CN105990248A - Semiconductor device and manufacture method thereof - Google Patents

Semiconductor device and manufacture method thereof Download PDF

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Publication number
CN105990248A
CN105990248A CN201510087815.2A CN201510087815A CN105990248A CN 105990248 A CN105990248 A CN 105990248A CN 201510087815 A CN201510087815 A CN 201510087815A CN 105990248 A CN105990248 A CN 105990248A
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CN
China
Prior art keywords
layer
dielectric
semiconductor device
layers
dielectric layer
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CN201510087815.2A
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Chinese (zh)
Inventor
赖二琨
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Macronix International Co Ltd
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Macronix International Co Ltd
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Priority to CN201510087815.2A priority Critical patent/CN105990248A/en
Publication of CN105990248A publication Critical patent/CN105990248A/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/40Electrodes ; Multistep manufacturing processes therefor
    • H01L29/401Multistep manufacturing processes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/40Electrodes ; Multistep manufacturing processes therefor
    • H01L29/41Electrodes ; Multistep manufacturing processes therefor characterised by their shape, relative sizes or dispositions
    • H01L29/423Electrodes ; Multistep manufacturing processes therefor characterised by their shape, relative sizes or dispositions not carrying the current to be rectified, amplified or switched
    • H01L29/42312Gate electrodes for field effect devices
    • H01L29/42316Gate electrodes for field effect devices for field-effect transistors
    • H01L29/4232Gate electrodes for field effect devices for field-effect transistors with insulated gate
    • H01L29/4234Gate electrodes for transistors with charge trapping gate insulator
    • H01L29/42352Gate electrodes for transistors with charge trapping gate insulator with the gate at least partly formed in a trench
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/40Electrodes ; Multistep manufacturing processes therefor
    • H01L29/41Electrodes ; Multistep manufacturing processes therefor characterised by their shape, relative sizes or dispositions
    • H01L29/423Electrodes ; Multistep manufacturing processes therefor characterised by their shape, relative sizes or dispositions not carrying the current to be rectified, amplified or switched
    • H01L29/42312Gate electrodes for field effect devices
    • H01L29/42316Gate electrodes for field effect devices for field-effect transistors
    • H01L29/4232Gate electrodes for field effect devices for field-effect transistors with insulated gate
    • H01L29/42364Gate electrodes for field effect devices for field-effect transistors with insulated gate characterised by the insulating layer, e.g. thickness or uniformity
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10BELECTRONIC MEMORY DEVICES
    • H10B43/00EEPROM devices comprising charge-trapping gate insulators
    • H10B43/30EEPROM devices comprising charge-trapping gate insulators characterised by the memory core region
    • H10B43/35EEPROM devices comprising charge-trapping gate insulators characterised by the memory core region with cell select transistors, e.g. NAND

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  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Ceramic Engineering (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Manufacturing & Machinery (AREA)
  • Non-Volatile Memory (AREA)
  • Semiconductor Memories (AREA)

Abstract

The invention discloses a semiconductor device and a manufacture method thereof. The manufacture method of the semiconductor device comprises the following steps that a bottom insulation layer is formed on a substrate; two lamination structures are formed on the bottom insulation layer; and each lamination structure comprises a grid layers, grid insulation layers, a top insulation layer and a conductive mask layer; each charge capturing structure comprises first dielectric layers and second dielectric layers; part of the first dielectric layers is etched to expose part of the second dielectric layers; part of the second dielectric layers is etched to expose part of channel layers; and a landing pad layer is formed on the conductive mask layer and the first and second conductive layers to connect the conductive mask layers with the channel layers.

