CN105985853A - Polyaniline cutting fluid - Google Patents
Polyaniline cutting fluid Download PDFInfo
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- CN105985853A CN105985853A CN201510089319.0A CN201510089319A CN105985853A CN 105985853 A CN105985853 A CN 105985853A CN 201510089319 A CN201510089319 A CN 201510089319A CN 105985853 A CN105985853 A CN 105985853A
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- polyaniline
- cutting fluid
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- triethanolamine
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Abstract
The invention discloses a polyaniline cutting fluid. The polyaniline cutting fluid is prepared from, by mass, 12-30 parts of water soluble polyaniline, 22-42 parts of polyacrylamide, 5-9 parts of polyether polyol, 18-33 parts of triethanolamine, 11-18 parts of di-n-butyl phosphite, 5-13 parts of sodium molybdate, 17-24 parts of petroleum barium sulfonate, 7-16 parts of boracic acid, 10-25 parts of emulsified silicone oil and 33-48 parts of water. The invention further discloses a preparation method of the polyaniline cutting fluid. The product not only has good anti-corrosion and mildew-preventing properties, also has good lubricity and extreme pressure resistance and meanwhile is safe, environmentally friendly and free of environmental pollution.
Description
Technical field
The invention belongs to chemical technology field, relate to a kind of cutting fluid, specifically a kind of polyaniline cutting fluid.
Background technology
Cutting fluid is that one is used in metal and cuts, cuts, grinds in the course of processing, is used for cooling down and lubricating the industrial type fluid of cutter and workpiece, and cutting fluid is combined compatibility by multiple super strong functional auxiliary agent through science and forms.In prior art, the greasy property of oil base cutting fluid is preferable, and cooling effect is poor.Water-base cutting fluid greasy property compared with oil base cutting fluid is relatively poor, and cooling effect is preferable.
Along with the development of mechanical industry overall technology, faster, cutting load is bigger, and cutting temperature is higher, constantly has new technology to occur adapting to the processing of new material simultaneously, and this is required for novel high-performance cutting fluid and meets processing request for machine cut speed；Simultaneously according to work hygiene and the requirement of environmental conservation, cutting fluid should not contain as far as possible and be detrimental to health and the material of ecological environment.Carry out the sophisticated equipments such as the Digit Control Machine Tool of China's import, machining center to get more and more, if its cutting fluid used is from external import, transport inconvenience, cost is the highest, therefore, develop the task of top priority with import substitutes Yi Shi China of the high-performance cutting fluid, develop high-performance, environment-friendly degradable, long-life cutting fluid；Research extends the method in cutting fluid service life, thus reduces the discharging of waste liquid amount of cutting fluid, is an important content of domestic and international cutting fluid research.
Summary of the invention
The technical problem to be solved is, the shortcoming overcoming prior art, it is provided that a kind of polyaniline cutting fluid, product of the present invention not only has good anti-corrosion and anti-mildew performance, and there is good lubricity and resistance to extreme pressure, simultaneously safety and environmental protection, environmentally safe.
In order to solve above technical problem, the present invention provides a kind of polyaniline cutting fluid, and its constituent is as follows:
Water-soluble polyaniline 12-30 part
Polyacrylamide 22-42 part
Polyether polyol 5-9 part
Triethanolamine 18-33 part
Di-n-butyl phosphite 11-18 part
Sodium molybdate 5-13 part
Barium mahogany sulfonate 17-24 part
Boric acid 7-16 part
Emulsified silicone oil 10-25 part
Water 33-48 part.
The technical scheme that the present invention limits further is:
The present invention also provides for the preparation method of a kind of polyaniline cutting fluid, comprises the following specific steps that:
Step one: triethanolamine and boric acid are mixed, adds polyacrylamide, 35-45 DEG C of stirring 2-2.5h, is cooled to room temperature, decompression distillation, obtains mixture I；
Step 2: water-soluble polyaniline, polyether polyol, di-n-butyl phosphite, barium mahogany sulfonate are added to the water, 34-38 DEG C of stirring 3-4h, it is cooled to room temperature, obtains mixture II；
Step 3: added to by step one gained mixture I in step 2 gained mixture II, stirs 24-42min, is cooled to room temperature, obtains mixture III after being warming up to 46-52 DEG C；
Step 4: sodium molybdate and emulsified silicone oil are added in step 3 gained mixture III, stirs 2-2.4h, is cooled to room temperature, obtains environment friendly heat resistant cutting fluid after being warming up to 46-48 DEG C.
