CN105969255A - Adhesive for bamboo-woven artware and preparation method of adhesive - Google Patents

Abstract

The invention relates to an adhesive for bamboo-woven artware and a preparation method of the adhesive. A stirring tank and two reactors work separately so as to prepare base materials, and the base materials are mixed so as to prepare the adhesive. The adhesive prepared by the method is semi-viscous, so that construction can be facilitated; meanwhile, the adhesive is dropped, is high in adhesive power and high in setting speed and is free of flowing and off odors, and the adhesive effect time is longer; the adhesive is integrally free of corrosion, so that the condition that bamboo-woven interface points are broken due to long-time attachment of a bamboo-woven adhesive is effectively avoided, and popularization and use are facilitated.

Description

Bamboo handicraft product adhesive and preparation method thereof

Technical field:

The present invention relates to relate to a kind of adhesive, be specifically related to bamboo handicraft product adhesive and preparation method thereof.

Background technology:

Chemical industry is to develop the most rapid mainstay of the national economy industry modern times, and fine chemistry industry tail Gas important component part, has obtained the development advanced by leaps and bounds, the clothing, food, lodging and transportion--basic necessities of life of the unresolved mankind in 20th century And the energy, resource and environment problem make significant contribution.

Adhesive is development of modern industry and human living standard improves requisite important materials, gluing Agent and bonding technology with the incomparable special warfare of other connected modes, modern economy, modern national defense, Modern science and technology plays great effect.

Summary of the invention:

The technical problem to be solved is to overcome the defect of prior art, it is provided that a kind of bamboo weaving work Skill product adhesive and preparation method thereof.

The technical problem to be solved realizes by the following technical solutions.

Bamboo handicraft product adhesive, it is characterised in that: mainly include that following mass parts component is prepared from:

1) chlorosulfonated polyethylene 100-110 part, 30-40 part ethyl acetate, 20-25 part n-octyl alcohol, 25-30 Part isoamyl alcohol, 20-25 part isobutanol, 8-10 part castor oil polyoxyethylene ether, 6-8 part detergent alkylate sulphur Acid sodium, Herba Moslae 0.5-1 part, Flos Lonicerae 0.5-1 part, Fructus Forsythiae 0.5-1 part, Herba Artemisiae Annuae 0.2-0.5 part, Radix Isatidis 1-2 part and Folium Isatidis 1-2 part；

Take Herba Moslae 0.5-1 part, Flos Lonicerae 0.5-1 part, Fructus Forsythiae 0.5-1 part, Herba Artemisiae Annuae 0.2-0.5 part, Radix Isatidis 1-2 part and Folium Isatidis 1-2 part, grind to form powdery, adds in the water of 10 parts, and steaming and decocting treats that raw material is the most molten In Xie Shui, entirety is in the pasty state；

By chloromethyloxirane, ethyl acetate, n-octyl alcohol, isoamyl alcohol, isobutanol, Oleum Ricini polyoxy Vinyl Ether, dodecylbenzene sodium sulfonate, being placed in agitator tank, mixing speed is 2500r/mim, stirring temperature Degree is 80-90 DEG C, 5 minutes time；

Pasty mixture is filtered, adds and agitator tank continues stirring；

2) PVA:50-60 part, starch: 12-15 part, AA, AAm mixture: 0.3-0.4 part, over cure Acid ammonium: 0.2-0.3 part, ammonium bisulfite: 0.2-0.3 part, preservative: 0.1-0.2 part, water: 40-50 Part, Herba Ephedrae 10-15 part, Semen Armeniacae Amarum 10-15 part, Ramulus Cinnamomi 7-12 part, Radix Glycyrrhizae Preparata 5-10 part；

Take after Herba Ephedrae 10-15 part, Semen Armeniacae Amarum 10-15 part, Ramulus Cinnamomi 7-12 part and Radix Glycyrrhizae Preparata 5-10 part pulverizes Joining in the water of 50% and soak, soaking temperature is 40 DEG C, soaks and is often 30 parts, takes out liquid；

PVA and 70% liquid mixing are added in reactor, within 4 hours, make PVA be completely dissolved with 90 DEG C of stirrings, It is cooled to 75 DEG C, by Ammonium persulfate., ammonium bisulfite and 10% liquid mixing, drips AA, AAm mixture With Ammonium persulfate., ammonium bisulfite and water mixed solution, within about 1-2 hour, drip off, insulation reaction 1 hour, It is subsequently adding starch, continues heated and stirred 1 hour, add preservative stirring, drop to less than 50 DEG C to temperature；

