CN105994292A - Insecticidal composition containing tolfenpyrad - Google Patents
Insecticidal composition containing tolfenpyrad Download PDFInfo
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- CN105994292A CN105994292A CN201610498019.2A CN201610498019A CN105994292A CN 105994292 A CN105994292 A CN 105994292A CN 201610498019 A CN201610498019 A CN 201610498019A CN 105994292 A CN105994292 A CN 105994292A
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- tolfenpyrad
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
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- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
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- Engineering & Computer Science (AREA)
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- General Health & Medical Sciences (AREA)
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Abstract
The invention relates to insecticide compositions in the agricultural field and in particular relates to an insecticidal composition containing tolfenpyrad. The composition is prepared by compounding active ingredients including pyrazoleindanylformamide or a derivative thereof and tolfenpyrad, wherein the mass ratio of pyrazoleindanylformamide or the derivative thereof to tolfenpyrad is (4 to 1)-(1 to 40); and the mass fraction of the active ingredients is 6-82%. The composition can be used for controlling various pests of fruit trees, cotton, wheat, vegetables, flowers, rice, and other crops, such as empoasca pirisuga matumura, scale insects, psylla chinensis, rice planthopper, thrips, cotton aphid and diamondback moth, has the characteristics of high efficiency, low toxicity and residues, wide insecticidal spectrum, obvious synergistic effects, reduction of the use cost, and the like, especially high efficiency and low toxicity and residues, and is especially beneficial to production of green food.
Description
Technical field
The invention belongs to agricultural insecticide field, be specifically related to a kind of Pesticidal combination Han Tolfenpyrad.
Background technology
(1) Tolfenpyrad:
Trade name: catch worm youth
Chemical name: 4-chloro-3-ethyl-1-methyl-N-{ [4-(4-methylphenoxy) phenyl]-methyl }-1H pyrazoles-5-carboxylic acyl
Amine；
Molecular weight: 383.87128；
Molecular structural formula: C21H22N3O2Cl；
Fusing point: 87 DEG C～89 DEG C；
Structural formula:
Its mechanism of action is to hinder the electronics in mitochondrial metabolic system to pass on system complex I, is subject to so that electronics is passed on
To hindering, make insecticide not be provided that and storing energy, be referred to as Mitochondrial electron and pass on complex Inhibitors (METI).
(2) pyrazoles indanyl Carbox amide is as a kind of novel active composition, has sterilization, parasite killing, has killed the virus
Activity and the effect of regulation crop production.Its chemical name: 3-difluoromethyl-N-(7-fluoro-1,1,3-trimethyl-4-indane
Base)-1-methyl-4-pyrazolecarboxamide, follow-up abbreviation pyrazoles indanyl Methanamide；Its molecular structural formula following (Me represent methyl-
CH3):
Its mechanism of action is: pyrazoles pyrazoles indanyl Methanamide and derivant thereof are due to amide groups replacement site on pyrazole ring
Different and produce different biological activitys, suppress receptor, thus have different insecticidal effects.
The most they do not use report and the record of situation with, and inventor in experiments it is found that, this two classes drug effect is used with
Obvious potentiation and lasting effect can be played.
Summary of the invention
It is an object of the invention to provide a kind of efficient spectrum Pesticidal combination based on Tolfenpyrad.
The object of the present invention is achieved like this, based on pyrazoles indanyl Methanamide and the characteristic research of Tolfenpyrad, and will
Pyrazoles indanyl Methanamide and derivant and Tolfenpyrad thereof be active ingredient carry out compounding, produce obvious synergistic effect,
Improve quick-acting and lasting period, and expand preventing and treating spectrum, reduce use cost, also have simultaneously and reduce crop morbidity, improve
The effect of crop growing state.
A kind of Pesticidal combination Han Tolfenpyrad, is activity by pyrazoles indanyl Methanamide or derivatives thereof and Tolfenpyrad
Composition is compounding to be formed, and described pyrazoles indanyl Methanamide or derivatives thereof is 4:1～1:40 with the mass ratio of Tolfenpyrad；
Preferably, described pyrazoles indanyl Methanamide or derivatives thereof is 1:1～1:10 with the mass ratio of Tolfenpyrad；
It is 6～82% that the described Pesticidal combination containing Tolfenpyrad obtains the mass fraction of active ingredient；
Described pyrazoles indanyl carboxamides derivatives be 3-dichloromethyl-N-(7-chloro-1,1,3-trimethyl-4-indanyl)-
1-methyl-4-pyrazolecarboxamide or 3-difluoromethyl-N-(7-fluoro-1,1-dimethyl, 3-ethyl base-4-indanyl)-1-ethyl-
4-pyrazolecarboxamide.
