar Substances 0.000 claims description 5
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 5
- 239000010453 quartz Substances 0.000 claims description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 5
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 5
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 5
- 239000001509 sodium citrate Substances 0.000 claims description 4
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 claims description 4
- 229940038773 trisodium citrate Drugs 0.000 claims description 4
- 229910052723 transition metal Inorganic materials 0.000 claims description 3
- 238000003854 Surface Print Methods 0.000 claims description 2
- 229910001510 metal chloride Inorganic materials 0.000 claims description 2
- 239000007921 spray Substances 0.000 claims description 2
- 150000003624 transition metals Chemical group 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 11
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- 239000002689 soil Substances 0.000 abstract description 3
- ORILYTVJVMAKLC-UHFFFAOYSA-N adamantane Chemical compound C1C(C2)CC3CC1CC2C3 ORILYTVJVMAKLC-UHFFFAOYSA-N 0.000 abstract description 2
- 229910001573 adamantine Inorganic materials 0.000 abstract description 2
- 239000011159 matrix material Substances 0.000 abstract description 2
- 238000005507 spraying Methods 0.000 abstract description 2
- 239000004575 stone Substances 0.000 description 11
- 239000011449 brick Substances 0.000 description 10
- 210000003298 dental enamel Anatomy 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 229910021556 Chromium(III) chloride Inorganic materials 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 5
- QSWDMMVNRMROPK-UHFFFAOYSA-K chromium(3+) trichloride Chemical compound [Cl-].[Cl-].[Cl-].[Cr+3] QSWDMMVNRMROPK-UHFFFAOYSA-K 0.000 description 5
- 229910021580 Cobalt(II) chloride Inorganic materials 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 4
- 229910021380 Manganese Chloride Inorganic materials 0.000 description 4
- GLFNIEUTAYBVOC-UHFFFAOYSA-L Manganese chloride Chemical compound Cl[Mn]Cl GLFNIEUTAYBVOC-UHFFFAOYSA-L 0.000 description 4
- 238000005299 abrasion Methods 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 239000011636 chromium(III) chloride Substances 0.000 description 4
- 230000007547 defect Effects 0.000 description 4
- 239000011565 manganese chloride Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 230000000007 visual effect Effects 0.000 description 4
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 3
- 238000010257 thawing Methods 0.000 description 3
- -1 Transition metal hydrochloride Chemical class 0.000 description 2
- 230000003373 anti-fouling effect Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- SOBHUZYZLFQYFK-UHFFFAOYSA-K trisodium;hydroxy-[[phosphonatomethyl(phosphonomethyl)amino]methyl]phosphinate Chemical compound [Na+].[Na+].[Na+].OP(O)(=O)CN(CP(O)([O-])=O)CP([O-])([O-])=O SOBHUZYZLFQYFK-UHFFFAOYSA-K 0.000 description 2
- LRZSAGKIMYFLHY-UHFFFAOYSA-N 2-hydroxypropane-1,2,3-tricarboxylic acid;dihydrate Chemical compound O.O.OC(=O)CC(O)(C(O)=O)CC(O)=O LRZSAGKIMYFLHY-UHFFFAOYSA-N 0.000 description 1
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 description 1
- 240000003273 Passiflora laurifolia Species 0.000 description 1
- 235000013762 Passiflora laurifolia Nutrition 0.000 description 1
- 239000002928 artificial marble Substances 0.000 description 1
- 238000005282 brightening Methods 0.000 description 1
- 229960000359 chromic chloride Drugs 0.000 description 1
- GVPFVAHMJGGAJG-UHFFFAOYSA-L cobalt dichloride Chemical compound [Cl-].[Cl-].[Co+2] GVPFVAHMJGGAJG-UHFFFAOYSA-L 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 description 1
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Finishing Walls (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a kind of preparation methods of ink-jet marble ceramic tile, by directly spraying nanometer penetration-assisting agent in green compact matrix surface, it is uniform to promote to ooze the colorant in fancy glaze using nanometer penetration-assisting agent, completely go deep into inside green body, thereafter pass through the effect of nanometer colour former again, colorant is set to be generated inside green body clearly, excellent color and pattern, wear-resisting adamantine layer is generated in billet surface simultaneously, ink-jet marble ceramic tile wearability obtained is good, soil resistance is good, application is good, pattern color is abundant simultaneously, pattern line, clean mark, decorative effect is good, production stage is simple, production cost is relatively low.
