CN105986488A - 一种汽车内饰用抗静电仿皮革材料及其制备方法 - Google Patents

一种汽车内饰用抗静电仿皮革材料及其制备方法 Download PDF

Info

Publication number
CN105986488A
CN105986488A CN201610048804.8A CN201610048804A CN105986488A CN 105986488 A CN105986488 A CN 105986488A CN 201610048804 A CN201610048804 A CN 201610048804A CN 105986488 A CN105986488 A CN 105986488A
Authority
CN
China
Prior art keywords
parts
minutes
nano
antistatic
revs
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610048804.8A
Other languages
English (en)
Inventor
陈峻
章云
张娉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
WUHU HUANRUI AUTO INTERIOR DECORATION CO Ltd
Original Assignee
WUHU HUANRUI AUTO INTERIOR DECORATION CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by WUHU HUANRUI AUTO INTERIOR DECORATION CO Ltd filed Critical WUHU HUANRUI AUTO INTERIOR DECORATION CO Ltd
Priority to CN201610048804.8A priority Critical patent/CN105986488A/zh
Publication of CN105986488A publication Critical patent/CN105986488A/zh
Pending legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0011—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using non-woven fabrics
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/68—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof
    • D06M11/70—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof with oxides of phosphorus; with hypophosphorous, phosphorous or phosphoric acids or their salts
    • D06M11/71—Salts of phosphoric acids
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0004—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using ultra-fine two-component fibres, e.g. island/sea, or ultra-fine one component fibres (< 1 denier)
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0059—Organic ingredients with special effects, e.g. oil- or water-repellent, antimicrobial, flame-resistant, magnetic, bactericidal, odour-influencing agents; perfumes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0086—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
    • D06N3/0088—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by directly applying the resin
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32—Polyesters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/34—Polyamides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/30—Flame or heat resistance, fire retardancy properties
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/04—Properties of the materials having electrical or magnetic properties
    • D06N2209/046—Anti-static
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/06—Properties of the materials having thermal properties
    • D06N2209/067—Flame resistant, fire resistant
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/10—Properties of the materials having mechanical properties
    • D06N2209/103—Resistant to mechanical forces, e.g. shock, impact, puncture, flexion, shear, compression, tear
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/16—Properties of the materials having other properties
    • D06N2209/1635—Elasticity
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/16—Properties of the materials having other properties
    • D06N2209/1678—Resistive to light or to UV
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/16—Properties of the materials having other properties
    • D06N2209/1685—Wear resistance
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00—Specially adapted uses
    • D06N2211/12—Decorative or sun protection articles
    • D06N2211/26—Vehicles, transportation
    • D06N2211/263—Cars
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00—Specially adapted uses
    • D06N2211/12—Decorative or sun protection articles
    • D06N2211/28—Artificial leather

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)

Abstract

本发明公开了一种汽车内饰用抗静电仿皮革材料，由下列重量份的原料制成：聚酰胺-675-77、碱溶性聚酯切片25-26、浓度为20%氢氧化钠溶液适量、水性聚氨酯50-53、纳米氢氧化镁5-6、聚磷酸铵3-4、十二烷基苯磺酸钠5-6、金红石钛白色浆3-4、水适量、α-烯基磺酸钠0.6-0.8、聚乙二醇4004-5、纳米ATO粉体4-5、硬脂酸单甘油酯0.8-1、乙二酸2-3、丙二醇***0.8-1、甲基丙烯酸甲酯3-4。本发明添加硬脂酸单甘油酯改性后的纳米ATO粉体，能够解决粉体容易团聚的问题，使得粉体分散均匀，协同聚乙二醇400与乙二酸，进一步增强了产品的抗静电性，同时提高产品的韧性、强度。