The dosage form that said composition can be made has: suspending agent, wettable powder, water dispersion granule, dry suspending agent.
Said composition can be used to prevent and treat the insects such as crop such as fruit tree, Cotton Gossypii, Semen Tritici aestivi, vegetable, flowers, Oryza sativa L., such as: tea is little
The various plants insect such as greenery Cicadae, scale insect, pear sucker and planthopper, thrips, cotten aphid, diamondback moth, has efficiently, low toxicity, low
Residual, insecticidal spectrum are wide, potentiation significantly and reduces the features such as use cost, particularly its high efficiency, low toxicity, low-residual, especially
It is conducive to the production of pollution-free food.
The auxiliary agent that said composition can be selected has: 602#, soybean oil, triphenoethyl benzene phenol polyethenoxy ether, and ammonium sulfate is swollen
Profit soil, organosilicon, xanthan gum, APG, sodium lignin sulfonate, white carbon, aluminium-magnesium silicate, silicone oil, glycerol, pulls open
Powder, di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate, calcium dodecyl benzene sulfonate, triphenoethyl benzene phenol polyethenoxy ether, phenethyl phenol mela mine-formaldehyde resin
Polyoxyethylene ether, dodecylbenzene sodium sulfonate, Pulvis Talci, mineral oil, carboxymethyl starch sodium, wooden calcium carbonate, the di-2-ethylhexylphosphine oxide bitter edible plant
Sodium sulfonate, polycarboxylate, sodium lauryl sulphate, Kaolin, di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate, polycarboxylate, octyl phenol polyoxy second
Alkene ether, carboxymethyl starch sodium.
The invention have the benefit that by being activity by pyrazoles indanyl Methanamide and derivant thereof and Tolfenpyrad
It is compounding that composition is carried out, and improves quick-acting and lasting period, and expands preventing and treating spectrum, reduce use cost, also has fall simultaneously
Low crop falls ill, and improves the effect of crop growing state.
Detailed description of the invention
The technical scheme related to invention below in conjunction with embodiment is further described, in order to contribute to the reason of the present invention
Solve, but not as the restriction to technical scheme, in addition to specifically mentioned, component ratio is part by weight.
Embodiment one
20% pyrazoles indanyl Methanamide Tolfenpyrad suspending agent
Raw material consists of: the 16% pyrazoles former medicine of indanyl Methanamide, the 4% former medicine of Tolfenpyrad, 10%600#, 5% soybean oil, 5% 3
Phenethyl phenol polyoxyethylene ether, 4% ammonium sulfate, 3% bentonite, 0.3 % organosilicon, 0.3% xanthan gum, 5% APG, its
Remaining water is supplied, routinely the preparation of the suspending agent mode of production.
This embodiment is used for preventing and treating Caulis et Folium Brassicae capitatae diamondback moth, by 20% pyrazoles indanyl Methanamide Tolfenpyrad suspending agent 1500 times
Being watered dilution spraying, after medicine, the prevention effect of 7 d and 15 d is respectively 90.2% and 96.7%, and during 20 d, prevention effect also reaches
87.3%.15% Tolfenpyrad suspending agent 800 times, uses by same method, after medicine the preventive effect of 7 d and 15 d be respectively 77.8%,
80.3%, prevention effect during 20 d is 70.1%；Tolfenpyrad and the compounding rear potentiation of pyrazoles indanyl Methanamide are obvious, right
The prevention effect of Caulis et Folium Brassicae capitatae diamondback moth is better than single dose, extends the lasting period obvious.
By pyrazoles indanyl Methanamide and Tolfenpyrad suspending agent respectively by 30/1,25/1,20/1,15/1,10/1,5/1,
3/1,1/1,1/3,1/5,1/10,1/15,1/20,1/25,1/30, ratio compounds, respectively with 5% pyrazoles indanyl Methanamide SC
Carrying out diamondback moth toxicity test with 15% Tolfenpyrad SC as comparison, co-toxicity coefficient is 130.7～165.4, wherein 5:1～1:
20 is 147.5～165.4,1:1～1:10 is 152.3～165.4, and synergistic effect is notable.