Description
Technical field
The present invention relates to Dali stone ceramic tiles, the especially technical field of ink-jet marble ceramic tile.
Background technology
Dali stone ceramic tile refers to the Ceramic Tiles for having marble surface feature, and appearance is close with marble, decorative effect
Well, and in some main performances, as impact resistance, wearability, flexural strength, water absorption rate etc. are better than natural marble
Stone, cost of upkeep are relatively low.
Because of the features described above of Dali stone ceramic tile, it is applied in construction industry more and more widely, people are to its performance and dress
The requirement of decorations effect is also continuously improved.Dali stone ceramic tile presses the difference of its processing method, and common includes oozing colored polished bricks, ink-jet
Full-glazed tile etc..
It is to combine the polished bricks for oozing colored technology wherein to ooze colored polished bricks, for by being carried out on the surface of all-body tile green body
The ceramic tile of surface-brightening obtained from sanding and polishing, surface do not contain enamel, and wearability is preferable with skid resistance, but in making
Concave-convex stomata is often left in the process, and antifouling capacity is very poor, and in terms of decorative effect, the pattern color that oozes colored polished bricks is single, line
Texture is unintelligible, is unsuitable for applying the place high in decorative effect requirement.
Ink-jet Full-glazed tile is the ceramic tile that re-polishing obtains after the surface glazing of traditional polished bricks, and procedure of processing is usual
Including on green body apply ground-coat enamel, again stamp, apply overglaze again, the process for being polished overglaze after firing.As publication No. is
A kind of artificial marble ceramic tiles proposed in the Chinese patent application file of CN101973784A comprising blank, ground-coat enamel, fancy glaze,
And transparent overglaze.Relative to colored polished bricks are oozed, the pattern of ink-jet Full-glazed tile is more rich, color is more bright-coloured, texture is apparent, but
Its wearability, skid resistance are poor, and work in-process, are very easy to generate glaze stomata, poor so as to cause its antifouling capacity, together
When ink-jet Full-glazed tile production cost it is higher.
Invention content
It is an object of the invention to propose that a kind of wearability is good, soil resistance is good, and pattern color is abundant, pattern line, texture
Clearly, decorative effect is good, the preparation method of the lower Dali stone ceramic tile of production cost.
Technical scheme is as follows：
A kind of preparation method of ink-jet marble ceramic tile, includes the following steps：
（1）It is compressed to ceramic green after ceramic green powder is mixed with nanometer stabilizer；
（2）Nanometer penetration-assisting agent is sprayed to ceramic green surface；
（3）After nanometer penetration-assisting agent drying fancy glaze is oozed in green surface printing using the mode of ink jet printing；
（4）To completion step（3）Green surface spray nanometer colour former, obtain presoma after dry；
（5）Presoma is fired at 1150 ~ 1250 DEG C to 60 ~ 70 minutes to get to the ink-jet marble ceramic tile；
The wherein described nanometer stabilizer is the mixture being made of ammonium hydroxide, ethylenediamine, trisodium citrate.
Herein trisodium citrate can also its hydrate form be added, such as citrate dihydrate trisodium.
The preferable amount of the nanometer stabilizer is 5% ~ 10 ﹪ of green body powder.
The ink-jet marble ceramic tile is the mode general that ink jet printing can be used directly after penetration-assisting agent is added on green compact
Glaze is printed on green body, without other intermediate steps and complicated processing procedure.
The Dali stone ceramic tile is preferably further polished.
The feed postition of nanometer stabilizer is preferably the mode that when green compact are suppressed and powder is uniformly mixed jointly.
Nanometer stabilizer is used to promote the good bonding between powder particles in the present invention, and is prevented during processing
It is absorbed in green compact and oozes fancy glaze excess diffusion, appearance phenomena such as so as to cause pattern line is fuzzy, color mixes.
In the present invention nanometer penetration-assisting agent be used to help to ooze fancy glaze quickly, uniformly, it is complete and synchronously penetrate into green compact, to
It ensure that the point of pattern, the depth and width uniformity of line.
Nanometer colour former is used in sintering procedure in the present invention, plays reduction so that the pigment oozed in fancy glaze exists
In green body color development evenly, naturally, keeping pattern apparent, color is distincter, shows aestheticism, effect true to nature.
Preferably：The step（2）Described in nanometer penetration-assisting agent be by active water, sodium carboxymethylcellulose（CMC）, second
The mixture of glycol composition.