Description

一种汽车内饰用抗静电仿皮革材料及其制备方法
技术领域
本发明涉及合成革材料技术领域，尤其涉及一种汽车内饰用抗静电仿皮革材料及其制备方法。
背景技术
随着经济的高速发展，人们的生活水平越来越高，对生活质量的要求也逐渐提高。皮革制品的需求量越来越大，档次也越来越高。我国人口多资源少，真皮来源有限，难以满足人们的需求。如今汽车内饰革已广泛地应用在乘用汽车、运输汽车的内饰件中。随着生活水平的提高，人们对汽车内饰革的质量要求、环保要求、舒适要求也越来越高。汽车内饰用革，最佳选择为真皮，但真皮在其自身生产过程中污染环境严重，重金属含量容易超标，在内饰件加工过程中成材率较低，其造价高昂，难以为中低档乘用车所接受；而且人们对环境保护逐渐重视，在提倡环保节能、可持续发展的今天，人们也开始开发出仿皮面料来取代动物皮革，以避免对野生动物的伤害和对自然环境的破坏。
目前，汽车门板、汽车座椅面料、仪表板、车厢内壁、车顶篷、方向盘把套等部位，主要采用非织造布等与聚氯乙烯、聚氨酯等复合的材料。普通的聚氯乙烯人造皮革存在手感硬、舒适性差、耐老化性能差、气味重、增塑剂易迁移析出等缺陷，所以目前汽车内饰中的普通PVC人造革已逐渐被聚氨酯（PU）合成革所取代。而聚氨酯合成革的生产采用溶剂型的生产***，大量有机溶剂的使用，不仅污染环境，而且也严重地损害了人们的健康。随着环保法规和人们环保意识的加强，水性聚氨酯合成革技术成为该领域的研究热点。
因此，制造一种与真皮具有同样触感，同样舒适，且对环境友好、各项物理性能与真皮相同或超过真的仿皮汽车内饰革成为人造革生产领域的研究开发任务。
发明内容
本发明目的就是为了弥补已有技术的缺陷，提供一种汽车内饰用抗静电仿皮革材料及其制备方法。
本发明是通过以下技术方案实现的：
一种汽车内饰用抗静电仿皮革材料，由下列重量份的原料制成：聚酰胺-675-77、碱溶性聚酯切片25-26、浓度为20%氢氧化钠溶液适量、水性聚氨酯50-53、纳米氢氧化镁5-6、聚磷酸铵3-4、十二烷基苯磺酸钠5-6、金红石钛白色浆3-4、水适量、α-烯基磺酸钠0.6-0.8、聚乙二醇4004-5、纳米ATO粉体4-5、硬脂酸单甘油酯0.8-1、乙二酸2-3、丙二醇***0.8-1、甲基丙烯酸甲酯3-4。
根据权利要求书1所述一种汽车内饰用抗静电仿皮革材料，由下列具体方法制备而成：
（1）将聚酰胺-6切片后与碱溶性聚酯切片分别进行干燥，控制含水量小于1%，分别通过各自的单螺杆纺丝机搅拌熔融进入海岛型喷丝组件进行喷丝，得到的丝束经过牵伸（在温度为75℃下牵伸3.5倍）、上油、卷绕、干燥（55-65℃烘干5-10分钟）、切断（控制纤维长度为50-55mm，纤度为5-7dtex）得到复合超细短纤维；将复合超细短纤维经过开松棉之后采用梳理机梳理成单层纤维网，然后经过交叉铺网机形成复合层纤维网，再在针刺机上穿刺，最后利用切边机裁剪整齐，在120-140℃的条件下进行热收缩定型，得到超细纤维合成革基布；
（2）将十二烷基苯磺酸钠溶于5倍量的水中，加入纳米氢氧化镁、金红石钛白色浆聚磷酸铵以及一半量的水性聚氨酯，加热至50℃，以500转/分的速度搅拌15分钟后，再以1000转/分的速度搅拌10分钟，得到纳米改性材料乳液，将其放入浸渍槽中，然后将上述超细纤维合成革基布浸渍其中，充分浸渍后经轧辊挤压，将基布取出放入烘箱中，在120-130℃的温度下充分干燥，得到阻燃抗晒改性超细纤维合成革基布；
（3）将上述阻燃抗晒改性超细纤维合成革基布浸入浓度为20%氢氧化钠溶液中，加热至60-70℃，浸泡40分钟，抽出碱溶性聚酯进行开纤处理，用水洗净后干燥待用；
（4）将纳米ATO粉体放入研磨机中，加入硬脂酸单甘油酯，加热至70℃，充分研磨2小时后待用；将聚乙二醇400加入待用冷凝回流装置的反应釜中，边搅拌边缓慢加入乙二酸，直至完全加入，加热冷凝回流2小时，自然冷却后取出的混合液；将α-烯基磺酸钠溶于10倍量的水中，继续加入余量的水性聚氨酯、研磨后的纳米ATO粉体、冷凝回流后的混合液以及其余剩余成分，放入搅拌釜中，以300转/分的速度搅拌10分钟后，再以800转/分的速度搅拌5分钟，得到水性改性聚氨酯浆料；