Embodiment two
30% pyrazoles indanyl carboxamides derivatives Tolfenpyrad suspending agent
Raw material consists of: 15%3-dichloromethyl-N-(7-chloro-1,1,3-trimethyl-4-indanyl)-1-methyl-4-pyrazoles formyl
Amine, the 15% former medicine of Tolfenpyrad, 10% sodium lignin sulfonate, 1% white carbon, 1% aluminium-magnesium silicate, 0.2% silicone oil, 0.12% xanthan gum,
The glycerol of 5%, remaining supplies with water, routinely the preparation of the suspending agent mode of production.
This embodiment is used for preventing and treating smaller green leaf hopper, by 30% pyrazoles indanyl carboxamides derivatives Tolfenpyrad suspending agent
1500 times are watered dilution spraying, and after medicine, the prevention effect of 7 d and 15 d is respectively 88.7% and 95.6%, prevention effect during 20 d
It is 86.1%.The method use that 20% Tolfenpyrad suspending agent 800 times use is same, after medicine, the preventive effect of 7 d and 15 d is respectively
73.6%, 85.7%, the prevention effect of 20 d is 62.9%；Tolfenpyrad and the compounding rear potentiation of pyrazoles indanyl carboxamides derivatives
Effect substantially, is better than single dose to the prevention effect of smaller green leaf hopper.
Pyrazoles indanyl carboxamides derivatives and Tolfenpyrad suspending agent are pressed 30/1,25/1,20/1,15/1,10/1,5/ respectively
1,3/1,1/1,1/3,1/5,1/10,1/15,1/20,1/25,1/30, ratio compounds, respectively with 15% pyrazoles indanyl Methanamide
Derivant SC and 15% Tolfenpyrad SC carry out smaller green leaf hopper toxicity test as comparison, and co-toxicity coefficient is 127.17 ~ 156.39,
Wherein 5:1～1:20 is 142.2～161.3,1:1～1:10 is 150.1～161.3, and synergistic effect is notable.
Embodiment three
35% pyrazoles indanyl Methanamide Tolfenpyrad suspending agent
Raw material consists of: the 25% pyrazoles former medicine of indanyl Methanamide, the 10% former medicine of Tolfenpyrad, 1.2% pulls open powder, 1% di-2-ethylhexylphosphine oxide
Bitter edible plant sodium sulfonate, 1.7% calcium dodecyl benzene sulfonate, 2.3% triphenoethyl benzene phenol polyethenoxy ether, 1.5% phenethyl phenol mela mine-formaldehyde resin
Polyoxyethylene ether, 0.8% white carbon, 1.2% aluminium-magnesium silicate, 0.12% xanthan gum, the glycerol of 5%, remaining is supplied with water, routinely
The suspending agent mode of production is prepared.
This embodiment is used for preventing and treating coccid, by 35% pyrazoles indanyl Methanamide Tolfenpyrad suspending agent 1500-3000
Being watered dilution spraying again, after medicine, the prevention effect of 7 d and 15 d is respectively 89.7% and 96.4%, and the prevention effect of 20 d is
83.2%.The same method of 20% Tolfenpyrad suspending agent 800 times use uses, after medicine the preventive effect of 7 d and 15 d be respectively 76.9%,
79.7%, the prevention effect of 20 d is 63.4%；Tolfenpyrad and the compounding rear potentiation of pyrazoles indanyl Methanamide are obvious, to a red-spotted lizard
The prevention effect of shell worm is better than single dose.
By pyrazoles indanyl Methanamide and Tolfenpyrad suspending agent respectively by 30/1,25/1,20/1,15/1,10/1,5/1,
3/1,1/1,1/3,1/5,1/10,1/15,1/20,1/25,1/30, ratio compounds, respectively with 25% pyrazoles indanyl Methanamide SC
Carrying out coccid toxicity test with 10% Tolfenpyrad SC as comparison, co-toxicity coefficient is 149.8～170.1, wherein 5:1～1:
20 is 153.6～170.1,1:1～1:10 is 152.3～170.1, and synergistic effect is notable.
