CN105969558A - Kieselguhr powder for removing pesticide residues on fruits and vegetables and preparation method thereof - Google Patents
Kieselguhr powder for removing pesticide residues on fruits and vegetables and preparation method thereof Download PDFInfo
- Publication number
- CN105969558A CN105969558A CN201610399920.4A CN201610399920A CN105969558A CN 105969558 A CN105969558 A CN 105969558A CN 201610399920 A CN201610399920 A CN 201610399920A CN 105969558 A CN105969558 A CN 105969558A
- Authority
- CN
- China
- Prior art keywords
- kieselguhr
- powder
- fruits
- vegetables
- fruit
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims abstract description 39
- 239000000447 pesticide residue Substances 0.000 title claims abstract description 33
- 235000012055 fruits and vegetables Nutrition 0.000 title claims abstract description 30
- 239000000843 powder Substances 0.000 title claims abstract description 27
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 229920002472 Starch Polymers 0.000 claims abstract description 17
- 239000008107 starch Substances 0.000 claims abstract description 17
- 235000019698 starch Nutrition 0.000 claims abstract description 17
- 239000011734 sodium Substances 0.000 claims abstract description 16
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 16
- 235000013527 bean curd Nutrition 0.000 claims abstract description 9
- 229940077388 benzenesulfonate Drugs 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 9
- -1 sodium alkyl benzene Chemical class 0.000 claims abstract description 9
- 235000013343 vitamin Nutrition 0.000 claims abstract description 9
- 239000011782 vitamin Substances 0.000 claims abstract description 9
- 229940088594 vitamin Drugs 0.000 claims abstract description 9
- 229930003231 vitamin Natural products 0.000 claims abstract description 9
- 150000003722 vitamin derivatives Chemical class 0.000 claims abstract description 9
- 238000005406 washing Methods 0.000 claims abstract description 3
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims abstract 2
- 239000001768 carboxy methyl cellulose Substances 0.000 claims abstract 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims abstract 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims abstract 2
- MSLRPWGRFCKNIZ-UHFFFAOYSA-J tetrasodium;hydrogen peroxide;dicarbonate Chemical compound [Na+].[Na+].[Na+].[Na+].OO.OO.OO.[O-]C([O-])=O.[O-]C([O-])=O MSLRPWGRFCKNIZ-UHFFFAOYSA-J 0.000 claims description 10
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 7
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 claims description 7
- 239000006185 dispersion Substances 0.000 claims description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 238000001354 calcination Methods 0.000 claims description 2
- 239000004033 plastic Substances 0.000 claims description 2
- 238000007789 sealing Methods 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 22
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract description 11
- 239000011707 mineral Substances 0.000 abstract description 11
- 239000000126 substance Substances 0.000 abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 8
- 238000001179 sorption measurement Methods 0.000 abstract description 5
- 239000012459 cleaning agent Substances 0.000 abstract description 2
- 102000004169 proteins and genes Human genes 0.000 abstract description 2
- 108090000623 proteins and genes Proteins 0.000 abstract description 2
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 abstract 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 12
- 239000000463 material Substances 0.000 description 11
- 239000000575 pesticide Substances 0.000 description 11
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 9
- 235000010755 mineral Nutrition 0.000 description 9
- 239000001301 oxygen Substances 0.000 description 9
- 229910052760 oxygen Inorganic materials 0.000 description 9
- 239000000047 product Substances 0.000 description 6
- 238000010521 absorption reaction Methods 0.000 description 5
- 150000002500 ions Chemical class 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 230000000274 adsorptive effect Effects 0.000 description 2
- 229930013930 alkaloid Natural products 0.000 description 2
- 150000003797 alkaloid derivatives Chemical class 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 238000005342 ion exchange Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 230000001629 suppression Effects 0.000 description 2
- TUSDEZXZIZRFGC-UHFFFAOYSA-N 1-O-galloyl-3,6-(R)-HHDP-beta-D-glucose Natural products OC1C(O2)COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC1C(O)C2OC(=O)C1=CC(O)=C(O)C(O)=C1 TUSDEZXZIZRFGC-UHFFFAOYSA-N 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 1
