CN105970732A - Rosin emulsion - Google Patents
Rosin emulsion Download PDFInfo
- Publication number
- CN105970732A CN105970732A CN201610313823.9A CN201610313823A CN105970732A CN 105970732 A CN105970732 A CN 105970732A CN 201610313823 A CN201610313823 A CN 201610313823A CN 105970732 A CN105970732 A CN 105970732A
- Authority
- CN
- China
- Prior art keywords
- parts
- rosin
- cardanol
- ethanol
- colophonium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/16—Sizing or water-repelling agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
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- Paper (AREA)
Abstract
The invention discloses rosin emulsion, belonging to the technical field of rosin deep processing. The rosin emulsion is prepared from the following raw materials in parts by weight: 100 parts of rosin, 15-20 parts of maleic acid, 5-8 parts of cardanol, 1-2 parts of polyethylether-modified trisiloxane, 6-10 parts of ethanol, 0.1-0.2 part of sulfonated lignin, 15-25 parts of lauryl sodium sulfate and 10-15 parts of deionized water with conductivity less than 5mu S/cm. By adding the maleic acid, the cardanol, the polyethylether-modified trisiloxane, the ethanol, the sulfonated lignin, the lauryl sodium sulfate and the deionized water with conductivity less than 5mu S/cm into the rosin, the prepared rosin emulsion has the advantage of being high in stability.
Description
Technical field
The invention belongs to Colophonium deep process technology field, particularly relate to a kind of rosin milk.
Background technology
Colophonium, refers to pine resin as raw material, the non-volatile natural resin obtained by different processing modes, and it is important industrial chemicals, is widely used in the industries such as soap, papermaking, paint, rubber.Additionally, Colophonium can also be made the performance in a certain respect of Colophonium be significantly improved by modified or carry out emulsifying and make emulsion, thus expanded the using value of Colophonium.
Wherein, Colophonium, after Over emulsfication makes emulsion, can be used for paper industry, fills between the fibers, reaches " gluing " or the purpose of " applying glue ", thus increase the water repelling property of paper, prevent ink bleed, improve intensity and smoothness, reduces dilatability.
But, the stability of rosin milk that existing market is sold is poor, still have much room for improvement.
Summary of the invention
The technical problem to be solved is to provide a kind of rosin milk, this rosin milk good stability.
In order to solve above-mentioned technical problem, the technical solution adopted in the present invention is:
It is prepared by the raw material of following weight portion:
Colophonium 100 parts, maleic acid 15 parts～20 parts, Cardanol 5 parts～8 parts, polytrimethylene ether change trisiloxanes 1 part～2 parts, ethanol 6 parts～10 parts, lignosulfonate 0.1 part～0.2 part, sodium lauryl sulphate 15 parts～25 parts and the electrical conductivity deionized water 10 parts～15 parts less than 5 μ S/cm.
In technique scheme, more specifically technical scheme is: Colophonium 100 parts, maleic acid 15 parts, Cardanol 5 parts, polytrimethylene ether change trisiloxanes 2 parts, ethanol 8 parts, lignosulfonate 0.15 part, sodium lauryl sulphate 20 parts and the electrical conductivity deionized water 15 parts less than 5 μ S/cm；
Further, Colophonium 100 parts, maleic acid 17 parts, Cardanol 8 parts, polytrimethylene ether change trisiloxanes 1 part, ethanol 10 parts, lignosulfonate 0.1 part, sodium lauryl sulphate 15 parts and the electrical conductivity deionized water 12 parts less than 5 μ S/cm；
Further, Colophonium 100 parts, maleic acid 20 parts, Cardanol 6 parts, polytrimethylene ether change trisiloxanes 1.5 parts, ethanol 6 parts, lignosulfonate 0.2 part, sodium lauryl sulphate 25 parts and the electrical conductivity deionized water 10 parts less than 5 μ S/cm.
Owing to using technique scheme, there is advantages that
The present invention changes trisiloxanes, ethanol, lignosulfonate, sodium lauryl sulphate and the electrical conductivity deionized water less than 5 μ S/cm by addition maleic acid in Colophonium, Cardanol, polytrimethylene ether, so that the product rosin milk prepared has the advantage that stability is strong.
Detailed description of the invention
Below in conjunction with instantiation, the invention will be further described:
Embodiment 1
The preparation method of this rosin milk is as follows:
Under stirring, first Colophonium 100 kg is added thermal melting, be subsequently adding maleic acid 15 kg, Cardanol 5kg, polytrimethylene ether change trisiloxanes 2kg, ethanol 8kg, lignosulfonate 0.15kg, sodium lauryl sulphate 20kg and the electrical conductivity deionized water 15kg less than 5 μ S/cm, it is then heated to 80 DEG C, isothermal reaction 2 hours.
The rosin milk good stability that the present embodiment prepares, can store 2 years when 40 DEG C.