Embodiment four
50% pyrazoles indanyl Methanamide Tolfenpyrad wettable powder
Raw material consists of the 20% pyrazoles former medicine of indanyl Methanamide, the 30% former medicine of Tolfenpyrad, 5% dodecylbenzene sodium sulfonate, 8%
Sodium lignin sulfonate, 8% Pulvis Talci, 4% white carbon, attapulgite supply 100%.
Manner of formulation: after uniformly being mixed by above-mentioned each material, obtains 50% pyrazoles indanyl first after carrying out comminution by gas stream, pulverizing
Amide Tolfenpyrad wettable powder.
This embodiment is used for preventing and treating pear sucker, by 50% pyrazoles indanyl Methanamide Tolfenpyrad water-dispersible granules 3000
Being watered dilution spraying again, after medicine, the prevention effect of 7 d and 15 d, 20 d is respectively 89.1%, 96.7% and 88.4%.20% azoles worm
The method use that 600 times of use of amide suspending agents are same, after medicine, the preventive effect of 7 d, 15 d and 20 d is respectively 79.1%, 88.9% and
77.5%；Tolfenpyrad and the compounding rear potentiation of pyrazoles indanyl Methanamide are obvious, and the prevention effect of pear sucker is better than list
Agent.
Pyrazoles indanyl Methanamide and Tolfenpyrad water dispersible granules are pressed 30/1,25/1,20/1,15/1,10/1 respectively,
5/1,3/1,1/1,1/3,1/5,1/10,1/15,1/20,1/25,1/30, ratio compounds, respectively with 10% pyrazoles indanyl formyl
Amine WG and 20% Tolfenpyrad WG carry out pear sucker toxicity test as comparison, and co-toxicity coefficient is 136.9～162.4, wherein 5:1
～1:20 is 146.4～162.4,1:1～1:10 is 151.5～162.4, and synergistic effect is notable.
Embodiment five
35% pyrazoles indanyl Methanamide Tolfenpyrad water dispersion granule
Raw material consists of: the 10% pyrazoles former medicine of indanyl Methanamide, the 25% former medicine of Tolfenpyrad, 4% mineral oil, 4% triphenoethyl benzene
Phenol polyethenoxy ether, 5% carboxymethyl starch sodium, 8% sodium lignin sulfonate, 2% sodium lauryl sulphate, 5% ammonium sulfate, wooden carbonic acid
Calcium complements to 100%.
Manner of formulation: by above-mentioned formula dry pulverization process, pelletize, dry, the prepared 25% pyrazoles indanyl Methanamide azoles of screening
Insect amide water dispersion granule.
This embodiment is used for preventing and treating Semen Maydis Prodenia litura, 24% pyrazoles indanyl Methanamide Tolfenpyrad dispersibles oil outstanding
Floating agent 800 is watered dilution spraying again, and after medicine, the prevention effect of 7 d and 15 d, 20 d is respectively 87.2%, 95.3% and 82.4%.
The method use that 20% Tolfenpyrad suspending agent 800 times use is same, after medicine, the preventive effect of 7 days and 15 days is respectively 76.4%, 79.9% and
70.9%；Tolfenpyrad and the compounding rear potentiation of pyrazoles indanyl Methanamide are obvious, good to the prevention effect of Semen Maydis Prodenia litura
In single dose.
By pyrazoles indanyl Methanamide and Tolfenpyrad suspending agent respectively by 30/1,25/1,20/1,15/1,10/1,5/1,
3/1,1/1,1/3,1/5,1/10,1/15,1/20,1/25,1/30, ratio compounds, and hangs with 10% pyrazoles indanyl Methanamide respectively
Floating agent and 20% Tolfenpyrad suspending agent carry out Semen Maydis Prodenia litura toxicity test as comparison, co-toxicity coefficient be 148.7～
169.4, wherein 5:1～1:20 is 153.6～169.4,1:1～1:10 is 157.3～169.4, and synergistic effect is notable.
Embodiment six
70% pyrazoles indanyl Methanamide Tolfenpyrad wettable powder
Raw material consists of the 10% pyrazoles former medicine of indanyl Methanamide, the 60% former medicine of Tolfenpyrad, 10% di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate,
7% polycarboxylate salt dispersant, 2% sodium lauryl sulphate, 5% naphthalenesulfonatedispersant dispersant, remaining is supplied with Kaolin.Routinely may be used
The wet-milling mode of production is prepared.