- 239000001263 FEMA 3042 Substances 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- LRBQNJMCXXYXIU-PPKXGCFTSA-N Penta-digallate-beta-D-glucose Natural products OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-PPKXGCFTSA-N 0.000 description 1
- 240000003768 Solanum lycopersicum Species 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 244000144987 brood Species 0.000 description 1
- 238000004523 catalytic cracking Methods 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000011365 complex material Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000007857 degradation product Substances 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000002207 metabolite Substances 0.000 description 1
- 239000003863 metallic catalyst Substances 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000004531 microgranule Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- 239000011022 opal Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000001226 reprecipitation Methods 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- LRBQNJMCXXYXIU-NRMVVENXSA-N tannic acid Chemical compound OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-NRMVVENXSA-N 0.000 description 1
- 229940033123 tannic acid Drugs 0.000 description 1
- 235000015523 tannic acid Nutrition 0.000 description 1
- 229920002258 tannic acid Polymers 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/226—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin esterified
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/32—Amides; Substituted amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3932—Inorganic compounds or complexes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Molecular Biology (AREA)
- Emergency Medicine (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to the field of environment-friendly cleaning agent, in particular to kieselguhr powder for removing pesticide residues on fruits and vegetables and a preparation method thereof. The kieselguhr powder is prepared from, by weight, 54-60% of kieselguhr, 19-22% of sodium peroxycarbonate, 15-18% of sodium alkyl benzene sulfonate, 1% of starch, 1% of protein, 1% of vitamin, 2% of carboxymethylcellulose and 1% of fermented bean curd dry powder. Pure natural mineral is adopted as raw material modified kieselguhr, and the green and environment-friendly powder for removing pesticide residues on fruits and vegetables is prepared. Due to the fact that kieselguhr has extremely strong adsorption performance, the product has the effects of being natural, environmentally friendly, gentle to hand, small in using amount, capable of saving water and achieving multi-color mixed washing, and the like, and is widely applied to various kinds of fruits and vegetables. The ore mineral raw materials are adopted, the preparation process is simple, and the product is good in adsorbability, stable in chemical property and capable of stably and enduringly removing pesticide residues on fruits and vegetables.
Description
Technical field
The present invention relates to a kind of environment-friendly cleaning agent field.I.e. a kind of kieselguhr fruit and vegetable pesticide residue goes gumming and preparation method thereof.
Background technology
In the prior art, fruit and vegetable pesticide residues are not decomposed in being Pesticide use later period and the trace pesticide substance, poisonous that residues in fruit and vegetable
The general name of metabolite, degradation product and impurity.Residual pesticide is directly arrived in human body by fruit and vegetable, or is ultimately transferred to people by environment, food chain, and especially organic agricultural chemicals is used in a large number, causes serious Pesticides Residues, becomes health
Serious threat.Removing pesticide residues method and formula is of a great variety, effect is different.
Summary of the invention
The kieselguhr fruit and vegetable pesticide residue that it is an object of the invention to provide a kind of environmental protection, removal effect good for above-mentioned deficiency goes gumming and preparation method thereof.
The technical solution of the present invention is: a kind of kieselguhr fruit and vegetable pesticide residue goes gumming, it is made up of the raw material of following percentage by weight: kieselguhr 60% 54%, sodium carbonate peroxide 19% 22%, sodium alkyl benzene sulfonate 15% 18%, starch 1%, egg albumen powder 1%, vitamin 1%, carboxymethyl starch sodium 2%, fermented bean curd dry powder 1%.
Preparation method: kieselguhr through 600 DEG C calcining and be the sulfuric acid washing of 70% through mass concentration, make powder body, diatomaceous SiO after process2Content more than 96%；The powder body that all proportionings are good is put into the powder tank of dispersion machine, loads in plastic sealing bag after high speed dispersion is uniform.