Nanometer penetration-assisting agent can be adsorbed and be lubricated to green body herein, and further be penetrated into inside green body, high temperature firing
Afterwards, inorganic salts are promoted to be chemically reacted with green body, the color development inside green body.
It is also preferred that：The step（4）Described in nanometer colour former be transition metal HCI solution.
Transition metal hydrochloride, such as MnCl2、CoCl2、CrCl3、FeCl3Deng by the effect of penetration-assisting agent, can directly penetrating into
In green body, after high-temperature oxydation reacts in green body color development.
It is also preferred that：The component of the ceramic green includes feldspar, quartz, kaolin.
It is also preferred that：The step（3）Described in ooze fancy glaze include colorant, modified starch bonding agent, it is described
Toner is metal chloride, and the modified starch bonding agent includes one or more in ethylene glycol, ethylenediamine, deionized water.
Colorant such as nickel chloride, chromium trichloride, cobalt chloride, iron chloride etc..
Its further preferably described viscosity for oozing fancy glaze is 200 ~ 300m.Pa.s.
It is also preferred that：The addition of the nanometer stabilizer is the 5 ~ 10% of the ceramic green powder.
It is also preferred that：Relative to the surface area of green compact, the step（2）Described in the dosage of nanometer penetration-assisting agent be
200~300g/m²。
It is also preferred that：The content of the nanometer colour former is the 30% ~ 40% of the ceramic green powder.
The solution that the preferred stirring of nanometer colour former is 0.2 ~ 3mPa.s of viscosity, coloring appropriate is selected according to the requirement of color
Agent is proportionally added into, and can penetrate into color development inside green body.
The enamel of Dali stone ceramic tile made from the preparation method of the present invention is permeated with inside ceramic body, and wherein colorant oozes
It is 1.5 ~ 2.0mm to enter thickness.
0.5 ﹪ of ink-jet marble ceramic tile water absorption rate ＜ obtained, abrasion resistance >=7 grade, flexural strength are 40 ~ 50Mpa,
Frozen-thawed cycled 20 is without visual defects at -15 ~ 20 DEG C.Moisture expantion is minimum, wear-resistant, acid and alkali-resistance, non-discolouring, long lifespan.
The present invention is oozed using the promotion of nanometer penetration-assisting agent in fancy glaze by directly spraying nanometer penetration-assisting agent in green compact matrix surface
Colorant uniformly, completely go deep into inside green body, enable colorant in green body by the effect of nanometer colour former again thereafter
Inside generates clear, excellent color and pattern, while wear-resisting adamantine layer is generated in billet surface, ink-jet marble porcelain
Brick wearability is good, and soil resistance is good, and pattern color is abundant, and pattern line, clean mark, decorative effect is good, and production stage is simple,
Production cost is relatively low.
Specific implementation mode
In the following, the present invention will be further described in detail by way of specific embodiments, but this should not be interpreted as to the present invention
Range be only limitted to example below.Without departing from the idea of the above method of the present invention, according to ordinary skill
The various replacements or change that knowledge and customary means are made, should be included in the scope of the present invention.
Embodiment 1
（1）It is its 5% ammonium hydroxide, ethylenediamine, citrate dihydrate by ceramic green powder feldspar, quartz, kaolin and quality
Trisodium composition mixture be uniformly mixed, wherein ammonium hydroxide, ethylenediamine, citrate dihydrate trisodium mass ratio be 3:3:4, mixing
After uniformly ceramic green is compressed under 30Mpa in brick machine；
（2）The nanometer penetration-assisting agent of 200g/m2 is sprayed to ceramic green surface, nanometer penetration-assisting agent is active water, carboxymethyl fibre
The plain sodium of dimension（CMC）, ethylene glycol composition mixture, wherein active water, sodium carboxymethylcellulose（CMC）, ethylene glycol mass ratio
Example is 6:1:3；
（3）After 5min, the drying of nanometer penetration-assisting agent is oozed fancy glaze using the 8 channel computerized ink jet printing of 5D ink jet printers, is oozed in fancy glaze
Containing colorant and modified starch bonding agent, modified starch bonding agent is ethylene glycol, and oozing fancy glaze viscosity after the two allotment is
200m.Pa.s；
（4）To completion step（3）Green surface sprinkling quality be green compact powder 30% nanometer colour former, it is dry after
To presoma, nanometer colour former is MnCl2、CoCl2、CrCl3、FeCl3Mixture be dissolved in the viscosity obtained after deionized water and be
The solution of 0.8mPa.s；
（5）Presoma is fired at 1250 DEG C to 60 minutes to get to the ink-jet marble ceramic tile；
Enamel is permeated with inside ceramic body in the stone ceramic tile of gained Dali, and colorant generates color in green body at 1.5mm,
Tile image is clear, various colors, and water absorption rate is 0.3 ﹪, and abrasion resistance is 7 grades, flexural strength 40Mpa, the freeze thawing at -20 DEG C
Without visual defects, moisture expantion is minimum, wear-resistant, acid and alkali-resistance, non-discolouring for cycle 20 times.