This embodiment is used for preventing and treating thrips in Oryza sativa L., by 70% pyrazoles indanyl Methanamide Tolfenpyrad wettable powder
2000 times are watered dilution spraying, and after medicine, the prevention effect of 7 d and 15 d, 20 d is respectively 80.8%, 94.6% and 79.8%.20% azoles
The same method of 500 times of use of insect amide suspending agent uses, after medicine the prevention effect of 7 d and 15 d, 20 d be respectively 75.2%,
85.4% and 72.1%；Tolfenpyrad and the compounding rear potentiation of pyrazoles indanyl Methanamide are obvious, good to the prevention effect of thrips
In single dose.
By pyrazoles indanyl Methanamide and Tolfenpyrad can wet-milling respectively by 30/1,25/1,20/1,15/1,10/1,5/1,
3/1,1/1,1/3,1/5,1/10,1/15,1/20,1/25,1/30, ratio compounds, respectively can with 10% pyrazoles indanyl Methanamide
Wet-milling and 20% Tolfenpyrad can wet-milling be that comparison carries out bollworm toxicity test, and co-toxicity coefficient is 139.5～167.7 wherein 5:1
～1:20 is 146.6～167.7,1:1～1:10 is 151.3～167.7, and synergistic effect is notable.
Embodiment seven
54% pyrazoles indanyl carboxamides derivatives Tolfenpyrad wettable powder
Raw material forms: 6% 3-difluoromethyl-N-(7-fluoro-1,1-dimethyl, 3-ethyl base-4-indanyl)-1-ethyl-4-pyrrole
Azoles Methanamide, the 48% former medicine of Tolfenpyrad, 8% di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate, 5% polycarboxylate salt dispersant, 2% dodecyl sulfur
Acid sodium, 10% calcium lignosulfonate, remaining is supplied with Kaolin.3-difluoromethyl-N-(7-fluoro-1,1-dimethyl, 3-ethyl base-
4-indanyl)-1-ethyl-4-pyrazolecarboxamide.Routinely can the preparation of the wet-milling mode of production.
This embodiment is used for preventing and treating Chinese cabbage Pieris rapae, by 54% pyrazoles indanyl carboxamides derivatives Tolfenpyrad wettability
Powder 2000 is watered dilution spraying again, and after medicine, the prevention effect of 7 d and 15 d, 20 d is respectively 88.7%, 96.7% and 85.8%.
20% Tolfenpyrad suspending agent 800 times and 5% pyrazoles indanyl Methanamide aqueous suspension agent 1000 times, use by same method, medicine
The preventive effect of rear 7 d and 15 d, 20 d is respectively 78.3%, 93.7% and 79.1%；Tolfenpyrad and pyrazoles indanyl Methanamide compound
Rear potentiation is obvious, and the prevention effect of Chinese cabbage Pieris rapae is better than single dose, its growing way of Chinese cabbage simultaneously processed by this embodiment
Significantly better than contrast, Chinese cabbage is had obvious growth promoting effect.
Pyrazoles indanyl carboxamides derivatives and Tolfenpyrad can be pressed 30/1,25/1,20/1,15/1,10/ by wet-milling respectively
1,5/1,3/1,1/1,1/3,1/5,1/10,1/15,1/20,1/25,1/30, ratio compounds, respectively with 10% pyrazoles indanyl first
Amide derivatives can wet-milling and 20% Tolfenpyrad can wet-milling be that comparison carries out Pieris rapae toxicity test, co-toxicity coefficient be 146.3～
174.6 wherein 5:1～1:20 be 150.5～174.6,1:1～1:10 is 161.2～174.6, and synergistic effect is notable.
Embodiment eight
82% pyrazoles indanyl Methanamide Tolfenpyrad dry suspending agent
Raw material consists of the 2% pyrazoles former medicine of indanyl Methanamide, the 80% former medicine of Tolfenpyrad, 8% naphthalenesulfonatedispersant dispersant, 5% gathers
Carboxylate dispersants, 2% OPEO, carboxymethyl starch sodium are supplied.Manner of formulation: first add 200 in sand milling still
Gram water, the every material being subsequently adding in above-mentioned formula, carry out sand milling after mixing, grind qualified after be spray-dried, spraying
Dried detection, detects qualified rear subpackage and gets product.