1, diatomaceous effect and requirement: kieselguhr is a kind of silicastone, diatom remains deposition form, and main mineral constituent is opal.White or light yellow, its stable performance, acidproof, pore volume is big, aperture is big, and specific surface area is big, and adsorptivity is strong, can adsorb and be equal to sole mass 1.5～the liquid of 4 times, and the oil that can adsorb sole mass 1.1～1.5 times divides.Its current potential is negative, and absolute value is big, and absorption positive charge ability is strong.Therefore organophosphor is had fabulous absorption purifying effect.Needing Purification of Diatomite to containing amorphous silica more than 96%, internal structure cleaning does not contains impurity, and has shown fabulous current potential.(1) adsorptivity and adsorptive selectivity: the dispersion force that the electrostatic attraction produced by kieselguhr microstructure and particle surface exist, makes mineral have the strongest adsorption.Inorganic matter and Organic substance can be adsorbed.But it is different to absorption habit and the ability of different material, therefore has again adsorptive selectivity and screening.(2) absorption-exchange rejection: when temperature is of a relatively high, mineral crystal cavity increases the most relatively, the molecule now entered through absorption or exchange or ion, and fall, crystal cavity reduce and are trapped, and be saved with the highest density at temperature.The most in a long time, along with the change of outside climatic condition, more gradually discharged by new absorption-exchange interaction.(3) ion exchangeable: have crystal structure space in mineral, unstable tradable cation (K+, Na+, Ca2+) of space internal adsorption etc. and other materials, to balance the negative charge in crystal.Under certain condition, external cationic or polar molecule with lattice cation generation exchange interaction, and can have sizable exchange capacity.Due to the affinity difference to all kinds of ions, therefore there is again the selectivity of ion exchange.(4) catalytic cracking: mineral itself is a kind of important non-metallic catalyst, also can collectively form " combination catalyst " or the carrier as chemical catalyst with other catalyst, and it has the strongest catalysis activity, cracking performance and multifunctionality.(5) chemical conversion: adsorb the complex material existed with the various states that gather together of exchange, under catalytic action, after chemical reaction and reconfigure, form new material.Useless material can be converted utility, noxious substance becomes innocuous substance.(6) gluing-flocculability: when kieselguhr is crushed to microgranule, ultra micron, has suspensoid, caking property and surface activity in aqueous.The bonding of suspension colloid and flocculate, flocculate precipitates because self tool weight.(7) toxicity is gone in desorption dephosphorization: this kind of performance also has certain selectivity, for fruit and vegetable pesticide residue, has obvious removal effect.
2, sodium carbonate peroxide effect and requirement: sodium carbonate peroxide is the material that sodium carbonate (soda) and hydrogen peroxide (active oxygen) combine formation.Sodium carbonate peroxide or title active oxygen soda, decompose at once after dissolving and generate soda, water and three kinds of compositions of active oxygen in water, and therefore it has been provided simultaneously with the cleaning capacity of soda and active oxygen.
" active oxygen " is a kind of strong oxidizer, has the effect of extensive killing microorganisms, including antibacterial, brood cell, virus, fungus etc..Meanwhile, " active oxygen " is the most water insoluble to those but also can not be had the effect of oxidation Decomposition by the pesticide residues of soda leaching.Pesticide molecule is cut off by the activity of available oxygen atom, becomes little molecule soluble in water, thus reaches to remove the effect of pesticide.Under the dual function of soda and active oxygen, active oxygen soda can be for more pesticide residues, and including containing acid and without acidity pesticide, especially obstinate pesticide residues, cleaning performance is greatly improved compared with common soda.It is faintly acid that the pesticide being applied on vegetable is mostly organic phosphates. the basic ion in alkaline solution and the acid ion generation chemical reaction in residual pesticide, and generate innocuous substance and be diluted in water by diatomite adsorption.Active oxygen soda, it, at the green cleaning product that America and Europe is considered as than sodium bicarbonate and soda higher level, has the effect preferably removing pesticide.
3, sodium alkyl benzene sulfonate (surfactant): there is the performances such as decontamination, moistening, foaming, emulsifying, dispersion.Its biological degradability > 90%.
4, the effect of carboxymethyl starch sodium (CMS) and requirement: because CMS is starch conversion, there is viscosity.The precipitate neutralized can be clung.CMS has the functions such as chelating, ion exchange, polycation flocculation, can be used as the stabilizer in gumming formula, finishing agent and dirt-carrying agent etc..The especially anti-pesticide residue reprecipitation excellent effect to fruit and vegetable.
5, Starch Protein vitamin composition powder: generate alkaloid after fermented, the pesticide residue of centering is removed fabulous effect.
6, fermented bean curd dry powder: the plant sterilization material containing high concentration, tannic acid, plant alkaloid, it is the plant sterilization material of a kind of high concentration.It remains preferable removal effect to biological pesticide.
Kieselguhr fruit and vegetable pesticide residue goes the performance of gumming, is really determined by the performance of various materials.Kieselguhr fruit and vegetable pesticide residue goes why gumming can eliminate fruit and vegetable pesticide residue, is the comprehensive effect of above-mentioned various performance.