（5）将步骤（3）得到的基布浸渍在上述水性聚氨酯混合浆料中，充分浸渍后经轧辊挤压，将基布取出放入烘箱中，先以80℃的温度干燥5分钟，使其水分在可控条件下挥发，再升温至100℃继续干燥5分钟，最后升温至140℃，使表面其完全交联固化成膜，之后经过磨毛、染色、压花、后整理等工序制成本发明材料。
本发明的优点是：本发明首先添加纳米氢氧化镁、金红石钛白色浆等耐碱成分配合水性聚氨酯对聚酰胺-6、聚酯混合纤维制成的合成革基布进行第一次浸渍改性，使纳米粒子均匀的覆盖在基布的表面以及缝隙中，形成良好的阻燃、防晒效果；之后不再采用甲苯而是利用氢氧化钠对改性后的基布进行开纤，在形成多空经的表面的同时不会在产品中造成有机溶剂残留，对人体以及环境安全友好。本发明两次浸渍液均采用水性聚氨酯，摒弃传统的溶剂型聚氨酯，具有无毒不残留、不燃、不污染环境的优点，而且保留了溶剂型聚氨酯的加工性能好、产品力学强度高、弹性好、耐磨的优良性能。
本发明添加硬脂酸单甘油酯改性后的纳米ATO粉体，能够解决粉体容易团聚的问题，使得粉体分散均匀，协同聚乙二醇400与乙二酸，进一步增强了产品的抗静电性，同时可以提高浸渍后产品的韧性、强度，使得制成的产品具有良好的抗划伤以及耐磨性。
具体实施方式
一种汽车内饰用抗静电仿皮革材料，由下列重量份（公斤）的原料制成：聚酰胺-675、碱溶性聚酯切片25、浓度为20%氢氧化钠溶液适量、水性聚氨酯50、纳米氢氧化镁5、聚磷酸铵3、十二烷基苯磺酸钠5、金红石钛白色浆3、水适量、α烯基磺酸钠0.6、聚乙二醇4004、纳米ATO粉体4、硬脂酸单甘油酯0.8、乙二酸2、丙二醇***0.8、甲基丙烯酸甲酯3。
根据权利要求书1所述一种汽车内饰用抗静电仿皮革材料，由下列具体方法制备而成：
（1）将聚酰胺-6切片后与碱溶性聚酯切片分别进行干燥，控制含水量小于1%，分别通过各自的单螺杆纺丝机搅拌熔融进入海岛型喷丝组件进行喷丝，得到的丝束经过牵伸（在温度为75℃下牵伸3.5倍）、上油、卷绕、干燥（55℃烘干5分钟）、切断（控制纤维长度为50mm，纤度为5dtex）得到复合超细短纤维；将复合超细短纤维经过开松棉之后采用梳理机梳理成单层纤维网，然后经过交叉铺网机形成复合层纤维网，再在针刺机上穿刺，最后利用切边机裁剪整齐，在120℃的条件下进行热收缩定型，得到超细纤维合成革基布；
（2）将十二烷基苯磺酸钠溶于5倍量的水中，加入纳米氢氧化镁、金红石钛白色浆聚磷酸铵以及一半量的水性聚氨酯，加热至50℃，以500转/分的速度搅拌15分钟后，再以1000转/分的速度搅拌10分钟，得到纳米改性材料乳液，将其放入浸渍槽中，然后将上述超细纤维合成革基布浸渍其中，充分浸渍后经轧辊挤压，将基布取出放入烘箱中，在120℃的温度下充分干燥，得到阻燃抗晒改性超细纤维合成革基布；
（3）将上述阻燃抗晒改性超细纤维合成革基布浸入浓度为20%氢氧化钠溶液中，加热至60℃，浸泡40分钟，抽出碱溶性聚酯进行开纤处理，用水洗净后干燥待用；
（4）将纳米ATO粉体放入研磨机中，加入硬脂酸单甘油酯，加热至70℃，充分研磨2小时后待用；将聚乙二醇400加入待用冷凝回流装置的反应釜中，边搅拌边缓慢加入乙二酸，直至完全加入，加热冷凝回流2小时，自然冷却后取出的混合液；将α烯基磺酸钠溶于10倍量的水中，继续加入余量的水性聚氨酯、研磨后的纳米ATO粉体、冷凝回流后的混合液以及其余剩余成分，放入搅拌釜中，以300转/分的速度搅拌10分钟后，再以800转/分的速度搅拌5分钟，得到水性改性聚氨酯浆料；
（5）将步骤（3）得到的基布浸渍在上述水性聚氨酯混合浆料中，充分浸渍后经轧辊挤压，将基布取出放入烘箱中，先以80℃的温度干燥5分钟，使其水分在可控条件下挥发，再升温至100℃继续干燥5分钟，最后升温至140℃，使表面其完全交联固化成膜，之后经过磨毛、染色、压花、后整理等工序制成本发明材料。
本发明制得的仿皮革材料经过一系列的检测，数据如下：撕裂负荷大于80N，剥离负荷大于70（N/20mm），23℃10万次耐折牢度为五级，-10℃4万次耐折牢度为五级，干擦等级五级，湿擦等级四级，耐碱10%的氢氧化钠中浸泡24小时后的剥离强度保持在 80%以上，1000g负重条件下磨 500 次的情况下无破损。