3) chlorosulfonated polyethylene 100-110 part, gas-phase silica 2-3 part, titanium dioxide 3-5 part, disproportionation pine Fragrant 5-10 part, TOTD2-3 part, ethylene thiourea 2-3 part, epoxy resin 15-20 part, four sulfuration tetramethyl Flos Cymbidii Ensifolii Nurse 2-5 part, Oryza glutinosa 10-70 part, purple rice 10-70 part, fructus zizaniae caduciflorae 10-70 part, SEMEN COICIS 5-10 part, Semen arachidis hypogaeae 5-10 Part, kidney bean 1-5 part, Bulbus Lilii 5-10 part, Semen Phaseoli 1-5 part, Semen phaseoli radiati 1-5 part, water 80-90 part；

Raw material is preheated, loads in tank, select chlorosulfonated polyethylene, gas-phase silica, titanium dioxide, Add reactor, be simultaneously introduced fructus zizaniae caduciflorae, SEMEN COICIS, Semen arachidis hypogaeae water grinds, add 50% water mixing, make Mixture one,

Select disproportionated rosin, TOTD, epoxy resin, four sulfuration tetramethyl thiuram, ethylene thioureas, add simultaneously Enter Oryza glutinosa, purple rice, kidney bean, Bulbus Lilii, Semen Phaseoli, Semen phaseoli radiati mixing, add 50% water mixing, make mixture Two, take 50% mixture one and the mixture two of 85%, add in reactor and heat, heating-up temperature 160 DEG C, 1 hour time, it is cooled to 100 DEG C, 1 hour time, then it is down to 50 DEG C, and impurity screening, obtain hot glue；

4) take 50% mixture one and add step 1) agitator tank in, add 20% hot glue；Take 15 mixed Compound two adds step 2) in reactor in, add the hot glue of 30%, then both mixed, obtain half Finished product adhesive；Take the hot glue of 50%, distillation, take distilled water, add in semi-finished product adhesive, become Product.

The present invention has the beneficial effects that: the adhesive prepared by this law, and adhesive is half thick, can Convenient construction, instills adhesive simultaneously, and adhesive adhesive force is strong, without flowing, free from extraneous odour, also fast rapid hardening Gu, the gluing effect time is longer, overall corrosion-free, is prevented effectively from bamboo weaving viscose and adheres to over a long time and cause bamboo Rupturing in volume junction, it is simple to promotes and use.

Detailed description of the invention:

For the technological means making the present invention realize, creation characteristic, reach purpose and effect and be readily apparent from Solve, below in conjunction with specific embodiment, the present invention is expanded on further.

Embodiment 1: bamboo handicraft product adhesive, mainly includes that following mass parts component is prepared from:

1) 100 parts, 30 parts ethyl acetate of chlorosulfonated polyethylene, 20 parts of n-octyl alcohols, 25 parts of isoamyl alcohol, 20 Part isobutanol, 8 parts of castor oil polyoxyethylene ethers, 6 parts of dodecylbenzene sodium sulfonate, Herba Moslae 0.5 part, Flos Lonicerae 0.5 part, Fructus Forsythiae 0.5 part, Herba Artemisiae Annuae 0.2 part, Radix Isatidis 1 part and Folium Isatidis 1 part；

Take Herba Moslae 0.5 part, Flos Lonicerae 0.5 part, Fructus Forsythiae 0.5 part, Herba Artemisiae Annuae 0.2 part, Radix Isatidis 1 part and Folium Isatidis 1 part, grind to form powdery, add in the water of 10 parts, steaming and decocting, treat that raw material is dissolved completely in water, overall in Pasty state；

By chloromethyloxirane, ethyl acetate, n-octyl alcohol, isoamyl alcohol, isobutanol, Oleum Ricini polyoxy Vinyl Ether, dodecylbenzene sodium sulfonate, being placed in agitator tank, mixing speed is 2500r/mim, stirring temperature Degree is 80-90 DEG C, 5 minutes time；