The invention have the advantage that employing pure natural mineral are material modification kieselguhr, be configured to environmental protection fruit and vegetable pesticide residue and go gumming.Due to the absorption property that kieselguhr is extremely strong, product have natural environmental-protective, do not hurt hands, consumption is few, water saving, colors the effect such as can shuffle, and is widely used in all kinds of fruit and vegetable.This product uses pure natural raw mineral materials, and preparation technology is simple, product excellent adsorption, stable chemical nature, can remove the pesticide residue on fruit and vegetable stably and lastingly.2, kieselguhr fruit and vegetable pesticide residue goes gumming to be with complex mineral as body material, and diatomaceous earth products has difference substantially with the fruit and vegerable detergent of chemosynthesis.In fruit and vegetable processes, any side effect not occurring, kieselguhr can claim its environment-friendly and green product.It is with the intrinsic various performances of natural minerals, then adds artificial activation, just can effectively remove all kinds of pesticide residues on fruit and vegetable.Heavy metal, Toxic, ammonia nitrogen, radioactivity etc. then be can be rated as and have specially good effect to remove function.
Below in conjunction with embodiment, embodiments of the present invention are described in further detail.
Detailed description of the invention
Embodiment 1
A kind of kieselguhr fruit and vegetable pesticide residue goes gumming, it is characterised in that be made up of the raw material of following percentage by weight: kieselguhr 60%, sodium carbonate peroxide 19%, sodium alkyl benzene sulfonate 15%, starch 1%, egg albumen powder 1%, vitamin 1%, carboxymethyl starch sodium 2%, fermented bean curd dry powder 1%.
Embodiment 2
A kind of kieselguhr fruit and vegetable pesticide residue goes gumming, it is characterised in that be made up of the raw material of following percentage by weight: kieselguhr 58%, sodium carbonate peroxide 20%, sodium alkyl benzene sulfonate 16%, starch 1%, egg albumen powder 1%, vitamin 1%, carboxymethyl starch sodium 2%, fermented bean curd dry powder 1%.
Embodiment 3
A kind of kieselguhr fruit and vegetable pesticide residue goes gumming, it is characterised in that be made up of the raw material of following percentage by weight: kieselguhr 56% 54%, sodium carbonate peroxide 21%, sodium alkyl benzene sulfonate 17%, starch 1%, egg albumen powder 1%, vitamin 1%, carboxymethyl starch sodium 2%, fermented bean curd dry powder 1%.
Embodiment 4
A kind of kieselguhr fruit and vegetable pesticide residue goes gumming, it is characterised in that be made up of the raw material of following percentage by weight: kieselguhr 54%, sodium carbonate peroxide 22%, sodium alkyl benzene sulfonate 18%, starch 1%, egg albumen powder 1%, vitamin 1%, carboxymethyl starch sodium 2%, fermented bean curd dry powder 1%.
Experimental example: buy a kilo of tomato instrument for detecting pesticide residue through in food market and detect, when suppression ratio >=50% on Fructus Lycopersici esculenti surface, represents that in Fructus Lycopersici esculenti, organophosphor or carbamate chemicals for agriculture exceed national standard.The Fructus Lycopersici esculenti that pesticide residue is exceeded standard put into gumming (embodiment 2) 30 grams with in the mixing liquid of 1000 grams of water, invade bubble 20 minutes, detect with instrument for detecting pesticide residue through again after 20 minutes, the suppression ratio on Fructus Lycopersici esculenti surface substantially drops to less than 38%.
Being described above, simply the detailed description of the invention of the present invention, the flesh and blood of the present invention is not construed as limiting by various illustrations.
Claims (3)
1. a kieselguhr fruit and vegetable pesticide residue goes gumming, it is characterised in that be made up of the raw material of following percentage by weight: kieselguhr 54-60%, sodium carbonate peroxide 19% 22%, sodium alkyl benzene sulfonate 15% 18%, starch 1%, egg albumen powder 1%, vitamin 1%, carboxymethyl cellulose 2%, fermented bean curd dry powder 1%.
2. go gumming according to a kind of kieselguhr fruit and vegetable pesticide residue described in claim 1, it is characterized in that being made up of the raw material of following percentage by weight: kieselguhr 58%, sodium carbonate peroxide 20%, sodium alkyl benzene sulfonate 16%, starch 1%, egg albumen powder 1%, vitamin 1%, carboxymethyl starch sodium 2%, fermented bean curd dry powder 1%.