This embodiment is used for preventing and treating cotton worm, is converted again by 80% pyrazoles indanyl Methanamide Tolfenpyrad wettable powder 3000
Water dilution spraying, after medicine, the prevention effect of 7 d and 15 d, 20 d is respectively 88.8%, 95.6% and 85.7%.20% Tolfenpyrad
The method use that 800 times of use of suspending agent are same, after medicine, the preventive effect of 7 d and 15 d, 20 d is respectively 80.2%, 92.6% and 80.1%；
Tolfenpyrad and the compounding rear potentiation of pyrazoles indanyl Methanamide are obvious, and the prevention effect of cotton worm is better than single dose.
Pyrazoles indanyl Methanamide and Tolfenpyrad water dry suspending agent are pressed 30/1,25/1,20/1,15/1,10/1 respectively,
5/1,3/1,1/1,1/3,1/5,1/10,1/15,1/20,1/25,1/30, ratio compounds, respectively with 30% pyrazoles indanyl formyl
Amine dry suspending agent and 50% Tolfenpyrad dry suspending agent carry out cotton worm moth toxicity test as comparison, co-toxicity coefficient be 135.8～
162.1, wherein 5:1～1:20 is 146.1～162.1,1:1～1:10 is 152.2～162.1, and synergistic effect is notable.
Claims (5)
1. a Pesticidal combination Han Tolfenpyrad, it is characterised in that: said composition active component includes pyrazoles indanyl formyl
Amine or derivatives thereof and Tolfenpyrad, described pyrazoles indanyl Methanamide or derivatives thereof is 4 with the mass ratio of Tolfenpyrad:
1～1:40；The mass fraction of active component is 6～82%.
It is the most according to claim 1 containing Tolfenpyrad Pesticidal combination, it is characterised in that: described pyrazoles indanyl formyl
Amine or derivatives thereof is 1:1～1:10 with the mass ratio of Tolfenpyrad.
It is the most according to claim 1 containing Tolfenpyrad Pesticidal combination, it is characterised in that: described pyrazoles indanyl formyl
Amine derivative is 3-dichloromethyl-N-(7-chloro-1,1,3-trimethyl-4-indanyl)-1-methyl-4-pyrazolecarboxamide or 3-bis-
Methyl fluoride-N-(7-fluoro-1,1-dimethyl, 3-ethyl base-4-indanyl)-1-ethyl-4-pyrazolecarboxamide.
It is the most according to claim 1 containing Tolfenpyrad Pesticidal combination, it is characterised in that: the dosage form of said composition is wettable
Property powder, suspending agent, the one that dispersibles in oil-suspending agent, water-dispersible granules and dry suspending agent.
5. to can be used for preventing and treating fruit tree, Cotton Gossypii, Semen Tritici aestivi, vegetable, flowers, rice crop many for the Pesticidal combination described in claim 1
Plant the application of insect.
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| CN102858172A (en) * | 2010-04-28 | 2013-01-02 | 住友化学株式会社 | Plant disease control composition and its use |
| WO2013186325A1 (en) * | 2012-06-15 | 2013-12-19 | Stichting I-F Product Collaboration | Synergistic compositions for the protection of agrarian crops and the use thereof |
| CN104411689A (en) * | 2012-05-09 | 2015-03-11 | 拜尔农作物科学股份公司 | Pyrazole indanyl carboxamides |
| GB2521255A (en) * | 2013-10-22 | 2015-06-17 | Syngenta Participations Ag | Method of combating corynespora |
| CN104768934A (en) * | 2012-05-09 | 2015-07-08 | 拜耳农作物科学股份公司 | Pyrazole indanyl carboxamides |
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- 2016-06-30 CN CN201610498019.2A patent/CN105994292A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102858172A (en) * | 2010-04-28 | 2013-01-02 | 住友化学株式会社 | Plant disease control composition and its use |
| CN104411689A (en) * | 2012-05-09 | 2015-03-11 | 拜尔农作物科学股份公司 | Pyrazole indanyl carboxamides |
| CN104768934A (en) * | 2012-05-09 | 2015-07-08 | 拜耳农作物科学股份公司 | Pyrazole indanyl carboxamides |
| WO2013186325A1 (en) * | 2012-06-15 | 2013-12-19 | Stichting I-F Product Collaboration | Synergistic compositions for the protection of agrarian crops and the use thereof |
| GB2521255A (en) * | 2013-10-22 | 2015-06-17 | Syngenta Participations Ag | Method of combating corynespora |
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