Description

Semiconductor device and manufacture method thereof
Technical field
The invention relates to a kind of semiconductor device and manufacture method thereof, and in particular to one Vertical channel semiconductor device and manufacture method thereof.
Background technology
In recent years, the constantly evolution of the structure of semiconductor device, and the storage volume of device increases constantly Add.Storage arrangement is used for storing many electronic products, e.g. MP3 archives, digitized video, Computer documents etc..Along with range of application is constantly increasing, the demand of storage arrangement focuses on corpusculum Amass and Large Copacity.In order to meet its requirement, need the memory device with high component density and small size Put and manufacture method.
Therefore, one can be reached big storage volume, small size and have good performance and stability Vertical channel storage arrangement, it has also become the important directions of research and development.
Summary of the invention
The invention relates to a kind of semiconductor device and manufacture method, its etched portions charge-trapping Structure and form a cushion layer, to form a thick connection pad, firmly connect a bit line.
According to the first aspect of the invention, the manufacture method of a kind of semiconductor device is proposed.Manufacture method Comprise the following steps.Form a bottom insulation layer on a substrate.Form two laminated construction exhausted in bottom In edge layer.Each laminated construction includes multiple grid layer, multiple gate insulator, a top layer And a conductive mask layer.Grid layer and gate insulator are alternately arranged in bottom insulation layer.Top Insulating barrier is arranged on grid layer and gate insulator.Conductive mask layer is arranged in top layer. Form a charge trapping structure and a channel layer in a side surface of each laminated construction and bottom insulation One upper surface of layer.Each charge trapping structure includes multiple first dielectric layer and multiple second dielectric layer. Each first dielectric layer of etched portions, with each second dielectric layer of expose portion.Etched portions Each second dielectric layer, with the channel layer of expose portion.Formed a cushion layer in conductive mask layer, On one dielectric layer and the second dielectric layer, to connect conductive mask layer and channel layer.
According to the second aspect of the invention, it is provided that semiconductor device.Quasiconductor include a substrate, one Bottom insulation layer, two laminated construction, a charge trapping structure and a cushion layer.Bottom insulation layer is arranged On substrate.Laminated construction is arranged in bottom insulation layer.Each laminated construction include multiple grid layer, Multiple gate insulators, a top layer and a conductive mask layer.Grid layer is handed over gate insulator Alternately it is arranged in bottom insulation layer.Top layer is arranged on grid layer and gate insulator.Lead Electricity mask layer is arranged in top layer.Charge trapping structure and channel layer are arranged at each lamination knot On one side surface of structure and a upper surface of bottom insulation layer.Each charge trapping structure includes multiple One dielectric layer and multiple second dielectric layer.The top of channel layer higher than each the first dielectric layer top and The top of each the second dielectric layer.Cushion layer is arranged at conductive mask layer, the first dielectric layer and second and is situated between In electric layer, to connect conductive mask layer and channel layer.
More preferably understand in order to the above-mentioned and other aspect of the present invention is had, preferred embodiment cited below particularly, And coordinate institute's accompanying drawings, it is described in detail below:
Accompanying drawing explanation
Fig. 1 illustrates semiconductor device.
Fig. 2 A~Fig. 2 F illustrates the flow chart of the manufacture method of the semiconductor device of an embodiment.
Fig. 3 A~Fig. 3 F illustrates the flow chart of the manufacture method of the semiconductor device of another embodiment.
[symbol description]
100,200: semiconductor device
110: substrate
120: bottom insulation layer
120a: upper surface
130,230: laminated construction
130a: groove
130b: side surface
131: grid layer
132: gate insulator
133: top layer
134,234: conductive mask layer
135: insulating mask layer
140: charge trapping structure
141: the first dielectric layers
142: the second dielectric layers
150: channel layer
160: cushion layer
170: spacer insulator layer
D: drain electrode
G: grid
T1, T2, T3: thickness
S: source electrode
Detailed description of the invention
The following is the various embodiments of proposition to be described in detail, it utilizes etched portions charge trapping structure (charge trapping structure), and a cushion layer (landing pad layer) is set, to be formed The connection pad (landing pad) of one thickness, is strongly attached to a bit line (bit line).But, real Execute example only in order to illustrate as example, can't the scope to be protected of the limit present invention.Additionally, implement Graphic in example is to omit unnecessary element, to clearly show that the technical characterstic of the present invention.