Embodiment 2
（1）It is its 10% ammonium hydroxide, ethylenediamine, citric acid three by ceramic green powder feldspar, quartz, kaolin and quality
Sodium composition mixture be uniformly mixed, wherein ammonium hydroxide, ethylenediamine, trisodium citrate mass ratio be 1:1:1, after mixing
In brick machine ceramic green is compressed under 30Mpa；
（2）The nanometer penetration-assisting agent of 250g/m2 is sprayed to ceramic green surface, nanometer penetration-assisting agent is active water, carboxymethyl fibre
The plain sodium of dimension（CMC）, ethylene glycol composition mixture, wherein active water, sodium carboxymethylcellulose（CMC）, ethylene glycol mass ratio
Example is respectively 6:2:3；
（3）After 10min, the drying of nanometer penetration-assisting agent oozes fancy glaze using the 8 channel computerized ink jet printing of 5D ink jet printers, oozes fancy glaze
In containing colorant and modified starch bonding agent, modified starch bonding agent is ethylene glycol, and viscosity is 300mPa.s after the two allotment；
（4）To completion step（3）Green surface sprinkling quality be green compact powder 30% nanometer colour former, it is dry after
To presoma, nanometer colour former is MnCl2、CoCl2、CrCl3、FeCl3Mixture be dissolved in the viscosity obtained after deionized water and be
The solution of 1mPa.s；
（5）Presoma is fired at 1150 DEG C to 70 minutes to get to the ink-jet marble ceramic tile；
Enamel is permeated with inside ceramic body in the stone ceramic tile of gained Dali, and colorant generates color in green body at 2.0mm,
Tile image is clear, various colors, and water absorption rate is 0.4 ﹪, and abrasion resistance is 7 grades, flexural strength 45Mpa, the freeze thawing at -15 DEG C
Without visual defects, moisture expantion is minimum, wear-resistant, acid and alkali-resistance, non-discolouring for cycle 20 times.
Embodiment 3
（1）It is its 10% ammonium hydroxide, ethylenediamine, two water lemons by ceramic green powder feldspar, quartz, kaolin and quality
The mixture of sour trisodium composition is uniformly mixed, wherein ammonium hydroxide, ethylenediamine, citrate dihydrate trisodium mass ratio be 2:1:2, it mixes
After closing uniformly ceramic green is compressed under 30Mpa in brick machine；
（2）The nanometer penetration-assisting agent of 300g/m2 is sprayed to ceramic green surface, nanometer penetration-assisting agent is active water, carboxymethyl fibre
The plain sodium of dimension（CMC）, ethylene glycol composition mixture, wherein active water, sodium carboxymethylcellulose（CMC）, ethylene glycol mass ratio
Example is 6:3:2；
（3）After 10min, the drying of nanometer penetration-assisting agent oozes fancy glaze using the 8 channel computerized ink jet printing of 5D ink jet printers, oozes fancy glaze
In containing colorant and modified starch bonding agent, modified starch bonding agent is ethylene glycol, and viscosity is 250mPa.s after the two allotment；
（4）To completion step（3）Green surface sprinkling quality be green compact powder 40% nanometer colour former, it is dry after
To presoma, nanometer colour former is MnCl2、CoCl2、CrCl3、FeCl3Mixture be dissolved in the viscosity obtained after deionized water and be
The solution of 2mPa.s；
（5）Presoma is fired at 1200 DEG C to 70 minutes to get to the ink-jet marble ceramic tile；
Enamel is permeated with inside ceramic body in the stone ceramic tile of gained Dali, and colorant generates color in green body at 2.0mm,
Tile image is clear, various colors, and water absorption rate is 0.3 ﹪, and abrasion resistance is 7 grades, flexural strength 45Mpa, the freeze thawing at -20 DEG C
Without visual defects, moisture expantion is minimum, wear-resistant, acid and alkali-resistance, non-discolouring for cycle 20 times.