The invention has the beneficial effects as follows:
Product of the present invention has excellent rustless property, and without harmful composition, to no skin irritation, selected import additive, antibiotic property is extremely strong, has the longest life-span in center system or unit oil groove；Having outstanding anti-foaming property simultaneously, can be used for high-pressure system and require the operating condition of high air release property, soft or hard water is suitable for；Use unique surfactant, emulsifying agent；Greasy property is far above like product, hence it is evident that reduce the cost of charp tool, improves surface processing accuracy, and alternative cutting oil uses, and creates good environment for operator；There is good cooling and cleaning, keep lathe and the cleaning of workpiece, reduce goo residual.
Product of the present invention not only has good anti-corrosion and anti-mildew performance, and has good lubricity and resistance to extreme pressure, simultaneously safety and environmental protection, environmentally safe.
Detailed description of the invention
Embodiment
1
The present embodiment provides a kind of polyaniline cutting fluid, and its constituent is as follows:
Water-soluble polyaniline 12 parts
Polyacrylamide 22 parts
Polyether polyol 5 parts
Triethanolamine 18 parts
Di-n-butyl phosphite 11 parts
Sodium molybdate 5 parts
Barium mahogany sulfonate 17 parts
Boric acid 7 parts
Emulsified silicone oil 10 parts
33 parts of water.
The present embodiment also provides for the preparation method of a kind of polyaniline cutting fluid, comprises the following specific steps that:
Step one: triethanolamine and boric acid are mixed, adds polyacrylamide, 35 DEG C of stirring 2.5h, it is cooled to room temperature, decompression distillation, obtains mixture I；
Step 2: water-soluble polyaniline, polyether polyol, di-n-butyl phosphite, barium mahogany sulfonate are added to the water, 34 DEG C of stirring 4h, it is cooled to room temperature, obtains mixture II；
Step 3: added to by step one gained mixture I in step 2 gained mixture II, stirs 42min, is cooled to room temperature, obtains mixture III after being warming up to 46 DEG C；
Step 4: sodium molybdate and emulsified silicone oil are added in step 3 gained mixture III, stirs 2.4h, is cooled to room temperature, obtains environment friendly heat resistant cutting fluid after being warming up to 46 DEG C.
Embodiment
2
The present embodiment provides a kind of polyaniline cutting fluid, and its constituent is as follows:
Water-soluble polyaniline 30 parts
Polyacrylamide 42 parts
Polyether polyol 9 parts
Triethanolamine 33 parts
Di-n-butyl phosphite 18 parts
Sodium molybdate 13 parts
Barium mahogany sulfonate 24 parts
Boric acid 16 parts
Emulsified silicone oil 25 parts
48 parts of water.
The present embodiment also provides for the preparation method of a kind of polyaniline cutting fluid, comprises the following specific steps that:
Step one: triethanolamine and boric acid are mixed, adds polyacrylamide, 45 DEG C of stirring 2h, it is cooled to room temperature, decompression distillation, obtains mixture I；
Step 2: water-soluble polyaniline, polyether polyol, di-n-butyl phosphite, barium mahogany sulfonate are added to the water, 38 DEG C of stirring 3h, it is cooled to room temperature, obtains mixture II；
Step 3: added to by step one gained mixture I in step 2 gained mixture II, stirs 24min, is cooled to room temperature, obtains mixture III after being warming up to 52 DEG C；
Step 4: sodium molybdate and emulsified silicone oil are added in step 3 gained mixture III, stirs 2h, is cooled to room temperature, obtains environment friendly heat resistant cutting fluid after being warming up to 48 DEG C.
Embodiment
3
The present embodiment provides a kind of polyaniline cutting fluid, and its constituent is as follows:
Water-soluble polyaniline 22 parts
Polyacrylamide 30 parts
Polyether polyol 7 parts
Triethanolamine 25 parts
Di-n-butyl phosphite 15 parts
Sodium molybdate 9 parts
Barium mahogany sulfonate 20 parts
Boric acid 12 parts
Emulsified silicone oil 17 parts
42 parts of water.
The present embodiment also provides for the preparation method of a kind of polyaniline cutting fluid, comprises the following specific steps that:
Step one: triethanolamine and boric acid are mixed, adds polyacrylamide, 40 DEG C of stirring 2.3h, it is cooled to room temperature, decompression distillation, obtains mixture I；
Step 2: water-soluble polyaniline, polyether polyol, di-n-butyl phosphite, barium mahogany sulfonate are added to the water, 36 DEG C of stirring 3.5h, it is cooled to room temperature, obtains mixture II；
Step 3: added to by step one gained mixture I in step 2 gained mixture II, stirs 33min, is cooled to room temperature, obtains mixture III after being warming up to 49 DEG C；
Step 4: sodium molybdate and emulsified silicone oil are added in step 3 gained mixture III, stirs 2.2h, is cooled to room temperature, obtains environment friendly heat resistant cutting fluid after being warming up to 47 DEG C.
Above example is only the technological thought that the present invention is described, it is impossible to limiting protection scope of the present invention with this, every technological thought proposed according to the present invention, any change done on the basis of technical scheme, within each falling within scope.