Refer to Fig. 1, it illustrates the schematic diagram of semiconductor device 100.For example, quasiconductor Device 100 can be a three-dimensional perpendicular passage NAND device (three-dimensional vertical channel NAND device).Semiconductor device 100 includes a substrate (substrate) 110, Bottom insulation layer (bottom insulating layer) 120, at least two layer stacked structure (stacked Structures) 130, one charge trapping structure 140, channel layer (channel layer) 150, Cushion layer 160 and a spacer insulator layer (spaced insulating layer) 170.
Each laminated construction 130 includes multiple grid layer (gate layer) 131, multiple gate insulator Layer (gate insulating layer) 132, one top layer (top insulating layer) 133 and One conductive mask layer (conductive mask layer) 134.Charge trapping devices 140 includes multiple First dielectric layer (first dielectric layer) 141 and multiple second dielectric layer 142 (second dielectric layer).Each grid layer 131 is connected to a grid (gate) G.Cushion layer 160 is even It is connected to a source electrode (source) S or drain electrode (drain) D.
Cushion layer 160 is connected to a bit line.As it is shown in figure 1, due to conductive mask layer 134 and connection pad The thickness T1 of the combination of layer 160 is more than the thickness T2 of channel layer 150, between bit line and cushion layer 160 Between contact resistance just can reduce.Additionally, the Joining Technology carrying out bit line and cushion layer 160 also becomes It is easier to.
Refer to Fig. 2 A~Fig. 2 F, it illustrates the manufacture of the semiconductor device 100 according to an embodiment The flow chart of method.As shown in Figure 2 A, it is provided that substrate 110.Then, as shown in Figure 2 A, formed Bottom insulation layer 120 is on substrate 110.For example, the material of bottom insulation layer 120 is e.g. Silicon oxide (silicon oxide).This manufacture method be self-aligned technique and need not be extra mask journey Sequence.Additionally, the connection of channel layer 150 and cushion layer 160 is in the sidewall of channel layer 150, and It it not the top at channel layer 150.Consequently, it is possible to process window (process window) can be increased And reduce resistance.Furthermore, this structure will not occur corner edge effect (corner edge effect), Its reason is that the first dielectric layer 141 is neither positioned at any corner edge, therefore will not be because of field effect Easily it is programmed or wipes.
Then, as shown in Figure 2 A, grid layer 131 is alternately formed with gate insulator 132 end of in On portion's insulating barrier 120 so that each grid layer 131 can mutually insulated.Each grid layer 131 Material e.g. N+ or P+ DOPOS doped polycrystalline silicon (N+or P+doping polysilicon), preferably P+ DOPOS doped polycrystalline silicon.The material of each gate insulator 132 e.g. silicon oxide.
Then, as shown in Figure 2 A, top layer 133 is formed in grid layer 131 and gate insulator On layer 132.The material of top layer 133 e.g. silicon nitride (silicon nitride).
Then, as shown in Figure 2 A, formed conductive mask layer 134 in top layer 133, with Avoid top layer 133 to be etched, and may be used to connect cushion layer 160 (being illustrated in Fig. 1) and Channel layer 150 (being illustrated in Fig. 1).
Then, as shown in Figure 2 A, insulating mask layer 135 is formed on conductive mask layer 134.Absolutely The material of edge mask layer 135 e.g. silicon nitride.
Then, as shown in Figure 2 B, etching grid layer 131, gate insulator 132, top layer 133, conductive mask layer 134 and insulating mask layer 135, to form at least two laminated construction 130 And the groove 130a between adjacent laminated construction 130.In manufacture process, insulating mask layer 135 Laminated construction 130 can be consolidated, to avoid laminated construction 130 avalanche.
Then, as shown in Figure 2 C, form charge trapping structure 140 and channel layer 150 to fold in each One side surface 130b of a Rotating fields 130 and upper surface 120a of bottom insulation layer 120.Electric charge is caught Catch structure 140 and channel layer 150 for U-shaped.The material of channel layer 150 can be intrinsic or undoped p Channel layer 150.Charge trapping structure 140 can be O1N1O2N2O3N3O4 structure (O1 Close to channel layer 150, O4 is close to laminated construction 130).Four silicon oxide layers (O1, O2, O3, O4) there is different thickness and three silicon nitride layers (N1, N2, N3) have different thickness Degree.Or, charge trapping structure 140 can be that (O1 is close to passage for O1N1O2N2O3 structure Layer 150, O3 is close to laminated construction 130).The silicon oxide layer (O1, O2, O3) of three has not Same thickness, two silicon nitride layers (N1, N2) have different thickness.These different thickness It is to catch (trapping), O3 or O3N3O4 based on O1N1O2 tunnelling (tunneling), N2 The purpose of barrier (blocking) designs.