Claims (8)
1. a kind of preparation method of ink-jet marble ceramic tile, it is characterised in that：Include the following steps：
（1）It is compressed to ceramic green after ceramic green powder is mixed with nanometer stabilizer；
（2）Nanometer penetration-assisting agent is sprayed to ceramic green surface；
（3）After nanometer penetration-assisting agent drying fancy glaze is oozed in green surface printing using the mode of ink jet printing；
（4）To completion step（3）Green surface spray nanometer colour former, obtain presoma after dry；
（5）Presoma is fired at 1150 ~ 1250 DEG C to 60 ~ 70 minutes to get to the ink-jet marble ceramic tile；
The wherein described nanometer stabilizer is the mixture being made of ammonium hydroxide, ethylenediamine, trisodium citrate；The step（2）Middle institute
It is by active water, sodium carboxymethylcellulose to state nanometer penetration-assisting agent（CMC）, ethylene glycol composition mixture；The step（4）Middle institute
State the HCI solution that nanometer colour former is transition metal.
2. the preparation method of ink-jet marble ceramic tile according to claim 1, it is characterised in that：The nanometer color development
The viscosity of agent is 0.2 ~ 3mPa.s.
3. the preparation method of ink-jet marble ceramic tile according to claim 1, it is characterised in that：The ceramic green
Powder includes feldspar, quartz, kaolin.
4. the preparation method of ink-jet marble ceramic tile according to claim 1, it is characterised in that：The step（3）
Described in ooze fancy glaze include colorant, modified starch bonding agent, the colorant is metal chloride, and the modified starch combines
Agent includes one or more in ethylene glycol, ethylenediamine, deionized water.
5. the preparation method of ink-jet marble ceramic tile according to claim 4, it is characterised in that：The fancy glaze of oozing
Viscosity is 200 ~ 300m.Pa.s.
6. the preparation method of ink-jet marble ceramic tile according to claim 1, it is characterised in that：The step（1）
Described in nanometer stabilizer addition be the ceramic green powder 5 ~ 10%.
7. the preparation method of ink-jet marble ceramic tile according to claim 1, it is characterised in that：Relative to green compact
Surface area, the step（2）Described in nanometer penetration-assisting agent dosage be 200 ~ 300g/m2.
8. the preparation method of ink-jet marble ceramic tile according to claim 1, it is characterised in that：The step（4）
Described in nanometer colour former content be the ceramic green powder 30% ~ 40%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610346688.8A CN106007806B (en) | 2016-05-24 | 2016-05-24 | A kind of preparation method of ink-jet marble ceramic tile |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201610346688.8A CN106007806B (en) | 2016-05-24 | 2016-05-24 | A kind of preparation method of ink-jet marble ceramic tile |
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| CN106518162A (en) * | 2016-12-27 | 2017-03-22 | 清远纳福娜陶瓷有限公司 | Blank storage heat-insulation device, ceramic brick drying and heat-insulation system and method |
| CN107266023B (en) * | 2017-06-21 | 2019-10-29 | 广东宏宇新型材料有限公司 | Surface is gentle as jade has the ink-jet of translucency to seep flower polished brick in porcelain character and preparation method |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1408679A (en) * | 2002-08-28 | 2003-04-09 | 佛山欧神诺陶瓷有限公司 | Method for producing pattern permeating ceramic tile |
| CN1553033A (en) * | 2003-06-05 | 2004-12-08 | 佛山欧神诺陶瓷有限公司 | Ceramic glazed brick and manufacturing method thereof |
| CN101177352A (en) * | 2006-11-10 | 2008-05-14 | 霍炳祥 | Method for solving glaze lamination of ceramic products |
| CN102795892A (en) * | 2012-09-10 | 2012-11-28 | 杭州诺贝尔陶瓷有限公司 | Soluble salt ceramic tile and production method thereof |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1408679A (en) * | 2002-08-28 | 2003-04-09 | 佛山欧神诺陶瓷有限公司 | Method for producing pattern permeating ceramic tile |
| CN1553033A (en) * | 2003-06-05 | 2004-12-08 | 佛山欧神诺陶瓷有限公司 | Ceramic glazed brick and manufacturing method thereof |
| CN101177352A (en) * | 2006-11-10 | 2008-05-14 | 霍炳祥 | Method for solving glaze lamination of ceramic products |
| CN102795892A (en) * | 2012-09-10 | 2012-11-28 | 杭州诺贝尔陶瓷有限公司 | Soluble salt ceramic tile and production method thereof |
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