Claims (5)
1. a polyaniline cutting fluid, it is characterised in that its constituent is as follows:
Water-soluble polyaniline 12-30 part
Polyacrylamide 22-42 part
Polyether polyol 5-9 part
Triethanolamine 18-33 part
Di-n-butyl phosphite 11-18 part
Sodium molybdate 5-13 part
Barium mahogany sulfonate 17-24 part
Boric acid 7-16 part
Emulsified silicone oil 10-25 part
Water 33-48 part.
2. according to the polyaniline cutting fluid described in claim 1, it is characterised in that its constituent is as follows:
Water-soluble polyaniline 12 parts
Polyacrylamide 22 parts
Polyether polyol 5 parts
Triethanolamine 18 parts
Di-n-butyl phosphite 11 parts
Sodium molybdate 5 parts
Barium mahogany sulfonate 17 parts
Boric acid 7 parts
Emulsified silicone oil 10 parts
33 parts of water.
3. according to the polyaniline cutting fluid described in claim 1, it is characterised in that its constituent is as follows:
Water-soluble polyaniline 30 parts
Polyacrylamide 42 parts
Polyether polyol 9 parts
Triethanolamine 33 parts
Di-n-butyl phosphite 18 parts
Sodium molybdate 13 parts
Barium mahogany sulfonate 24 parts
Boric acid 16 parts
Emulsified silicone oil 25 parts
48 parts of water.
4. according to the polyaniline cutting fluid described in claim 1, it is characterised in that its constituent is as follows:
Water-soluble polyaniline 22 parts
Polyacrylamide 30 parts
Polyether polyol 7 parts
Triethanolamine 25 parts
Di-n-butyl phosphite 15 parts
Sodium molybdate 9 parts
Barium mahogany sulfonate 20 parts
Boric acid 12 parts
Emulsified silicone oil 17 parts
42 parts of water.
5. preparation method based on the polyaniline cutting fluid described in claim 1-4 any claim, it is characterised in that comprise the following specific steps that:
Step one: triethanolamine and boric acid are mixed, adds polyacrylamide, 35-45 DEG C of stirring 2-2.5h, is cooled to room temperature, decompression distillation, obtains mixture I；
Step 2: water-soluble polyaniline, polyether polyol, di-n-butyl phosphite, barium mahogany sulfonate are added to the water, 34-38 DEG C of stirring 3-4h, it is cooled to room temperature, obtains mixture II；
Step 3: added to by step one gained mixture I in step 2 gained mixture II, stirs 24-42min, is cooled to room temperature, obtains mixture III after being warming up to 46-52 DEG C；
Step 4: sodium molybdate and emulsified silicone oil are added in step 3 gained mixture III, stirs 2-2.4h, is cooled to room temperature, obtains environment friendly heat resistant cutting fluid after being warming up to 46-48 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510089319.0A CN105985853A (en) | 2015-02-27 | 2015-02-27 | Polyaniline cutting fluid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510089319.0A CN105985853A (en) | 2015-02-27 | 2015-02-27 | Polyaniline cutting fluid |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105985853A true CN105985853A (en) | 2016-10-05 |
Family
ID=57039066
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510089319.0A Pending CN105985853A (en) | 2015-02-27 | 2015-02-27 | Polyaniline cutting fluid |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5693596A (en) * | 1994-10-25 | 1997-12-02 | Shin-Etsu Handotai Co., Ltd. | Cutting fluid, method for production thereof, and method for cutting ingot |
| CN103184094A (en) * | 2011-12-29 | 2013-07-03 | 辽宁奥克化学股份有限公司 | Cooling liquid for diamond wire cutting technology |
| CN103194306A (en) * | 2013-03-29 | 2013-07-10 | 长春工业大学 | Polyaniline cutting fluid |
| CN103351929A (en) * | 2013-06-19 | 2013-10-16 | 天长市润达金属防锈助剂有限公司 | Antirust metal cutting fluid |
-
2015
- 2015-02-27 CN CN201510089319.0A patent/CN105985853A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5693596A (en) * | 1994-10-25 | 1997-12-02 | Shin-Etsu Handotai Co., Ltd. | Cutting fluid, method for production thereof, and method for cutting ingot |
| CN103184094A (en) * | 2011-12-29 | 2013-07-03 | 辽宁奥克化学股份有限公司 | Cooling liquid for diamond wire cutting technology |
| CN103194306A (en) * | 2013-03-29 | 2013-07-10 | 长春工业大学 | Polyaniline cutting fluid |
| CN103351929A (en) * | 2013-06-19 | 2013-10-16 | 天长市润达金属防锈助剂有限公司 | Antirust metal cutting fluid |
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Application publication date: 20161005 |