Then, as shown in Figure 2 C, the spacer insulator layer 170 ditch between laminated construction 130 is filled Groove 130a.The material of spacer insulator layer 170 e.g. silicon oxide.Spacer insulator layer 170 can not be complete Entirely fill up groove 130a so that the air gap is formed in spacer insulator layer 170.Air is also fine Insulator.
Furthermore, as shown in Figure 2 D, each first dielectric layer 141 of etching part, with expose portion Each second dielectric layer 142.In this step, it is to utilize phosphoric acid (H3PO4) carry out etch nitride Silicon.Owing to phosphoric acid has a high selectivity for polysilicon and silicon oxide, conductive mask layer 134, logical Channel layer the 150, second dielectric layer 142 and spacer insulator layer 170 will not be etched in this step.In this In step, insulating mask layer 135 (being illustrated in Fig. 2 C) is also removed so that conductive mask layer 134 Surface be exposed.Owing to each first dielectric layer 141 of part is etched, therefore the second dielectric Two sidewalls of at least the one of layer 142 are partially exposed.
Owing to the thickness of the first dielectric layer 141 is different, the first dielectric layer 141 is at etching effect (etching Loading effect) under can be etched out the different degree of depth.
Then, as shown in Figure 2 E, each second dielectric layer 142 of etched portions, with expose portion Channel layer 150.In this step, it is to utilize dilute hydrofluoric acid solution (DHF) to carry out etching oxidation Silicon.Because dilute hydrofluoric acid solution has high selectivity, conductive mask for polysilicon and silicon nitride Layer 134, channel layer the 150, first dielectric layer 141 will not be etched.
In this step, owing to each second dielectric layer 142 of part is etched, therefore each first Jie Two sidewalls of electric layer 141 are partially exposed out.Furthermore, due to the spacing insulating barrier 170 of part Also it is etched, therefore two sidewalls of channel layer 150 also are partially exposed out so that channel layer 150 Top higher than the top of the first dielectric layer 141 and the top of the second dielectric layer 142.
Owing to the thickness of the second dielectric layer 142 is different, the second dielectric layer 142 can quilt under etching effect Etch the different degree of depth.In this step, conductive mask layer 134 then can avoid top layer 133 are etched.
Then, as shown in Figure 2 F, cushion layer 160 is formed in conductive mask layer the 134, first dielectric layer 141 and second on dielectric layer 142, to connect conductive mask layer 134 and channel layer 150.Cushion layer The material of 160 e.g. n-type doping polysilicon.
In this step, cushion layer 160 and channel layer 150 are more ground so that cushion layer 160, The top of channel layer 150 and spacer insulator layer 170 is all positioned at identical height.Conductive mask layer 134 and The combination of cushion layer 160 can connect bit line as a connection pad.Conductive mask layer 134 and cushion layer The thickness T1 of the combination of 160 is more than the thickness T2 of channel layer 150 so that between bit line and cushion layer Contact resistance between 160 just can reduce.Additionally, the connection of channel layer 150 and cushion layer 160 is position In the sidewall of channel layer 150 rather than at the top of channel layer 150.Consequently, it is possible to can increase Process window (process window) also reduces resistance.Furthermore, carry out bit line and cushion layer 160 Joining Technology also become easier to.Corner edge effect (corner edge will not occur in this structure Effect), its reason is that the first dielectric layer 141 is neither positioned at any corner edge, therefore will not be because of electricity Field effect and be easily programmed or wipe.
In above-mentioned manufacture method, insulating mask layer 135 in order to consolidate laminated construction 130 in process, To avoid laminated construction 130 avalanche in technique.In another embodiment, the manufacture of semiconductor device Method can not use insulating mask layer 135.Refer to Fig. 3 A~Fig. 3 F, it illustrates another and implements The flow chart of the manufacture method of the semiconductor device 200 of example.In this embodiment, conductive mask layer 234 Thickness increase so that conductive mask layer 234 i.e. can be used to firm laminated construction 230.
As illustrated in Figure 3 F, cushion layer 160 and conductive mask layer 234 are in order to connect as a connection pad Connect bit line.The thickness T3 of conductive mask layer 234 and cushion layer 160 is greater than the thickness T2 of channel layer, Contact resistance between bit line and cushion layer 160 just can be reduced.Furthermore, carry out bit line and connect The Joining Technology of bed course 160 also becomes easier to.
In sum, although the present invention is disclosed above with preferred embodiment, and so it is not limited to The present invention.Persond having ordinary knowledge in the technical field of the present invention, in the spirit without departing from the present invention With in scope, when being used for a variety of modifications and variations.Therefore, protection scope of the present invention is when depending on enclosing Being as the criterion of being defined of right.