Pasty mixture is filtered, adds and agitator tank continues stirring；

2) PVA:50 part, starch: 12 parts, AA, AAm mixture: 0.3 part, Ammonium persulfate.: 0.2 part, Ammonium bisulfite: 0.2 part, preservative: 0.1 part, water: 40 parts, 10 parts of Herba Ephedrae, 10 parts of Semen Armeniacae Amarum, osmanthus Branch 7 parts, Radix Glycyrrhizae Preparata 5 parts；

Take the water joining 50% after 10 parts of Herba Ephedrae, 10 parts of Semen Armeniacae Amarum, Ramulus Cinnamomi 7 parts and Radix Glycyrrhizae Preparata 5 parts are pulverized Middle immersion, soaking temperature is 40 DEG C, soaks and is often 30 parts, takes out liquid；

PVA and 70% liquid mixing are added in reactor, within 4 hours, make PVA be completely dissolved with 90 DEG C of stirrings, It is cooled to 75 DEG C, by Ammonium persulfate., ammonium bisulfite and 10% liquid mixing, drips AA, AAm mixture With Ammonium persulfate., ammonium bisulfite and water mixed solution, within about 1-2 hour, drip off, insulation reaction 1 hour, It is subsequently adding starch, continues heated and stirred 1 hour, add preservative stirring, drop to less than 50 DEG C to temperature；

3) chlorosulfonated polyethylene 100 parts, gas-phase silica 2 parts, titanium dioxide 3 parts, disproportionated rosin 5 parts, TOTD2 part, ethylene thiourea 2 parts, epoxy resin 15 parts, four sulfuration tetramethyl thiurams 2 parts, 10 parts of Oryza glutinosa, Purple rice 10 parts, fructus zizaniae caduciflorae 10 parts, SEMEN COICIS 5 parts, Semen arachidis hypogaeae 5 parts, kidney bean 1 part, Bulbus Lilii 5 parts, 1 part of Semen Phaseoli, 1 part of Semen phaseoli radiati, 80 parts of water；

Raw material is preheated, loads in tank, select chlorosulfonated polyethylene, gas-phase silica, titanium dioxide, Add reactor, be simultaneously introduced fructus zizaniae caduciflorae, SEMEN COICIS, Semen arachidis hypogaeae water grinds, add 50% water mixing, make Mixture one,

Select disproportionated rosin, TOTD, epoxy resin, four sulfuration tetramethyl thiuram, ethylene thioureas, add simultaneously Enter Oryza glutinosa, purple rice, kidney bean, Bulbus Lilii, Semen Phaseoli, Semen phaseoli radiati mixing, add 50% water mixing, make mixture Two, take 50% mixture one and the mixture two of 85%, add in reactor and heat, heating-up temperature 160 DEG C, 1 hour time, it is cooled to 100 DEG C, 1 hour time, then it is down to 50 DEG C, and impurity screening, obtain hot glue；

4) take 50% mixture one and add step 1) agitator tank in, add 20% hot glue；Take 15 mixed Compound two adds step 2) in reactor in, add the hot glue of 30%, then both mixed, obtain half Finished product adhesive；Take the hot glue of 50%, distillation, take distilled water, add in semi-finished product adhesive, become Product.

Embodiment 2: bamboo handicraft product adhesive, mainly includes that following mass parts component is prepared from:

1) 110 parts, 40 parts ethyl acetate of chlorosulfonated polyethylene, 25 parts of n-octyl alcohols, 30 parts of isoamyl alcohol, 25 Part isobutanol, 10 parts of castor oil polyoxyethylene ethers, 8 parts of dodecylbenzene sodium sulfonate, Herba Moslae 1 part, Flos Lonicerae 1 Part, Fructus Forsythiae 1 part, Herba Artemisiae Annuae 0.5 part, Radix Isatidis 2 parts and Folium Isatidis 2 parts；

Take Herba Moslae 1 part, Flos Lonicerae 1 part, Fructus Forsythiae 1 part, Herba Artemisiae Annuae 0.5 part, Radix Isatidis 2 parts and Folium Isatidis 2 parts, Grind to form powdery, add in the water of 10 parts, steaming and decocting, treat that raw material is dissolved completely in water, entirety is in the pasty state；

By chloromethyloxirane, ethyl acetate, n-octyl alcohol, isoamyl alcohol, isobutanol, Oleum Ricini polyoxy Vinyl Ether, dodecylbenzene sodium sulfonate, being placed in agitator tank, mixing speed is 2500r/mim, stirring temperature Degree is 80-90 DEG C, 5 minutes time；