3. a kieselguhr fruit and vegetable pesticide residue as claimed in claim 1 or 2 goes the preparation method of gumming, it is characterised in that kieselguhr through 600 DEG C calcining and be the sulfuric acid washing of 70% through mass concentration, make powder body, diatomaceous SiO after process2Content more than 96%；The powder body that all proportionings are good is put into the powder tank of dispersion machine, loads in plastic sealing bag after high speed dispersion is uniform.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610399920.4A CN105969558B (en) | 2016-06-08 | 2016-06-08 | A kind of diatomite fruit and vegetable pesticide residue goes gumming and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610399920.4A CN105969558B (en) | 2016-06-08 | 2016-06-08 | A kind of diatomite fruit and vegetable pesticide residue goes gumming and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105969558A true CN105969558A (en) | 2016-09-28 |
| CN105969558B CN105969558B (en) | 2019-01-04 |
Family
ID=57010199
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610399920.4A Active CN105969558B (en) | 2016-06-08 | 2016-06-08 | A kind of diatomite fruit and vegetable pesticide residue goes gumming and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105969558B (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107439734A (en) * | 2017-08-17 | 2017-12-08 | 广西贵港市覃塘富伟茶业有限公司 | A kind of health-care black tea and preparation method thereof |
| CN108130230A (en) * | 2018-01-16 | 2018-06-08 | 白山市和硅藻科技有限公司 | A kind of fruit vegetable cleaning agent containing loaded modified diatom soil |
| CN109965189A (en) * | 2019-04-23 | 2019-07-05 | 深圳前海千水生物科技有限公司 | A kind of plant complex enzyme pesticide scavenger |
| CN110041125A (en) * | 2019-04-26 | 2019-07-23 | 北京日宏科技有限公司 | A kind of compound fertilizer and its preparation method and application with absorption heavy metal effect |
| CN111304010A (en) * | 2020-04-01 | 2020-06-19 | 孙健勃 | Novel food-grade fruit and vegetable comprehensive cleaning combined particle and preparation method thereof |
| CN111592939A (en) * | 2020-04-02 | 2020-08-28 | 自然资源部天津海水淡化与综合利用研究所 | Fruit and vegetable cleaning agent |
| CN114621822A (en) * | 2020-12-12 | 2022-06-14 | 石家庄天旭环保科技有限公司 | Diatom ooze hand washing powder |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000051433A1 (en) * | 1999-03-03 | 2000-09-08 | Hedley Technologies Inc. | Low toxicity insecticides |
| CN104388208A (en) * | 2014-11-07 | 2015-03-04 | 舟山赛莱特海洋科技有限公司 | Method for preparing pesticide-removing fruit and vegetable cleaning agent based on shell powder |
| CN105036881A (en) * | 2015-06-18 | 2015-11-11 | 安徽徽普生物科技有限责任公司 | Tealeaf residue containing peanut fertilizer additive capable of improving soil environment |
-
2016
- 2016-06-08 CN CN201610399920.4A patent/CN105969558B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000051433A1 (en) * | 1999-03-03 | 2000-09-08 | Hedley Technologies Inc. | Low toxicity insecticides |
| CN104388208A (en) * | 2014-11-07 | 2015-03-04 | 舟山赛莱特海洋科技有限公司 | Method for preparing pesticide-removing fruit and vegetable cleaning agent based on shell powder |
| CN105036881A (en) * | 2015-06-18 | 2015-11-11 | 安徽徽普生物科技有限责任公司 | Tealeaf residue containing peanut fertilizer additive capable of improving soil environment |
Non-Patent Citations (2)
| Title |
|---|
| 孙秀兰: "《食品安全与化学品污染防治》", 28 February 2009, 化学工业出版社 * |
| 迟玉森: "《养生之王：大豆营养全书》", 31 July 2014, 中国医药科技出版社 * |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107439734A (en) * | 2017-08-17 | 2017-12-08 | 广西贵港市覃塘富伟茶业有限公司 | A kind of health-care black tea and preparation method thereof |
| CN108130230A (en) * | 2018-01-16 | 2018-06-08 | 白山市和硅藻科技有限公司 | A kind of fruit vegetable cleaning agent containing loaded modified diatom soil |
| CN109965189A (en) * | 2019-04-23 | 2019-07-05 | 深圳前海千水生物科技有限公司 | A kind of plant complex enzyme pesticide scavenger |
| CN110041125A (en) * | 2019-04-26 | 2019-07-23 | 北京日宏科技有限公司 | A kind of compound fertilizer and its preparation method and application with absorption heavy metal effect |
| CN111304010A (en) * | 2020-04-01 | 2020-06-19 | 孙健勃 | Novel food-grade fruit and vegetable comprehensive cleaning combined particle and preparation method thereof |