Claims (10)

1. a manufacture method for semiconductor device, including:
Form a bottom insulation layer on a substrate;
Forming two laminated construction in this bottom insulation layer, respectively this laminated construction includes multiple grid Layer, multiple gate insulator, a top layer and a conductive mask layer, these grid layers and these Gate insulator is alternately arranged in this bottom insulation layer, and this top layer is arranged at these grids On layer and these gate insulators, this conductive mask layer is arranged in this top layer;
Form a charge trapping structure and a channel layer in a side surface of respectively this laminated construction and this end One upper surface of portion's insulating barrier, respectively this charge trapping structure includes multiple first dielectric layer and multiple Second dielectric layer;
Respectively this first dielectric layer of etched portions, with respectively this second dielectric layer of expose portion;
Respectively this second dielectric layer of etched portions, with this channel layer of expose portion;And
Form a cushion layer (1anding pad layer) in this conductive mask layer, these first dielectric layers And on these second dielectric layers, to connect this conductive mask layer and this channel layer.
The manufacture method of semiconductor device the most according to claim 1, respectively this lamination knot Structure further includes an insulating mask layer, and this insulating mask layer is arranged on this conductive mask layer, in etching portion In the step of respectively this first dielectric layer divided, this insulating mask layer is to be removed.
The manufacture method of semiconductor device the most according to claim 1, wherein in etched portions Respectively this first dielectric layer step in, the degree of depth that respectively this first dielectric layer is etched is different.
The manufacture method of semiconductor device the most according to claim 1, wherein in etched portions Respectively this first dielectric layer step in, two sidewalls of at least the one of these the second dielectric layers are by partly Expose.
The manufacture method of semiconductor device the most according to claim 1, wherein in etched portions Respectively this second dielectric layer step in, the degree of depth that respectively this second dielectric layer is etched is different.
The manufacture method of semiconductor device the most according to claim 1, further includes:
Filling a spacer insulator layer in a groove, this groove is formed between these laminated construction;
Wherein in the step of respectively this second dielectric layer of etched portions, this spacer insulator layer of part is also It is etched so that the top of this channel layer is higher than top and these second dielectrics of these the first dielectric layers The top of layer.
7. a semiconductor device, including:
One substrate;
One bottom insulation layer, is arranged on this substrate;
Two laminated construction, are arranged in this bottom insulation layer, and respectively this laminated construction includes:
Multiple grid layers and multiple gate insulator, these grid layers and these gate insulators are handed over Alternately it is arranged in this bottom insulation layer;
One top layer, is arranged on these grid layers and these gate insulators;And
One conductive mask layer, is arranged in this top layer;
One charge trapping structure and a channel layer, be arranged at a side surface and this end of respectively this laminated construction On one upper surface of portion's insulating barrier, respectively this charge trapping structure includes multiple first dielectric layer and many Individual second dielectric layer, the top of this channel layer higher than each this first dielectric layer top and respectively this second is situated between The top of electric layer;And
One cushion layer, is arranged at this conductive mask layer, these first dielectric layers and these the second dielectric layers On, to connect this conductive mask layer and this channel layer.
Semiconductor device the most according to claim 7, wherein this cushion layer and this conduction mask The thickness of the combination of layer is more than the thickness of this channel layer.
Semiconductor device the most according to claim 7, the wherein top of these the first dielectric layers It is positioned at differing heights.
Semiconductor device the most according to claim 7, respectively two sides of this first dielectric layer It is contacted with this cushion layer rim portion.
CN201510087815.2A 2015-02-26 2015-02-26 Semiconductor device and manufacture method thereof Pending CN105990248A (en)

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CN201510087815.2A CN105990248A (en) 2015-02-26 2015-02-26 Semiconductor device and manufacture method thereof

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109801919A (en) * 2017-11-17 2019-05-24 旺宏电子股份有限公司 The manufacturing method of 3-D stacks semiconductor structure and its structure obtained

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US20140035026A1 (en) * 2012-07-31 2014-02-06 Byong-hyun JANG Semiconductor memory devices and methods of fabricating the same
US8803222B2 (en) * 2011-07-07 2014-08-12 Samsung Electronics Co., Ltd. Three-dimensional semiconductor memory devices using direct strapping line connections
US20150008499A1 (en) * 2013-07-08 2015-01-08 Jae-Goo Lee Vertical semiconductor device
CN105914184A (en) * 2015-02-24 2016-08-31 旺宏电子股份有限公司 Semiconductor device and manufacturing method thereof

Patent Citations (4)

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Publication number Priority date Publication date Assignee Title
US8803222B2 (en) * 2011-07-07 2014-08-12 Samsung Electronics Co., Ltd. Three-dimensional semiconductor memory devices using direct strapping line connections
US20140035026A1 (en) * 2012-07-31 2014-02-06 Byong-hyun JANG Semiconductor memory devices and methods of fabricating the same
US20150008499A1 (en) * 2013-07-08 2015-01-08 Jae-Goo Lee Vertical semiconductor device
CN105914184A (en) * 2015-02-24 2016-08-31 旺宏电子股份有限公司 Semiconductor device and manufacturing method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109801919A (en) * 2017-11-17 2019-05-24 旺宏电子股份有限公司 The manufacturing method of 3-D stacks semiconductor structure and its structure obtained
CN109801919B (en) * 2017-11-17 2021-06-04 旺宏电子股份有限公司 Method for fabricating three-dimensional stacked semiconductor structure and structure fabricated thereby

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