Embodiment 2
This rosin milk includes following preparation process:
Under stirring, first Colophonium 100 kg is added thermal melting, be subsequently adding maleic acid 17 kg, Cardanol 8kg, polytrimethylene ether change trisiloxanes 1kg, ethanol 10kg, lignosulfonate 0.1kg, sodium lauryl sulphate 15kg and the electrical conductivity deionized water 12kg less than 5 μ S/cm, it is then heated to 65 DEG C, isothermal reaction 2 hours.
The rosin milk good stability that the present embodiment prepares, can store 2 years when 40 DEG C.
Embodiment 3
This rosin milk includes following preparation process:
Under stirring, first Colophonium 100 kg is added thermal melting, be subsequently adding maleic acid 20 kg, Cardanol 6kg, polytrimethylene ether change trisiloxanes 1.5kg, ethanol 6kg, lignosulfonate 0.2kg, sodium lauryl sulphate 25kg and the electrical conductivity deionized water 10kg less than 5 μ S/cm, it is then heated to 60 DEG C, isothermal reaction 1 hour.
The rosin milk good stability that the present embodiment prepares, can store 2 years when 40 DEG C.
Claims (4)
1. a rosin milk, it is characterised in that prepared by the raw material of following weight portion:
Colophonium 100 parts, maleic acid 15 parts～20 parts, Cardanol 5 parts～8 parts, polytrimethylene ether change trisiloxanes 1 part～2 parts, ethanol 6 parts～10 parts, lignosulfonate 0.1 part～0.2 part, sodium lauryl sulphate 15 parts～25 parts and the electrical conductivity deionized water 10 parts～15 parts less than 5 μ S/cm.
Rosin milk the most according to claim 1, it is characterised in that: Colophonium 100 parts, maleic acid 15 parts, Cardanol 5 parts, polytrimethylene ether change trisiloxanes 2 parts, ethanol 8 parts, lignosulfonate 0.15 part, sodium lauryl sulphate 20 parts and the electrical conductivity deionized water 15 parts less than 5 μ S/cm.
Rosin milk the most according to claim 1, it is characterised in that: Colophonium 100 parts, maleic acid 17 parts, Cardanol 8 parts, polytrimethylene ether change trisiloxanes 1 part, ethanol 10 parts, lignosulfonate 0.1 part, sodium lauryl sulphate 15 parts and the electrical conductivity deionized water 12 parts less than 5 μ S/cm.
Rosin milk the most according to claim 1, it is characterised in that: Colophonium 100 parts, maleic acid 20 parts, Cardanol 6 parts, polytrimethylene ether change trisiloxanes 1.5 parts, ethanol 6 parts, lignosulfonate 0.2 part, sodium lauryl sulphate 25 parts and the electrical conductivity deionized water 10 parts less than 5 μ S/cm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610313823.9A CN105970732A (en) | 2016-05-12 | 2016-05-12 | Rosin emulsion |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610313823.9A CN105970732A (en) | 2016-05-12 | 2016-05-12 | Rosin emulsion |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105970732A true CN105970732A (en) | 2016-09-28 |
Family
ID=56992985
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610313823.9A Pending CN105970732A (en) | 2016-05-12 | 2016-05-12 | Rosin emulsion |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105970732A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1215444A (en) * | 1996-02-02 | 1999-04-28 | 赫尔克里士公司 | Emulsifier system for rosin sizing agents |
| CN1281390A (en) * | 1997-10-10 | 2001-01-24 | 联合碳化化学品及塑料技术公司 | Spray application of additive composition to sheet materials |
| CN101880989A (en) * | 2010-06-24 | 2010-11-10 | 杭州杭化播磨造纸化学品有限公司 | Rosin emulsion sizing agent for temperature-resistant paper |
| CN103232605A (en) * | 2013-05-21 | 2013-08-07 | 济南圣泉集团股份有限公司 | Hydrogenated phenolic pyrolysis lignin and preparation method thereof |
| CN105325407A (en) * | 2014-08-11 | 2016-02-17 | 宋淑芹 | Surfactant containing humic acid |
-
2016
- 2016-05-12 CN CN201610313823.9A patent/CN105970732A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1215444A (en) * | 1996-02-02 | 1999-04-28 | 赫尔克里士公司 | Emulsifier system for rosin sizing agents |
| CN1281390A (en) * | 1997-10-10 | 2001-01-24 | 联合碳化化学品及塑料技术公司 | Spray application of additive composition to sheet materials |
| CN101880989A (en) * | 2010-06-24 | 2010-11-10 | 杭州杭化播磨造纸化学品有限公司 | Rosin emulsion sizing agent for temperature-resistant paper |
| CN103232605A (en) * | 2013-05-21 | 2013-08-07 | 济南圣泉集团股份有限公司 | Hydrogenated phenolic pyrolysis lignin and preparation method thereof |
| CN105325407A (en) * | 2014-08-11 | 2016-02-17 | 宋淑芹 | Surfactant containing humic acid |
Non-Patent Citations (2)
| Title |
|---|
| 侯国柱 等: "《分散松香胶原料、技术、应用及发展》", 31 December 1996, 中国化工信息出版部 * |
| 哈成勇 等: "《天然产物化学与应用》", 31 July 2003, 化学工业出版社 * |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160928 |
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| RJ01 | Rejection of invention patent application after publication |