Pasty mixture is filtered, adds and agitator tank continues stirring；

2) PVA:60 part, starch: 15 parts, AA, AAm mixture: 0.4 part, Ammonium persulfate.: 0.3 part, Ammonium bisulfite: 0.3 part, preservative: 0.2 part, water: 50 parts, 15 parts of Herba Ephedrae, 15 parts of Semen Armeniacae Amarum, osmanthus Branch 12 parts, Radix Glycyrrhizae Preparata 10 parts；

Take after 15 parts of Herba Ephedrae, 15 parts of Semen Armeniacae Amarum, Ramulus Cinnamomi 12 parts and Radix Glycyrrhizae Preparata 10 parts are pulverized and join 50% Soaking in water, soaking temperature is 40 DEG C, soaks and is often 30 parts, takes out liquid；

PVA and 70% liquid mixing are added in reactor, within 4 hours, make PVA be completely dissolved with 90 DEG C of stirrings, It is cooled to 75 DEG C, by Ammonium persulfate., ammonium bisulfite and 10% liquid mixing, drips AA, AAm mixture With Ammonium persulfate., ammonium bisulfite and water mixed solution, within about 1-2 hour, drip off, insulation reaction 1 hour, It is subsequently adding starch, continues heated and stirred 1 hour, add preservative stirring, drop to less than 50 DEG C to temperature；

3) chlorosulfonated polyethylene 110 parts, gas-phase silica 3 parts, titanium dioxide 5 parts, disproportionated rosin 10 parts, TOTD3 part, ethylene thiourea 3 parts, epoxy resin 20 parts, four sulfuration tetramethyl thiurams 5 parts, 70 parts of Oryza glutinosa, Purple rice 70 parts, fructus zizaniae caduciflorae 70 parts, SEMEN COICIS 10 parts, Semen arachidis hypogaeae 10 parts, kidney bean 5 parts, Bulbus Lilii 10 parts, Semen Phaseoli 5 Part, 5 parts of Semen phaseoli radiati, 90 parts of water；

Raw material is preheated, loads in tank, select chlorosulfonated polyethylene, gas-phase silica, titanium dioxide, Add reactor, be simultaneously introduced fructus zizaniae caduciflorae, SEMEN COICIS, Semen arachidis hypogaeae water grinds, add 50% water mixing, make Mixture one,

Select disproportionated rosin, TOTD, epoxy resin, four sulfuration tetramethyl thiuram, ethylene thioureas, add simultaneously Enter Oryza glutinosa, purple rice, kidney bean, Bulbus Lilii, Semen Phaseoli, Semen phaseoli radiati mixing, add 50% water mixing, make mixture Two, take 50% mixture one and the mixture two of 85%, add in reactor and heat, heating-up temperature 160 DEG C, 1 hour time, it is cooled to 100 DEG C, 1 hour time, then it is down to 50 DEG C, and impurity screening, obtain hot glue；

4) take 50% mixture one and add step 1) agitator tank in, add 20% hot glue；Take 15 mixed Compound two adds step 2) in reactor in, add the hot glue of 30%, then both mixed, obtain half Finished product adhesive；Take the hot glue of 50%, distillation, take distilled water, add in semi-finished product adhesive, become Product.

The ultimate principle of the present invention, principal character and advantages of the present invention have more than been shown and described.One's own profession Skilled person will appreciate that of industry, the present invention is not restricted to the described embodiments, above-described embodiment and explanation The principle that the present invention is simply described described in book, without departing from the spirit and scope of the present invention, The present invention also has various changes and modifications, and these changes and improvements both fall within claimed invention model In enclosing.Claimed scope is defined by appending claims and equivalent thereof.