Claims (2)

1.一种汽车内饰用抗静电仿皮革材料，其特征在于，由下列重量份的原料制成：聚酰胺-675-77、碱溶性聚酯切片25-26、浓度为20%氢氧化钠溶液适量、水性聚氨酯50-53、纳米氢氧化镁5-6、聚磷酸铵3-4、十二烷基苯磺酸钠5-6、金红石钛白色浆3-4、水适量、α-烯基磺酸钠0.6-0.8、聚乙二醇4004-5、纳米ATO粉体4-5、硬脂酸单甘油酯0.8-1、乙二酸2-3、丙二醇***0.8-1、甲基丙烯酸甲酯3-4。
2.根据权利要求书1所述一种汽车内饰用抗静电仿皮革材料，其特征在于，由下列具体方法制备而成：
（1）将聚酰胺-6切片后与碱溶性聚酯切片分别进行干燥，控制含水量小于1%，分别通过各自的单螺杆纺丝机搅拌熔融进入海岛型喷丝组件进行喷丝，得到的丝束经过牵伸（在温度为75℃下牵伸3.5倍）、上油、卷绕、干燥（55-65℃烘干5-10分钟）、切断（控制纤维长度为50-55mm，纤度为5-7dtex）得到复合超细短纤维；将复合超细短纤维经过开松棉之后采用梳理机梳理成单层纤维网，然后经过交叉铺网机形成复合层纤维网，再在针刺机上穿刺，最后利用切边机裁剪整齐，在120-140℃的条件下进行热收缩定型，得到超细纤维合成革基布；
（2）将十二烷基苯磺酸钠溶于5倍量的水中，加入纳米氢氧化镁、金红石钛白色浆聚磷酸铵以及一半量的水性聚氨酯，加热至50℃，以500转/分的速度搅拌15分钟后，再以1000转/分的速度搅拌10分钟，得到纳米改性材料乳液，将其放入浸渍槽中，然后将上述超细纤维合成革基布浸渍其中，充分浸渍后经轧辊挤压，将基布取出放入烘箱中，在120-130℃的温度下充分干燥，得到阻燃抗晒改性超细纤维合成革基布；
（3）将上述阻燃抗晒改性超细纤维合成革基布浸入浓度为20%氢氧化钠溶液中，加热至60-70℃，浸泡40分钟，抽出碱溶性聚酯进行开纤处理，用水洗净后干燥待用；
（4）将纳米ATO粉体放入研磨机中，加入硬脂酸单甘油酯，加热至70℃，充分研磨2小时后待用；将聚乙二醇400加入待用冷凝回流装置的反应釜中，边搅拌边缓慢加入乙二酸，直至完全加入，加热冷凝回流2小时，自然冷却后取出的混合液；将α-烯基磺酸钠溶于10倍量的水中，继续加入余量的水性聚氨酯、研磨后的纳米ATO粉体、冷凝回流后的混合液以及其余剩余成分，放入搅拌釜中，以300转/分的速度搅拌10分钟后，再以800转/分的速度搅拌5分钟，得到水性改性聚氨酯浆料；
（5）将步骤（3）得到的基布浸渍在上述水性聚氨酯混合浆料中，充分浸渍后经轧辊挤压，将基布取出放入烘箱中，先以80℃的温度干燥5分钟，使其水分在可控条件下挥发，再升温至100℃继续干燥5分钟，最后升温至140℃，使表面其完全交联固化成膜，之后经过磨毛、染色、压花、后整理等工序制成本发明材料。
CN201610048804.8A 2016-01-26 2016-01-26 一种汽车内饰用抗静电仿皮革材料及其制备方法 Pending CN105986488A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610048804.8A CN105986488A (zh) 2016-01-26 2016-01-26 一种汽车内饰用抗静电仿皮革材料及其制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610048804.8A CN105986488A (zh) 2016-01-26 2016-01-26 一种汽车内饰用抗静电仿皮革材料及其制备方法