| CN111592939A (en) * | 2020-04-02 | 2020-08-28 | 自然资源部天津海水淡化与综合利用研究所 | Fruit and vegetable cleaning agent |
| CN114621822A (en) * | 2020-12-12 | 2022-06-14 | 石家庄天旭环保科技有限公司 | Diatom ooze hand washing powder |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105969558B (en) | 2019-01-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105969558A (en) | Kieselguhr powder for removing pesticide residues on fruits and vegetables and preparation method thereof | |
| Lairini et al. | The adsorption of Crystal violet from aqueous solution by using potato peels (Solanum tuberosum): equilibrium and kinetic studies | |
| CN103436391B (en) | A kind of washing salt being exclusively used in melon and fruit, vegetable residual pesticide | |
| CN102499259B (en) | Clothing degerming liquid and preparation method thereof | |
| CN108464302A (en) | A kind of slow-release chlorine dioxide of solid carrier Zeolite support and preparation method thereof | |
| Abbas et al. | Iraqi Rice Husk potency to eliminate toxic metals from aqueous solutions and utilization from process residues | |
| CN108970397A (en) | A kind of air purifying composition, preparation and preparation method thereof | |
| Nsaifabbas et al. | Application of rice husk to remove humic acid from aqueous solutions and profiting from waste leftover | |
| CN106753902A (en) | A kind of agricultural product cleaning agent and preparation method thereof | |
| Diez et al. | Influence of novel lignocellulosic residues in a biobed biopurification system on the degradation of pesticides applied in repeatedly high doses | |
| UA99304C2 (en) | Powder preparation, a method for producing thereof, a liquid composition for the treatment of farm plants and a method for the preparation thereof | |
| CN107902736A (en) | The preparation method and composite flocculation algae-inhibiting agent of composite flocculation algae-inhibiting agent | |
| CN101070513A (en) | Farm-chemical biological decomposing composition and preparing method | |
| Exley et al. | Silicon, aluminium and the biological availability of phosphorus in algae | |
| CN110747071A (en) | Fruit and vegetable pesticide residue cleaning agent and preparation method thereof | |
| CN104225656A (en) | Indoor air purifying agent | |
| CN1830259A (en) | Chlorine dioxide disinfectant and preparation method thereof | |
| Sarfraz et al. | Removal of hexavalent chromium ions using micellar modified adsorbent: isothermal and kinetic investigations | |
| EP3098203B1 (en) | Process for ammonia removal from wastewater | |
| CN103386296A (en) | Medical stone as well as improvement method and application thereof | |
| CN101082014B (en) | Plant extractive for removing organophosphorus pesticide | |
| KR101119741B1 (en) | Ecological detergent and method for preparing the same | |
| Liang et al. | Pesticides and herbicides | |
| CN102318644A (en) | Method for preparing material slowly releasing chlorine dioxide and application thereof | |
| CN1312264C (en) | Fruit and vegetable pesticide residue cleaning agent |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20181204 Address after: 134303 Jinying Village, Banshi Street, Hunjiang District, Baishan City, Jilin Province (Jiangbei Development Zone) Applicant after: Jilin Fadelong diatomite new Mstar Technology Ltd Address before: 134300 No. 4, No. 4, No. 602, Guotai District, Baishan City, Jilin Province Applicant before: Diao Guangxiang |
|
| TA01 | Transfer of patent application right | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20210611 Address after: Group 6, Hongqi Street, Badaojiang District, Baishan City, Jilin Province Patentee after: Diao Guangxiang Address before: 134303 Jinying Village, Banshi Street, Hunjiang District, Baishan City, Jilin Province (Jiangbei Development Zone) Patentee before: JILIN FA DE LONG DIATOMITE NEW MATERIAL TECHNOLOGY Co.,Ltd. |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20210930 Address after: 134300 group 4, Jinying village, Banshi street, Hunjiang District, Baishan City, Jilin Province (500m south of Xingtai mixing plant) (Jiangbei Development Zone) Patentee after: Jilin Jingyu Changbaishan daily chemical plant Baishan branch Address before: Group 6, Hongqi Street, Badaojiang District, Baishan City, Jilin Province Patentee before: Diao Guangxiang |
|
| TR01 | Transfer of patent right |