Claims (1)

1. bamboo handicraft product adhesive, it is characterised in that: mainly include that following mass parts component is prepared from:

1) chlorosulfonated polyethylene 100-110 part, 30-40 part ethyl acetate, 20-25 part n-octyl alcohol, 25-30 Part isoamyl alcohol, 20-25 part isobutanol, 8-10 part castor oil polyoxyethylene ether, 6-8 part detergent alkylate sulphur Acid sodium, Herba Moslae 0.5-1 part, Flos Lonicerae 0.5-1 part, Fructus Forsythiae 0.5-1 part, Herba Artemisiae Annuae 0.2-0.5 part, Radix Isatidis 1-2 part and Folium Isatidis 1-2 part；

Take Herba Moslae 0.5-1 part, Flos Lonicerae 0.5-1 part, Fructus Forsythiae 0.5-1 part, Herba Artemisiae Annuae 0.2-0.5 part, Radix Isatidis 1-2 part and Folium Isatidis 1-2 part, grind to form powdery, adds in the water of 10 parts, and steaming and decocting treats that raw material is the most molten In Xie Shui, entirety is in the pasty state；

By chloromethyloxirane, ethyl acetate, n-octyl alcohol, isoamyl alcohol, isobutanol, Oleum Ricini polyoxy Vinyl Ether, dodecylbenzene sodium sulfonate, being placed in agitator tank, mixing speed is 2500r/mim, stirring temperature Degree is 80-90 DEG C, 5 minutes time；

Pasty mixture is filtered, adds and agitator tank continues stirring；

2) PVA:50-60 part, starch: 12-15 part, AA, AAm mixture: 0.3-0.4 part, over cure Acid ammonium: 0.2-0.3 part, ammonium bisulfite: 0.2-0.3 part, preservative: 0.1-0.2 part, water: 40-50 Part, Herba Ephedrae 10-15 part, Semen Armeniacae Amarum 10-15 part, Ramulus Cinnamomi 7-12 part, Radix Glycyrrhizae Preparata 5-10 part；

Take after Herba Ephedrae 10-15 part, Semen Armeniacae Amarum 10-15 part, Ramulus Cinnamomi 7-12 part and Radix Glycyrrhizae Preparata 5-10 part pulverizes Joining in the water of 50% and soak, soaking temperature is 40 DEG C, soaks and is often 30 parts, takes out liquid；

PVA and 70% liquid mixing are added in reactor, within 4 hours, make PVA be completely dissolved with 90 DEG C of stirrings, It is cooled to 75 DEG C, by Ammonium persulfate., ammonium bisulfite and 10% liquid mixing, drips AA, AAm mixture With Ammonium persulfate., ammonium bisulfite and water mixed solution, within about 1-2 hour, drip off, insulation reaction 1 hour, It is subsequently adding starch, continues heated and stirred 1 hour, add preservative stirring, drop to less than 50 DEG C to temperature；

3) chlorosulfonated polyethylene 100-110 part, gas-phase silica 2-3 part, titanium dioxide 3-5 part, disproportionation pine Fragrant 5-10 part, TOTD2-3 part, ethylene thiourea 2-3 part, epoxy resin 15-20 part, four sulfuration tetramethyl Flos Cymbidii Ensifolii Nurse 2-5 part, Oryza glutinosa 10-70 part, purple rice 10-70 part, fructus zizaniae caduciflorae 10-70 part, SEMEN COICIS 5-10 part, Semen arachidis hypogaeae 5-10 Part, kidney bean 1-5 part, Bulbus Lilii 5-10 part, Semen Phaseoli 1-5 part, Semen phaseoli radiati 1-5 part, water 80-90 part；

Raw material is preheated, loads in tank, select chlorosulfonated polyethylene, gas-phase silica, titanium dioxide, Add reactor, be simultaneously introduced fructus zizaniae caduciflorae, SEMEN COICIS, Semen arachidis hypogaeae water grinds, add 50% water mixing, make Mixture one,

Select disproportionated rosin, TOTD, epoxy resin, four sulfuration tetramethyl thiuram, ethylene thioureas, add simultaneously Enter Oryza glutinosa, purple rice, kidney bean, Bulbus Lilii, Semen Phaseoli, Semen phaseoli radiati mixing, add 50% water mixing, make mixture Two, take 50% mixture one and the mixture two of 85%, add in reactor and heat, heating-up temperature 160 DEG C, 1 hour time, it is cooled to 100 DEG C, 1 hour time, then it is down to 50 DEG C, and impurity screening, obtain hot glue；

4) take 50% mixture one and add step 1) agitator tank in, add 20% hot glue；Take 15 mixed Compound two adds step 2) in reactor in, add the hot glue of 30%, then both mixed, obtain half Finished product adhesive；Take the hot glue of 50%, distillation, take distilled water, add in semi-finished product adhesive, become Product.