Publications (1)

Publication Number Publication Date
CN105986488A true CN105986488A (zh) 2016-10-05

Family

ID=57040010

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610048804.8A Pending CN105986488A (zh) 2016-01-26 2016-01-26 一种汽车内饰用抗静电仿皮革材料及其制备方法

Country Status (1)

Country Link
CN (1) CN105986488A (zh)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102115983A (zh) * 2011-01-26 2011-07-06 烟台华大化学工业有限公司 一种水性聚氨酯超细纤维合成革及其制备方法
CN102304221A (zh) * 2011-08-25 2012-01-04 吴江市北厍盛源纺织品助剂厂 用于制备抗静电聚氨酯的抗静电剂
CN103993482A (zh) * 2014-05-07 2014-08-20 陕西科技大学 一种阻燃型水性聚氨酯超细纤维合成革基布及其制造方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102115983A (zh) * 2011-01-26 2011-07-06 烟台华大化学工业有限公司 一种水性聚氨酯超细纤维合成革及其制备方法
CN102304221A (zh) * 2011-08-25 2012-01-04 吴江市北厍盛源纺织品助剂厂 用于制备抗静电聚氨酯的抗静电剂
CN103993482A (zh) * 2014-05-07 2014-08-20 陕西科技大学 一种阻燃型水性聚氨酯超细纤维合成革基布及其制造方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
李正军 等: "《皮革涂饰剂与整饰技术》", 31 July 2002 *

Similar Documents

Publication Publication Date Title
CN105507015A (zh) 一种碳纳米管增强吸附型环保汽车内饰件用人造革及其制备方法
CN102168384B (zh) 一种能够释放负离子的合成革及其制造方法
CN105507005A (zh) 一种汽车内饰用阻燃耐冲击超细纤维聚氨酯合成革及其制备方法
EP2474663B1 (en) Pilling-resistant artificial leather
CN101787586B (zh) 一种定岛超细纤维、聚氨酯合成革及其基布，及制备方法
CN113302355B (zh) 用作仿制皮革的层状复合材料
CN103410009A (zh) 高透气型超细纤维聚氨酯绒面合成革、制备工艺及其制品
CN107794774B (zh) 一种高耐磨人工皮革及其制备方法
CN105507010A (zh) 一种适合生产汽车座椅面料的耐磨耗超纤聚氨酯人造革及其制备方法
CN101929083A (zh) 一种超细纤维聚氨酯合成革及其基布，及制备方法和应用
CN105002748A (zh) 一种抗皱、无折痕鞋用无纺布聚氨酯合成革及其制备方法
CN105442340A (zh) 高速列车座椅用高阻燃超细纤维合成革及其制备方法
CN105986489A (zh) 一种柔软耐磨的超细纤维聚氨酯仿皮汽车座椅面料及其制备方法
CN109972414A (zh) 一种超轻型仿真皮超细纤维合成革的加工方法
CN105525511A (zh) 一种基于羟基磷灰石强度增强的超纤聚氨酯人造汽车革及其制备方法
US20050202268A1 (en) Three-dimensional shaped bodies having a leather-like surface
CN105507009A (zh) 一种慢回弹抗曲折的超纤聚氨酯汽车内饰革及其制备方法
CN105986485A (zh) 一种添加天然皮革粉的高透湿汽车内饰革及其制备方法
CN105985633A (zh) 一种新型超细纤维聚氨酯汽车内饰用仿皮材料及其制备方法
CN105986487A (zh) 一种耐紫外老化的超细纤维聚氨酯仿真汽车革及其制备方法
CN105525510A (zh) 一种具有吸音降噪功效的汽车内饰件用仿皮材料及其制备方法
CN105887508A (zh) 一种真皮的非织造制造方法
CN106515100A (zh) 汽车内饰、家装内饰不吸异味，负离子超纤材料及制品的制备工艺
CN105507016A (zh) 一种耐候耐老化的汽车内饰用复合聚氨酯人造革及其制备方法
CN105525512A (zh) 一种添加载银磷酸锆的抗菌型仿皮汽车内饰材料及其制备方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20161005